Pre-desilication and digestion of gibbsitic bauxite with lime in sodium aluminate liquor

Abstract

The effect of lime on the pre-desilication and digestion of gibbsitic bauxite in synthetic sodium aluminate liquor at different temperatures was investigated. The bauxite is comprised of gibbsite, aluminogoethite, hematite, kaolin, quartz, and minor boehmite. Lime increases the desilication efficiency of the bauxite during the pre-desilication process by promoting the conversion of sodalite and cancrinite to hydrogarnet. Desilication reactions during the digestion process promoted by lime result in the loss of Al₂O₃ entering the red mud, but the amount of aluminogoethite-to-hematite conversion promoted by lime leads to the increase of aluminogoethitic Al₂O₃ entering the digested liquor. The alumina digestion rate at 245°C is higher than that at 145°C due to the more pronounced conversion of aluminogoethite to hematite. The soda consumption during the digestion process decreases due to lime addition, especially at higher temperatures.

Keywords

bauxite ore treatment / lime / sodium aluminate / desilication / alumina / Bayer process

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