A new method to improve CO₂ photoreduction efficiency by regulating the electron localization of metal sites on 3D ordered macroporous frames assembled by 2D nanosheets

Keywords

Photoreduction / electron localization / metal sites / macroporous frames / nanosheets

References

[1] Li X,Xu J.Selective visible-light-driven photocatalytic CO₂ reduction to CH₄ mediated by atomically thin CuIn₅S₈ layers.Nat Energy2019;4:690-9

[2] Stanley PM,Fischer RA.Analysis of metal–organic framework-based photosynthetic CO₂ reduction.Nat Synth2024;3:307-18

[3] Wu YA,Liu C.Facet-dependent active sites of a single Cu₂O particle photocatalyst for CO₂ reduction to methanol.Nat Energy2019;4:957-68

[4] Gong E,Hiragond CB.Solar fuels: research and development strategies to accelerate photocatalytic CO₂ conversion into hydrocarbon fuels.Energy Environ Sci2022;15:880-937

[5] Stanley PM,Ramm V.Photocatalytic CO₂-to-syngas evolution with molecular catalyst metal-organic framework nanozymes.Adv Mater2023;35:2207380

[6] Lyu W,Zhou J.Modulating the reaction configuration by breaking the structural symmetry of active sites for efficient photocatalytic reduction of low-concentration CO₂.Angew Chem Int Ed Engl2023;62:e202310733

[7] Zhou W,Zhao W.Photocatalytic CO₂ reduction to syngas using metallosalen covalent organic frameworks.Nat Commun2023;14:6971 PMCID:PMC10620383

[8] Qian G,Zhao X.Efficient photoreduction of diluted CO₂ to tunable syngas by Ni-Co dual sites through d-band center manipulation.Angew Chem Int Ed Engl2022;61:e202210576

[9] Li X,Jaroniec M.Cocatalysts for selective photoreduction of CO₂ into solar fuels.Chem Rev2019;119:3962-4179

[10] Maeda K.Metal-complex/semiconductor hybrid photocatalysts and photoelectrodes for CO₂ reduction driven by visible light.Adv Mater2019;31:1808205

[11] Pan Q,Cao Y.Ultrafast charge transfer dynamics in 2D covalent organic frameworks/Re-complex hybrid photocatalyst.Nat Commun2022;13:845 PMCID:PMC8837612

[12] Zhou Y,Liu M.Dopant-induced electron localization drives CO₂ reduction to C₂ hydrocarbons.Nat Chem2018;10:974-80

[13] Wang Y,Meng J.Constructing atomic surface concaves on Bi₅O₇Br nanotube for efficient photocatalytic CO₂ reduction.Nano Energy2023;109:108305

[14] Yan S,Yang C.Electron localization and lattice strain induced by surface lithium doping enable ampere-level electrosynthesis of formate from CO₂.Angew Chem Int Ed Engl2021;60:25741-5

[15] Lyu W,Chen D,Li Y.Engineering the electron localization of metal sites on nanosheets assembled periodic macropores for CO₂ photoreduction.Nat Commun2024;15:10589 PMCID:PMC11618665

[16] Yang D,Chen R.Flower-like superstructure of boron carbon nitride nanosheets with adjustable band gaps for photocatalytic hydrogen peroxide production.J Mater Sci Technol2024;183:23-31