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Abstract
In this study, wearable triboelectric nanogenerators comprising bar-printed polyvinylidene fluoride (PVDF) films incorporated with cobalt-based metal–organic framework (Co-MOF) were developed. The enhanced output performance of the TENGs was attributed to the phase transition of PVDF from α-crystals to β-crystals, as facilitated by the incorporation of the MOF. The synthesis conditions, including metal ion, concentration, and particle size of the MOF, were optimized to increase open-circuit voltage (VOC) and open-circuit current (ISC) of PVDF-based TENGs. In addition to high operational stability, mechanical robustness, and long-term reliability, the developed TENG consisting of PVDF incorporated with Co-MOF (Co-MOF@PVDF) achieved a VOC of 194 V and an ISC of 18.8 µA. Furthermore, the feasibility of self-powered mobile electronics was demonstrated by integrating the developed wearable TENG with rectifier and control units to power a global positioning system (GPS) device. The local position of the user in real-time through GPS was displayed on a mobile interface, powered by the battery charged through friction-induced electricity generation.
Keywords
bar printing
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phase transition
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polyvinylidene fluoride incorporated with cobalt-based metal–organic framework
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self-powered mobile electronics
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wearable triboelectric nanogenerators
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Myeong-Hyeon Kim, Sang-Joon Park, Tae-Jun Ha.
Wearable Triboelectric Nanogenerators Based on Printed Polyvinylidene Fluoride Films Incorporated with Cobalt-Based Metal–Organic Framework for Self-Powered Mobile Electronics.
Energy & Environmental Materials, 2024, 7(4): e12675 DOI:10.1002/eem2.12675
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2023 The Authors. Energy & Environmental Materials published by John Wiley & Sons Australia, Ltd on behalf of Zhengzhou University.
