Developing solid oxide electrolysis cells for CO2 conversion: A critical power-to-X approach

Yuhui Jin , Fengchao Li , Yun Zheng , Wenqiang Zhang , Shufan Wang , Wei Yan , Bo Yu , Jiujun Zhang

Front. Energy ›› 2025, Vol. 19 ›› Issue (4) : 419 -434.

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Front. Energy ›› 2025, Vol. 19 ›› Issue (4) : 419 -434. DOI: 10.1007/s11708-025-1012-6
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Developing solid oxide electrolysis cells for CO2 conversion: A critical power-to-X approach

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Abstract

The substitution of traditional fossil fuels with renewable energy sources is a crucial endeavor for achieving carbon neutrality targets. However, the intermittency of solar, wind, and other renewables poses significant challenges to the power grid. Power-to-X (P2X) technologies play an essential role in enabling the efficient consumption of renewable energy. High-temperature solid oxide electrolysis cells (SOECs) to convert CO2 offer a promising method for CO2 conversion, allowing renewable electricity to be stored in chemical form and facilitating the resourceful utilization of carbon resources. In this paper, the mechanism of CO2 reduction through SOECs is reviewed, two pathways for converting CO2 to chemicals via SOECs are summarized, and the current markets and manufacturers of SOECs are elucidated. Based on this discussion and analysis, the main challenges and development directions for the large-scale application of SOECs in CO2 conversion are further proposed.

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solid oxide electrolysis cells (SOECs) / CO2 conversion / power-to-X (P2X)

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Yuhui Jin, Fengchao Li, Yun Zheng, Wenqiang Zhang, Shufan Wang, Wei Yan, Bo Yu, Jiujun Zhang. Developing solid oxide electrolysis cells for CO2 conversion: A critical power-to-X approach. Front. Energy, 2025, 19(4): 419-434 DOI:10.1007/s11708-025-1012-6

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References

[1]

Allen M R, Frame D J, Friedlingstein P. . Geological Net Zero and the need for disaggregated accounting for carbon sinks. Nature, 2025, early access

[2]

Rogger J, Judd E J, Mills B J W. . Biogeographic climate sensitivity controls Earth system response to large igneous province carbon degassing. Science, 2024, 385(6709): 661–666

[3]

An Z, Zhou W, Zhang Z. . Mid-pleistocene climate transition triggered by Antarctic Ice Sheet growth. Science, 2024, 385(6708): 560–565

[4]

Lachs L, Bozec Y M, Bythell J C. . Natural selection could determine whether Acropora corals persist under expected climate change. Science, 2024, 386(6727): 1289–1294

[5]

Schleussner C F, Ganti G, Lejeune Q. . Overconfidence in climate overshoot. Nature, 2024, 634(8033): 366–373

[6]

Walmsley T G, Philipp M, Picón-Núñez M. . Hybrid renewable energy utility systems for industrial sites: A review. Renewable & Sustainable Energy Reviews, 2023, 188: 113802

[7]

Wen Z, Yao L, Cheng F. . A comprehensive review of wind power based power system frequency regulation. Frontiers in Energy, 2023, 17(5): 611–634

[8]

Xu Y, Du Y, Chen H. . Recent advances in rational design for high-performance potassium-ion batteries. Chemical Society Reviews, 2024, 53(13): 7202–7298

[9]

Kang H, Ma J, Perathoner S. . Understanding the complexity in bridging thermal and electrocatalytic methanation of CO2. Chemical Society Reviews, 2023, 52(11): 3627–3662

[10]

Jang I, SA Carneiro J, Crawford J O. . Electrocatalysis in solid oxide fuel cells and electrolyzers. Chemical Reviews, 2024, 124(13): 8233–8306

[11]

Ashraf S, Gohar O, Khan M Z. . Exploring the frontiers of electrochemical CO2 conversion: A comprehensive review. Nano Materials Science, 2024,

[12]

Liu R T, Xu Z L, Li F M. . Recent advances in proton exchange membrane water electrolysis. Chemical Society Reviews, 2023, 52(16): 5652–5683

[13]

Wan L, Xu Z, Xu Q. . Key components and design strategy of the membrane electrode assembly for alkaline water electrolysis. Energy & Environmental Science, 2023, 16(4): 1384–1430

[14]

Cao J, Hu Y, Zheng Y. . Recent advances and challenges of nitrogen/nitrate electro catalytic reduction to ammonia synthesis. Frontiers in Energy, 2024, 18(2): 128–140

[15]

Kang S, Pan Z, Guo J. . Scientometric analysis of research trends on solid oxide electrolysis cells for green hydrogen and syngas production. Frontiers in Energy, 2024, 18(5): 583–611

[16]

Hou X, Jiang Y, Wei K. . Syngas production from CO2 and H2O via solid-oxide electrolyzer cells: Fundamentals, materials, degradation, operating conditions, and applications. Chemical Reviews, 2024, 124(8): 5119–5166

[17]

Liu H, Yu M, Tong X. . High temperature solid oxide electrolysis for green hydrogen production. Chemical Reviews, 2024, 124(18): 10509–10576

[18]

Zheng Y, Chen Z, Zhang J. Solid oxide electrolysis of H2O and CO2 to produce hydrogen and low-carbon fuels. Electrochemical Energy Reviews, 2021, 4(3): 508–517

[19]

Tezel E, Whitten A, Yarema G. . Electrochemical reduction of CO2 using solid oxide electrolysis cells: Insights into catalysis by nonstoichiometric mixed metal oxides. ACS Catalysis, 2022, 12(18): 11456–11471

[20]

Zong S, Zhao X, Jewell L L. . Advances and challenges with SOEC high temperature co-electrolysis of CO2/H2O: Materials development and technological design. Carbon Capture Science & Technology, 2024, 12: 100234

[21]

Xu R, Liu S, Yang M. . Advancements and prospects of perovskite-based fuel electrodes in solid oxide cells for CO2 electrolysis to CO. Chemical Science, 2024, 15(29): 11166–11187

[22]

Malavasi L, Fisher C A, Islam M S. Oxide-ion and proton conducting electrolyte materials for clean energy applications: Structural and mechanistic feature. Chemical Society Reviews, 2010, 39(11): 4370–4387

[23]

Luo Y, Zhang D, Liu T. . In situ exsolution of quaternary alloy nanoparticles for CO2‒CO mutual conversion using reversible solid oxide cell. Advanced Functional Materials, 2024, 34(40): 2403922

[24]

Du Y, Zhao L, Xiao Y. . High electrolysis performance of the SOEC cathode by creating oxygen vacancies to regulate the adsorption energy. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2024, 12(42): 28911–28918

[25]

Jing J, Pang J, Chen L. . Structure, synthesis, properties and solid oxide electrolysis cells application of Ba(Ce, Zr)O3 based proton conducting materials. Chemical Engineering Journal, 2022, 429: 132314

[26]

Medvedev D, Lyagaeva J, Plaksin S. . Sulfur and carbon tolerance of BaCeO3-BaZrO3 proton-conducting materials. Journal of Power Sources, 2015, 273: 716–723

[27]

Danilov N A, Lyagaeva J G, Medvedev D A. . Transport properties of highly dense proton-conducting BaCe0.8–xZrxDy0.2O3–δ materials in low- and high-temperature ranges. Electrochimica Acta, 2018, 284: 551–559

[28]

Gore C M, White J O, Wachsman E D. . Effect of composition and microstructure on electrical properties and CO2 stability of donor-doped, proton conducting BaCe1‒(x+y)ZrxNbyO3. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2014, 2(7): 2363–2373

[29]

Zhang Y, Song R, Zou J. . Research on CO2 reduction reaction in the proton conducting solid oxide electrolysis reactor with Fe catalyst layer coverage. International Journal of Hydrogen Energy, 2025, 98: 86–95

[30]

Hanif M B, Rauf S, Khan M Z. . Innovative advances and challenges in solid oxide electrolysis cells: Exploring surface segregation dynamics in perovskite electrodes. Materials Science and Engineering R Reports, 2024, 161: 100864

[31]

Zhang L, Sun W, Xu C. . Two-fold improvement in chemical adsorption ability to achieve effective carbon dioxide electrolysis. Applied Catalysis B: Environmental, 2022, 317: 121754

[32]

Liu Q, Song Y, Li R. . A vanadium-doped BSCF perovskite for CO2 electrolysis in solid oxide electrolysis cells. International Journal of Hydrogen Energy, 2021, 46(38): 19814–19821

[33]

Hu F, Ling Y, Fang S. . Engineering dual-exsolution on self-assembled cathode to achieve efficient electrocatalytic CO2 reduction. Applied Catalysis B: Environmental, 2023, 337: 122968

[34]

Wang Z, Tan T, Du K. . A high-entropy layered perovskite coated with in situ exsolved core-shell CuFe@FeOx nanoparticles for efficient CO2 electrolysis. Advanced Materials, 2024, 36(11): 2312119

[35]

Akhmadjonov A, Bae K T, Lee K T. Novel perovskite oxide hybrid nanofibers embedded with nanocatalysts for highly efficient and durable electrodes in direct CO2 electrolysis. Nano-Micro Letters, 2024, 16(1): 93

[36]

Han F, Wang Z, Zhang S. . Highly efficient perovskite-based fuel electrodes for solid oxide electrochemical cells via iin-situ nanoparticle exsolution and electron conduction enhancement. Applied Catalysis B: Environment and Energy, 2025,

[37]

Liu Q, Shen F, Song G. . Tailoring ion ordering in perovskite oxide for high-temperature oxygen evolution reaction. Angewandte Chemie International Edition, 2023, 62(32): e202307057

[38]

Li J, Wu Z, Shen Y. . Suppressing surface segregation by introducing lanthanides to enhance high-temperature oxygen evolution reaction activity and durability. Journal of Physics: Energy, 2025, 7(2): 025002

[39]

Yang C, Wang Z, Tan Y. . Interface engineering of La0.6Sr0.4Co0.2Fe0.8O3−δ/Gd0.1Ce0.9O1.95 heterostructure oxygen electrode for solid oxide electrolysis cells with enhanced CO2 electrolysis performance. Chemical Engineering Journal, 2024, 498: 155461

[40]

Yang K, Wang Y, Jiang L. . Cobalt-free perovskite Ba0.95La0.05FeO3−δ as efficient and durable oxygen electrode for solid oxide electrolysis cells. International Journal of Hydrogen Energy, 2023, 48(71): 27464–27472

[41]

Wu K T, Matsuda J, Staykov A. . Crucial role of self-exsolved heterostructured cermet nanoparticles in highly active spinel electrodes for CO2/H2O co-electrolysis. Advanced Energy Materials, 2023, 13(41): 2301042

[42]

Wu K, Ishihara T. Superior syngas product control of La(Sr)Fe(Mn)O3 perovskite in high-temperature CO2/H2O co-electrolysis. Applied Catalysis B. Environment and Energy, 2024, 357: 124335

[43]

Zhang N, Naden A, Zhang L. . Enhanced CO2 electrolysis through Mn substitution coupled with Ni exsolution in lanthanum calcium titanate electrodes. Advanced Materials, 2024, 36(19): 2308481

[44]

Bausá N, Escolástico S, Serra J M. Direct CO2 conversion to syngas in a BaCe0.2Zr0.7Y0.1O3−δ-based proton-conducting electrolysis cell. Journal of CO2 Utilization, 2019, 34: 231–238

[45]

Li W, Luo J. High-temperature electrochemical devices based on dense ceramic membranes for CO2 conversion and utilization. Electrochemical Energy Reviews, 2021, 4(3): 518–544

[46]

Liu F, Chen Z, Zhou H. . Highly efficient CH4-assisted CO2 electrolysis for syngas production in a quasi-symmetric Ni-ceramic electrolyzer. Journal of Power Sources, 2024, 609: 234703

[47]

Dong C, Jiang F, Yang L. . Enhancing electrocatalytic reforming of CO2/CH4 with in situ exsolved metal-oxide interfaces in a solid oxide electrolysis cell. Separation and Purification Technology, 2022, 299: 121714

[48]

Song Y, Liu T, Feng W. . Atomically dispersed Ru species induced by strong metal-support interaction for electrochemical methane reforming. Journal of the American Chemical Society, 2024, 146(46): 31825–31835

[49]

Guo Y, Wang S, Li R. . In situ exsolved CoFe alloy nanoparticles for stable anodic methane reforming in solid oxide electrolysis cells. Joule, 2024, 8(7): 2016–2032

[50]

Xie K, Zhang Y, Meng G. . Direct synthesis of methane from CO2/H2O in an oxygen-ion conducting solid oxide electrolyser. Energy & Environmental Science, 2011, 4(6): 2218–2222

[51]

Chen L, Chen F, Xia C. Direct synthesis of methane from CO2–H2O co-electrolysis in tubular solid oxide electrolysis cells. Energy & Environmental Science, 2014, 7(12): 4018–4022

[52]

Lei L, Liu T, Fang S. . The co-electrolysis of CO2–H2O to methane via a novel micro-tubular electrochemical reactor. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2017, 5(6): 2904–2910

[53]

Błaszczak P, Zając M, Ducka A. . High-temperature Co-electrolysis of CO2/H2O and direct methanation over Co-impregnated SOEC. Bimetallic synergy between Co and Ni. International Journal of Hydrogen Energy, 2022, 47(82): 35017–35037

[54]

Duan C, Kee R, Zhu H. . Highly efficient reversible protonic ceramic electrochemical cells for power generation and fuel production. Nature Energy, 2019, 4(3): 230–240

[55]

Li M, Hua B, Wang L. . Switching of metal–oxygen hybridization for selective CO2 electrohydrogenation under mild temperature and pressure. Nature Catalysis, 2021, 4(4): 274–283

[56]

Pan Z, Duan C, Pritchard T. . High-yield electrochemical upgrading of CO2 into CH4 using large-area protonic ceramic electrolysis cells. Applied Catalysis B: Environmental, 2022, 307: 121196

[57]

Ye Y, Lee W, Pan J. . Tuning the product selectivity of CO2/H2O co-electrolysis using CeO2-modified proton-conducting electrolysis cells. Energy & Environmental Science, 2023, 16(7): 3137–3145

[58]

Zhu C, Hou S, Hu X. . Electrochemical conversion of methane to ethylene in a solid oxide electrolyzer. Nature Communications, 2019, 10(1): 1173

[59]

Song Y, Lin L, Feng W. . Interfacial enhancement by γ-Al2O3 of electrochemical oxidative dehydrogenation of ethane to ethylene in solid oxide electrolysis cells. Angewandte Chemie International Edition, 2019, 58(45): 16043–16046

[60]

Ye L, Duan X, Xie K. Electrochemical oxidative dehydrogenation of ethane to ethylene in a solid oxide electrolyzer. Angewandte Chemie International Edition, 2021, 60(40): 21746–21750

[61]

Ye L, Shang Z, Xie K. Selective oxidative coupling of methane to ethylene in a solid oxide electrolyser based on porous single-crystalline CeO2 monoliths. Angewandte Chemie International Edition, 2022, 61(32): e202207211

[62]

Sun X, Yang H, Chen B. . Electrochemical activation of surface oxygen for efficient oxidative dehydrogenation reaction at elevated temperatures. ACS Catalysis, 2024, 14(8): 5827–5837

[63]

He X, Huang X, Sun H. . Electrochemical oxidative dehydrogenation of ethane to ethylene in a solid oxide electrolysis cell with in situ grown metal-oxide interface active electrodes. International Journal of Hydrogen Energy, 2024, 79: 1030–1036

[64]

Qin M, Zhang S, Sun W. . Novel Sr1.95Fe1.4Co0.1Mo0.5O6‒δ anode heterostructure for efficient electrochemical oxidative dehydrogenation of ethane to ethylene by solid oxide electrolysis cells. Ceramics International, 2023, 49(18): 30178–30186

[65]

Zhang S, Xu C, Ren R. . Self-assembly dual active site nanocomposite anode Ce0.6Mn0.3Fe0.1O2-δ/NiFe/MnOx for electrooxidative dehydrogenation of ethane to ethylene. ACS Applied Materials & Interfaces, 2024, 16(3): 3451–3459

[66]

Zhang X, Ye L, Li H. . Electrochemical dehydrogenation of ethane to ethylene in a solid oxide electrolyzer. ACS Catalysis, 2020, 10(5): 3505–3513

[67]

Wang L, Pérez-Fortes M, Madi H. . Optimal design of solid-oxide electrolyzer based power-to-methane systems: A comprehensive comparison between steam electrolysis and co-electrolysis. Applied Energy, 2018, 211: 1060–1079

[68]

Al-Kalbani H, Xuan J, García S. . Comparative energetic assessment of methanol production from CO2: Chemical versus electrochemical process. Applied Energy, 2016, 165: 1–13

[69]

Zong Z, Koers N, Cai G. . CO2-to-methanol: Economic and environmental comparison of emerging and established technologies with dry reforming and methane pyrolysis. Chemical Engineering Journal, 2024, 487: 150274

[70]

Ferguson K M, Saafan H, Wildeboer E K H. . Production of carbon neutral methanol using co-electrolysis of CO2 and steam in solid oxide electrolysis cell in tandem with direct air capture. ECS Transactions, 2021, 103(1): 663–676

[71]

Zhang H, Desideri U. Techno-economic optimization of power-to-methanol with co-electrolysis of CO2 and H2O in solid-oxide electrolyzers. Energy, 2020, 199: 117498

[72]

Khan M S, Abid M, Chen C. . Sustainable hydrogen storage and methanol synthesis through solar-powered co-electrolysis using SOEC. Energy Storage, 2024, 6(8): e70095

[73]

Zhang Y, Li A, Fei Y. . Techno-economic assessment of electro-synthetic fuel based on solid oxide electrolysis cell coupled with Fischer-Tropsch strategy. Journal of CO2 Utilization, 2024, 86: 102905

[74]

Pratschner S, Hammerschmid M, Müller S. . Off-grid vs. grid-based: Techno-economic assessment of a power-to-liquid plant combining solid-oxide electrolysis and Fischer-Tropsch synthesis. Chemical Engineering Journal, 2024, 481: 148413

[75]

Chatenet M, Pollet B G, Dekel D R. . Water electrolysis: From textbook knowledge to the latest scientific strategies and industrial developments. Chemical Society Reviews, 2022, 51(11): 4583–4762

[76]

Precedence Research. Electrolyzer market size, share, and trends 2024 to 2033. 2024, ,

[77]

Can W, Cai W, Zhang S. . Global carbon neutrality annual progress report. 2024–10, available at website of Tsinghua University. , ,

[78]

Zheng Y, Gao L, He S. . Reduction potential of the energy penalty for CO2 capture in CCS. Frontiers in Energy, 2023, 17(3): 390–399

[79]

Zhu F, Ge J, Gao Y. . Molten salt electro-preparation of graphitic carbons. Exploration, 2023, 3(1): 20210186

[80]

Habibzadeh F, Mardle P, Zhao N. . Ion exchange membranes in electrochemical CO2 reduction processes. Electrochemical Energy Reviews, 2023, 6(1): 26

[81]

Tang T, Wang Z, Guan J. Achievements and challenges of copper-based single-atom catalysts for the reduction of carbon dioxide to C2+ products. Exploration, 2023, 3(5): 20230011

[82]

Prakash J, Chen Z, Saini S. . Advancements on metal oxide semiconductor photocatalysts in photo-electrochemical conversion of carbon dioxide into fuels and other useful products. Frontiers in Energy, 2024, 18(2): 187–205

[83]

Xue J, Chen Z, Zhang Y. . A review on plasmonic enhancement of activity and selectivity in electrocatalytic CO2 reduction. Frontiers in Energy, 2024, 18(4): 399–417

[84]

Hossain M N, Zhang L, Neagu R. . Free-standing single-atom catalyst-based electrodes for CO2 reduction. Electrochemical Energy Reviews, 2024, 7(1): 5

[85]

Li F, Li Y, Chen H. . Impact of strain-induced changes in defect chemistry on catalytic activity of Nd2NiO4+δ electrodes. ACS Applied Materials & Interfaces, 2018, 10(43): 36926–36932

[86]

Song Y, Zhang X, Xiao Z. . Coupled amorphous NiFeP/crystalline Ni3S2 nanosheets enables accelerated reaction kinetics for high current density seawater electrolysis. Applied Catalysis B. Environment and Energy, 2024, 352: 124028

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