Kinetic study on the direct nitridation of silicon powders diluted with α-Si₃N₄ at normal pressure

Abstract

Silicon nitride (Si₃N₄) powders were prepared by the direct nitridation of silicon powders diluted with α-Si₃N₄ at normal pressure. Silicon powders of 2.2 μm in average diameter were used as the raw materials. The nitriding temperature was from 1623 to 1823 K, and the reaction time ranged from 0 to 20 min. The phase compositions and morphologies of the products were analyzed by X-ray diffraction and scanning electron microscopy, respectively. The effects of nitriding temperature and reaction time on the conversion rate of silicon were determined. Based on the shrinking core model as well as the relationship between the conversion rate of silicon and the reaction time at different temperatures, a simple model was derived to describe the reaction between silicon and nitrogen. The model revealed an asymptotic exponential trend of the silicon conversion rate with time. Three kinetic parameters of silicon nitridation at atmospheric pressure were calculated, including the pre-exponential factor (2.27 cm·s⁻¹) in the Arrhenius equation, activation energy (114 kJ·mol⁻¹), and effective diffusion coefficient (6.2×10⁻⁸ cm²·s⁻¹). A formula was also derived to calculate the reaction rate constant.

Keywords

silicon nitride / powders / nitridation / reaction kinetics / activation energy

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