Identification of thermal effects involved in DSC experiment on Al-Cu-Mg-Ag alloys with high Cu:Mg ratio

Abstract

Precipitation reactions in the differential scanning calorimetry (DSC) of an Al-Cu-Mg-Ag alloy were identified by analyzing the results from hardness test, electrical conductivity test, and transmission electron microscope (TEM) examination. It is discovered that thermal effects can be identified through selected area electron diffraction and bright-field images. The reaction peaks around 171, 231, and 276°C can be attributed to a structural rearrangement of coherent zones, to the precipitation of Ω phases, and to the precipitation of Ω and θ′ and possible combination with the transition of θ′→θ, respectively. In addition, the hardness and electrical conductivity of the alloy change proportionately with the progression of reactions during the heating process. This phenomenon can be attributed to the evolution of the microstructure.

Keywords

aluminum alloys / thermal effects / identification / differential scanning calorimetry / microstructure

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