Thick Electrodes of a Self-Assembled MXene Hydrogel Composite for High-Rate Energy Storage

Leiqiang Qin; Jianxia Jiang; Lintao Hou; Fengling Zhang; Johanna Rosen

doi:10.1002/eem2.12653

Energy & Environmental Materials ›› 2024, Vol. 7 ›› Issue (4) : e12653 DOI: 10.1002/eem2.12653

RESEARCH ARTICLE

Thick Electrodes of a Self-Assembled MXene Hydrogel Composite for High-Rate Energy Storage

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Abstract

Supercapacitors based on two-dimensional MXene (Ti₃C₂T_z) have shown extraordinary performance in ultrathin electrodes with low mass loading, but usually there is a significant reduction in high-rate performance as the thickness increases, caused by increasing ion diffusion limitation. Further limitations include restacking of the nanosheets, which makes it challenging to realize the full potential of these electrode materials. Herein, we demonstrate the design of a vertically aligned MXene hydrogel composite, achieved by thermal-assisted self-assembled gelation, for high-rate energy storage. The highly interconnected MXene network in the hydrogel architecture provides very good electron transport properties, and its vertical ion channel structure facilitates rapid ion transport. The resulting hydrogel electrode show excellent performance in both aqueous and organic electrolytes with respect to high capacitance, stability, and high-rate capability for up to 300 µm thick electrodes, which represents a significant step toward practical applications.

Keywords

energy storage / high-rate / hydrogel / MXene / self-assemble

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Leiqiang Qin, Jianxia Jiang, Lintao Hou, Fengling Zhang, Johanna Rosen. Thick Electrodes of a Self-Assembled MXene Hydrogel Composite for High-Rate Energy Storage. Energy & Environmental Materials, 2024, 7(4): e12653 DOI:10.1002/eem2.12653

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