Additive Manufacturing of Tungsten-Alloyed Tantalum from Polyhedral Shaped Powder Blends

Silja-Katharina Rittinghaus , Markus Benjamin Wilms , Fengxiang Lin , Dimitrios Nikas , Janett Schmelzer , Pavel Krakhmalev

High-Temp. Mat. ›› 2025, Vol. 2 ›› Issue (1) : 10005

PDF (3281KB)
High-Temp. Mat. ›› 2025, Vol. 2 ›› Issue (1) :10005 DOI: 10.70322/htm.2025.10005
research-article
Additive Manufacturing of Tungsten-Alloyed Tantalum from Polyhedral Shaped Powder Blends
Author information +
History +
PDF (3281KB)

Abstract

Tantalum and tungsten are completely soluble in each other and are used in applications in the combined form of so-called tantaloys. They provide high melting points (Ta: 3017 °C, W: 3410 °C) and excellent corrosion resistance while maintaining high ductility for W contents up to 7.5 wt%. Providing good resistance to hydrogen embrittlement, Ta-W alloys are attractive candidates for applications in fusion reactors. This study demonstrated the feasibility of producing chemically homogeneous bulk material with fine grained microstructure from non-spherical powder blends with up to 7.5% tungsten using laser powder bed fusion (PBF-L/M). It is observed that cracking remains a challenge, especially with the increase in tungsten content. The effect of rapid solidification on the microhardness of up to 385 HV0.1 for 7.5% W is discussed. It provides initial indications of the possibility of achieving higher strengths and paves the way for further alloy development with regard to the additive manufacturing of this alloy family.

Keywords

Additive Manufacturing / Tantalum / Tantaloy / Refractory metals

Cite this article

Download citation ▾
Silja-Katharina Rittinghaus, Markus Benjamin Wilms, Fengxiang Lin, Dimitrios Nikas, Janett Schmelzer, Pavel Krakhmalev. Additive Manufacturing of Tungsten-Alloyed Tantalum from Polyhedral Shaped Powder Blends. High-Temp. Mat., 2025, 2(1): 10005 DOI:10.70322/htm.2025.10005

登录浏览全文

4963

注册一个新账户 忘记密码

Acknowledgments

We would like to thank Herbert Horn-Solle and Oliver Michels for their well appreciated support in analytics and Thomas Wachowiak for his assistance in material processing and preparation. Additionally, we would like to acknowledge Andreas Weisheit for providing the necessary resources for the initial sample production at Fraunhofer ILT, Aachen.

Author Contributions

Conceptualization, S.-K.R. and M.B.W.; Methodology, S.-K.R., M.B.W. and P.K.; Validation, S.-K.R., M.B.W. and P.K.; Investigation, S.-K.R., M.B.W., F.L., D.N., J.S., P.K.; Resources, S.-K.R. and P.K.; Data Curation, S.-K.R. and P.K.; Writing—Original Draft Preparation, S.-K.R. and M.B.W.; Writing—Review & Editing, F.L., D.N., J.S. and P.K.; Visualization, S.-K.R. and P.K.; Supervision, S.-K.R. and P.K.

Ethics Statement

Not applicable.

Informed Consent Statement

Not applicable.

5Data Availability Statement

The datasets generated and analyzed during the current study are available from the corresponding author on reasonable request.

Funding

S.-K.R. gratefully acknowledges financial support from the German Research Foundation (DFG) for the project RI 3559/2-1(grant no. 536270088)

Declaration of Competing Interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

References

[1]

Oh J, Ishimoto T, Sun S-H, Nakano T. Crystallographic texture formation of pure tantalum by selective laser melting method. J. Smart. Proc. 2019, 8, 151-154. doi:10.7791/jspmee.8.151.

[2]

Song C, Deng Z, Zou Z, Liu L, Xu K, Yang Y. Pure tantalum manufactured by laser powder bed fusion: Influence of scanning speed on the evolution of microstructure and mechanical properties. Int. J. Refract. Met. Hard Mater. 2022, 107, 105882. doi:10.1016/j.ijrmhm.2022.105882.

[3]

Zhou L, Chen J, Li C, He J, Li W, Yuan T, et al. Microstructure tailoring to enhance strength and ductility in pure tantalum processed by selective laser melting. Mater. Sci. Eng. A 2020, 785, 139352. doi:10.1016/j.msea.2020.139352.

[4]

Thijs L, Montero Sistiaga ML, Wauthle R, Xie Q, Kruth J-P, van Humbeeck J. Strong morphological and crystallographic texture and resulting yield strength anisotropy in selective laser melted tantalum. Acta Mater. 2013, 61, 4657-4668. doi:10.1016/j.actamat.2013.04.036.

[5]

Zhou L, Yuan T, Li R, Tang J, Wang G, Guo K. Selective laser melting of pure tantalum: Densification, microstructure and mechanical behaviors. Mater. Sci. Eng. A 2017, 707, 443-451. doi:10.1016/j.msea.2017.09.083.

[6]

Shi Q, Mao X, Tan C, Ding C, Liu X. Microstructure and mechanical properties of selective laser melted pure tantalum using radio frequency plasma spheroidized powder. Rare Met. Mater. Eng. 2020, 49, 4023-4030. doi:10.12442/j.issn.1002-185X.2021.49.12.40234030.

[7]

Sungail C, Abid AD. Additive manufacturing of tantalum—A study of chemical and physical properties of printed tantalum. Met. Powder Rep. 2020, 75, 28-33. doi:10.1016/j.mprp.2019.03.001.

[8]

Luo Y, Bi M, Cai H, Hu C, Wei Y, Chen L, et al. Influence of crystal planes on corrosion behavior of tantalum: Experimental and first-principles study. Int. J. Electrochem. Sci. 2022, 17, 220314. doi:10.20964/2022.03.18.

[9]

Li J, Chen Y, Li Y, Bai Z, Wang K. Influence of aluminium addition on oxidation resistance of Ta-W alloy. Powder Met. 2019, 62, 322-330. doi:10.1080/00325899.2019.1662559.

[10]

Wauthle R, van der Stok J, Yavari SA, van Humbeeck J, Kruth J-P, Zadpoor AA, et al.Additively manufactured porous tantalum implants. Acta Biomater. 2015, 14, 217-225. doi:10.1016/j.actbio.2014.12.003.

[11]

Yang J, Jin X, Gao H, Zhang D, Chen H, Zhang S, et al. Additive manufacturing of trabecular tantalum scaffolds by laser powder bed fusion: Mechanical property evaluation and porous structure characterization. Mater. Charact. 2020, 170, 110694. doi:10.1016/j.matchar.2020.110694.

[12]

Gao H, Jin X, Yang J, Zhang D, Zhang S, Zhang F, et al. Porous structure and compressive failure mechanism of additively manufactured cubic-lattice tantalum scaffolds. Mater. Today Adv. 2021, 12, 100183. doi:10.1016/j.mtadv.2021.100183.

[13]

Chen W, Yang J, Kong H, Helou M, Zhang D, Zhao J, et al. Fatigue behaviour and biocompatibility of additively manufactured bioactive tantalum graded lattice structures for load-bearing orthopaedic applications. Mater. Sci. Eng. C 2021, 130, 112461. doi:10.1016/j.msec.2021.112461.

[14]

Kim Y, Kim E-P, Noh J-W, Lee S-H, Kwon Y-S, Oh I-S. Fabrication and mechanical properties of powder metallurgy tantalum prepared by hot isostatic pressing. Int. J. Refract. Met. Hard Mater. 2015, 48, 211-216. doi:10.1016/j.ijrmhm.2014.09.012.

[15]

Jakubowicz J, Adamek G, Sopata M, Koper JK, Kachlicki T, Jarzebski M. Microstructure and electrochemical properties of refractory nanocrystalline tantalum-based alloys. Int. J. Electrochem. Sci. 2018, 13, 1956-1975. doi:10.20964/2018.02.67.

[16]

Seyyedin S, Zangi H, Bozorgmehr M, Ghasemi B, Tavallaei MM, Adib S. The effect of mechanical alloying time on the microstructural and mechanical properties of spark plasma sintered Ta-10W. Mater. Sci. Eng. A 2020, 798, 140024. doi:10.1016/j.msea.2020.140024.

[17]

Browning PN, Alagic S, Carroll B, Kulkarni A, Matson L, Singh J. Room and ultrahigh temperature mechanical properties of field assisted sintered tantalum alloys. Mater. Sci. Eng. A 2017, 680, 141-151. doi:10.1016/j.msea.2016.09.067.

[18]

Ma G, Wei Z, Wu G, Mao X. The microstructure and strength of a tantalum alloy: Influence of temperature. Mater. Sci. Eng. A 2023, 880, 145312. doi:10.1016/j.msea.2023.145312.

[19]

Iveković A, Omidvari N, Vrancken B, Lietaert K, Thijs L, Vanmeensel K, et al. Selective laser melting of tungsten and tungsten alloys. Int. J. Refract. Met. Hard Mater. 2018, 72, 27-32. doi:10.1016/j.ijrmhm.2017.12.005.

[20]

Guo M, Liu K, Sun J, Gu D. Laser powder bed fusion of a novel nano-modified tungsten alloy with refined microstructure and enhanced strength. Mater. Sci. Eng. A 2022, 843, 143096. doi:10.1016/j.msea.2022.143096.

[21]

Seyam MS, Koshy P, Elbestawi MA. Laser powder bed fusion of unalloyed tungsten: A review of process, structure, and properties relationships. Metals 2022, 12, 274. doi:10.3390/met12020274.

[22]

Xue J, Feng Z, Tang J, Tang C, Zhao Z. Selective laser melting additive manufacturing of tungsten with niobium alloying: Microstructure and suppression mechanism of microcracks. J. Alloys Compd. 2021, 874, 159879. doi:10.1016/j.jallcom.2021.159879.

[23]

Rebesan P, Bonesso M, Gennari C, Dima R, Pepato A, Vedani M. Tungsten fabricated by laser powder bed fusion. BHM 2021, 166, 263-269. doi:10.1007/s00501-021-01109-y.

[24]

Faidel D, Jonas D, Natour G, Behr W. Investigation of the selective laser melting process with molybdenum powder. Addit. Manuf. 2015, 8, 88-94. doi:10.1016/j.addma.2015.09.002.

[25]

Braun J, Kaserer L, Staikovic J, Leitz K-H, Tabernig B, Singer P, et al. Molybdenum and tungsten manufactured by selective laser melting: Analysis of defect structure and solidification mechanisms. Int. J. Refract. Met. Hard Mater. 2019, 84, 104999. doi:10.1016/j.ijrmhm.2019.104999.

[26]

Alinejadian N, Wang P, Kollo L, Prashanth KG. Selective laser melting of commercially pure molybdenum by laser rescanning. 3D Print. Addit. Manuf. 2022, 10, 785-791. doi:10.1089/3dp.2021.0265.

[27]

Kaserer L, Braun J, Staikovic J, Leitz K-H, Tabernig B, Singer P, et al. Fully dense and crack free molybdenum manufactured by selective laser melting through alloying with carbon. Int. J. Refract. Met. Hard Mater. 2019, 84, 105000. doi:10.1016/j.ijrmhm.2019.105000.

[28]

Griemsmann T, Abel A, Hoff C, Hermsdorf J, Weinmann M, Kaierle S. Laser-based powder bed fusion of niobium with different build-up rates. Int. J. Adv. Manuf. Techn. 2021, 114, 305-317. doi:10.1007/s00170-021-06645-y.

[29]

Chen J, Ding W, Tao Q, Ma C, Zhang C, Chen G, et al. Laser powder bed fusion of a Nb-based refractory alloy: Microstructure and tensile properties. Mater. Sci. Eng. A 2022, 843, 143153. doi:10.1016/j.msea.2022.143153.

[30]

Lian F, Chen L, Wu C, Zhao Z, Tang J, Zhu J. Selective laser melting additive manufactured tantalum: Effect of microstructure and impurities on the strengthening-toughing mechanism. Materials 2023, 16, 3161. doi:10.3390/ma16083161.

[31]

Valentino GM, Banerjee A, Lark A, Barr CM, Myers SH, McCue ID. Influence of laser processing parameters on the density-ductility tradeoff in additively manufactured pure tantalum. Addit. Manuf. Lett. 2023, 4, 100117. doi:10.1016/j.addlet.2022.100117.

[32]

Livescu V, Knapp CM, Gray GT, Martinez RM, Morrow BM, Ndefru BG.Additively manufactured tantalum microstructures. Materialia 2018, 1, 15-24. doi:10.1016/j.mtla.2018.06.007.

[33]

Abdu Aliyu AA, Poungsiri K, Shinjo J, Panwisawas C, Reed RC, Puncreobutr C, et al. Additive manufacturing of tantalum scaffolds: Processing, microstructure and process-induced defects. Int. J. Refract. Met. Hard Mater. 2023, 112, 106132. doi:10.1016/j.ijrmhm.2023.106132.

[34]

Zhang Y, Aiyiti W, Du S, Jia R, Jiang H. Design and mechanical behaviours of a novel tantalum lattice structure manufactured by SLM. Virt. Phys. Prototyp. 2023, 18, e2192702. doi:10.1080/17452759.2023.2192702.

[35]

Song C, Deng Z, Chen J, Yang Z, Zou Z, Liu L, et al. Study on the influence of oxygen content evolution on the mechanical properties of tantalum powder fabricated by laser powder bed fusion. Mater. Charact. 2023, 205, 113235. doi:10.1016/j.matchar.2023.113235.

[36]

Tan C, Shi Q, Li K, Khanlari K, Liu X. Effect of oxygen content of tantalum powders on the characteristics of parts processed by laser powder bed fusion. Int. J. Refract. Met. Hard Mater. 2023, 110, 106008. doi:10.1016/j.ijrmhm.2022.106008.

[37]

Du J, Ren Y, Zhang M, Liang L, Chen C, Zhou K, et al. Improving the microstructure and mechanical properties of laser powder bed fusion-fabricated tantalum by high laser energy density. Mater. Lett. 2023, 333, 133547. doi:10.1016/j.matlet.2022.133547.

[38]

Guo Y, Chen C, Wang Q, Cao Y, Wu C, Zhou K. Microstructural evolution and mechanical behavior of additively manufactured tantalum produced by electron beam powder bed fusion. Int. J. Refract. Met. Hard Mater. 2023, 110, 106046. doi:10.1016/j.ijrmhm.2022.106046.

[39]

Guo Y, Chen C, Pan YM, Wang QB, Wu C, Zhou KC. Influence of pore structures on deformation behavior and mechanical properties of porous tantalum scaffolds fabricated by electron beam powder bed fusion. Trans. Nonferrous Met. Soc. China 2023, 33, 3725-3738. doi:10.1016/S1003-6326(23)66366-6.

[40]

Marinelli G, Martina F, Ganguly S, Williams S. Microstructure, hardness and mechanical properties of two different unalloyed tantalum wires deposited via wire + arc additive manufacture. Int. J. Refract. Met. Hard Mater. 2019, 83, 104974. doi:10.1016/j.ijrmhm.2019.104974.

[41]

Guan B, Xu M, Yang X, Zhou Y, Li C, Ji Y, et al. Microstructure and strengthening mechanisms of tantalum prepared using laser melting deposition. Int. J. Refract. Met. Hard Mater. 2022, 103, 105773. doi:10.1016/j.ijrmhm.2021.105773.

[42]

Jafarlou DM, Sousa BC, Gleason MA, Ferguson G, Nardi AT, Cote DL, et al. Solid-state additive manufacturing of tantalum using high-pressure cold gas-dynamic spray. Addit. Manuf. 2021, 47, 102243. doi:10.1016/j.addma.2021.102243.

[43]

Yu D, Bi X, Xing L, Zhang Q. Microstructural evolution and mechanical properties of spark plasma sintering of tantalum-tungsten alloys. Metals 2023, 13, 533. doi:10.3390/met13030533.

[44]

Sopata M, Siwak P, Adamek G, Jakubowicz J. The mechanical properties of the novel nanocrystalline refractory tantalum alloys. Prot. Met. Phys. Chem. Surf. 2020, 56, 759-765. doi:10.1134/S2070205120040231.

[45]

Buckman RW Jr. Development of high-strength-fabricable tantalum-base alloys. MRS Online Proc. Libr. 1993, 322, 329-339. doi:10.1557/PROC-322-329.

[46]

Ma J, Guo X, Xue H, Pan K, Liu C, Pang H. Niobium/tantalum-based materials: Synthesis and applications in electrochemical energy storage. Chem. Eng. J. 2020, 380, 122428. doi:10.1016/j.cej.2019.122428.

[47]

Hancock D, Homfray D, Porton M, Todd I, Wynne B. Refractory metals as structural materials for fusion high heat flux components. J. Nucl. Mater. 2018, 512, 169-183. doi:10.1016/j.jnucmat.2018.09.052.

[48]

Nemat-Nasser S, Kapoor R. Deformation behavior of tantalum and a tantalum tungsten alloy. Int. J. Plast. 2001, 17, 1351-1366. doi:10.1016/S0749-6419(00)00088-7.

[49]

Sopata M, Sadej M, Jakubowicz J. High temperature resistance of novel tantalum-based nanocrystalline refractory compounds. J. Alloys Compd. 2019, 788, 476-484. doi:10.1016/j.jallcom.2019.02.230.

[50]

Yukawa H, Nambu T, Matsumoto Y. Ta-W Alloy for Hydrogen Permeable Membranes. Mater. Trans. 2011, 52, 610-613. doi:10.2320/matertrans.MA201007.

[51]

Li X, Wan C, Li H, Zhao R, Ju X. Towards understanding the trapping, migration and clustering of He atoms in W-Ta alloy. J. Nucl. Mater. 2021, 554, 153095. doi:10.1016/j.jnucmat.2021.153095.

[52]

Cao J, Kong L, Chen Y, Zhang Z, Liang X, Xia M, et al. Laser metal deposition of Ta-10W alloy based on annular laser cladding with internal wire feeding. J. Phys. Conf. Ser. 2022, 2285, 012002. doi:10.1088/1742-6596/2285/1/012002.

[53]

Wang X, Wang D, Zhang Y, Li P, Tan Y, Liu B. Characterization of microstructure and mechanical properties of Ta-10W alloy manufactured by laser powder bed fusion. Int. J. Refract. Met. Hard Mater. 2024, 122, 106728. doi:10.1016/j.ijrmhm.2024.106728.

[54]

Smirnov YM, Finkel VA. Crystal structure of tantalum, niobium, and vanadium at 110-400 k. Sov. Phys. JETP 1966, 22, 750-753.

[55]

Muthuswamy P. Influence of powder characteristics on properties of parts manufactured by metal additive manufacturing. Lasers Manuf. Mater. Process. 2022, 9, 312-337. doi:10.1007/s40516-022-00177-3.

[56]

Kim YS, Goekcekaya O, Matsugaki A, Ozasa R, Nakano T. Laser energy-dependent processability of non-equiatomic TiNbMoTaW high-entropy alloy through in-situ alloying of elemental feedstock powders by laser powder bed fusion. Materialia 2024, 38, 102241. doi:10.1016/j.mtla.2024.102241.

[57]

Jobes D, Rubio-Ejchel D, Lopez L, Jenkins W, Sundar A, Tandoc C, et al. Computationally guided alloy design and microstructure-property relationships for non-equiatomic Ti-Zr-Nb-Ta-V-Cr alloys with tensile ductility made by laser powder bed fusion. Mater. Sci. Eng. A 2024, 911, 146922. doi:10.1016/j.msea.2024.146922.

[58]

Xu J, Qin M, Du S, Kumar P, Zhu J, Jia Y, et al. Enhancing the strength and plasticity of laser powder bed fused NbMoTaW refractory high-entropy alloy via Ti alloying. J. Alloys Compd. 2024, 1001, 175043. doi:10.1016/j.jallcom.2024.175043.

[59]

Jiang D, Wang Q, Hu W, Wei Z, Tong J, Wan H. The effect of tantalum (Ta) doping on mechanical properties of tungsten (W): A first-principles study. J. Mater. Res. 2016, 31, 3401-3406. doi:10.1557/jmr.2016.358.

[60]

Strauch AL, Uhlenwinkel V, Steinbacher M, Großwendt F, Röttger A, Chereh AB, et al. Comparison of the processability and influence on the microstructure of different starting powder blends for laser powder bed fusion of a Fe3.5Si1.5C alloy. Metals 2021, 11, 1107. doi:10.3390/met11071107.

[61]

Riener K, Oswald S, Winkler M, Leichtfried GJ. Influence of storage conditions and reconditioning of AlSi10Mg powder on the quality of parts produced by laser powder bed fusion (LPBF). Addit. Manuf. 2021, 39, 101896. doi:10.1016/j.addma.2021.101896.

[62]

Rahm M, Hoffmann R, Ashcroft NW. Atomic and ionic radii of elements 1-96. Chem. Eur. J. 2016, 22, 14625-14632. doi:10.1002/chem.201602949.

[63]

Zhao R, Chen C, Wang W, Cao T, Shuai S, Xu S, et al. On the role of volumetric energy density in the microstructure and mechanical properties of laser powder bed fusion Ti-6Al-4V alloy. Addit. Manuf. 2022, 51, 102605. doi:10.1016/j.addma.2022.102605.

[64]

Wilms MB, Rittinghaus S-K, Goßling M, Gökce B. Additive manufacturing of oxide-dispersion strengthened alloys: Materials, synthesis and manufacturing. Progr. Mater. Sci. 2023, 133, 101049. doi:10.1016/j.pmatsci.2022.101049.

PDF (3281KB)

0

Accesses

0

Citation

Detail

Sections
Recommended

/