Recent progress of in-situ/operando characterization approaches of zinc-air batteries

Abstract

Zinc-air batteries (ZABs) belong to the category of metal-air batteries, with high theoretical energy density, safety, and low cost. Nevertheless, there are still many challenges that need to be solved for the practical application of ZABs, including high overpotential, poor cycle life, and so on. This article first briefly introduced the principle of ZABs, covering the key components, functions of each element, and challenges faced by the system. Subsequently, seven methods for studying ZABs in-situ or operando were introduced, including X-ray computed tomography (XCT), optical microscopy imaging (OMI), transmission electron microscopy (TEM), nuclear magnetic resonance imaging (MRI), X-ray diffraction (XRD), Raman spectroscopy, and X-ray absorption spectroscopy (XAS), accompanied by specific research examples. The future perspectives of ZAB characterization have also been discussed.

Keywords

In-situ characterization / operando characterization / imaging techniques / spectroscopy techniques / zinc-air battery

References

[1] Chen Y,Zhao Y.A review of lithium-ion battery safety concerns: the issues, strategies, and testing standards.J Energy Chem2021;59:83-99

[2] Eftekhari A.On the theoretical capacity/energy of lithium batteries and their counterparts.ACS Sustainable Chem Eng2019;7:3684-7

[3] Liu JN,Wang J,Li BQ.A brief history of zinc-air batteries: 140 years of epic adventures.Energy Environ Sci2022;15:4542-53

[4] Fu J,Liu G.Recent progress in electrically rechargeable zinc-air batteries.Adv Mater2019;31:1805230

[5] Fu J,Park MG,Fowler M.Electrically rechargeable zinc-air batteries: progress, challenges, and perspectives.Adv Mater2017;29:1604685

[6] Ren S,Liang S,Zheng H.Bifunctional electrocatalysts for Zn-air batteries: recent developments and future perspectives.J Mater Chem A2020;8:6144-82

[7] Zhang D.Study on failure mechanism on rechargeable alkaline zinc-air battery during charge/discharge cycles at different depths of discharge.Front Chem2023;11:1121215

[8] Yadav SK,Schneider JJ.Secondary zinc-air batteries: a view on rechargeability aspects.Batteries2022;8:244

[9] Li H,Zhou H.In-situ/operando characterization techniques in lithium-ion batteries and beyond.J Energy Chem2021;59:191-211

[10] Sun Z,Liu Y,Yuan C.Recent progress on in situ/operando characterization of rechargeable alkali ion batteries.ChemPlusChem2021;86:1487-96

[11] Liu D,Lin R.Review of recent development of in situ/operando characterization techniques for lithium battery research.Adv Mater2019;31:1806620

[12] Chen X,Karahan HE,Wei L.Recent advances in materials and design of electrochemically rechargeable zinc-air batteries.Small2018;14:1801929

[13] Yu W,He Y,Ma Y.Unraveling the mechanism of non-uniform zinc deposition in rechargeable zinc-based batteries with vertical orientation.Chem Eng J2022;431:134032

[14] Christensen MK,Simonsen SB.Transformation and migration in secondary zinc-air batteries studied by in situ synchrotron X-ray diffraction and X-ray tomography.J Mater Chem A2019;7:6459-66

[15] Hosseini S,Li YY.Current status and technical challenges of electrolytes in zinc-air batteries: an in-depth review.Chem Eng J2021;408:127241

[16] Yufit V,Eastwood DS.Operando visualization and multi-scale tomography studies of dendrite formation and dissolution in zinc batteries.Joule2019;3:485-502

[17] Cai Z,Lu Z.Ultrafast metal electrodeposition revealed by in situ optical imaging and theoretical modeling towards fast-charging Zn battery chemistry.Angew Chem Int Ed Engl2022;61:e202116560

[18] Naveed A,Raza B.Addressing thermodynamic instability of Zn anode: classical and recent advancements.Energy Stor Mater2022;44:206-30

[19] Arlt T,Krewer U.In operando monitoring of the state of charge and species distribution in zinc air batteries using X-ray tomography and model-based simulations.Phys Chem Chem Phys2014;16:22273-80

[20] Fan X,Xie X,Wang R.The electrochemical behaviors of Zn-Al-La-hydrotalcite in Zn-Ni secondary cells.J Power Sources2013;241:404-9

[21] Chen J,Quan Y.Ionic liquid additive enabling anti-freezing aqueous electrolyte and dendrite-free Zn metal electrode with organic/inorganic hybrid solid electrolyte interphase layer.Energy Stor Mater2022;53:629-37

[22] Hao J,Zeng X,Mao J.Deeply understanding the Zn anode behaviour and corresponding improvement strategies in different aqueous Zn-based batteries.Energy Environ Sci2020;13:3917-49

[23] Zhang Y,Wang N.Anode optimization strategies for aqueous zinc-ion batteries.Chem Sci2022;13:14246-63

[24] Liu H,Zhu D.Chemical doping of graphene.J Mater Chem2011;21:3335-45

[25] Zhang J,Xia Z.A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions.Nat Nanotechnol2015;10:444-52

[26] Li L,Xiao D,Zhi C.Phase-transition tailored nanoporous zinc metal electrodes for rechargeable alkaline zinc-nickel oxide hydroxide and zinc-air batteries.Nat Commun2022;13:2870

[27] Li G,Zhang R,Lei L.Electrochemical performance of MnO₂-based air cathodes for zinc-air batteries.Fuel Cells2016;16:395-400

[28] Li J,Mi H.Bifunctional oxygen electrocatalysis on ultra-thin Co₉S₈/MnS carbon nanosheets for all-solid-state zinc-air batteries.J Mater Chem A2021;9:22635-42

[29] Sun C,Bian J.Recent advances in perovskite-type oxides for energy conversion and storage applications.Adv Energy Mater2021;11:2000459

[30] Gao Y,Mao Y,Sun C.Highly efficient bifunctional layered triple Co, Fe, Ru hydroxides and oxides composite electrocatalysts for zinc-air batteries.J Electroanal Chem2023;935:117315

[31] Li H,Wang X.Atomic-layer-deposited ultrathin Co₉S₈ on carbon nanotubes: an efficient bifunctional electrocatalyst for oxygen evolution/reduction reactions and rechargeable Zn-air batteries.J Mater Chem A2017;5:21353-61

[32] Niu Y,Liu X.Engineering iron-group bimetallic nanotubes as efficient bifunctional oxygen electrocatalysts for flexible Zn-air batteries.eScience2022;2:546-56

[33] Wang Y,Wang X.Engineering carbon-chainmail-shell coated Co₉Se₈ nanoparticles as efficient and durable catalysts in seawater-based Zn-air batteries.Acta Physico Chimica Sinica2024;40:2305004

[34] Han X,He Y.Engineering catalytic active sites on cobalt oxide surface for enhanced oxygen electrocatalysis.Adv Energy Mater2018;8:1702222

[35] Li YW,Li J.Fe-MOF-derived efficient ORR/OER bifunctional electrocatalyst for rechargeable zinc-air batteries.ACS Appl Mater Interfaces2020;12:44710-9

[36] Ma J,Wang R.Hierarchical porous S-doped Fe-N-C electrocatalyst for high-power-density zinc-air battery.Mater Today Energy2021;19:100624

[37] Li G,Huang Z.Poly-active centric Co₃O₄-CeO₂/Co-N-C composites as superior oxygen reduction catalysts for Zn-air batteries.Sci China Mater2021;64:73-84

[38] Chen P,Tang D.Recent progress in electrolytes for Zn-air batteries.Front Chem2020;8:372

[39] Sharma Y,Yusof J.Triethanolamine as an additive to the anode to improve the rechargeability of alkaline manganese dioxide batteries.J Power Sources2001;94:129-31

[40] Yang H,Ai X.Improved discharge capacity and suppressed surface passivation of zinc anode in dilute alkaline solution using surfactant additives.J Power Sources2004;128:97-101

[41] Zhu Y,Zheng X.Concentrated dual-cation electrolyte strategy for aqueous zinc-ion batteries.Energy Environ Sci2021;14:4463-73

[42] Qiu K,Liao M.A fumed SiO₂-based composite hydrogel polymer electrolyte for near-neutral zinc-air batteries.Acta Phys Chim Sin2024;40:2304036

[43] Xu M,Xie Z.Electrochemical behavior of Zn/Zn(II) couples in aprotic ionic liquids based on pyrrolidinium and imidazolium cations and bis(trifluoromethanesulfonyl)imide and dicyanamide anions.Electrochim Acta2013;89:756-62

[44] Shinde SS,Wagh NK.Ampere-hour-scale zinc-air pouch cells.Nat Energy2021;6:592-604

[45] Liu Q,He C.Advanced polymer-based electrolytes in zinc-air batteries.eScience2022;2:453-66

[46] Xu M,Xie Z.Rechargeable Zn-air batteries: progress in electrolyte development and cell configuration advancement.J Power Sources2015;283:358-71

[47] Wang MY,Xiong JF,Li JF.Critical role and recent development of separator in zinc-air batteries.Acta Phys Chim Sin2024;40:2307017

[48] Teng HT,Han XF,Yang R.Recent development and perspectives of flexible zinc-air batteries.Acta Phys Chim Sin2023;39:2107017

[49] Lee HJ,Kim HW.Electrospun polyetherimide nanofiber mat-reinforced, permselective polyvinyl alcohol composite separator membranes: a membrane-driven step closer toward rechargeable zinc-air batteries.J Membr Sci2016;499:526-37

[50] Liu Y,Xie X.A functionalized separator enables dendrite-free Zn anode via metal-polydopamine coordination chemistry.InfoMat2023;5:e12374

[51] Jana KK,Huang A,Tung KL.Separator membranes for high energy-density batteries.ChemBioEng Rev2018;5:346-71

[52] Boebinger MG,Sandoval SE.Understanding transformations in battery materials using in situ and operando experiments: progress and outlook.ACS Energy Lett2020;5:335-45

[53] Schröder D,Krewer U.Analyzing transport paths in the air electrode of a zinc air battery using X-ray tomography.Electrochem Commun2014;40:88-91

[54] Hack J,Bailey JJ,Shearing PR.In situ x-ray computed tomography of zinc-air primary cells during discharge: correlating discharge rate to anode morphology.J Phys Mater2022;5:014001

[55] Li G,Saqib M.Operando optoelectrochemical analysis of single zinc dendrites with a reflective nanopore electrode.Chem Asian J2022;17:e202200824

[56] Mao J,Saqib M,Hao R.Super-resolved dynamics of isolated zinc formation during extremely fast electrochemical deposition/dissolution processes.Chem Sci2022;13:12782-90

[57] Sasaki Y,Kawasaki T,Ukyo Y.In situ electron microscopy analysis of electrochemical Zn deposition onto an electrode.J Power Sources2021;481:228831

[58] Li M,Knibbe R.Zn electrodeposition by an in situ electrochemical liquid phase transmission electron microscope.J Phys Chem Lett2021;12:913-8

[59] Britton MM,Howlett PC,Forsyth M.In situ, real-time visualization of electrochemistry using magnetic resonance imaging.J Phys Chem Lett2013;4:3019-23

[60] Wang T,Mori T.Carbonate formation on carbon electrode in rechargeable zinc-air battery revealed by in-situ Raman measurements.J Power Sources2022;533:231237

[61] Santos F,Vila M,Urbina A.In situ synchrotron x-ray diffraction study of Zn/Bi₂O₃ electrodes prior to and during discharge of Zn-air batteries: influence on ZnO deposition.Electrochim Acta2018;281:133-41

[62] Han X,Chen W.Mn-N₄ oxygen reduction electrocatalyst: operando investigation of active sites and high performance in zinc-air battery.Adv Energy Mater2021;11:2002753

[63] Sun Z,Cao L.Understanding synergistic catalysis on Cu-Se dual atom sites via operando X-ray absorption spectroscopy in oxygen reduction reaction.Angew Chem Int Ed Engl2023;62:e202217719

[64] Withers PJ,Carmignato S.X-ray computed tomography.Nat Rev Methods Primers2021;1:18

[65] Schröder D,Arlt T.In operando x-ray tomography for next-generation batteries: a systematic approach to monitor reaction product distribution and transport processes.J Phys D Appl Phys2016;49:404001

[66] Franke-Lang R,Manke I.X-ray tomography as a powerful method for zinc-air battery research.J Power Sources2017;370:45-51

[67] Chen B,Xuan J,Wang H.Seeing is believing: in situ/operando optical microscopy for probing electrochemical energy systems.Adv Mater Technol2020;5:2000555

[68] Rukari T.Transmission electron microscopy-an overview.IRJIPS2013;1:1-7Available from: https://www.researchgate.net/publication/332104143_Review_Article_TRANSMISSION_ELECTRON_MICROSCOPY. [Last accessed on 20 Dec 2023]

[69] Santhosh Kumar R,Sagaya Selvam Neethinathan C.Highly mixed high-energy d-orbital states enhance oxygen evolution reactions in spinel catalysts.Appl Surf Sci2023;641:158469

[70] Braidy N,de Souza Terra JC.Experimental methods in chemical engineering: transmission electron microscopy - TEM.Can J Chem Eng2020;98:628-41

[71] Sasaki Y,Kuwabara A.On-chip electrochemical analysis combined with liquid-phase electron microscopy of zinc deposition/dissolution.J Electrochem Soc2021;168:112511

[72] Mohammadi M.In situ and operando magnetic resonance imaging of electrochemical cells: a perspective.J Magn Reson2019;308:106600

[73] Hess C.New advances in using Raman spectroscopy for the characterization of catalysts and catalytic reactions.Chem Soc Rev2021;50:3519-64

[74] Campion A.Surface-enhanced Raman scattering.Chem Soc Rev1998;27:241-50

[75] Stiles PL,Shah NC.Surface-enhanced Raman spectroscopy.Annu Rev Anal Chem2008;1:601-26

[76] Wei X,An Q,Mai L.Operando X-ray diffraction characterization for understanding the intrinsic electrochemical mechanism in rechargeable battery materials.Small Methods2017;1:1700083

[77] Bunaciu AA,Aboul-Enein HY.X-ray diffraction: instrumentation and applications.Crit Rev Anal Chem2015;45:289-99

[78] Ameh ES.A review of basic crystallography and x-ray diffraction applications.Int J Adv Manuf Technol2019;105:3289-302

[79] Kumar RS,Prabhakaran S.Trimetallic oxide electrocatalyst for enhanced redox activity in zinc-air batteries evaluated by in situ analysis.Adv Sci2023;10:2303525

[80] Wu Z,Chen L,Guo Z.In situ synchrotron X-ray absorption spectroscopy studies of anode materials for rechargeable batteries.Batteries Supercaps2021;4:1547-66

[81] Wang M.Pitfalls in X-ray absorption spectroscopy analysis and interpretation: a practical guide for general users.Curr Opin Electrochem2021;30:100803

[82] Young NA.The application of synchrotron radiation and in particular X-ray absorption spectroscopy to matrix isolated species.Coord Chem Rev2014;277-8:224-74

[83] Kerr BV,Garibello CF.Characterization of energy materials with X-ray absorption spectroscopy - advantages, challenges, and opportunities.Energy Fuels2022;36:2369-89