Regioselectivity of N-heteroarene electrocarboxylations: divided vs. undivided cell

Gang Zhong , Yang Huang , Lin He

Chemical Synthesis ›› 2023, Vol. 3 ›› Issue (3) : 19

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Chemical Synthesis ›› 2023, Vol. 3 ›› Issue (3) :19 DOI: 10.20517/cs.2023.03
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Regioselectivity of N-heteroarene electrocarboxylations: divided vs. undivided cell

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Carbon dioxide / electrochemistry / carboxylation / regioselectivity / N-heteroarenes

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Gang Zhong, Yang Huang, Lin He. Regioselectivity of N-heteroarene electrocarboxylations: divided vs. undivided cell. Chemical Synthesis, 2023, 3(3): 19 DOI:10.20517/cs.2023.03

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References

[1]

Ye JH,Huang H,Yu DG.Radical carboxylative cyclizations and carboxylations with CO2.Acc Chem Res2021;54:2518-31

[2]

Murakami K,Kaneda T.C-H functionalization of azines.Chem Rev2017;117:9302-32

[3]

Tortajada A,Börjesson M,Martin R.Transition-metal-catalyzed carboxylation reactions with carbon dioxide.Angew Chem Int Ed Engl2018;57:15948-82

[4]

Fosu SC,Chen AD,Nagib DA.Site-selective C-H functionalization of (Hetero)arenes via transient, non-symmetric iodanes.Chem2019;5:417-28 PMCID:PMC6481961

[5]

Cheng C.Rhodium-catalyzed intermolecular C-H silylation of arenes with high steric regiocontrol.Science2014;343:853-7

[6]

Liu Q,Jackstell R.Using carbon dioxide as a building block in organic synthesis.Nat Commun2015;6:5933

[7]

Proctor RSJ.Recent advances in Minisci-type reactions.Angew Chem Int Ed Engl2019;58:13666-99

[8]

Ye M,Yu JQ.Ligand-promoted C-3 selective C-H olefination of pyridines with Pd catalysts.J Am Chem Soc2011;133:6964-7

[9]

Kim JH,Simonetti M,Sheikh NS.A radical approach for the selective C-H borylation of azines.Nature2021;595:677-83

[10]

Fuchs P,Holst H,Enzell CR.Electrochemical carboxylation of some heteroaromatic compounds.Acta Chem Scand B1982;13:185-92

[11]

Sun GQ,Zhang W.Electrochemical reactor dictates site selectivity in N-heteroarene carboxylations.Nature2023;615:67-72 PMCID:PMC10036166

[12]

Zhao Z,Wang S.Site-selective electrochemical C-H carboxylation of arenes with CO2.Angew Chem Int Ed Engl2023;62:e202214710

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