Catalytic methane decomposition process on carbon-based catalyst under contactless induction heating

Abstract

Hydrogen obtained from decomposition of natural gas with direct sequestration of carbon in solid form could be an attractive and cost-effective alternative for large-scale hydrogen production. We report here the use of a carbon-based catalyst to achieve the catalytic decomposition of methane (CMD) at medium temperature, 800 °C, under induction heating (IH). Analyses of the catalytic results and characterizations of the spent catalyst have shown that the carbon deposited during the reaction acts as the active phase for the reaction and can, therefore, be recycled infinitely. This autocatalytic effect can only be observed when the carbon catalyst operates under IH because the same catalyst operating under Joule heating (JH) deactivates rapidly in the same way as that already reported in the literature and no autocatalytic effect has been observed. The carbon formed is in the form of a graphene layer with a high degree of graphitization and is completely different from the carbon black powder obtained in other processes. These promising results could lay the groundwork for the development of an industrially and economically viable way to convert natural gas into turquoise hydrogen, using renewable energy and low-cost catalysts, with better resistance to poisoning by impurities present in the processing load. The combination of a carbon-based catalyst and non-contact IH could also lead to combined catalytic processes for many challenging reactions.

Keywords

Catalytic methane decomposition / carbon catalyst / induction heating / turquoise hydrogen / electrification process

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