Porous Organic Framework-Based Materials (MOFs, COFs and HOFs) for Lithium-/Sodium-/Potassium-/Zinc-/Aluminum-/Calcium-Ion Batteries: A Review

Abstract

Porous organic frameworks (POFs), including metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded frameworks (HOFs), have become research and development hotspots in the field of metal-ion batteries (MIBs) because of their unique structures, variable pore sizes, high specific surface areas, abundant active sites and customizable frameworks. These natural advantages of POF materials provide sufficient conditions for high-performance electrode materials for MIBs. However, some POF-based materials are still in the early stages of development, and more efforts are needed to make them competitive in practical applications. This updated review provides a comprehensive overview of recent advancements in the application of POF-based materials for MIBs, including lithium-ion, sodium-ion, potassium-ion, zinc-ion, aluminum-ion and calcium-ion batteries. In addition, advanced characterization technologies and computational simulation techniques, including machine learning, are reviewed. The main challenges and prospects of the application of POF-based materials in MIBs are briefly discussed, which can provide insights into the design and synthesis of high-performance electrode materials.

Graphical Abstract

This updated review provides a comprehensive overview of the recent advancements in the application of POF-based materials (MOFs, COFs, and HOFs) for metal-ion batteries (MIBs) including lithium-ion, sodium-ion, potassium-ion, zinc-ion, aluminum-ion and calcium-ion batteries. The advanced characterization technologies and computational simulation techniques including machine learning are reviewed. The main challenges and prospects of POF-based materials used in MIBs are discussed, providing insights into the design and synthesis of high-performance electrode materials.

Keywords

Porous organic frameworks / Energy storage / Derivatives / Electrode materials / Metal-ion batteries

References

[1] Wang QY, O’Carroll T, Shi FCet al. . Designing organic material electrodes for lithium-ion batteries: progress, challenges, and perspectives. Electrochem. Energy Rev.. 2024, 7: 15.

[2] Wang Y, Yang X, Meng YFet al. . Fluorine chemistry in rechargeable batteries: challenges, progress, and perspectives. Chem. Rev.. 2024, 1243494-3589.

[3] Yuan D, Dou YH, Wu ZZet al. . Atomically thin materials for next-generation rechargeable batteries. Chem. Rev.. 2022, 122: 957-999.

[4] Yao WQ, Liao K, Lai TXet al. . Rechargeable metal-sulfur batteries: key materials to mechanisms. Chem. Rev.. 2024, 124: 4935-5118.

[5] Zheng Y, Yao YZ, Ou JHet al. . A review of composite solid-state electrolytes for lithium batteries: fundamentals, key materials and advanced structures. Chem. Soc. Rev.. 2020, 49: 8790-8839.

[6] Zhang S, Ma J, Dong SMet al. . Designing all-solid-state batteries by theoretical computation: a review. Electrochem. Energy Rev.. 2023, 6: 4.

[7] Xie CL, Liu SF, Zhang WXet al. . Robust and wide temperature-range zinc metal batteries with unique electrolyte and substrate design. Angew. Chem. Int. Ed.. 2023, 622304259.

[8] Liu HM, Gao XR, Lou YTet al. . Coupled photochemical storage materials in solar rechargeable batteries: progress, challenges, and prospects. Adv. Energy Mater.. 2024, 142402381.

[9] Huang F, Xu P, Fang GZet al. . In-depth understanding of interfacial Na⁺ behaviors in sodium metal anode: migration, desolvation, and deposition. Adv. Mater.. 2024, 362405310.

[10] Xie ZH, Sun LD, Sajid Met al. . Rechargeable alkali metal-chlorine batteries: advances, challenges, and future perspectives. Chem. Soc. Rev.. 2024, 538424-8456.

[11] Ji YC, Yin ZW, Yang ZZet al. . From bulk to interface: electrochemical phenomena and mechanism studies in batteries via electrochemical quartz crystal microbalance. Chem. Soc. Rev.. 2021, 50: 10743-10763.

[12] Wu Z, Li XH, Zheng Cet al. . Interfaces in sulfide solid electrolyte-based all-solid-state lithium batteries: characterization, mechanism and strategy. Electrochem. Energy Rev.. 2023, 6: 10.

[13] Yang YJ, Zhou JB, Wang LLet al. . Prussian blue and its analogues as cathode materials for Na-, K-, Mg-, Ca-. Zn- and Al-ion batteries. Nano Energy. 2022, 99. 107424

[14] Wang ZW, Zeng ZT, Wang Het al. . Bismuth-based metal-organic frameworks and their derivatives: opportunities and challenges. Coord. Chem. Rev.. 2021, 439. 213902

[15] Lin J, Reddy CKet al. . Metal-organic frameworks and their derivatives as electrode materials for potassium ion batteries: a review. Coord. Chem. Rev.. 2021, 446214118.

[16] Zhang Q, Jiang S, Lv TTet al. . Application of conductive MOF in zinc-based batteries. Adv. Mater.. 2023, 352305532.

[17] Peng J, Zhang W, Liu QNet al. . Prussian blue analogues for sodium-ion batteries: past, present, and future. Adv. Mater.. 2022, 342108384.

[18] Ge P, Li SJ, Shuai HLet al. . Ultrafast sodium full batteries derived from X-Fe (X = Co, Ni, Mn) Prussian blue analogs. Adv. Mater.. 2019, 311806092.

[19] Wang WX, Kale VS, Cao Zet al. . Phenanthroline covalent organic framework electrodes for high-performance zinc-ion supercapattery. ACS Energy Lett.. 2020, 52256-2264.

[20] Zhao ZD, Wang R, Peng CXet al. . Horizontally arranged zinc platelet electrodeposits modulated by fluorinated covalent organic framework film for high-rate and durable aqueous zinc ion batteries. Nat. Commun.. 2021, 12: 6606.

[21] Zhao J, Ying YP, Wang GLet al. . Covalent organic framework film protected zinc anode for highly stable rechargeable aqueous zinc-ion batteries. Energy Storage Mater.. 2022, 4882-89.

[22] Guo C, Zhou J, Chen YTet al. . Synergistic manipulation of hydrogen evolution and zinc ion flux in metal-covalent organic frameworks for dendrite-free Zn-based aqueous batteries. Angew. Chem. Int. Ed.. 2022, 61: 2210871.

[23] Wang WX, Kale VS, Cao Zet al. . Molecular engineering of covalent organic framework cathodes for enhanced zinc-ion batteries. Adv. Mater.. 2021, 332103617.

[24] Wu K, Shi XS, Yu FFet al. . Molecularly engineered three-dimensional covalent organic framework protection films for highly stable zinc anodes in aqueous electrolyte. Energy Storage Mater.. 2022, 51391-399.

[25] Peng HJ, Huang SH, Montes-García Vet al. . Supramolecular engineering of cathode materials for aqueous zinc-ion energy storage devices: novel benzothiadiazole functionalized two-dimensional olefin-linked COFs. Angew. Chem. Int. Ed.. 2023, 62: 2216136.

[26] Zheng SB, Shi DJ, Yan Det al. . Orthoquinone-based covalent organic frameworks with ordered channel structures for ultrahigh performance aqueous zinc-organic batteries. Angew. Chem. Int. Ed.. 2022, 612117511.

[27] Park JH, Kwak MJ, Hwang Cet al. . Self-assembling films of covalent organic frameworks enable long-term, efficient cycling of zinc-ion batteries. Adv. Mater.. 2021, 332101726.

[28] Zhao XJ, Pachfule P, Thomas A. Covalent organic frameworks (COFs) for electrochemical applications. Chem. Soc. Rev.. 2021, 506871-6913.

[29] Kong LJ, Liu M, Huang Het al. . Metal/covalent-organic framework based cathodes for metal-ion batteries. Adv. Energy Mater.. 2022, 12: 2100172.

[30] Wei CL, Tan LW, Zhang YCet al. . Covalent organic frameworks and their derivatives for better metal anodes in rechargeable batteries. ACS Nano. 2021, 1512741-12767.

[31] Sun BW, Sun ZX, Yang Yet al. . Covalent organic frameworks: their composites and derivatives for rechargeable metal-ion batteries. ACS Nano. 2024, 18: 28-66.

[32] Xu J, Tang WQ, Yang Cet al. . A highly conductive COF@CNT electrocatalyst boosting polysulfide conversion for Li-S chemistry. ACS Energy Lett.. 2021, 6: 3053-3062.

[33] Guo CF, Han B, Sun WWet al. . Hydrogen-bonded organic framework for high-performance lithium/sodium-iodine organic batteries. Angew. Chem. Int. Ed.. 2022, 61. e202213276

[34] Chu J, Liu ZL, Yu Jet al. . Boosting H⁺ storage in aqueous zinc ion batteries via integrating redox-active sites into hydrogen-bonded organic frameworks with strong π-π stacking. Angew. Chem. Int. Ed.. 2023, 63. e202314411

[35] Wang B, Lin RB, Zhang ZJet al. . Hydrogen-bonded organic frameworks as a tunable platform for functional materials. J. Am. Chem. Soc.. 2020, 142: 14399-14416.

[36] Lin ZJ, Mahammed SAR, Liu TFet al. . Multifunctional porous hydrogen-bonded organic frameworks: current status and future perspectives. ACS Cent. Sci.. 2022, 8: 1589-1608.

[37] Zhao R, Liang ZB, Zou RQet al. . Metal-organic frameworks for batteries. Joule. 2018, 2: 2235-2259.

[38] Tang XX, Liu C, Wang Het al. . Pristine metal-organic frameworks for next-generation batteries. Coord. Chem. Rev.. 2023, 494. 215361

[39] Soltani N, Bahrami A, Giebeler Let al. . Progress and challenges in using sustainable carbon anodes in rechargeable metal-ion batteries. Prog. Energy Combust. Sci.. 2021, 87. 100929

[40] Cao SC, Tan J, Ma LLet al. . Covalent organic frameworks-based functional separators for rechargeable batteries: design, mechanism, and applications. Energy Storage Mater.. 2024, 66. 103232

[41] Li C, Liu L, Kang JLet al. . Pristine MOF and COF materials for advanced batteries. Energy Storage Mater.. 2020, 31: 115-134.

[42] He TQ, Kang XY, Wang FJet al. . Capacitive contribution matters in facilitating high power battery materials toward fast-charging alkali metal ion batteries. Mater. Sci. Eng. R. Rep.. 2023, 154. 100737

[43] Jia C, Duan A, Liu Cet al. . One-dimensional covalent organic framework as high-performance cathode materials for lithium-ion batteries. Small. 2023, 19: 2300518.

[44] Zhao JJ, Zhou MM, Chen Jet al. . Two birds one stone: Graphene assisted reaction kinetics and ionic conductivity in phthalocyanine-based covalent organic framework anodes for lithium-ion batteries. Small. 2023, 192303353.

[45] Biswas S, Pramanik A, Dey Aet al. . 2D covalent organic framework covalently anchored with carbon nanotube as high-performance cathodes for lithium and sodium-ion batteries. Small. 2024, 202406173.

[46] Li X, Liu W, Wang Yet al. . A novel organic anode with 14 electrons participating in redox reactions prepared under mild conditions. Chem. Eng. J.. 2023, 473. 145310

[47] Qiu TY, Tang WS, Han Xet al. . Fluorine/sulfur-comodulated covalent organic frameworks cathode for high-performance lithium ion batteries. Chem. Eng. J.. 2023, 466. 143149

[48] Min Y, Guo L, Wei GYet al. . Enhancing the safety and cyclic performance of lithium-ion batteries using heat resistant and wettable separator based on covalent organic framework and polybenzimidazole. Chem. Eng. J.. 2022, 443. 136480

[49] Xu XJ, Liu J, Liu JWet al. . A general metal-organic framework (MOF)-derived selenidation strategy for in situ carbon-encapsulated metal selenides as high-rate anodes for Na-ion batteries. Adv. Funct. Mater.. 2018, 281707573.

[50] Zhai LP, Li GJ, Yang XBet al. . 30 Li⁺-accommodating covalent organic frameworks as ultralong cyclable high-capacity Li-ion battery electrodes. Adv. Funct. Mater.. 2022, 322108798.

[51] Tian ZN, Kale VS, Thomas Set al. . An ultrastable aqueous ammonium-ion battery using a covalent organic framework anode. Adv. Mater.. 2024, 362409354.

[52] Wakamatsu K, Yamaguchi Y, Furuno Set al. . Application of hydrogen-bonded organic frameworks with redox-active imide units as cathode-active materials in lithium- and sodium-ion batteries. ChemElectroChem. 2024, 11. e202300607

[53] Haldar S, Roy K, Kushwaha Ret al. . Chemical exfoliation as a controlled route to enhance the anodic performance of COF in LIB. Adv. Energy Mater.. 2019, 91902428.

[54] Cai JB, Wang JL, Yu Xet al. . ZnO quantum dots@covalent organic frameworks for high-performance alkaline zinc-based batteries. J. Mater. Chem. A. 2023, 1125692-25702.

[55] Lee J, Lim H, Park Jet al. . Fluorine-rich covalent organic framework to boost electrochemical kinetics and storages of K⁺ ions for potassium-ion battery. Adv. Energy Mater.. 2023, 13: 2300442.

[56] Wu MM, Zhao Y, Zhao RQet al. . Chemical design for both molecular and morphology optimization toward high-performance lithium-ion batteries cathode material based on covalent organic framework. Adv. Funct. Mater.. 2022, 322107703.

[57] Ge, J.M., Ma, C.S., Zhang, Y.Y., et al.: Edge electron effect induced high-entropy SEI for durable anode-free sodium batteries. Adv. Mater. 2413253 (2024). https://doi.org/10.1002/adma.202413253

[58] Gong WZ, Wan M, Zeng Ret al. . Ultrafine Prussian blue as a high-rate and long-life sodium-ion battery cathode. Energy Technol.. 2019, 71900108.

[59] Biswal BP, Chandra S, Kandambeth Set al. . Mechanochemical synthesis of chemically stable isoreticular covalent organic frameworks. J. Am. Chem. Soc.. 2013, 1355328-5331.

[60] Liu XL, Yang XY, Wang HLet al. . A robust redox-active hydrogen-bonded organic framework for rechargeable batteries. J. Mater. Chem. A. 2022, 10: 1808-1814.

[61] Zhang FY, Shen YL, Xu HHet al. . Bismuth nanoparticle-embedded carbon microrod for high-rate electrochemical magnesium storage. ACS Appl. Mater. Interfaces. 2023, 15: 23353-23360.

[62] Li CQ, Yu A, Zhao WKet al. . Extending the π-conjugation of a donor-acceptor covalent organic framework for high-rate and high-capacity lithium-ion batteries. Angew. Chem. Int. Ed.. 2024, 63: 2409421.

[63] Tang JL, Yang RX, Peng YTet al. . Ultra-thin hydrogen-organic-framework (HOF) nanosheets for ultra-stable alkali ions battery storage. Small. 2024, 202307827.

[64] Wu YL, Mao XN, Zhang MCet al. . 2D molecular sheets of hydrogen-bonded organic frameworks for ultrastable sodium-ion storage. Adv. Mater.. 2021, 332106079.

[65] Tang XX, Wang H, Fan Jet al. . CNT boosted two-dimensional flaky metal-organic nanosheets for superior lithium and potassium storage. Chem. Eng. J.. 2022, 430. 133023

[66] Ritchie LK, Trewin A, Reguera-Galan Aet al. . Synthesis of COF-5 using microwave irradiation and conventional solvothermal routes. Microporous Mesoporous Mater.. 2010, 132132-136.

[67] Wang JH, Jia HF, Liu ZLet al. . Anchoring π-d conjugated metal-organic frameworks with dual-active centers on carbon nanotubes for advanced potassium-ion batteries. Adv. Mater.. 2024, 36: 2305605.

[68] Xia YJ, Yang TL, Wang ZJet al. . Van der Waals forces between S and P ions at the CoP-C@MoS₂/C heterointerface with enhanced lithium/sodium storage. Adv. Funct. Mater.. 2023, 332302830.

[69] Feng YT, Xu MZ, He Tet al. . CoPSe: a new ternary anode material for stable and high-rate sodium/potassium-ion batteries. Adv. Mater.. 2021, 332007262.

[70] Tian YX, Liu NN, Li JLet al. . Covalent organic frameworks derived F/N co-doped porous carbon for potassium-ion batteries. J. Alloys Compd.. 2023, 952. 169998

[71] An YF, Zhang H, Geng DXet al. . Double redox-active polyimide-based covalent organic framework induced by lithium ion for boosting high-performance aqueous Zn²⁺ storage. Chem. Eng. J.. 2023, 477. 147275

[72] Tong YF, Sun ZP, Wang JWet al. . Covalent organic framework containing dual redox centers as an efficient anode in Li-ion batteries. SmartMat. 2022, 3685-694.

[73] Sinha N, Joshi H, Pakhira S. Lithium intercalation in covalent organic frameworks: a porous electrode material for lithium-ion batteries. ACS Appl. Electron. Mater.. 2022, 4: 6237-6252.

[74] Zhou R, Huang Y, Li ZHet al. . Piperazine-based two-dimensional covalent organic framework for high performance anodic lithium storage. Energy Storage Mater.. 2021, 40: 124-138.

[75] Chu J, Wang YX, Zhong FPet al. . Metal/covalent-organic frameworks for electrochemical energy storage applications. EcoMat. 2021, 3. e12133

[76] Wang S, Wang QY, Shao PPet al. . Exfoliation of covalent organic frameworks into few-layer redox-active nanosheets as cathode materials for lithium-ion batteries. J. Am. Chem. Soc.. 2017, 139: 4258-4261.

[77] Yan J, Cui YT, Xie Met al. . Immobilizing redox-active tricycloquinazoline into a 2D conductive metal-organic framework for lithium storage. Angew. Chem. Int. Ed.. 2021, 60: 24467-24472.

[78] Song GJ, Shi YX, Jiang Set al. . Recent progress in MOF-derived porous materials as electrodes for high-performance lithium-ion batteries. Adv. Funct. Mater.. 2023, 33: 2303121.

[79] Yan JJ, Gao CW, Qi SBet al. . Encapsulation of nano-Si into MOF glass to enhance lithium-ion battery anode performances. Nano Energy. 2022, 103. 107779

[80] Zhao H, Sheng L, Wang Let al. . The opportunity of metal organic frameworks and covalent organic frameworks in lithium (ion) batteries and fuel cells. Energy Storage Mater.. 2020, 33360-381.

[81] Gong L, Yang XY, Gao Yet al. . Two-dimensional covalent organic frameworks with p- and bipolar-type redox-active centers for organic high-performance Li-ion battery cathodes. J. Mater. Chem. A. 2022, 10: 16595-16601.

[82] Yang XB, Lin C, Han DDet al. . In situ construction of redox-active covalent organic frameworks/carbon nanotube composites as anodes for lithium-ion batteries. J. Mater. Chem. A. 2022, 10: 3989-3995.

[83] Wen YC, Wang XS, Yang Yet al. . Covalent organic framework-regulated ionic transportation for high-performance lithium-ion batteries. J. Mater. Chem. A. 2019, 7: 26540-26548.

[84] Chen XD, Li YS, Wang Let al. . High-lithium-affinity chemically exfoliated 2D covalent organic frameworks. Adv. Mater.. 2019, 31: 1901640.

[85] Zhang Y, Qiu TP, Jiang Fet al. . Spindle-like Ni₃(HITP)₂ MOFs: synthesis and Li⁺ storage mechanism. Appl. Surf. Sci.. 2021, 556. 149818

[86] Zheng JC, Yao YY, Mao GQet al. . Iron-zinc sulfide Fe₂Zn₃S₅/Fe_1−xS@C derived from a metal-organic framework as a high performance anode material for lithium-ion batteries. J. Mater. Chem. A. 2019, 716479-16487.

[87] Sun LJ, Wang HL, Zhai SLet al. . Edge-on-plane-confined covalent organic frameworks enable a defect- and nitrogen-rich carbon matrix for high-rate lithium-ion storage. ACS Appl. Energy Mater.. 2021, 4: 5957-5962.

[88] Ma P, Zhang YY, Li WBet al. . Tailoring alloy-reaction-induced semi-coherent interface to guide sodium nucleation and growth for long-term anode-less sodium-metal batteries. Sci. China Mater.. 2024, 67: 3648-3657.

[89] You Y, Wu XL, Yin YXet al. . High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries. Energy Environ. Sci.. 2014, 7: 1643-1647.

[90] Gu S, Wu SF, Cao LJet al. . Tunable redox chemistry and stability of radical intermediates in 2D covalent organic frameworks for high performance sodium ion batteries. J. Am. Chem. Soc.. 2019, 141: 9623-9628.

[91] Guo CF, Gao Y, Li SQet al. . Chemical-stabilized aldehyde-tuned hydrogen-bonded organic frameworks for long-cycle and high-rate sodium-ion organic batteries. Adv. Funct. Mater.. 2024, 34: 2314851.

[92] Wang LY, Cai ZP, Ma Cet al. . Poly(p-phenylenediamine)-coated metal-organic frameworks for high-performance sodium-ion batteries: the balance of capacity and stability. ACS Appl. Mater. Interfaces. 2023, 1544364-44372.

[93] Yuan WY, Weng JY, Ding MHet al. . Novel covalent organic framework/carbon nanotube composites with multiple redox-active sites for high-performance Na storage. Energy Storage Mater.. 2024, 65. 103142

[94] Li QH, Zhang W, Peng Jet al. . Metal-organic framework derived ultrafine Sb@Porous carbon octahedron via in situ substitution for high-performance sodium-ion batteries. ACS Nano. 2021, 15: 15104-15113.

[95] Xiao PT, Li S, Yu CBet al. . Interface engineering between the metal-organic framework nanocrystal and graphene toward ultrahigh potassium-ion storage performance. ACS Nano. 2020, 14: 10210-10218.

[96] Yang SH, Park SK, Kang YC. MOF-derived CoSe₂@N-doped carbon matrix confined in hollow mesoporous carbon nanospheres as high-performance anodes for potassium-ion batteries. Nano Micro Lett.. 2020, 13: 9.

[97] Cheng QH, Zhao X, Yang GYet al. . Recent advances of metal phosphates-based electrodes for high-performance metal ion batteries. Energy Storage Mater.. 2021, 41842-882.

[98] Li Y, Zhang JW, Chen MH. MOF-derived carbon and composites as advanced anode materials for potassium ion batteries: a review. Sustain. Mater. Technol.. 2020, 26. e00217

[99] Ho Na J, Kang YC, Park SK. Electrospun MOF-based ZnSe nanocrystals confined in N-doped mesoporous carbon fibers as anode materials for potassium ion batteries with long-term cycling stability. Chem. Eng. J.. 2021, 425. 131651

[100] Lu XL, Zhang DD, Zhong Jet al. . MOF-5 as anodes for high-temperature potassium-ion batteries with ultrahigh stability. Chem. Eng. J.. 2022, 432. 134416

[101] Na JH, Oh HG, Lee Set al. . Designing a 3D MXene microsphere encapsulating MOF-derived ZnSe nanoparticles as an anode for highly stable potassium-ion batteries. J. Mater. Chem. A. 2024, 12: 2848-2855.

[102] Yang MH, Zeng X, Xie Met al. . Conductive metal-organic framework with superior redox activity as a stable high-capacity anode for high-temperature K-ion batteries. J. Am. Chem. Soc.. 2024, 146: 6753-6762.

[103] Chen XL, Xie M, Zheng ZLet al. . Multiple accessible redox-active sites in a robust covalent organic framework for high-performance potassium storage. J. Am. Chem. Soc.. 2023, 145: 5105-5113.

[104] Hu RX, Sha DW, Cao Xet al. . Anchoring metal-organic framework-derived ZnTe@C onto elastic Ti₃C₂T_x MXene with 0D/2D dual confinement for ultrastable potassium-ion storage. Adv. Energy Mater.. 2022, 12: 2203118.

[105] Tong HG, Wang CL, Lu Jet al. . Energetic metal–organic frameworks derived highly nitrogen-doped porous carbon for superior potassium storage. Small. 2020, 162002771.

[106] Zang SL, Chu XK, Wang Het al. . Enhanced K-storage boosted by compatible ester-based electrolyte for COFs-derived non-graphitic carbon. Appl. Surf. Sci.. 2023, 630. 157530

[107] Chen XD, Liu JH, Jiang HXet al. . Metal organic framework-based cathode materials for aqueous zinc-ion batteries: recent advances and perspectives. Energy Storage Mater.. 2024, 65. 103168

[108] Wu XT, Luo L, Peng SNet al. . A universal fabrication strategy for MOFs-driven vanadium-based composite for aqueous zinc ion batteries. Chem. Eng. J.. 2024, 482. 148836

[109] Ru Y, Zheng SS, Xue HGet al. . Layered V-MOF nanorods for rechargeable aqueous zinc-ion batteries. Mater. Today Chem.. 2021, 21. 100513

[110] Li C, Zheng CM, Jiang HLet al. . Conductive flower-like Ni-PTA-Mn as cathode for aqueous zinc-ion batteries. J. Alloys Compd.. 2021, 882. 160587

[111] Li LH, Yang HH, Wang Xet al. . An anthraquinone-based covalent organic framework for highly reversible aqueous zinc-ion battery cathodes. J. Mater. Chem. A. 2023, 1126221-26229.

[112] Li HB, Cao MG, Fu ZLet al. . A covalent organic framework as a dual-active-center cathode for a high-performance aqueous zinc-ion battery. Chem. Sci.. 2024, 15: 4341-4348.

[113] Wang YY, Wang XL, Tang Jet al. . A quinoxalinophenazinedione covalent triazine framework for boosted high-performance aqueous zinc-ion batteries. J. Mater. Chem. A. 2022, 10: 13868-13875.

[114] Yang LX, Ma QY, Yin YLet al. . Construction of desolvated ionic COF artificial SEI layer stabilized Zn metal anode by in situ electrophoretic deposition. Nano Energy. 2023, 117. 108799

[115] Sang ZY, Liu JX, Zhang XQet al. . One-dimensional π-d conjugated conductive metal-organic framework with dual redox-active sites for high-capacity and durable cathodes for aqueous zinc batteries. ACS Nano. 2023, 17: 3077-3087.

[116] Deng SZ, Xu BG, Zhao JXet al. . Unlocking double redox reaction of metal-organic framework for aqueous zinc-ion battery. Angew. Chem. Int. Ed.. 2024, 63: 2401996.

[117] Khayum Met al. . Zinc ion interactions in a two-dimensional covalent organic framework based aqueous zinc ion battery. Chem. Sci.. 2019, 108889-8894.

[118] Fu YQ, Wei QL, Zhang GXet al. . High-performance reversible aqueous Zn-ion battery based on porous MnO_x nanorods coated by MOF-derived N-doped carbon. Adv. Energy Mater.. 2018, 8: 1801445.

[119] Zhong LH, Wang CF, He Jet al. . Self-charging aqueous Zn//COF battery with UltraHigh self-charging efficiency and rate. Adv. Mater.. 2024, 362314050.

[120] Zhuang RY, Miao G, Huang ZLet al. . Non-stoichiometric CoS_1.097 nanoparticles prepared from CoAl-layered double hydroxide and MOF template as cathode materials for aluminum-ion batteries. J. Energy Chem.. 2021, 54639-643.

[121] Hu YX, Huang HJ, Yu DSet al. . All-climate aluminum-ion batteries based on binder-free MOF-derived FeS₂@C/CNT cathode. Nano Micro Lett.. 2021, 13: 159.

[122] Wang L, Zhu GY, Lin YHet al. . MOF-derived hierarchical porous carbon octahedrons for aluminum-ion batteries. Carbon. 2023, 202305-313.

[123] Li XY, Wu AY, Gao CTet al. . Copper hexacyanoferrate as a long-life cathode for aqueous aluminum ion batteries. Mater. Today Energy. 2023, 31. 101205

[124] Guo YX, Wang W, Lei HPet al. . Alternate storage of opposite charges in multisites for high-energy-density Al-MOF batteries. Adv. Mater.. 2022, 34: 2110109.

[125] Jin JZ, Zhang RY, Zhi XDet al. . Aluminum vacancy-rich MOF-derived carbon nanosheets for high-capacity and long-life aqueous aluminum-ion battery. EcoEnergy. 2024, 2466-477.

[126] Hong H, Liu JL, Huang HWet al. . Ordered macro-microporous metal-organic framework single crystals and their derivatives for rechargeable aluminum-ion batteries. J. Am. Chem. Soc.. 2019, 141: 14764-14771.

[127] Peng XY, Baktash A, Alghamdi Net al. . Boosting aluminum storage in highly stable covalent organic frameworks with abundant accessible carbonyl groups. Adv. Energy Mater.. 2024, 14: 2400147.

[128] Lu HY, Ning FY, Jin Ret al. . Two-dimensional covalent organic frameworks with enhanced aluminum storage properties. Chemsuschem. 2020, 133447-3454.

[129] Kuperman N, Padigi P, Goncher Get al. . High performance Prussian blue cathode for nonaqueous Ca-ion intercalation battery. J. Power. Sources. 2017, 342: 414-418.

[130] Vo TN, Kang JE, Lee Het al. . Ultra-stable calcium ion batteries with Prussian blue nanodisks. EcoMat. 2023, 5. e12285

[131] Li LY, Zhang GB, Deng XMet al. . A covalent organic framework for high-rate aqueous calcium-ion batteries. J. Mater. Chem. A. 2022, 10: 20827-20836.

[132] Zhang SQ, Zhu YL, Ren SYet al. . Covalent organic framework with multiple redox active sites for high-performance aqueous calcium ion batteries. J. Am. Chem. Soc.. 2023, 145: 17309-17320.

[133] Wang CF, Li R, Zhu YCet al. . A pyrazine-pyridinamine covalent organic framework as a low potential anode for highly durable aqueous calcium-ion batteries. Adv. Energy Mater.. 2024, 14: 2302495.

[134] Dong PP, Zhang XH, Hiscox Wet al. . Toward high-performance metal-organic-framework-based quasi-solid-state electrolytes: tunable structures and electrochemical properties. Adv. Mater.. 2023, 352211841.

[135] Liu HL, Pan HG, Yan Met al. . Extraordinary ionic conductivity excited by hierarchical ion-transport pathways in MOF-based quasi-solid electrolytes. Adv. Mater.. 2023, 352300888.

[136] Wang ZF, Zhang YS, Zhang PHet al. . Thermally rearranged covalent organic framework with flame-retardancy as a high safety Li-ion solid electrolyte. eScience. 2022, 2311-318.

[137] Zhang JM, Wu YT, Wang CYet al. . Hydrogen-bonded organic framework-ionic liquid composite quasi-solid electrolyte for high-performance lithium battery. Nano Res.. 2025, 18: 94906993.

[138] Zhang SP, Ling FX, Wang LFet al. . An open-ended Ni₃S₂-Co₉S₈ heterostructures nanocage anode with enhanced reaction kinetics for superior potassium-ion batteries. Adv. Mater.. 2022, 342201420.

[139] Zhao MY, Cheng WD, Wang Xet al. . A study on the nanostructural evolution of Bi/C anode materials during their first charge/discharge processes. Materials. 2024, 171140.

[140] Huang HW, Wang JW, Yang XFet al. . Unveiling the advances of nanostructure design for alloy-type potassium-ion battery anodes via in situ TEM. Angew. Chem. Int. Ed.. 2020, 5914504-14510.

[141] Zhang K, Li CX, Liu JWet al. . Defect-rich functional HfO_2−x for highly reversible Zn metal anode. Small. 2024, 20: 2306406.

[142] Deng SZ, Yuan ZSet al. . Electrochemically induced metal-organic-framework-derived amorphous V2O5 for superior rate aqueous zinc-ion batteries. Angew. Chem. Int. Ed.. 2020, 5922002-22006.

[143] Ke SW, Li W, Gao Let al. . Integrating multiple redox-active units into conductive covalent organic frameworks for high-performance sodium-ion batteries. Angew. Chem. Int. Ed.. 2024.

[144] Kang RK, Du YQ, Zhang DMet al. . Enhanced Al-storage performance by electronic properties optimization and structural customization in MOF-derived heterostructure. Adv. Funct. Mater.. 2024, 34: 2315603.

[145] Zhang B, Xu BH, Xiao ZMet al. . Inner-stress-dissipative, rapid self-healing core-shell sulfide quantum dots for remarkable potassium-ion storage. Energy Storage Mater.. 2023, 5696-107.

[146] Nandy A, Duan CR, Kulik HJ. Using machine learning and data mining to leverage community knowledge for the engineering of stable metal-organic frameworks. J. Am. Chem. Soc.. 2021, 143: 17535-17547.

[147] Luo Y, Bag S, Zaremba Oet al. . MOF synthesis prediction enabled by automatic data mining and machine learning. Angew. Chem. Int. Ed.. 2022, 61. e202200242

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