Characterization of polybenzoxazine and its electrochemical
polymerization mechanism

doi:10.1007/s11458-009-0105-9

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Front. Chem. China ›› 2009, Vol. 4 ›› Issue (4) : 390-395. DOI: 10.1007/s11458-009-0105-9

Research articles

Characterization of polybenzoxazine and its electrochemical polymerization mechanism

Wei CHEN,Jinbo HE,Liang LI,

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Abstract

Poly(3-(p-methyl)benzyl-3,4-dihydro-6-methyl-2H-1,3-benzoxazine) (poly(pCpT)), which was obtained from electrochemical polymerization in acetonitrile/alkali aqueous solution, was characterized by FT-IR, UV-Vis and ¹H-NMR. The results indicate a ring-opening structure of the polymer. By using a rotating-ring disc electrode (RRDE), the electrochemical behaviors of polymerization were studied and the polymerization mechanism was proposed.

Keywords

polybenzoxazine / electropolymerization / heat-resistance / rotating-ring disc electrode / electrochemical behavior

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Wei CHEN, Jinbo HE, Liang LI,. Characterization of polybenzoxazine and its electrochemical polymerization mechanism. Front. Chem. China, 2009, 4(4): 390‒395 https://doi.org/10.1007/s11458-009-0105-9