Effect of oxygen content and heat treatment on carbide precipitation behavior in PM Ni-base superalloys

Abstract

The influence of oxygen content and heat treatment on the evolution of carbides in a powder metallurgy (PM) Ni-base superalloy was characterized. The results reveal that oxygen content has little influence on the precipitation of carbides inside the particles. However, under the consolidated state, stable Ti oxides on the particle surface act as nuclei for the precipitation of prior particle boundaries (PPB). Also, oxygen can diffuse internally along grain boundaries under compressive stress, which favors the precipitation of carbides inside the particles. Therefore, a higher amount of carbides will appear with more oxygen content in the case of consolidated alloys. It is also observed that PPB can be disrupted into discontinuous particles at 1200°C, but this carbide network is hard to be eliminated completely. The combined MC-M₂₃C₆ morphology approves the nucleation and growth mechanism of carbide evolution.

Keywords

powder metallurgy / nickel alloys / superalloys / oxygen / heat treatment / carbides / precipitation

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