Microwave synthesis and photoluminescent properties of Sr2CeO4/Ln3+ (Ln = Er, Ho, Tm)

Abstract

Sr₂CeO₄/Ln³⁺ (Ln = Er, Ho, Tm) phosphors were synthesized with the microwave radiation method for the first time. The luminescent properties of the samples were investigated and the up-conversion luminescence of Er³⁺, Ho³⁺ and Tm³⁺ doped Sr₂CeO₄ phosphors was observed. The spectra indicate that the energy transfer takes place from the triplet excited state of MLCT (metal-to-ligand charge transfer) state for Sr₂CeO₄ (sensitizer) to the rare earth ions (activator).

Keywords

Sr₂CeO₄, Er³⁺, Ho³⁺, Tm³⁺, luminescence, up-conversion luminescence, microwave radiation