Desorption-diffusion specificity of deep coalbed methane under high-temperature effects: Implications for development

Benju Lu , Zhaobiao Yang , Yuting Hou , Cunlei Li , Jianan Wang , Changqing Liu , Yuhao Yao

Int J Min Sci Technol ›› 2025, Vol. 35 ›› Issue (9) : 1511 -1527.

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Int J Min Sci Technol ›› 2025, Vol. 35 ›› Issue (9) :1511 -1527. DOI: 10.1016/j.ijmst.2025.07.013
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Desorption-diffusion specificity of deep coalbed methane under high-temperature effects: Implications for development
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Abstract

China’s deep coalbed methane (CBM) resources demonstrate immense potential with extensive developmental prospects. However, the coupling relationship between the negative adsorption effect and the positive desorption-promotion effect under high-temperature conditions remains unclear. In this study, a self-built high-temperature adsorption-desorption system was used to investigate the coupled effects of temperature and coal rank on methane adsorption-desorption behavior in deep CBM. The results show that elevated temperatures significantly reduce methane adsorption capacity, with high-rank coals exhibiting greater sensitivity. Conversely, high-temperature conditions significantly enhance methane desorption and diffusion behavior, accelerating initial desorption rates, enabling rapid gas release in a short period, and thus improving desorption efficiency. The desorption volume and desorption-diffusion rate exhibited an asymmetric U-shaped variation with coal rank. By coupling the positive and negative effects of temperature and defining the desorption ratio, it was found that a 10 K increase in temperature raised the desorption ratio by 3.78%-8.05%. Finally, an effective gas content prediction model is proposed, and the key regulatory role of temperature in the resource potential and gas production characteristics of deep CBM is clarified. These findings can provide theoretical guidance for the subsequent optimization of deep CBM exploration and development strategies.

Keywords

Deep coalbed methane / Desorption-diffusion characteristics / High-temperature effect / Effective gas content / Development significance

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Benju Lu, Zhaobiao Yang, Yuting Hou, Cunlei Li, Jianan Wang, Changqing Liu, Yuhao Yao. Desorption-diffusion specificity of deep coalbed methane under high-temperature effects: Implications for development. Int J Min Sci Technol, 2025, 35(9): 1511-1527 DOI:10.1016/j.ijmst.2025.07.013

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Acknowledgments

This work was supported by the National Natural Science Fund of China (No. 42272195); the National Natural Science Fund of China (No. 42130802); the Fundamental Research Funds for the Central Universities (No. 2025ZDPY10); the China National Petro-leum Co., Ltd.. Research applied science and technology special (No. 2023ZZ18); and the PetroChina Changqing oilfield science and technology major project (No. 2023DZZ01).

References

[1]

Zou CN, Lin MJ, Ma F, Liu HL, Yang Z, Zhang GS, Yang YC, Guan CX, Liang YB, Wang Y, Xiong B, Yu H, Yu P.Development, challenges and strategies of natural gas industry under carbon neutral target in China. Petrol Explor Dev 2024; 51 (2):476-497.

[2]

Xu FY, Yan X, Wang FL, Ma XY, Yun J, Wang HN, Xu BR, Zhang SY, Mao DL. Development strategy and countermeasures of China’s CBM industry under the goal of ‘‘carbon peak and neutrality”. J Earth Sci 2023; 34(4):975-84.

[3]

Li GX, Zhang SC, He HQ, He XX, Zhao Z, Niu XB, Xiong XY, Zhao Q, Guo XJ, Hou YT, Zhang L, Liang K, Duan XW, Zhao ZY. Coal-rock gas: Concept, connotation and classification criteria. Petrol Explor Dev 2024; 51(4):897-911.

[4]

Fang ZM, Wang RD, Yang CL. Opportunities and challenges in deep coalbed methane development. J China Univ Min Technol 2025; 54(1):34-51. in Chinese.

[5]

Li S, Qin Y, Tang DZ, Shen J, Wang JJ, Chen SD. A comprehensive review of deep coalbed methane and recent developments in China. Int J Coal Geol 2023; 279:104369.

[6]

Li CL, Yang ZB, Yan X, Zhou GX, Wang G, Gao W, Liu CQ, Lu BJ, Liang YH. Distribution law of occurrence state and content prediction of deep CBM: A case study in the Ordos Basin. China Nat Resour Res 2024; 33(4):1843-69.

[7]

Yang XX, Tang SH, Xi ZD, Zhang SH, Zhang Q, Zhang K, Lin DL, Wang J. Dynamic evolution and differential enrichment of deep coalbed methane: A case study in Qinshui Basin. Int J Coal Geol 2025; 299:104696.

[8]

Chen SD, Tang DZ, Hou W, Huang DJ, Li YZ, Hu JL, Xu H, Tao S, Li S, Tang SL. Fluid characteristics, gas accumulation controlling factors and gas enrichment modes in coal reservoirs: A case study of the Upper Paleozoic in the central-eastern Ordos Basin. NW China Petrol Explor Dev 2025; 52(2):435-44.

[9]

Yang ZB, Li CL, Guo QZ, Wang B, Liu CQ, Qu HL, Liang YH, Wang YQ. Distribution patterns of various occurrence states of deep coalbed methane in the Baijiahai Uplift, Junggar Basin. Xinjiang J China Univ Min Technol 2025; 54(1):127-137. in Chinese.

[10]

Xiong XY, Yan X, Xu FY, Li SG, Nie ZH, Feng YQ, Liu Y, Chen M, Sun JY, Zhou K, Li CH. Analysis of multi-factor coupling control mechanism, desorption law and development effect of deep coalbed methane. Acta Petrolei Sin 2023; 44 (11):1812-26+53. in Chinese.

[11]

Li HQ, Zhou GX, Chen SD, Li S, Tang DZ. In situ gas content and extraction potential of ultra-deep coalbed methane in the Sichuan Basin. China Nat Resour Res 2025; 34(1):563-79.

[12]

Zhu QY, Du XJ, Zhang T, Yu HM, Liu XB. Investigation into the variation characteristics and influencing factors of coalbed methane gas content in deep coal seams. Sci Rep 2024; 14(1):18813.

[13]

Jia JZ, Xing YH, Li B, Wu YM, Wang DM. Molecular simulation study of adsorption-diffusion of CH4, CO2 and H2O in gas-fat coal. Sci Rep 2024; 14 (1):24131.

[14]

He YH, Li XJ, Xie HG, Li XX, Xia T, Chen SK. Dynamics change of coal methane adsorption/desorption and permeability under temperature and stress conditions. Phys Fluids 2025; 37:016605.

[15]

Zhao D, Li XW, Feng ZC, Pu YX, Chang HM, Jia YC. Study on the behavior and mechanism of methane desorption-diffusion for multi-scale coal samples under multi-temperature conditions. Fuel 2022; 328:125332.

[16]

Xu H, Qin YP, Yang DY, Wang G, Huang QM, Zhang FJ. Experimental investigation of gas diffusion kinetics and pore-structure characteristics during coalbed methane desorption within a coal seam. Gas Sci Eng 2024; 121:205173.

[17]

Liu T, Lin BQ. Time-dependent dynamic diffusion processes in coal: Model development and analysis. Int J Heat Mass Transf 2019; 134:1-9.

[18]

Gao YF, Wang YQ, Chen XL. Adsorption and diffusion characteristics of CO2 and CH4 in anthracite pores: Molecular dynamics simulation. Processes 2024; 12 (6):1131.

[19]

Zhao W, Wang K, Liu SM, Cheng YP. Gas transport through coal particles: Matrix-flux controlled or fracture-flux controlled? J Nat Gas Sci Eng 2020; 76:103216.

[20]

Liu SQ, Sang SX, Hu QJ, Fang HH. Characteristics of high-rank coal structure parallel and perpendicular to the bedding plane via NMR and X-ray CT. Pet Sci 2020; 17(4):925-38.

[21]

Li ZB, Ren T, Li XC, Qiao M, Yang XH, Tan LH, Nie BS. Multi-scale pore fractal characteristics of differently ranked coal and its impact on gas adsorption. Int J Min Sci Technol 2023; 33(4):389-401.

[22]

Fan LY, Zhou GX, Yang ZB, Wang HC, Lu BJ, Zhang BX, Chen YH, Li CL, Wang YQ, Gu JY. Geological control of differential enrichment of deep coalbed methane in the Ordos Basin. Coal Sci Technol 2025; 53(1):203-215. in Chinese.

[23]

Zhou KY, Sun FR, Yang C, Qiu F, Wang ZH, Xu SB, Chen JM. Evaluation of deep coalbed methane potential and prediction of favorable areas within the Yulin area, Ordos Basin, based on a multi-level fuzzy comprehensive evaluation method. Processes 2024; 12(4):820.

[24]

Song HR, Lin BQ, Zhong Z, Liu T. Experimental study on methane diffusion kinetics in three typical metamorphic coals. Fuel 2022; 311:122601.

[25]

Zhou DH, Chen G, Chen ZL, Liu ZQ. Exploration and development progress, key evaluation parameters and prospect of deep CBM in China. Nat Gas Ind 2022; 42(6):43-51. in Chinese.

[26]

Shen J, Qin Y, Fu XH, Wang G, Chen R, Zhao LJ. Study of high-pressure sorption of methane on chinese coals of different rank. Arab J Geosci 2015; 8 (6):3451-60.

[27]

Guo HJ, Gao Z, Yu YJ, Wang K, Yuan L, Wang L, Feng H, Ren B, Zhang H. Experimental investigation on the effect of multiscale pore characteristics of tectonic coal on gas adsorption/desorption and diffusion characteristics. Powder Technol 2024; 444:119945.

[28]

Guo HJ, Yu YJ, Wang YH, Wang K, Yuan L, Xu C, Ren B. Experimental study on the desorption law and diffusion kinetic characteristics of gas in raw coal and tectonic coal. Energy 2024; 289:129924.

[29]

Nie ZH, Xu FY, Shi XS, Xiong XY, Song W, Zhang L, Liu Y, Sun W, Feng YQ, Liu SR, Yan X, Sun XY, Wu MS. Outcomes and implications of pilot tests for deep coalbed methane production on the eastern margin of the Ordos Basin. Coal Geol Explor 2024; 52(2):1-12. in Chinese.

[30]

Zhao JL, Tang DZ, Qin Y, Xu H, Liu YL, Wu HY. Characteristics of methane (CH4) diffusion in coal and its influencing factors in the Qinshui and Ordos Basins. Energy Fuels 2018; 32(2):1196-205.

[31]

Xu H, Tang DZ, Zhao JL, Li S, Tao S. A new laboratory method for accurate measurement of the methane diffusion coefficient and its influencing factors in the coal matrix. Fuel 2015; 158:239-47.

[32]

Cheng XX, Cheng YP, Wang CH, Hu B, Wang J. Calculation methods on methane adsorption phase density in coal: A critical review and new insights. Chem Eng J 2023; 472:144778.

[33]

Liu DM, Yao YB, Chang YH. Measurement of adsorption phase densities with respect to different pressure: Potential application for determination of free and adsorbed methane in coalbed methane reservoir. Chem Eng J 2022; 446:137103.

[34]

Li ZQ, Wang AJ, Li L, Li JL, Zhang NC, Jin KQ, Chang J. Influence mechanism of gas pressure on multiscale dynamic apparent diffusion-permeability of coalbed methane. ACS Omega 2023; 8(39):35964-74.

[35]

Li ZT, Liu DM, Cai YD, Shi YL. Investigation of methane diffusion in low-rank coals by a multiporous diffusion model. J Nat Gas Sci Eng 2016; 33:97-107.

[36]

Li CW, Qiao Z, Hao M, Wang YL, Han BS. Gas desorption diffusion behavior in coal particles under constant volume conditions: Experimental research and model development. Energy Sources Part A Recovery Util Environ Eff 2022; 44 (1):1566-82.

[37]

Qin YP, Xu H, Liu W, Liu J, Duan WP. Time- and pressure-independent gas transport behavior in a coal matrix: Model development and improvement. Energy Fuels 2020; 34(8):9355-70.

[38]

Yan JW, Meng ZP, Li GQ. Diffusion characteristics of methane in various rank coals and the control mechanism. Fuel 2021; 283:118959.

[39]

Gürdal G, Yalçın MN. Pore volume and surface area of the carboniferous coals from the Zonguldak basin (NW Turkey) and their variations with rank and maceral composition. Int J Coal Geol 2001; 48(1-2):133-44.

[40]

Chen M, Wang DM, Yu LZ, Sun JY, Feng X, Zhang K, Gu XF, Wang LW, Yin ZS, Zhang H. Drainage system research and application of deep coalbed methane gas reservoirs in Daning-Jixian block. J China Coal Soc 2025; 50(4):2188-2197. in Chinese.

[41]

Liu CQ, Yang ZB, Qin Y, Yan X, Wang YH, Wang Z. Excess pore pressure behavior and evolution in deep coalbed methane reservoirs. Int J Min Sci Technol 2024; 34(6):763-81.

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