Stable Cycling of All-Solid-State Lithium Metal Batteries Enabled by Salt Engineering of PEO-Based Polymer Electrolytes

Lujuan Liu; Tong Wang; Li Sun; Tinglu Song; Hao Yan; Chunli Li; Daobin Mu; Jincheng Zheng; Yang Dai

doi:10.1002/eem2.12580

Energy & Environmental Materials ›› 2024, Vol. 7 ›› Issue (2) :12580 DOI: 10.1002/eem2.12580

RESEARCH ARTICLE

Stable Cycling of All-Solid-State Lithium Metal Batteries Enabled by Salt Engineering of PEO-Based Polymer Electrolytes

Lujuan Liu ¹
, Tong Wang ¹
, Li Sun ¹
, Tinglu Song ²
, Hao Yan ¹^,^†
, Chunli Li ²^,^†
, Daobin Mu ²^,^†
, Jincheng Zheng ³
, Yang Dai ¹^,^†

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Abstract

Poly (ethylene oxide) (PEO)-based polymer electrolytes show the prospect in all-solid-state lithium metal batteries; however, they present limitations of low room-temperature ionic conductivity, and interfacial incompatibility with high voltage cathodes. Therefore, a salt engineering of 1, 1, 2, 2, 3, 3-hexafluoropropane-1, 3-disulfonimide lithium salt (LiHFDF)/LiTFSI system was developed in PEO-based electrolyte, demonstrating to effectively regulate Li ion transport and improve the interfacial stability under high voltage. We show, by manipulating the interaction between PEO matrix and TFSI^--HFDF^-, the optimized solid-state polymer electrolyte achieves maximum Li⁺ conduction of 1.24 × 10^-4 S cm^-1 at 40 ℃, which is almost 3 times of the baseline. Also, the optimized polymer electrolyte demonstrates outstanding stable cycling in the LiFePO₄/Li and LiNi_0.8Mn_0.1Co_0.1O₂/Li (3.0-4.4 V, 200 cycles) based all-solid-state lithium batteries at 40 ℃.

Keywords

all-solid-state battery / high voltage / li-ion conductivity / molecular interaction / poly(ethylene oxide)

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Lujuan Liu, Tong Wang, Li Sun, Tinglu Song, Hao Yan, Chunli Li, Daobin Mu, Jincheng Zheng, Yang Dai. Stable Cycling of All-Solid-State Lithium Metal Batteries Enabled by Salt Engineering of PEO-Based Polymer Electrolytes. Energy & Environmental Materials, 2024, 7(2): 12580 DOI:10.1002/eem2.12580

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