A novel fluorescence enhancing F - probe based on intermolecular energy transfer

Abstract

A supramolecular fluorescent sensor of F^− based on intermolecular energy transfer is described. The maximum absorption wavelength of a pyrrolic compound 1 is 472 nm, which is coincident with the emission wavelength of a dipyridylamine-anthracene compound 2. In the CH₂Cl₂ solution of 1 and 2, the fluorescence of 2 was quenched because of the presence of intermolecular energy transfer from 2 to 1. When F^− was added to this solution, the absorption maximum wavelength of 1 shifted from 472 to 594 nm due to a deprotonation process. Simultaneously, the fluorescence of 2 was recovered because of the interruption of the intermolecular energy transfer. Based on these observations, the combination of 1 and 2 can be regarded as a novel supramolecular fluorescence enhancing F^− probe.

Keywords

fluoride sensor / intermolecular energy transfer / fluorescence enhancement