Synergistic utilization of bauxite residue (red mud) and multiple solid wastes for low carbon precast concrete materials: Mechanical performance, mechanism and sustainability assessment

Shanliang Ma , Xiaoming Liu , Zengqi Zhang , Yang Shao , Yinming Sun , Siyi Li , Weijie Du , Lilei Zhu , Junyong Wang

Green Energy and Resources ›› 2026, Vol. 4 ›› Issue (1) : 100172

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Green Energy and Resources ›› 2026, Vol. 4 ›› Issue (1) :100172 DOI: 10.1016/j.gerr.2026.100172
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Synergistic utilization of bauxite residue (red mud) and multiple solid wastes for low carbon precast concrete materials: Mechanical performance, mechanism and sustainability assessment
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Abstract

This study investigates the performance and mechanism of bauxite residue (red mud) and multiple solid wastes as active cement replacements in precast concrete. The effects of mixing ratio, water-to-binder ratio, and steam-curing temperature on mechanical properties and microstructural evolution were systematically evaluated. Results showed that incorporating 10%–20% red mud significantly accelerates early hydration under 45–60C steam curing, enabling demoulding strength above 15 MPa within 8 h. Microstructural characterization reveals that the enhancement originates from the alkali–thermal synergistic mechanism: alkali released from red mud promote dissolution of fly ash glass phases and formation of C–(A)–S–H gels, which interweave with AFt to generate a dense microstructure. A suitable steam curing temperature will further enhance this synergistic effect. This synergistic hydration not only improves early mechanical performance but also supports stable long-term strength development. Sustainability assessment further indicated that the optimized mix design reduces carbon emissions by 46.1% and lowers material cost by 40.8% compared with the pure cement system. Overall, this study clarifies the alkali-thermal synergistic hydration mechanism in solid-waste-based precast concrete and demonstrates an effective pathway for large-scale synergistic utilization of industrial solid wastes such as red mud.

Keywords

Red mud / Precast concrete / Synergistic effect / Compressive strength / Carbon emission

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Shanliang Ma, Xiaoming Liu, Zengqi Zhang, Yang Shao, Yinming Sun, Siyi Li, Weijie Du, Lilei Zhu, Junyong Wang. Synergistic utilization of bauxite residue (red mud) and multiple solid wastes for low carbon precast concrete materials: Mechanical performance, mechanism and sustainability assessment. Green Energy and Resources, 2026, 4 (1) : 100172 DOI:10.1016/j.gerr.2026.100172

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CRediT authorship contribution statement

Shanliang Ma: Writing – original draft, Visualization, Resources, Methodology, Investigation, Formal analysis, Data curation, Conceptualization. Xiaoming Liu: Writing – review & editing, Validation, Supervision, Funding acquisition, Conceptualization. Zengqi Zhang: Writing – review & editing, Validation, Supervision, Funding acquisition, Conceptualization. Yang Shao: Writing – review & editing, Methodology, Investigation, Data curation. Yinming Sun: Writing – review & editing, Validation, Supervision. Siyi Li: Writing – review & editing, Investigation, Data curation. Weijie Du: Writing – review & editing, Investigation, Data curation. Lilei Zhu: Writing – review & editing, Resources, Investigation, Data curation. Junyong Wang: Writing – review & editing, Resources, Investigation, Data curation.

Declaration of competing interest

The authors declare the following financial interests/personal relationships which may be considered as competing interests: Lilei Zhu and Junyong Wang are currently employed by China MCC22 Group Corporation Ltd. Other authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Acknowledgements

This research work was supported by the National Key R&D Program of China (2022YFB2602602) and the National Natural Science Foundation of China (No. U23A20557, 52478232).

References

[1]

Alghazali, H.H., Aljazaeri, Z.R., Myers, J.J., 2020. Effect of accelerated curing regimes on high volume fly ash mixtures in precast manufacturing plants. Cement Concr. Res. 131, 105913.

[2]

Ba, M.F., Qian, C.X., Guo, X.J., Han, X.Y., 2011. Effects of steam curing on strength and porous structure of concrete with low water/binder ratio. Constr. Build. Mater. 25, 123-128.

[3]

Cai, G.-H., Zhou, Y.-F., Li, J.-S., Han, L.-J., Poon, C.S., 2022. Deep insight into mechanical behavior and microstructure mechanism of quicklime-activated ground granulated blast-furnace slag pastes. Cem. Concr. Compos. 134, 104767.

[4]

Chen, T., Gao, Y., Li, Y., Zhu, J., Cheng, Z., Xiong, H., 2024. The strength, reaction mechanism, sustainable potential of full solid waste alkali-activated cementitious materials using red mud and carbide slag. Constr. Build. Mater. 449, 138454.

[5]

Cui, W., Liu, J., Duan, W., Xie, M., Li, X., Dong, X., 2024. Study on the synergistic effects and eco-friendly performance of red mud-based quaternary cementitious materials. Constr. Build. Mater. 428, 136352.

[6]

Dai, Z., Li, J., Yi, W., Li, W., 2025. Preparation and performance assessment of multi-solid waste synergistic red mud-based cementitious materials. Constr. Build. Mater. 475, 141222.

[7]

Geng, Y., Wang, Z., Shen, L., Zhao, J., 2019. Calculating of CO2 emission factors for Chinese cement production based on inorganic carbon and organic carbon. J. Clean. Prod. 217, 503-509.

[8]

Hao, X., Liu, X., Zhang, Z., Zhang, W., Lu, Y., Wang, Y., Yang, T., 2022. In-depth insight into the cementitious synergistic effect of steel slag and red mud on the properties of composite cementitious materials. J. Build. Eng. 52, 104449.

[9]

Harutyunyan, V., 2014. Inhomogeneity, anisotropy, and size effect in the interfacial energy of Ca(OH)2 hexagonal-prism shaped nanocrystals in water. Mater. Chem. Phys. 147, 410-422.

[10]

He, J., Long, G., Ma, K., Xie, Y., 2021. Influence of fly ash or slag on nucleation and growth of early hydration of cement. Thermochim. Acta 701, 178964.

[11]

Lee, Y.-J., Kim, H.-G., Kim, K.-H., 2021. Effect of ground granulated blast furnace slag replacement ratio on structural performance of precast concrete beams. Materials 14, 7159.

[12]

Li, M., Wang, Q., Yang, J., 2017. Influence of steam curing method on the performance of concrete containing a large portion of mineral admixtures. Adv. Mater. Sci. Eng. 2017, 9863219.

[13]

Li, S., Shao, Y., Ma, S., Wang, J., Zhang, Z., Liu, X., Sun, Y., Zhu, L., Han, C., 2025. Early-age mechanical properties and hydration mechanism of red mud-fly ash-ground granulated blast furnace slag-based steam-cured concrete. Constr. Build. Mater. 495, 143617.

[14]

Li, Z., Liu, X., Li, Y.,Ren, Y.,Wang, Y., Zhang, W., 2020. Effects of sulfate on the mechanical performances and hydration characteristics of red mud based non-burnt brick. Constr. Build. Mater. 262, 120722.

[15]

Liu, B., Jiang, J., Shen, S., Zhou, F., Shi, J., He, Z., 2020. Effects of curing methods of concrete after steam curing on mechanical strength and permeability. Constr. Build. Mater. 256, 119441.

[16]

Liu, B., Xie, Y., Li, J., 2005. Influence of steam curing on the compressive strength of concrete containing supplementary cementing materials. Cement Concr. Res. 35, 994-998.

[17]

Liu, X.,Liu, X., Zhang, Z., 2024. Application of red mud in carbon capture, utilization and storage (CCUS) technology. Renew. Sustain. Energy Rev. 202, 114683.

[18]

Liu, X., Zhang, N., 2011. Utilization of red mud in cement production: a review. Waste Manag. Res. 29, 1053-1063.

[19]

Liu, Y., Zhuge, Y., Chen, X., Duan, W., Fan, R., Outhred, L., Wang, L., 2023. Micro-chemomechanical properties of red mud binder and its effect on concrete. Composites, Part B 258, 110688.

[20]

Ma, S., Liu, X., Zhang, Z., Zhu, L., Wang, J., 2025a. Removal, conversion and utilization technologies of alkali components in bayer red mud. J. Environ. Manag. 373, 123781.

[21]

Ma, S., Shao, Y., Li, S., Chen, J., Du, W., Zhang, Z., Liu, X., 2025b. Preparation of low-carbon precast concrete with high-volume red mud and steel slag mineral admixtures. J. Build. Eng., 112931.

[22]

Patangia, J., Saravanan, T.J., Kabeer, K.S.A., Bisht, K ., 2023. Study on the utilization of red mud (bauxite waste) as a supplementary cementitious material: pathway to attaining sustainable development goals. Constr. Build. Mater. 375, 131005.

[23]

Pontikes, Y., Angelopoulos, G.N., 2013. Bauxite residue in cement and cementitious applications: current status and a possible way forward. Resour. Conserv. Recycl. 73, 53-63.

[24]

Rahla, K.M., Mateus, R., Bragança, L., 2019. Comparative sustainability assessment of binary blended concretes using supplementary cementitious materials (SCMs) and ordinary portland cement (OPC). J. Clean. Prod. 220, 445-459.

[25]

Romano, R.C.d.O., Bernardo, H.M., Maciel, M.H., Pileggi, R.G., Cincotto, M.A., 2018. Hydration of Portland cement with red mud as mineral addition. J. Therm. Anal. Calorim. 131, 2477-2490.

[26]

Shao, Y., Ma, S., Li, S., Chen, D., Zhang, Z., Ren, Q., 2024a. Low carbon research in precast concrete based on the synergistic mechanism of red mud-ground granulated blast furnace slag powder. J. Clean. Prod. 439, 140882.

[27]

Shao, Y., Zhang, Z., Liu, X., Zhu, L., Han, C., Li, S., Du, W., 2024b. Comprehensive utilization of industry by-products in precast concrete: a critical review from the perspective of physicochemical characteristics of solid waste and steam curing conditions. Materials 17, 4702.

[28]

Shi, J., Liu, B., Shen, S., Tan, J., Dai, J., Ji, R., 2020. Effect of curing regime on long-term mechanical strength and transport properties of steam-cured concrete. Constr. Build. Mater. 255, 119407.

[29]

Standard, I., 2006. Environmental management-life Cycle assessment-requirements and Guidelines. ISO, London.

[30]

Sun, D., Wang, X., Wang, J., Li, J., Mao, Y., Hu, Z., Li, Y., Song, Z., Wang, W., 2024. Properties and hydration characteristics of cementitious blends with two kinds of solid waste-based sulfoaluminate cement. Constr. Build. Mater. 411, 134482.

[31]

Tangpagasit, J., Cheerarot, R., Jaturapitakkul, C., Kiattikomol, K., 2005. Packing effect and pozzolanic reaction of fly ash in mortar. Cement Concr. Res. 35, 1145-1151.

[32]

Wang, D., Zhang, Z., Guo, W., Li, J., Li, X., Zhao, Q., 2025a. A novel all-solid-waste binder prepared by salt-alkali synergistic activation system constructed from phosphogypsum, soda residue and calcium carbide slag. Cem. Concr. Compos. 155, 105841.

[33]

Wang, S., Jin, H., Deng, Y., Xiao, Y., 2021a. Comprehensive utilization status of red mud in China: a critical review. J. Clean. Prod. 289, 125136.

[34]

Wang, Y., Bao, L., Wang, J., Yao, T., Sun, G., Zong, C., Zhang, H., 2025b. Effect of fluorgypsum and flue gas desulfurization gypsum on properties of aluminate cement based grouting materials. Constr. Build. Mater. 493, 143319.

[35]

Wang, Y., Liu, X.,Zhu, X.,Zhu, W., Yue, J., 2023. Synergistic effect of red mud, desulfurized gypsum and fly ash in cementitious materials: mechanical performances and microstructure. Constr. Build. Mater. 404, 133302.

[36]

Wang, Y., Luo, S., Yang, L., Ding, Y., 2021b. Microwave curing cement-fly ash blended paste. Constr. Build. Mater. 282, 122685.

[37]

Wu, P., Wei, C., Liu, X., Zhang, Z., Xue, Y., Liu, X., 2025. Impact of hematite in red mud on hydration characteristics and environmental performance of cementitious materials. Cem. Concr. Compos. 160, 106035.

[38]

Wu, P., Zeng, Q., Liu, X., Zhang, Z., Wei, C., Li, Y., Ma, S., 2024. Synergistic preparation of high-performance composite blast furnace slag powder from multiple industrial solid wastes: performance regulation and optimization. Constr. Build. Mater. 411, 134231.

[39]

Yang, J., Hu, H., He, X., Su, Y., Wang, Y., Tan, H., Pan, H., 2021. Effect of steam curing on compressive strength and microstructure of high volume ultrafine fly ash cement mortar. Constr. Build. Mater. 266, 120894.

[40]

Yao, T., Wang, Y., Li, M., Zhang, W., Luo, S., Tian, Q., Chen, J., 2025. Recycling coal gasification slag to produce eco-friendly ultra-high performance concrete: working properties, mechanical properties and microstructure. Cem. Concr. Compos., 106260.

[41]

Yao, T., Wang, Y., Zhang, W., Li, M., Luo, S., Qi, S., 2024. Influence of recycled waste concrete powders on the performances of sulphoaluminate cement. Constr. Build. Mater. 426, 136226.

[42]

Zachar, J ., 2011. Sustainable and economical precast and prestressed concrete using fly ash as a cement replacement. J. Mater. Civ. Eng. 23, 789-792.

[43]

Zeng, Q., Li, K., Fen-chong, T., Dangla, P., 2012. Determination of cement hydration and pozzolanic reaction extents for fly-ash cement pastes. Constr. Build. Mater. 27, 560-569.

[44]

Zeng, Q., Liu, X., Zhang, Z., Wei, C., Xu, C.C., 2023. Synergistic utilization of blast furnace slag with other industrial solid wastes in cement and concrete industry: synergistic mechanisms, applications, and challenges. Green Energy and Resources 1, 100012.

[45]

Zeyad, A.M., Tayeh, B. A.,Adesina, A., de Azevedo, A.R., Amin, M., Hadzima-Nyarko, M., Agwa, I.S., 2022. Review on effect of steam curing on behavior of concrete. Clean. Mater. 3, 100042.

[46]

Zhang, T., Ma, B., Jiang, D., Jiang, Q., Jin, Z., 2021a. Comparative research on the effect of various mineral admixtures on the early hydration process of cement. Constr. Build. Mater. 301, 124372.

[47]

Zhang, W., Liu, X., Wang, Y., Li, Z., Li, Y., Ren, Y., 2021b. Binary reaction behaviors of red mud based cementitious material: hydration characteristics and Na + utilization. J. Hazard. Mater. 410, 124592.

[48]

Zhuang, S., Sun, J., 2020. The feasibility of properly raising temperature for preparing high-volume fly ash or slag steam-cured concrete: an evaluation on DEF, 4-year strength and durability. Constr. Build. Mater. 242, 118094.

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