Numeric study on solar-driven pyrolysis of plastic waste

Kuangdong Jiang , Yuhan Jin , Yibo Wu , Yang Liu , Yaning Zhang , Ruming Pan

Energy, Ecology and Environment ›› 2025, Vol. 10 ›› Issue (6) : 789 -803.

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Energy, Ecology and Environment ›› 2025, Vol. 10 ›› Issue (6) :789 -803. DOI: 10.1007/s40974-025-00372-w
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Numeric study on solar-driven pyrolysis of plastic waste

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Abstract

Pyrolysis is a technology that converts plastics into fuel or chemicals at high temperatures, offering significant advantages over other plastic waste disposal methods. Currently, the energy required for plastic pyrolysis usually comes directly or indirectly from fossil fuels, thus causing carbon emissions. This study investigates a plastic pyrolysis method using solar energy as the heat source, aiming to reduce carbon emissions and achieve carbon neutrality. A numerical model was developed to investigate temperature distribution, reaction rates, yields, and energy utilization in plastic pyrolysis. Simulation results indicated that under certain conditions, the plastic conversion exceeded 73%, with an energy efficiency above 17.3%. Heat flux, structural parameters of porous medium and inlet parameters of plastic are the key factors affecting the plastic pyrolysis. Heat flux had a significant impact on the system performance, plastic conversion remained below 30% when heat flux was below 0.3  

MW/m2
. Structural parameters of porous medium affected the reaction through both temperature and heat transfer process, which made their impact more complex. Reducing the plastic inlet speed and increasing the temperature can improve the plastic conversion and increase the proportion of oil and gas components in the product.

Keywords

Solar energy / Plastic waste / Pyrolysis / Simulation / Porous media

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Kuangdong Jiang, Yuhan Jin, Yibo Wu, Yang Liu, Yaning Zhang, Ruming Pan. Numeric study on solar-driven pyrolysis of plastic waste. Energy, Ecology and Environment, 2025, 10(6): 789-803 DOI:10.1007/s40974-025-00372-w

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References

[1]

Aboulkas A, El Bouadili AJEC. Thermal degradation behaviors of polyethylene and polypropylene. Part I: Pyrolysis kinetics and mechanisms. Energy Convers Manag, 2010, 51(7): 1363-1369

[2]

Acomb JC, Wu C, Williams PT. The use of different metal catalysts for the simultaneous production of carbon nanotubes and hydrogen from pyrolysis of plastic feedstocks. Appl Catal B Environ, 2016, 180: 497-510

[3]

Bazargan A, McKay G. A review–synthesis of carbon nanotubes from plastic wastes. Chem Eng J, 2012, 195: 377-391

[4]

Cahyono MS, Styana UIF. Influence of heating rate and temperature on the yield and properties of pyrolysis oil obtained from waste plastic bag. Conserv J Energy Environ Stud, 2017, 1: 1-8

[5]

Chang SH. Plastic waste as pyrolysis feedstock for plastic oil production: a review. Sci Total Environ, 2023, 877 162719

[6]

Chen X, Wang F, Han Y, Yu R, Cheng Z. Thermochemical storage analysis of the dry reforming of methane in foam solar reactor. Energy Convers Manage, 2018, 158: 489-498

[7]

Dai L, Ruan R, You S, Lei H. Paths to sustainable plastic waste recycling. Science, 2022, 377(6609): 934-934

[8]

Debenest G, Guibert R, Horgue P, Yang C. Numerical simulation of solid combustion in microporous particles. Front Chem, 2020, 8 510686

[9]

Ding K, Xiong Q, Zhong Z, Zhong D, Zhang Y. CFD simulation of combustible solid waste pyrolysis in a fluidized bed reactor. Powder Technol, 2020, 362: 177-187

[10]

Dong Q, Lele AD, Zhao X, Li S, Cheng S, Wang Y, Cui M, Guo M, Brozena AH, Lin Y, Li T (2023) Depolymerization of plastics by means of electrified spatiotemporal heating. Nature 616(7957):488–494.https://www.nature.com/articles/s41586-023-05845-8

[11]

Feng B, Jing Y, Liu X, Guo Y, Wang Y. Waste PVC upcycling: transferring unmanageable Cl species into value-added Cl-containing chemicals. Appl Catal B Environ, 2023, 331 122671

[12]

Gourmelon G. Global plastic production rises, recycling lags. Vital Signs, 2015, 22: 91-95

[13]

Huang H, Lin M. Optimization of solar receivers for high-temperature solar conversion processes: direct vs. indirect illumination designs. Appl Energy, 2021, 304 117675

[14]

Jamradloedluk J, Lertsatitthanakorn C. Characterization and utilization of char derived from fast pyrolysis of plastic wastes. Procedia Eng, 2014, 69: 1437-1442

[15]

Jiang G, Fenwick R, Seville J, Mahood HB, Thorpe RB, Bhattacharya S, Monsalve DS, Leeke GA. Lumped kinetic modelling of polyolefin pyrolysis: a non-isothermal method to estimate rate constants. J Anal Appl Pyrolysis, 2022, 164 105530

[16]

Kazour M, Terki S, Rabhi K, Jemaa S, Khalaf G, Amara R. Sources of microplastics pollution in the marine environment: importance of wastewater treatment plant and coastal landfill. Mar Pollut Bull, 2019, 146: 608-618

[17]

Liang JZ. Effects of extrusion rate, temperature, and die diameter on melt flow properties during capillary flow of low-density-polyethylene. Polym-Plast Technol Eng, 2007, 46(3): 245-249

[18]

Liu Y, Pan R, Ansart R, Debenest G. Numerical simulation of solar-driven biomass gasification by using ceramic foam. Process Saf Environ Prot, 2024, 184: 300-313

[19]

Liu J, Li Y, Deng W, Wu Y, Chen D, Zhang X, Liu X, Han L. Study on a potential bone char catalyst for high efficiency catalytic pyrolysis of polypropylene plastic. Fuel, 2025, 381 133625

[20]

Luo H, Yao D, Zeng K, Li J, Yan S, Zhong D, Hu J, Yang H, Chen H. Solar pyrolysis of waste plastics with photothermal catalysts for high-value products. Fuel Process Technol, 2022, 230 107205

[21]

Miry SZ, Zanoni MA, Rashwan TL, Torero JL, Gerhard JI. Investigation of applied smouldering in different conditions: the effect of oxygen mass flux. Fuel Process Technol, 2023, 250 107849

[22]

Oehlmann J, Schulte-Oehlmann U, Kloas W, Jagnytsch O, Lutz I, Kusk KO, Wollenberger L, Santos EM, Paull GC, Van Look KJ, Tyler CR. A critical analysis of the biological impacts of plasticizers on wildlife. Philos Trans R Soci B: Biol Sci, 2009, 364(1526): 2047-2062

[23]

Pan R, Martins MF, Debenest G. Pyrolysis of waste polyethylene in a semi-batch reactor to produce liquid fuel: optimization of operating conditions. Energy Convers Manag, 2021, 237 114114

[24]

Pan R, Wu Y, Guene Lougou B, Shuai Y, Debenest G. Numerical study on waste polyethylene pyrolysis driven by self-sustaining smoldering. Sci China Technol Sci, 2024, 67(2): 627-638

[25]

Pan R, Yang Y, Lougou BG, Wu L, Wang W, Guo Y, Shuai Y. Thermal performance evaluation of a novel solar-driven pyrolysis reactor. Energy, 2024, 313 134051

[26]

Pinto F, Costa P, Gulyurtlu I, Cabrita I. Pyrolysis of plastic wastes. 1. Effect of plastic waste composition on product yield. J Anal Appl Pyrolysis, 1999, 51(1–2): 39-55

[27]

Sarker M, Rashid MM, Molla M. Waste polypropylene plastic conversion into liquid hydrocarbon fuel for producing electricity and energies. Environ Technol, 2012, 33(24): 2709-2721

[28]

Saebea D, Ruengrit P, Arpornwichanop A, & Patcharavorachot Y (2020) Gasification of plastic waste for synthesis gas production. Energy Rep 6:202–207. https://doi.org/10.1016/j.egyr.2019.08.043

[29]

Shi X, Wu H, Jin P, Zhang Y, Zhang Y, Jiao F, Zhang Y, Cao W. On the influence of material and shape of the hot particles on the ignition characteristics of coal dust. Energy, 2023, 281 128192

[30]

Singh RK, Ruj B, Sadhukhan AK, Gupta P. Thermal degradation of waste plastics under non-sweeping atmosphere: Part 1: Effect of temperature, product optimization, and degradation mechanism. J Environ Manage, 2019, 239: 395-406

[31]

Soni VK, Singh G, Vijayan BK, Chopra A, Kapur GS, Ramakumar SSV. Thermochemical recycling of waste plastics by pyrolysis: a review. Energy Fuels, 2021, 35(16): 12763-12808

[32]

Tee MY, Wang D, Wong KL, Lee TZE, Chong WWF, Ng JH, Chong CT, Zakaria ZA, Mong GR. Investigating waste valorization potential through the co-pyrolysis of waste activated sludge and polyethylene terephthalate: analysis on thermal degradation behavior, kinetic properties and by-products. Energy Convers Manage, 2025, 325 119412

[33]

Vafai K, Tien CL. Boundary and inertia effects on flow and heat transfer in porous media. Int J Heat Mass Transfer, 1981, 24(2): 195-203

[34]

Wang F, Shuai Y, Tan H, Yu C. Thermal performance analysis of porous media receiver with concentrated solar irradiation. Int J Heat Mass Transf, 2013, 62: 247-254

[35]

Wang F, Tan J, Yong S, Tan H, Chu S. Thermal performance analyses of porous media solar receiver with different irradiative transfer models. Int J Heat Mass Transfer, 2014, 78: 7-16

[36]

Yang H, Nuran Zaini I, Pan R, Jin Y, Wang Y, Li L, Caballero JJB, Shi Z, Subasi Y, Nurdiawati A, Wang S. Distributed electrified heating for efficient hydrogen production. Nat Commun, 2024, 15(13868

[37]

Yim H, Valizadeh S, Cho K, Park YK. Production of low-aromatic oil from catalytic pyrolysis of waste plastics-derived wax. J Anal Appl Pyrolysis, 2025

[38]

Zanoni MA, Wang J, Gerhard JI. Understanding pressure changes in smouldering thermal porous media reactors. Chem Eng J, 2021, 412 128642

[39]

Zhang H, Shuai Y, Lougou BG, Jiang B, Wang F, Cheng Z, Tan H. Effects of multilayer porous ceramics on thermochemical energy conversion and storage efficiency in solar dry reforming of methane reactor. Appl Energy, 2020, 265 114799

[40]

Zhang H, Shuai Y, Lougou BG, Jiang B, Yang D, Pan Q, Wang F, Huang X. Effects of foam structure on thermochemical characteristics of porous-filled solar reactor. Energy, 2022, 239 122219

Funding

National Key Research and Development Program of China(2024YFE0116800)

Natural Science Foundation of Heilongjiang Province, China(LH2024E040)

RIGHTS & PERMISSIONS

The Author(s), under exclusive licence to the International Society of Energy and Environmental Science

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