Direct melting polycondensation and characterization of poly(ε-caprolactone-co-lactic acid)

doi:10.1007/s11458-007-0036-2

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Front. Chem. China ›› 2007, Vol. 2 ›› Issue (2) : 178-182. DOI: 10.1007/s11458-007-0036-2

Direct melting polycondensation and characterization of poly(ε-caprolactone-co-lactic acid)

ZHAO Yaoming¹, ZHOU Ling², WANG Zhaoyang³

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Abstract

A kind of biodegradable material, poly(ε-caprolactone-co-lactic acid) [P(CL-co-LA)] was synthesized via the direct melting polycondensation of lactic acid (LA) and ?-caprolactone (CL). The influences of the polycondensation time, and the catalyst type on the intrinsic viscosity of P(CL-co-LA) were also investigated. The results indicate that P(CL-co-dl-LA), with an intrinsic viscosity of 0.4733 dL/g, can be prepared by direct melting polycondensation with the molar ratio LA/CL = 3:7 at 180?C and 70 Pa for 12 h, using 0.5% (mass fraction) of SnCl₂ as the catalyst. Compared with lactide ring-opening polycondensation (ROP), the direct melting polycondensation of LA and CL is more practicable and simple.

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ZHAO Yaoming, ZHOU Ling, WANG Zhaoyang. Direct melting polycondensation and characterization of poly(ε-caprolactone-co-lactic acid). Front. Chem. China, 2007, 2(2): 178‒182 https://doi.org/10.1007/s11458-007-0036-2