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Stability and physical properties of brucite at high pressures and temperatures: Implication for Earth’s deep water cycle

Ningyu Sun, Xinyang Li, Luo Li, Qingchun Zhang, Yingxin Yu, Zhu Mao, Cijin Zhou, Dongzhou Zhang

Geoscience Frontiers ›› 2025, Vol. 16 ›› Issue (1) : 101940.

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Geoscience Frontiers ›› 2025, Vol. 16 ›› Issue (1) : 101940. DOI: 10.1016/j.gsf.2024.101940

Stability and physical properties of brucite at high pressures and temperatures: Implication for Earth’s deep water cycle

• Ningyu Sun^a , 
• Xinyang Li^b , 
• Luo Li^a , 
• Qingchun Zhang^a , 
• Yingxin Yu^a , 
• Zhu Mao^{a, c, *} , 
• Cijin Zhou^a , 
• Dongzhou Zhang^d

Author information +

^aDeep Space Exploration Laboratory/School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, PR China

^bState Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, PR China

^cCAS Center for Excellence in Comparative Planetology, University of Science and Technology of China, Hefei 230026, Anhui, PR China

^dCenter for Advanced Radiation Sources, University of Chicago, Chicago, IL 60637, USA

* E-mail address: zhumao@ustc.edu.cn

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Published
01 Jan 2025
Issue Date
23 Mar 2025

Abstract

Brucite is a common hydrous mineral on Earth and may contribute to the deep water cycle of the Earth, but its stability and structure under mantle conditions remain uncertain. In this study, we investigated the stability of brucite up to 60 GPa at 800 K and 45 GPa at 1850 K. Within the experiment P-T conditions, no theoretically predicted new phase was observed, and brucite remained in the P$\overline{3}$m1 structure. With the determined thermal EoS of brucite and the elastic parameters of mantle minerals, we modeled the velocity and density profile of subducted hydrous harzburgite in the top lower mantle, assuming that the water was stored in brucite and phase D. Based on the modelling, 1 wt.% water will reduce the velocity and density of harzburgite by ∼ 5% and ∼ 2%, respectively, yet whether the water is stored in brucite or phase D has weak influence on both density and velocity. With a water content up to 2.4 wt.%, the density of hydrous harzburgite could be reduced to 2.2(2)%–2.8(2)% lower than the surrounding mantle, while the V_P and V_S of hydrous harzburgite are still 0.3(1)%–0.7(1)% and 0.7(2)%–1.8(2)% higher than that of the normal mantle. Thus, the low-density hydrous harzburgite may slow down the subducting of slab, despite being a high-velocity body in seismic observations.

Keywords

Brucite / Phase stability / High pressure–temperature / Subducted slabs / Hydrous harzburgite

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Ningyu Sun, Xinyang Li, Luo Li, Qingchun Zhang, Yingxin Yu, Zhu Mao, Cijin Zhou, Dongzhou Zhang. Stability and physical properties of brucite at high pressures and temperatures: Implication for Earth’s deep water cycle. Geoscience Frontiers, 2025, 16(1): 101940 https://doi.org/10.1016/j.gsf.2024.101940

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