Scalable Jet-Based Fabrication of PEI-Hydrogel Particles for CO₂ Capture

Abstract

The capture, regeneration, and conversion of CO₂ from ambient air and flue gas streams are critical aspects of mitigating global warming. Solid sorbents for CO₂ absorption are very promising as they have high mass transfer areas without energy input and reduce emissions and minimize corrosion as compared to liquid sorbents. However, precisely tunable solid CO₂ sorbents are difficult to produce. Here, we demonstrate the high-throughput production of hydrogel-based CO₂-absorbing particles via liquid jetting. By wrapping a liquid jet consisting of an aqueous solution of cross-linkable branched polyethylenimine (PEI) with a layer of suspension containing hydrophobic silica nanoparticles, monodisperse droplets with a silica nanoparticle coating layer was formed in the air. A stable Pickering emulsion containing PEI droplets was obtained after these ejected droplets were collected in a heated oil bath. The droplets turn into mm-sized particles after thermal curing in the bath. The diameter, PEI content, and silica content of the particles were systematically varied, and their CO₂ absorption was measured as a function of time. Steam regeneration of the particles enabled cyclic testing, revealing a CO₂ absorption capacity of 6.5 ± 0.5 mol kg⁻¹ solid PEI in pure CO₂ environments and 0.7 ± 0.3 mol kg⁻¹ solid PEI for direct air capture. Several thousands of particles were produced per second at a rate of around 0.5 kg per hour, with a single nozzle. This process can be further scaled by parallelization. The complete toolbox for the design, fabrication, testing, and regeneration of functional hydrogel particles provides a powerful route toward novel solid sorbents for regenerative CO₂ capture.

Keywords

CO ₂ capture / droplet / hydrogel / liquid jet / particle / steam regeneration

References

[1] “Global Climate Change: Evidence” NASA Global Climate Change and Global Warming: Vital Signs of the Planet Jet Propulsion Laboratory/National Aeronautics and Space Administration. https://climate.nasa.gov/vital-signs/carbon-dioxide/(Accessed January, 2022).

[2] A. Goeppert, M. Czaun, R. B. May, G. K. S. Prakash, G. A. Olah, S. R. Narayanan, J. Am. Chem. Soc. 2011, 133, 20164.

[3] P. Bains, P. Psarras, J. Wilcox, Prog. Energy Combust. Sci. 2017, 63, 146.

[4] G. T. Rochelle, Science 2009, 325, 1652.

[5] P. H. M. Feron, Absorption-based post-combustion capture of carbon dioxide, Woodhead Publishing, Amsterdam 2016.

[6] A. E. Poste, M. Grung, R. F. Wright, Sci. Total Environ. 2014, 481, 274.

[7] D. M. D’Alessandro, B. Smit, J. R. Long, Angew. Chem. Int. Ed. 2010, 49, 6058.

[8] G. Qi, Y. Wang, L. Estevez, X. Duan, N. Anako, A.-H. A. Park, W. Li, C. W. Jones, E. P. Giannelis, Energ. Environ. Sci. 2011, 4, 444.

[9] S. Meth, A. Goeppert, G. K. S. Prakash, G. A. Olah, Energy Fuel 2012, 26, 3082.

[10] X. Xu, C. Heath, B. Pejcic, C. D. Wood, J. Mater. Chem. A 2018, 6, 4829.

[11] C. White, E. Adam, Y. Sabri, M. B. Myers, B. Pejcic, C. D. Wood, Ind. Engin. Chem. Res. 2021, 60, 14758.

[12] D. Nagai, A. Suzuki, T. Kuribayashi, Macromol. Rapid Commun. 2011, 32, 404.

[13] M. Yue, K. Imai, C. Yamashita, Y. Miura, Y. Hoshino, Macromol. Chem. Phys. 2017, 218, 1600570.

[14] M. Yue, Y. Hoshino, Y. Ohshiro, K. Imamura, Y. Miura, Angew. Chem. Int. Ed. 2014, 53, 2654.

[15] J. Gao, Y. Liu, Y. Terayama, K. Katafuchi, Y. Hoshino, G. Inoue, Chem. Eng. J. 2020, 401, 126059.

[16] X. Xu, M. B. Myers, F. G. Versteeg, B. Pejcic, C. Heath, C. D. Wood, Chem. Commun. 2020, 56, 7151.

[17] X. Xu, B. Pejcic, C. Heath, C. D. Wood, J. Mater. Chem. A 2018, 6, 21468.

[18] R. D. Aines, C. M. Spaddaccini, E. B. Duoss, J. K. Stolaroff, J. Vericella, J. A. Lewis, G. Farthing, Energy Procedia 2013, 37, 219.

[19] J. J. Vericella, S. E. Baker, J. K. Stolaroff, E. B. Duoss, J. O. Hardin, J. Lewicki, E. Glogowski, W. C. Floyd, C. A. Valdez, W. L. Smith, J. H. Satcher, W. L. Bourcier, C. M. Spadaccini, J. A. Lewis, R. D. Aines, Nat. Commun. 2015, 6, 6124.

[20] S. Nawar, J. K. Stolaroff, C. Ye, H. Wu, D. T. Nguyen, F. Xin, D. A. Weitz, Lab Chip 2020, 20, 147.

[21] S. Battat, D. A. Weitz, G. M. Whitesides, Lab Chip 2022, 22, 530.

[22] A. R. Sujan, S. H. Pang, G. Zhu, C. W. Jones, R. P. Lively, ACS Sustain. Chem. Eng. 2019, 7, 5264.

[23] C. W. Visser, T. Kamperman, L. P. Karbaat, D. Lohse, M. Karperien, Sci. Adv. 2018, 4, eaao1175.

[24] T. Kamperman, V. D. Trikalitis, M. Karperien, C. W. Visser, J. Leijten, ACS Appl. Mater. Interfaces 2018, 10, 23433.

[25] M. A. Sakwa-Novak, S. Tan, C. W. Jones, ACS Appl. Mater. Interfaces 2015, 7, 24748.

[26] N. K. Sandhu, D. Pudasainee, P. Sarkar, R. Gupta, Ind. Eng. Chem. Res. 2016, 55, 2210.

[27] X. Shen, H. Du, R. H. Mullins, R. R. Kommalapati, Energ. Technol. 2017, 5, 822.

[28] J. Jiang, A. T. Poortinga, Y. Liao, T. Kamperman, C. H. Venner, C. W. Visser, Adv. Mater. 2023, 35, 2208894.

[29] E. J. Kim, R. L. Siegelman, H. Z. H. Jiang, A. C. Forse, J.-H. Lee, J. D. Martell, P. J. Milner, J. M. Falkowski, J. B. Neaton, J. A. Reimer, S. C. Weston, J. R. Long, Science 2020, 369, 392.

[30] J. M. Kolle, M. Fayaz, A. Sayari, Chem. Rev. 2021, 121, 7280.

[31] J. Jiang, G. Shea, P. Rastogi, T. Kamperman, C. H. Venner, C. W. Visser, Adv. Mater. 2021, 33, 2006336.

[32] J. K. Nunes, S. S. H. Tsai, J. Wan, H. A. Stone, J. Phys. D Appl. Phys. 2013, 46, 114002.

[33] M. Yew, Y. Ren, K. S. Koh, C. Sun, C. Snape, Y. Yan, Energy Procedia 2019, 160, 443.

[34] P.-Y. Gu, F. Zhou, G. Xie, P. Y. Kim, Y. Chai, Q. Hu, S. Shi, Q.-F. Xu, F. Liu, J.-M. Lu, T. P. Russell, Angew. Chem. Int. Ed. 2021, 60, 8694.

[35] Y. Chai, J. Hasnain, K. Bahl, M. Wong, D. Li, P. Geissler, P. Y. Kim, Y. Jiang, P. Gu, S. Li, D. Lei, B. A. Helms, T. P. Russell, P. D. Ashby, Sci. Adv. 2020, 6, eabb8675.

[36] A. R. Studart, H. C. Shum, D. A. Weitz, J. Phys. Chem. B 2009, 113, 3914.

[37] D. Cai, P. S. Clegg, Chem. Commun. 2015, 51, 16984.

[38] X. Li, Y. Xue, P. Lv, H. Lin, F. Du, Y. Hu, J. Shen, H. Duan, Soft Matter 2016, 12, 1655.

[39] F. Farhang, A. V. Nguyen, K. B. Sewell, Energy Fuel 2014, 28, 7025.

[40] B. O. Carter, W. Wang, D. J. Adams, A. I. Cooper, Langmuir 2010, 26, 3186.

[41] N. N. Nguyen, A. V. Nguyen, Energy Fuel 2017, 31, 10311.

[42] J. Bao, W.-H. Lu, J. Zhao, X. T. Bi, Carbon Res. Convers. 2018, 1, 183.

[43] R. Rodríguez-Mosqueda, E. A. Bramer, G. Brem, Chem. Eng. Sci. 2018, 189, 114.

[44] B.-K. Na, K.-K. Koo, H.-M. Eum, H. Lee, H. K. Song, Korean J. Chem. Eng. 2001, 18, 220.

[45] F. Foeth, M. Andersson, H. Bosch, G. Aly, T. Reith, Sep. Sci. Technol. 1994, 29, 93.

[46] V. R. Choudhary, S. Mayadevi, A. P. Singh, J. Chem. Soc. Faraday Trans. 1995, 91, 2935.

[47] P. J. E. Harlick, F. H. Tezel, Sep. Purif. Technol. 2003, 33, 199.

[48] S. Lee, T. P. Filburn, M. Gray, J.-W. Park, H.-J. Song, Ind. Eng. Chem. Res. 2008, 47, 7419.

[49] P. D. Jadhav, R. V. Chatti, R. B. Biniwale, N. K. Labhsetwar, S. Devotta, S. S. Rayalu, Energy Fuel 2007, 21, 3555.

[50] J. H. Drese, S. Choi, R. P. Lively, W. J. Koros, D. J. Fauth, M. L. Gray, C. W. Jones, Adv. Funct. Mater. 2009, 19, 3821.

[51] A. C. C. Chang, S. S. C. Chuang, M. Gray, Y. Soong, Energy Fuel 2003, 17, 468.

[52] G. Qi, L. Fu, B. H. Choi, E. P. Giannelis, Energ. Environ. Sci. 2012, 5, 7368.

[53] M. L. Sarazen, M. A. Sakwa-Novak, E. W. Ping, C. W. Jones, ACS Sustain. Chem. Eng. 2019, 7, 7338.

[54] J. Wang, H. Chen, H. Zhou, X. Liu, W. Qiao, D. Long, L. Ling, J. Environ. Sci. 2013, 25, 124.

[55] G.-J. Shin, K. Rhee, S.-J. Park, Int. J. Hydrogen Energy 2016, 41, 14351.

[56] H. He, L. Zhuang, S. Chen, H. Liu, Q. Li, Green Chem. 2016, 18, 5859.

[57] J.-T. Anyanwu, Y. Wang, R. T. Yang, Chem. Eng. J. 2022, 427, 131561.

[58] Y. J. Min, A. Ganesan, M. J. Realff, C. W. Jones, ACS Appl. Mater. Interfaces 2022, 14, 40992.

[59] L. B. Hamdy, A. Gougsa, W. Y. Chow, J. E. Russell, E. García-Díez, V. Kulakova, S. Garcia, A. R. Barron, M. Taddei, E. Andreoli, Mater. Adv. 2022, 3, 3174.

[60] A. Samanta, A. Zhao, G. K. H. Shimizu, P. Sarkar, R. Gupta, Ind. Eng. Chem. Res. 2012, 51, 1438.

[61] A. M. Varghese, G. N. Karanikolos, Int. J. Greenhouse Gas Contr. 2020, 96, 103005.

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