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Synthesis of hydrophobic association cationic
starch and its flocculation application on containing algae water
of Dianchi Lake
- XU Xiaojun1, LIU Xiangyi2, YANG Yuming2
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1.College of Environmental Science and Engineering, Kunming University of Science and Technology; 2.College of Environmental Science and Engineering, Kunming University of Science and Technology；Southwest Forestry College;
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History
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| Published |
| 05 Jun 2008 |
| Issue Date |
| 05 Jun 2008 |
Abstract
The hydrophobic formation cationic starch (PSOAMDA) was prepared from starch (St), octadecyl acrylate (OA), acrylamide (AM) and dimethyl diallyl ammonium chloride (DMDAAC) by means of inverse suspension polymerization with redox initiator. Water with algae from Dianchi Lake was tested with PSOAMDA. Results show that when the molar ratio of St: AM: DMDAAC: OA is 4:8:1.5:0.6 and the reaction temperature is 40°C with a reaction time of 3 h, the monomer conversion yield, graft percentage and cationic degree is 92.4%, 63.8% and 7.3%, respectively, and M? = 3.26 × 106 g/vmol. It had been found from the flocculation of disposed water with algae from Dianchi Lake that the transparency and COD elimination reach to 93.5% and 70.3%, respectively, with 15 mg/L PSOAMDA and at pH 6, vs. 91.3% and 69.2% obtained with the commercial cationic polyacrylamide (PAM-C). When PSOAMDA dosage is 10–25 mg/L and the pH of aqueous solution is 6–10, the flocculation performance is well capable of dealing with the water with algae from Dianchi Lake.
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XU Xiaojun, LIU Xiangyi, YANG Yuming.
Synthesis of hydrophobic association cationic
starch and its flocculation application on containing algae water
of Dianchi Lake. Front. Chem. China, 2008, 3(2): 166‒171 https://doi.org/10.1007/s11458-008-0032-1
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References
1. Mark H F Bikales N M Overberger C G Encyclopedia of Polymer Science and Engineering. 2nd EdNew YorkWileyInterscicnce 1989 732734
2. Mc Cormick C L Nonaka T Johons on C B Water soluble copolymers: 27 Synthesis and aqueous solutionbehavior of associative acrylamide/N-alkylacrylamide copolymersPoly Pr 1988 29731733
3. Schulz D N Manrer J J Copolymers of acrylamine andsurfactant macromonomers: synthesis and solution propertiesPolymer 1987 2821112114. doi:10.1016/0032‐3861(87)90050‐4
4. Zhao Yong He Binglin Ha Runhua The study on the synthesis and performance of the hydrophobicallyassociating acrylamide polymerization in the opposition phase micromilksolutionMacromolecule Transaction 2000 (5)550553 (in Chinese)
5. Guo Huaicheng Sun Yanfeng The probe on characteristicanalysis and control countermeasure about water eutrophic in DianchiLakeGeography Science Development 2002 21(5)3539 (in Chinese)
6. Ru Jingyu Yin Wen Zhou Junjie Zhu Ronggang Wang Jiaqiang Liu Shiqing Zhang Wudi Study of theeffect of an iron-compound on Dianchi Lake's algaeJournal of Yunnan University (Natural Sciences Edition) 2006 28(1)6063 (in Chinese)
7. Zhang Mei Li Yuan Wang Ruonan Dynamic variation for the species of phytoplankton in DianchiLake, ChinaJournal of Yunnan University(Natural Sciences Edition) 2006 28(1)7377 (in Chinese)
8. Yin Wen Ru Jingyu Zhou Junjie Zhu Ronggang Wang Jiaqiang Liu Shiqing Zhang Wudi Study of theeffect of a chloric-compound on the Dianchi's Lake algaeJournal of Yunnan University (Natural Sciences Edition) 2006 28(2)153156 (in Chinese)
9. Liu Xiangyi Xu Xiaojun The study on the crylic acidreaction to eighteen mellow in the of solid super powerful acidFine Petroleum Chemical Industry Intermediate 2005 (5)2426 (in Chinese)
10. Ge Xuewu Xu Xiangling Zhang Zhicheng The method of study on flocculant prepared by acrylamidegrafted starchMacromolecule Material Scienceand Engineering 1999 15(4)130132 (in Chinese)
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