Recent progress in strategies for preparation of metal-organic frameworks and their hybrids with different dimensions

Abstract

As a new kind of organic-inorganic hybrid porous material, metal-organic frameworks (MOFs) exhibit a wide application prospect in gas storage and separation, catalysis and sensing due to their characteristics of large specific surface area, high porosity and coordination unsaturation. As more and more types of MOFs were reported, the synthetic strategies of MOFs-based materials have become a hot research topic. According to the morphological dimension, MOFs can be roughly divided into one-dimensional, two-dimensional and three-dimensional structures. Herein, we summarize the synthetic methods and principles of MOFs from multi-dimensional perspectives, and explore the growth mechanism of MOFs with different morphologies based on dynamic and thermodynamic tuning. Finally, based on the above summaries, the challenges and opportunities of MOFs in the future are discussed.

Keywords

MOFs / MOF-based hybrids / different dimensions / dynamic and thermodynamic tuning

References

[1] Yaghi OM,Li H.Selective binding and removal of guests in a microporous metal-organic framework.Nature1995;378:703-6

[2] Schneemann A,Schwedler I,Kaskel S.Flexible metal-organic frameworks.Chem Soc Rev2014;43:6062-96

[3] Zhou HC.Metal-organic frameworks (MOFs).Chem Soc Rev2014;43:5415-8

[4] Islamoglu T,Li Z,Farha OK.Postsynthetic tuning of metal-organic frameworks for targeted applications.Acc Chem Res2017;50:805-13

[5] Zhao W,Wang W,Zhao Q.Ultrathin two-dimensional metal-organic framework nanosheets for functional electronic devices.Coord Chem Rev2018;377:44-63

[6] Chen L.Metal-organic framework composites for catalysis.Matter2019;1:57-89

[7] Jiao L,Skinner WS,Jiang H.Metal-organic frameworks: structures and functional applications.Materials Today2019;27:43-68

[8] Liu D,Pang G.Hollow metal-organic-framework micro/nanostructures and their derivatives: emerging multifunctional materials.Adv Mater2019;31:e1803291

[9] Xiao JD.Metal-organic frameworks for photocatalysis and photothermal catalysis.Acc Chem Res2019;52:356-66

[10] Li H,O’keeffe M.Design and synthesis of an exceptionally stable and highly porous metal-organic framework.Nature1999;402:276-9

[11] Schubert U.Cluster-based inorganic-organic hybrid materials.Chem Soc Rev2011;40:575-82

[12] Chen Z,Li M,Eddaoudi M.Reticular chemistry 3.2: typical minimal edge-transitive derived and related nets for the design and synthesis of metal-organic frameworks.Chem Rev2020;120:8039-65

[13] Kitagawa S.Functional micropore chemistry of crystalline metal complex-assembled compounds.BCSJ1998;71:1739-53

[14] Kitagawa S,Noro S.Functional porous coordination polymers.Angew Chem Int Ed Engl2004;43:2334-75

[15] An J,Rosi NL.Cation-triggered drug release from a porous zinc-adeninate metal-organic framework.J Am Chem Soc2009;131:8376-7

[16] Stock N.Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.Chem Rev2012;112:933-69

[17] Tian D,Xie ZJ.The first example of hetero-triple-walled metal-organic frameworks with high chemical stability constructed via flexible integration of mixed molecular building blocks.Adv Sci2016;3:1500283 PMCID:PMC5095769

[18] Liu W,Yang Q.Multi-shelled hollow metal-organic frameworks.Angew Chem Int Ed Engl2017;56:5512-6

[19] Liu Y,Zhang C.Enhanced CO₂/CH₄ separation performance of a mixed matrix membrane based on tailored MOF-polymer formulations.Adv Sci2018;5:1800982

[20] Peng Y,Zhang Y.A versatile MOF-based trap for heavy metal ion capture and dispersion.Nat Commun2018;9:187 PMCID:PMC5768720

[21] Zhang L,Shi W.Boosting lithium storage properties of MOF derivatives through a wet-spinning assembled fiber strategy.Chemistry2018;24:13792-9

[22] Xue D,Bai J.Amide-functionalized metal-organic frameworks: syntheses, structures and improved gas storage and separation properties.Coord Chem Rev2019;378:2-16

[23] Xie J,Xie Y.Defect engineering in two-dimensional electrocatalysts for hydrogen evolution.Nanoscale2020;12:4283-94

[24] Velásquez-hernández MDJ,Astria E.Towards applications of bioentities@MOFs in biomedicine.Coord Chem Rev2021;429:213651

[25] Tang Y,Cao S.Hollow mesoporous carbon nanospheres space-confining ultrathin nanosheets superstructures for efficient capacitive deionization.J Colloid Interface Sci2022;626:1062-9

[26] Wang F,Liu Y.Turning coordination environment of 2D nickel-based metal-organic frameworks by π-conjugated molecule for enhancing glucose electrochemical sensor performance.Mater Today Chem2022;24:100885

[27] Dybtsev DN,Kim K.Rigid and flexible: a highly porous metal-organic framework with unusual guest-dependent dynamic behavior.Angew Chem2004;116:5143-6

[28] Cohen SM.Postsynthetic methods for the functionalization of metal-organic frameworks.Chem Rev2012;112:970-1000

[29] Larsson EM,Zorić I.Nanoplasmonic probes of catalytic reactions.Science2009;326:1091-4

[30] Liu G,Pan J,Lu GQ.Titanium dioxide crystals with tailored facets.Chem Rev2014;114:9559-612

[31] Chen D,Tian J,Du M.Pore modulation of metal-organic frameworks towards enhanced hydrothermal stability and acetylene uptake via incorporation of different functional brackets.J Mater Chem A2017;5:4861-7

[32] Li X,Pang H.Facile synthesis and shape evolution of well-defined phosphotungstic acid potassium nanocrystals as a highly efficient visible-light-driven photocatalyst.Nanoscale2017;9:216-22

[33] Shi D,Sun MJ.Semiconductive copper(I)-organic frameworks for efficient light-driven hydrogen generation without additional photosensitizers and cocatalysts.Angew Chem Int Ed Engl2017;56:14637-41

[34] Cai G,Zhang L,Jiang HL.Metal-organic framework-based hierarchically porous materials: synthesis and applications.Chem Rev2021;121:12278-326

[35] Furukawa S,Diring S,Kitagawa S.Structuring of metal-organic frameworks at the mesoscopic/macroscopic scale.Chem Soc Rev2014;43:5700-34

[36] Farha OK.Rational design, synthesis, purification, and activation of metal-organic framework materials.Acc Chem Res2010;43:1166-75

[37] Li B,Feng Y.Ultrathin nickel-cobalt phosphate 2D nanosheets for electrochemical energy storage under aqueous/solid-state electrolyte.Adv Funct Mater2017;27:1605784

[38] Abednatanzi S,Depauw H.Mixed-metal metal-organic frameworks.Chem Soc Rev2019;48:2535-65

[39] Guo F,Liu Y,Huang J.Size engineering of metal-organic framework MIL-101(Cr)-Ag hybrids for photocatalytic CO₂ reduction.ACS Catal2019;9:8464-70

[40] Li Y,Liu Y.Exposing {001} crystal plane on hexagonal Ni-MOF with surface-grown cross-linked mesh-structures for electrochemical energy storage.Small2019;15:e1902463

[41] Lerma-Berlanga B,Almora-Barrios N.Effect of linker distribution in the photocatalytic activity of multivariate mesoporous crystals.J Am Chem Soc2021;143:1798-806

[42] Li W,Geng P.Rational design and general synthesis of multimetallic metal-organic framework nano-octahedra for enhanced Li-S battery.Adv Mater2021;33:e2105163

[43] Wei Y,Wang J.A series of novel Co(ii)-based MOFs: syntheses, structural diversity, and various properties.CrystEngComm2021;23:6376-87

[44] Parsaei M,White J.Modulating carbon dioxide storage by facile synthesis of nanoporous pillared-layered metal-organic framework with different synthetic routes.Inorg Chem2022;61:3893-902

[45] Zhang X,Zhu F.Route to the structure-controlled synthesis of Fe nanobelts and their oxygen evolution reaction application.Inorg Chem2022;61:3024-8

[46] Zorainy MY,Kaliaguine S,Boffito DC.Facile solvothermal synthesis of a MIL-47(V) metal-organic framework for a high-performance Epoxy/MOF coating with improved anticorrosion properties.RSC Adv2022;12:9008-22 PMCID:PMC8985107

[47] Ai L,Zhang C,Jiang J.MIL-53(Fe): a metal-organic framework with intrinsic peroxidase-like catalytic activity for colorimetric biosensing.Chemistry2013;19:15105-8

[48] Dao X.Al-based coordination polymer nanotubes: simple preparation, post-modification and application in Fe³⁺ ions sensing.Dalton Trans2017;46:5373-83

[49] He T,Zhang S.Ultrathin 2D zirconium metal-organic framework nanosheets: preparation and application in photocatalysis.Small2018;14:e1703929

[50] Zhao M,Ma Q.Ultrathin 2D metal-organic framework nanosheets.Adv Mater2015;27:7372-8

[51] Pathak A,Usman M.Integration of a (-Cu-S-)_n plane in a metal-organic framework affords high electrical conductivity.Nat Commun2019;10:1721 PMCID:PMC6461620

[52] Marsh C,Li J.Exceptional packing density of ammonia in a dual-functionalized metal-organic framework.J Am Chem Soc2021;143:6586-92 PMCID:PMC8154541

[53] Li XX,Zhang L.Hydrophobic polyoxometalate-based metal-organic framework for efficient CO₂ photoconversion.ACS Appl Mater Interfaces2019;11:25790-5

[54] Zhao S,Dong J.Ultrathin metal-organic framework nanosheets for electrocatalytic oxygen evolution.Nat Energy2016;1

[55] Pichon A,James SL.Solvent-free synthesis of a microporous metal-organic framework.CrystEngComm2006;8:211

[56] Katsenis AD,Štrukil V.In situ X-ray diffraction monitoring of a mechanochemical reaction reveals a unique topology metal-organic framework.Nat Commun2015;6:6662

[57] Pan ZW,Wang ZL.Nanobelts of semiconducting oxides.Science2001;291:1947-9

[58] Li X,Zhang L,Dai H.Chemically derived, ultrasmooth graphene nanoribbon semiconductors.Science2008;319:1229-32

[59] Liu Q,Kou J.High-yield synthesis of ultralong and ultrathin Zn₂GeO₄ nanoribbons toward improved photocatalytic reduction of CO₂ into renewable hydrocarbon fuel.J Am Chem Soc2010;132:14385-7

[60] He J,Xu B.Highly flexible sub-1 nm tungsten oxide nanobelts as efficient desulfurization catalysts.Small2015;11:1144-9

[61] Liang HW,Qian HS.Multiplex templating process in one-dimensional nanoscale: controllable synthesis, macroscopic assemblies, and applications.Acc Chem Res2013;46:1450-61

[62] Liu Y,Yin Y.Templated synthesis of nanostructured materials.Chem Soc Rev2013;42:2610-53

[63] Petkovich ND.Controlling macro- and mesostructures with hierarchical porosity through combined hard and soft templating.Chem Soc Rev2013;42:3721-39

[64] Yu L,Lou XW.Self-templated formation of hollow structures for electrochemical energy applications.Acc Chem Res2017;50:293-301

[65] Pachfule P,Kurungot S.One-dimensional confinement of a nanosized metal organic framework in carbon nanofibers for improved gas adsorption.Chem Commun2012;48:2009-11

[66] Zhang W,Jiang HL.Nanowire-directed templating synthesis of metal-organic framework nanofibers and their derived porous doped carbon nanofibers for enhanced electrocatalysis.J Am Chem Soc2014;136:14385-8

[67] Zhang G,Zhang H.High-performance and ultra-stable lithium-ion batteries based on MOF-derived ZnO@ZnO quantum dots/C core-shell nanorod arrays on a carbon cloth anode.Adv Mater2015;27:2400-5

[68] Yao MS,Wang GE,Xu G.MOF thin film-coated metal oxide nanowire array: significantly improved chemiresistor sensor performance.Adv Mater2016;28:5229-34

[69] Zhang W,Wu R.Templating synthesis of metal-organic framework nanofiber aerogels and their derived hollow porous carbon nanofibers for energy storage and conversion.Small2021;17:e2004140

[70] Jahan M,Yang JX.Structure-directing role of graphene in the synthesis of metal-organic framework nanowire.J Am Chem Soc2010;132:14487-95

[71] Caddeo F,Weil D,Toimil-Molares ME.Tuning the size and shape of NanoMOFs via templated electrodeposition and subsequent electrochemical oxidation.ACS Appl Mater Interfaces2019;11:25378-87

[72] Arbulu RC,Peterson EJ.Metal-organic framework (MOF) nanorods, nanotubes, and nanowires.Angew Chem Int Ed Engl2018;57:5813-7

[73] Li SC,Shang LM.General synthesis and solution processing of metal-organic framework nanofibers.Adv Mater2022;34:e2202504

[74] Steunou N.Rational design of one-dimensional vanadium(v) oxide nanocrystals: an insight into the physico-chemical parameters controlling the crystal structure, morphology and size of particles.CrystEngComm2015;17:6780-95

[75] Pan L,Tervoort E,Niederberger M.Surface energy-driven ex situ hierarchical assembly of low-dimensional nanomaterials on graphene aerogels: a versatile strategy.J Mater Chem A2018;6:18551-60

[76] Muschi M,Sene S.Formation of a single-crystal aluminum-based MOF nanowire with graphene oxide nanoscrolls as structure-directing agents.Angew Chem Int Ed Engl2020;59:10353-8

[77] Sharifi T,Barzegar HR.Formation of nitrogen-doped graphene nanoscrolls by adsorption of magnetic γ-Fe₂O₃ nanoparticles.Nat Commun2013;4:2319

[78] Qiao S,Zhang Q,He G.Sacrificial template method to synthesize atomically dispersed Mn atoms on S, N-codoped carbon as a separator modifier for advanced Li-S batteries.ACS Appl Mater Interfaces2022;14:42123-33

[79] Sun JK,Akita T.Toward homogenization of heterogeneous metal nanoparticle catalysts with enhanced catalytic performance: soluble porous organic cage as a stabilizer and homogenizer.J Am Chem Soc2015;137:7063-6

[80] Zhao M,Wang Y.Metal-organic frameworks as selectivity regulators for hydrogenation reactions.Nature2016;539:76-80

[81] Zhang W,Lu G.Mesoporous metal-organic frameworks with size-, shape-, and space-distribution-controlled pore structure.Adv Mater2015;27:2923-9

[82] Yang Q,Wang B.Regulating the spatial distribution of metal nanoparticles within metal-organic frameworks to enhance catalytic efficiency.Nat Commun2017;8:14429 PMCID:PMC5316883

[83] Reboul J,Horike N.Mesoscopic architectures of porous coordination polymers fabricated by pseudomorphic replication.Nat Mater2012;11:717-23

[84] Zhan WW,Zhou JZ,Xie ZX.Semiconductor@metal-organic framework core-shell heterostructures: a case of ZnO@ZIF-8 nanorods with selective photoelectrochemical response.J Am Chem Soc2013;135:1926-33

[85] Majano G.Scalable room-temperature conversion of copper(II) hydroxide into HKUST-1 (Cu₃ (btc)₂).Adv Mater2013;25:1052-7

[86] Li B,Cheng P.Silica-protection-assisted encapsulation of Cu₂O nanocubes into a metal-organic framework (ZIF-8) to provide a composite catalyst.Angew Chem Int Ed Engl2018;57:6834-7

[87] Roy P,Schmuki P.TiO₂ nanotubes: synthesis and applications.Angew Chem Int Ed Engl2011;50:2904-39

[88] Jiang Z,Li C,Xiao R.Strong synergistic effect of Co₃O₄ encapsulated in nitrogen-doped carbon nanotubes on the nonradical-dominated persulfate activation.Carbon2020;158:172-83

[89] Jang W,Seo S.Strong dark current suppression in flexible organic photodetectors by carbon nanotube transparent electrodes.Nano Today2021;37:101081

[90] Wu L,Liu Z.Carbon nanotube-based materials for persulfate activation to degrade organic contaminants: properties, mechanisms and modification insights.J Hazard Mater2022;431:128536

[91] Reddy MV,Chowdari BV.Metal oxides and oxysalts as anode materials for Li ion batteries.Chem Rev2013;113:5364-457

[92] Yu X,Lou XWD.Metal sulfide hollow nanostructures for electrochemical energy storage.Adv Energy Mater2016;6:1501333

[93] Schulze HA,Schäfer M,Behrens P.Electrically conducting nanocomposites of carbon nanotubes and metal-organic frameworks with strong interactions between the two components.ChemNanoMat2019;5:1159-69

[94] Hu X,Wang S.Separator modified by Co-porphyrin based Zr-MOF@CNT composite enabling efficient polysulfides catalytic conversion for advanced lithium-sulfur batteries.Electrochimica Acta2021;398:139317

[95] Chronopoulos DD,Tantis I,Jayaramulu K.Carbon nanotube based metal-organic framework hybrids from fundamentals toward applications.Small2022;18:e2104628

[96] Chen YM,Lou XW.Hierarchical tubular structures composed of Co₃O₄ hollow nanoparticles and carbon nanotubes for lithium storage.Angew Chem Int Ed Engl2016;55:5990-3

[97] Yin Y,Erdonmez CK,Somorjai GA.Formation of hollow nanocrystals through the nanoscale Kirkendall effect.Science2004;304:711-4

[98] Liu T,Xu J,Liu D.Conversion of Cu₂O nanowires into Cu₂O/HKUST-1 core/sheath nanostructures and hierarchical HKUST-1 nanotubes.RSC Adv2016;6:91440-4

[99] Li X,Zhang B,Wang Z.PAN-derived electrospun nanofibers for supercapacitor applications: ongoing approaches and challenges.J Mater Sci2021;56:10745-81

[100] Li X,Wang Z,He T.Electrospun metal-organic framework based nanofibers for energy storage and environmental applications: current approaches and challenges.J Mater Chem A2022;10:1642-81

[101] Kakade MV,Gardner K,Chase DB.Electric field induced orientation of polymer chains in macroscopically aligned electrospun polymer nanofibers.J Am Chem Soc2007;129:2777-82

[102] Sankar SS,Sangeetha K,Kundu S.Transition-metal-based zeolite imidazolate framework nanofibers via an electrospinning approach: a review.ACS Omega2020;5:57-67 PMCID:PMC6963905

[103] Sankar SS,Sangeetha K,Madhu R.Current perspectives on 3D ZIFs incorporated with 1D carbon matrices as fibers via electrospinning processes towards electrocatalytic water splitting: a review.J Mater Chem A2021;9:11961-2002

[104] Dou Y,Kaiser A.Electrospinning of metal-organic frameworks for energy and environmental applications.Adv Sci2020;7:1902590 PMCID:PMC7001619

[105] Lu AX,Browe MA,DeCoste JB.MOFabric: electrospun nanofiber mats from PVDF/UiO-66-NH₂ for chemical protection and decontamination.ACS Appl Mater Interfaces2017;9:13632-6

[106] Mccarthy DL,Dwyer DB.Electrospun metal-organic framework polymer composites for the catalytic degradation of methyl paraoxon.New J Chem2017;41:8748-53

[107] Bai Z,Chen P,Wu G.Enhanced proton conduction of imidazole localized in one-dimensional Ni-metal-organic framework nanofibers.Nanotechnology2020;31:125702

[108] Liang H,Jiao X,Chen D.Fast and sustained degradation of chemical warfare agent simulants using flexible self-supported metal-organic framework filters.ACS Appl Mater Interfaces2018;10:20396-403

[109] Ji D,Tao L.The kirkendall effect for engineering oxygen vacancy of hollow Co₃O₄ nanoparticles toward high-performance portable zinc-air batteries.Angew Chem Int Ed Engl2019;58:13840-4

[110] Niu Q,Chen B,Guo X.Bimetal-organic frameworks/polymer core-shell nanofibers derived heteroatom-doped carbon materials as electrocatalysts for oxygen reduction reaction.Carbon2017;114:250-60

[111] Efome JE,Matsuura T.Insight studies on metal-organic framework nanofibrous membrane adsorption and activation for heavy metal ions removal from aqueous solution.ACS Appl Mater Interfaces2018;10:18619-29

[112] Topuz F,Hardian R,Szekely G.Nanofibrous membranes comprising intrinsically microporous polyimides with embedded metal-organic frameworks for capturing volatile organic compounds.J Hazard Mater2022;424:127347

[113] Chen LF,Yu L.Designed formation of hollow particle-based nitrogen-doped carbon nanofibers for high-performance supercapacitors.Energy Environ Sci2017;10:1777-83

[114] Huang H,Yang X.Unveiling the advances of nanostructure design for alloy-type potassium-ion battery anodes via in situ TEM.Angew Chem Int Ed Engl2020;59:14504-10

[115] Dou Y,Kaiser A.Highly structured metal-organic framework nanofibers for methane storage.Sci China Mater2021;64:1742-50

[116] Zheng J,Deng K.Chirality-discriminated conductivity of metal-amino acid biocoordination polymer nanowires.ACS Nano2016;10:8564-70

[117] Shi J,Tan D.Rapid, room-temperature and template-free synthesis of metal-organic framework nanowires in alcohol.ChemCatChem2019;11:2058-62

[118] Hwang J,Antonietti M.Morphogenesis of metal-organic mesocrystals mediated by double hydrophilic block copolymers.J Am Chem Soc2018;140:2947-56

[119] Chi WS,Zhang K,Hayden SC.Mixed-matrix membranes formed from multi-dimensional metal-organic frameworks for enhanced gas transport and plasticization resistance.ChemSusChem2019;12:2355-60

[120] Rosnes MH,Opitz M.Morphology control in modulated synthesis of metal-organic framework CPO-27.Microporous Mesoporous Mater2019;275:207-13

[121] Yu B,Chen J.Membrane-supported 1D MOF hollow superstructure array prepared by polydopamine-regulated contra-diffusion synthesis for uranium entrapment.Environ Pollut2019;253:39-48

[122] Bonnett BL,De La Garza M.PCN-222 metal-organic framework nanoparticles with tunable pore size for nanocomposite reverse osmosis membranes.ACS Appl Mater Interfaces2020;12:15765-73

[123] Feng L,Lv XL,Zhou HC.Hierarchically porous metal-organic frameworks: synthetic strategies and applications.Natl Sci Rev2020;7:1743-58 PMCID:PMC8290954

[124] Liu X,Chen Z.Small molecules, big effects: tuning adsorption and catalytic properties of metal-organic frameworks.Chem Mater2021;33:1444-54

[125] Song Z,Doyle-davis K,Luo J.Recent advances in MOF-derived single atom catalysts for electrochemical applications.Adv Energy Mater2020;10:2001561

[126] Wen X,Guan J.Applications of metal-organic framework-derived materials in fuel cells and metal-air batteries.Coord Chem Rev2020;409:213214

[127] Wang Q.State of the art and prospects in metal-organic framework (MOF)-based and MOF-derived nanocatalysis.Chem Rev2020;120:1438-511

[128] Tsuruoka T,Takashima Y,Isoda S.Nanoporous nanorods fabricated by coordination modulation and oriented attachment growth.Angew Chem Int Ed Engl2009;48:4739-43

[129] Pachfule P,Majumder M.Fabrication of carbon nanorods and graphene nanoribbons from a metal-organic framework.Nat Chem2016;8:718-24

[130] Liu X,Fu Y.Exfoliation of metal-organic framework nanosheets using surface acoustic waves.Ultrason Sonochem2022;83:105943 PMCID:PMC8844814

[131] Zou L,Hong J.Fabrication of a spherical superstructure of carbon nanorods.Adv Mater2019;31:e1900440

[132] Mallick A,Díaz DD.Hydrolytic conversion of a metal-organic polyhedron into a metal-organic framework.Angew Chem Int Ed Engl2013;52:13755-9

[133] Shao D,Yin L.Reversible on-off switching of both spin crossover and single-molecule magnet behaviours via a crystal-to-crystal transformation.Chem Sci2018;9:7986-91 PMCID:PMC6202758

[134] Qu X.Zn(ii)/Cd(ii)-based metal-organic frameworks: crystal structures, Ln(iii)-functionalized luminescence and chemical sensing of dichloroaniline as a pesticide biomarker.J Mater Chem C2020;8:9427-39

[135] Ciupa-litwa A,Peksa P.Elucidation of the mechanism of phase transition in a zinc formate framework templated by a diammonium cation - structural, phonon and dielectric studies.Crystals2021;11:213

[136] Kim J,Lee JH.Solid-state phase transformations toward a metal-organic framework of 7-connected Zn₄O secondary building units.Nano Res2021;14:411-6

[137] Ying P,Zhong Z.Effect of phase transition on the thermal transport in isoreticular DUT materials.J Phys Chem C2021;125:12991-3001

[138] Zhou CC,Ding L,Wang SN.Single-crystal-to-single-crystal transformations among three Mn-MOFs containing different water molecules induced by reaction time: crystal structures and proton conductivities.Dalton Trans2021;50:11077-90

[139] Lv Y,Gong W.Hcp-phased Ni nanoparticles with generic catalytic hydrogenation activities toward different functional groups.Sci China Mater2022;65:1252-61

[140] Choi SB,Nam HJ.Reversible interpenetration in a metal-organic framework triggered by ligand removal and addition.Angew Chem Int Ed Engl2012;51:8791-5

[141] Coudert F.Responsive metal-organic frameworks and framework materials: under pressure, taking the heat, in the spotlight, with friends.Chem Mater2015;27:1905-16

[142] Li QQ,Huang YY.Thermally triggered solid-state single-crystal-to-single-crystal structural transformation accompanies property changes.Chemistry2015;21:4703-11

[143] Ghoufi A,Boukli-Hacene L.Electrically induced breathing of the MIL-53(Cr) metal-organic framework.ACS Cent Sci2017;3:394-8 PMCID:PMC5445524

[144] Evans JD,Senkovska I,Kaskel S.Four-dimensional metal-organic frameworks.Nat Commun2020;11:2690 PMCID:PMC7264271

[145] Krause S,Kitagawa S.Chemistry of soft porous crystals: structural dynamics and gas adsorption properties.Angew Chem Int Ed Engl2020;59:15325-41

[146] Li R,Zhou C.Ligand substitution induced single-crystal-to-single-crystal transformations in two Ni(ii) coordination compounds displaying consequential changes in proton conductivity.Inorg Chem Front2020;7:1880-91

[147] Han Y,Teat SJ.Desulfurization efficiency preserved in a heterometallic MOF: synthesis and thermodynamically controlled phase transition.Adv Sci2019;6:1802056 PMCID:PMC6446612

[148] Chen Y,Huang X.A tale of copper coordination frameworks: controlled single-crystal-to-single-crystal transformations and their catalytic C-H bond activation properties.Chemistry2015;21:13894-9

[149] Yang Y,Dong Z.1D coordination polymer nanofibers for low-temperature photothermal therapy.Adv Mater2017;29:1703588

[150] Rappe AK,Colwell KS,Skiff WM.UFF, a full periodic table force field for molecular mechanics and molecular dynamics simulations.J Am Chem Soc1992;114:10024-35

[151] Taylor KM,Lin W.Manganese-based nanoscale metal-organic frameworks for magnetic resonance imaging.J Am Chem Soc2008;130:14358-9

[152] Mazaj M,Žagar E.A facile strategy towards a highly accessible and hydrostable MOF-phase within hybrid polyHIPEs through in situ metal-oxide recrystallization.J Mater Chem A2017;5:1967-71

[153] Ding Y,He D.Design of multishell microsphere of transition metal oxides/carbon composites for lithium ion battery.Chem Eng J2020;380:122489

[154] Niu H,Yang X,Liu L.In situ growth of the ZIF-8 on the polymer monolith via CO₂-in-water HIPEs stabilized using metal oxide nanoparticles and its photocatalytic activity.Polym Adv Technol2021;32:3194-204

[155] Zou L,Liu Z,Xu Q.Superlong single-crystal metal-organic framework nanotubes.J Am Chem Soc2018;140:15393-401

[156] Novoselov KS,Morozov SV.Electric field effect in atomically thin carbon films.Science2004;306:666-9

[157] Yi M.A review on mechanical exfoliation for the scalable production of graphene.J Mater Chem A2015;3:11700-15

[158] Dong R,Feng X.Interface-assisted synthesis of 2D materials: trend and challenges.Chem Rev2018;118:6189-235

[159] Wang J,Xu Y.Emerging two-dimensional covalent and coordination polymers for stable lithium metal batteries: from liquid to solid.ACS Nano2021;15:19026-53

[160] Li C,Li J.Recent progress in stimulus-responsive two-dimensional metal-organic frameworks.ACS Materials Lett2020;2:779-97

[161] Zhao M,Peng Y,Ma Q.Two-dimensional metal-organic framework nanosheets: synthesis and applications.Chem Soc Rev2018;47:6267-95

[162] Schneemann A,Schwotzer F.2D framework materials for energy applications.Chem Sci2020;12:1600-19 PMCID:PMC8179301

[163] Zhu H.The synthetic strategies of metal-organic framework membranes, films and 2D MOFs and their applications in devices.J Mater Chem A2019;7:21004-35

[164] Faghani A,Fardin Gholami M.Controlled covalent functionalization of thermally reduced graphene oxide to generate defined bifunctional 2D nanomaterials.Angew Chem Int Ed Engl2017;56:2675-9 PMCID:PMC5324584

[165] López-Cabrelles J,Vitórica-Yrezábal IJ.Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization.Nat Chem2018;10:1001-7

[166] Tan C,Hu Y.High-yield exfoliation of ultrathin two-dimensional ternary chalcogenide nanosheets for highly sensitive and selective fluorescence DNA sensors.J Am Chem Soc2015;137:10430-6

[167] Zhang H.Ultrathin two-dimensional nanomaterials.ACS Nano2015;9:9451-69

[168] Al Obeidli A, Ben Salah H, Al Murisi M, Sabouni R. Recent advancements in MOFs synthesis and their green applications.Int J Hydrog Energy2022;47:2561-93

[169] Liu Y,Lyu M.Low overpotential in vacancy-rich ultrathin CoSe₂ nanosheets for water oxidation.J Am Chem Soc2014;136:15670-5

[170] Fang Z,De Vos DE.Defect-engineered metal-organic frameworks.Angew Chem Int Ed Engl2015;54:7234-54 PMCID:PMC4510710

[171] Lin S,Zhang YB.Covalent organic frameworks comprising cobalt porphyrins for catalytic CO₂ reduction in water.Science2015;349:1208-13

[172] Ashworth DJ,Schneemann A.Increasing alkyl chain length in a series of layered metal-organic frameworks aids ultrasonic exfoliation to form nanosheets.Inorg Chem2019;58:10837-45 PMCID:PMC7007210

[173] Hernandez Y,Lotya M.High-yield production of graphene by liquid-phase exfoliation of graphite.Nat Nanotechnol2008;3:563-8

[174] Shen J,Wu J.Liquid phase exfoliation of two-dimensional materials by directly probing and matching surface tension components.Nano Lett2015;15:5449-54

[175] Tan C,Dong J.Boosting enantioselectivity of chiral organocatalysts with ultrathin two-dimensional metal-organic framework nanosheets.J Am Chem Soc2019;141:17685-95

[176] Jian M,Xia Y.Ultrathin water-stable metal-organic framework membranes for ion separation.Sci Adv2020;6:eaay3998 PMCID:PMC7274808

[177] Ding Y,Zhang X.Controlled intercalation and chemical exfoliation of layered metal-organic frameworks using a chemically labile intercalating agent.J Am Chem Soc2017;139:9136-9

[178] Schoedel A,Li D,Yaghi OM.Structures of metal-organic frameworks with rod secondary building units.Chem Rev2016;116:12466-535

[179] Huang J,Huang RK.Electrochemical exfoliation of pillared-layer metal-organic framework to boost the oxygen evolution reaction.Angew Chem Int Ed Engl2018;57:4632-6

[180] Liu L,Zhang Y.Fabrication of ultrathin single-layer 2D metal-organic framework nanosheets with excellent adsorption performance.via9:546-55

[181] Gallego A,Castillo O.Solvent-induced delamination of a multifunctional two dimensional coordination polymer.Adv Mater2013;25:2141-6

[182] Wang X,Zhang K.Reversed thermo-switchable molecular sieving membranes composed of two-dimensional metal-organic nanosheets for gas separation.Nat Commun2017;8:14460 PMCID:PMC5316892

[183] Au VK,Huang H,Sato H.Stepwise expansion of layered metal-organic frameworks for nonstochastic exfoliation into porous nanosheets.J Am Chem Soc2019;141:53-7

[184] Lê Anh M, Potapov P, Lubk A, Doert T, Ruck M. Freestanding few-layer sheets of a dual topological insulator.npj 2D Mater Appl2021;5

[185] Lê Anh M,Wolf D.Freestanding nanolayers of a wide-gap topological insulator through liquid-phase exfoliation.Chemistry2021;27:794-801 PMCID:PMC7839554

[186] Chen JE,Koh HU.Current progress and scalable approach toward the synthesis of 2D metal-organic frameworks.Adv Materials Inter2022;9:2102560

[187] Li X,Bai X.Highly conducting graphene sheets and Langmuir-Blodgett films.Nat Nanotechnol2008;3:538-42

[188] Dong A,Vora PM,Murray CB.Binary nanocrystal superlattice membranes self-assembled at the liquid-air interface.Nature2010;466:474-7

[189] Yaghi OM.Evolution of MOF single crystals.Chem2022;8:1541-3

[190] Han J,Liu J.Determining factors in the growth of MOF single crystals unveiled by in situ interface imaging.Chemistry2022;8:1637-57

[191] Liu YL,Feng L.Two-dimensional metal-organic framework nanosheets: synthesis and applications in electrocatalysis and photocatalysis.ChemSusChem2022;15:e202102603

[192] Sakamoto R,Liu Q.A photofunctional bottom-up bis(dipyrrinato)zinc(II) complex nanosheet.Nat Commun2015;6:6713 PMCID:PMC4396372

[193] Ying Y,Peh SB.Pressure-responsive two-dimensional metal-organic framework composite membranes for CO₂ separation.Angew Chem Int Ed Engl2021;60:11318-25

[194] Zhang T,Li L,Song L.Fewer-layer conductive metal-organic Langmuir-Blodgett films as electrocatalysts enable an ultralow detection limit of H₂O₂.Appl Surf Sci2021;539:148255

[195] Lin Y,Cao Y.Two-dimensional MOFs: design & synthesis and applications.Chem Asian J2021;16:3281-98

[196] Shi Y,Yu Y,Zhang B.N-doped graphene wrapped hexagonal metallic cobalt hierarchical nanosheet as a highly efficient water oxidation electrocatalyst.J Mater Chem A2017;5:8897-902

[197] Xiao X,Jin H.Salt-templated synthesis of 2D metallic MoN and other nitrides.ACS Nano2017;11:2180-6

[198] Huang L,Han Y,Fang Y.In situ synthesis of ultrathin metal-organic framework nanosheets: a new method for 2D metal-based nanoporous carbon electrocatalysts.J Mater Chem A2017;5:18610-7

[199] Huang L,Zhang H,Fang Y.Self-dissociation-assembly of ultrathin metal-organic framework nanosheet arrays for efficient oxygen evolution.Nano Energy2020;68:104296

[200] Talin AA,Ford AC.Tunable electrical conductivity in metal-organic framework thin-film devices.Science2014;343:66-9

[201] Sun L,Dincă M.Electrically conductive porous metal-organic frameworks.Angew Chem Int Ed Engl2016;55:3566-79

[202] Stassen I,Talin A,Allendorf M.An updated roadmap for the integration of metal-organic frameworks with electronic devices and chemical sensors.Chem Soc Rev2017;46:3185-241

[203] Wu G,Zang Y,Xu G.Porous field-effect transistors based on a semiconductive metal-organic framework.J Am Chem Soc2017;139:1360-3

[204] Cui Y,Chen Z.[Cu₃(C₆Se₆)]_n: the first highly conductive 2D π-d conjugated coordination polymer based on benzenehexaselenolate.Adv Sci2019;6:1802235

[205] Yang C,Wang M.A semiconducting layered metal-organic framework magnet.Nat Commun2019;10:3260 PMCID:PMC6646349

[206] Arora H,Venanzi T.Demonstration of a broadband photodetector based on a two-dimensional metal-organic framework.Adv Mater2020;32:e1907063

[207] Schwotzer F,Senkovska I.Cooperative assembly of 2D-MOF nanoplatelets into hierarchical carpets and tubular superstructures for advanced air filtration.Angew Chem Int Ed Engl2022;61:e202117730 PMCID:PMC9315001

[208] Dong R,Arora H.High-mobility band-like charge transport in a semiconducting two-dimensional metal-organic framework.Nat Mater2018;17:1027-32

[209] Li FL,Huang X.Large-scale, bottom-up synthesis of binary metal-organic framework nanosheets for efficient water oxidation.Angew Chem Int Ed Engl2019;58:7051-6

[210] Liu B,Arslan HK,Wöll C.Enantiopure metal-organic framework thin films: oriented SURMOF growth and enantioselective adsorption.Angew Chem Int Ed Engl2012;51:807-10

[211] Haraguchi T,Sakata O,Kitagawa H.Remarkable lattice shrinkage in highly oriented crystalline three-dimensional metal-organic framework thin films.Inorg Chem2015;54:11593-5

[212] Haraguchi T,Sakata O,Fujiwara A.A three-dimensional accordion-like metal-organic framework: synthesis and unconventional oriented growth on a surface.Chem Commun2016;52:6017-20

[213] Begum S,Bräse S,Tsotsalas M.Metal-organic framework-templated biomaterials: recent progress in synthesis, functionalization, and applications.Acc Chem Res2019;52:1598-610

[214] Lugier O,Castellanos S.Impact of synthetic conditions on the morphology and crystallinity of FDMOF-1(Cu) thin films.Cryst Growth Des2020;20:5302-9

[215] Sakaida S,Otsubo K,Fujiwara A.Fabrication and structural characterization of an ultrathin film of a two-dimensional-layered metal-organic framework, {Fe(py)₂[Ni(CN)₄]} (py = pyridine).Inorg Chem2017;56:7606-9

[216] Xiao Y,Jiao Y,Lin H.Metal-phenolic network as precursor for fabrication of metal-organic framework (MOF) nanofiltration membrane for efficient desalination.J Membr Sci2021;624:119101

[217] Liu X,Marschner S.Photoinduced delamination of metal-organic framework thin films by spatioselective generation of reactive oxygen species.ACS Appl Mater Interfaces2021;13:57768-73

[218] Zhao W,Wang W.Layer-by-layer 2D ultrathin conductive Cu₃(HHTP)₂ film for high-performance flexible transparent supercapacitors.Adv Mater Interfaces2021;8:2100308

[219] Cao F,Yu Y.Synthesis of two-dimensional CoS1.097/nitrogen-doped carbon nanocomposites using metal-organic framework nanosheets as precursors for supercapacitor application.J Am Chem Soc2016;138:6924-7

[220] Liu X,Zhang Y.Two-dimensional metal-organic framework/enzyme hybrid nanocatalyst as a benign and self-activated cascade reagent for in vivo wound healing.ACS Nano2019;13:5222-30

[221] Hang L,Wen H.Controllable photodynamic performance via an acidic microenvironment based on two-dimensional metal-organic frameworks for photodynamic therapy.Nano Res2021;14:660-6

[222] Wang Z,Qi H.Ultrathin two-dimensional conjugated metal-organic framework single-crystalline nanosheets enabled by surfactant-assisted synthesis.Chem Sci2020;11:7665-71 PMCID:PMC8159486

[223] Liu X,Wu Z.Highly water-stable zirconium metal-organic framework UiO-66 membranes supported on alumina hollow fibers for desalination.J Am Chem Soc2015;137:6999-7002

[224] Bai Y,Xie LH,Li JR.Zr-based metal-organic frameworks: design, synthesis, structure, and applications.Chem Soc Rev2016;45:2327-67

[225] Zhang X,Chen C.Fabrication of 2D metal-organic framework nanosheets with tailorable thickness using bio-based surfactants and their application in catalysis.Green Chem2019;21:54-8

[226] Cho W,Oh M.Growth-controlled formation of porous coordination polymer particles.J Am Chem Soc2008;130:16943-6

[227] Umemura A,Furukawa S,Tsuruoka T.Morphology design of porous coordination polymer crystals by coordination modulation.J Am Chem Soc2011;133:15506-13

[228] Hu M,Liang K,Cui J.Void engineering in metal-organic frameworks via synergistic etching and surface functionalization.Adv Funct Mater2016;26:5827-34

[229] Guo X,Zhang G.Nanostructured graphene-based materials for flexible energy storage.Energy Stor Mater2017;9:150-69

[230] Bai XJ,Li LL.Fabrication of MOF thin films at miscible liquid-liquid interface by spray method.ACS Appl Mater Interfaces2018;10:25960-6

[231] Cui J,Yin X.Microfluidic synthesis of uniform single-crystalline MOF microcubes with a hierarchical porous structure.Nanoscale2018;10:9192-8

[232] Geng P,Du M.MIL-96-Al for Li-S batteries: shape or size?.Adv Mater2022;34:e2107836

[233] Xiao X,Pang H.Synthesis of micro/nanoscaled metal-organic frameworks and their direct electrochemical applications.Chem Soc Rev2020;49:301-31

[234] Carné-Sánchez A,Cano-Sarabia M.A spray-drying strategy for synthesis of nanoscale metal-organic frameworks and their assembly into hollow superstructures.Nat Chem2013;5:203-11

[235] Xu X,Wang X.Well-defined metal-organic-framework hollow nanostructures for catalytic reactions involving gases.Adv Mater2015;27:5365-71

[236] He T,Ni B.Fast and scalable synthesis of uniform zirconium-, hafnium-based metal-organic framework nanocrystals.Nanoscale2017;9:19209-15

[237] He T,Ni B.Metal-organic framework based microcapsules.Angew Chem Int Ed Engl2018;57:10148-52

[238] Qiu T,Liang Z.Pristine hollow metal-organic frameworks: design, synthesis and application.Angew Chem Int Ed Engl2021;60:17314-36

[239] Han L,Lou XW.Formation of prussian-blue-analog nanocages via a direct etching method and their conversion into Ni-Co-mixed oxide for enhanced oxygen evolution.Adv Mater2016;28:4601-5

[240] Kajiwara T,Tsujimoto M.Photochemical reduction of low concentrations of CO₂ in a porous coordination polymer with a ruthenium(II)-CO complex.Angew Chem Int Ed Engl2016;55:2697-700

[241] Lian X,Joseph E.Enzyme-MOF (metal-organic framework) composites.Chem Soc Rev2017;46:3386-401

[242] Diercks CS,Cordova KE.The role of reticular chemistry in the design of CO₂ reduction catalysts.Nat Mater2018;17:301-7

[243] Drake T,Lin W.Site isolation in metal-organic frameworks enables novel transition metal catalysis.Acc Chem Res2018;51:2129-38

[244] Li Z,Luo L,Tsung CK.Aperture-opening encapsulation of a transition metal catalyst in a metal-organic framework for CO₂ hydrogenation.J Am Chem Soc2018;140:8082-5

[245] Luo L,Si X.Directional engraving within single crystalline metal-organic framework particles via oxidative linker cleaving.J Am Chem Soc2019;141:20365-70

[246] Khan NA.Synthesis of metal-organic frameworks (MOFs) with microwave or ultrasound: rapid reaction, phase-selectivity, and size reduction.Coord Chem Rev2015;285:11-23

[247] Cai X,Li D,Zang S.Nano-sized metal-organic frameworks: synthesis and applications.Coord Chem Rev2020;417:213366

[248] Thi Dang Y,Dong HC.Microwave-assisted synthesis of nano Hf- and Zr-based metal-organic frameworks for enhancement of curcumin adsorption.Microporous Mesoporous Mater2020;298:110064

[249] Gabriel C,Grant EH,Halstead BSJ.Dielectric parameters relevant to microwave dielectric heating.Chem Soc Rev1998;27:213

[250] Lee Y,Ahn W.Synthesis of metal-organic frameworks: a mini review.Korean J Chem Eng2013;30:1667-80

[251] Yang W,Hu S.Self-assembled three-dimensional macroporous Co₂(OH)₃ Cl-MnO₂ spheres synthesized by microwave-assisted method: a new hybrid for high-performance asymmetric supercapacitors.ACS Sustain Chem Eng2017;5:4563-72

[252] Thomas-hillman I,Dodds C.Realising the environmental benefits of metal-organic frameworks: recent advances in microwave synthesis.J Mater Chem A2018;6:11564-81

[253] Kumar A,Liang Z.Microwave chemistry, recent advancements, and eco-friendly microwave-assisted synthesis of nanoarchitectures and their applications: a review.Mater Today Nano2020;11:100076

[254] Ma M,Weber I,Fischer RA.Iron-based metal-organic frameworks MIL-88B and NH₂-MIL-88B: high quality microwave synthesis and solvent-induced lattice “breathing”.Cryst Growth Des2013;13:2286-91

[255] Li Y,Gao W.Microwave-assisted synthesis of UIO-66 and its adsorption performance towards dyes.CrystEngComm2014;16:7037-42

[256] Babu R,Kathalikkattil AC,Park DW.Rapid, microwave-assisted synthesis of cubic, three-dimensional, highly porous MOF-205 for room temperature CO₂ fixation via cyclic carbonate synthesis.ACS Appl Mater Interfaces2016;8:33723-31

[257] Chen C,Zhu Q.Microwave-assisted rapid synthesis of well-shaped MOF-74 (Ni) for CO₂ efficient capture.Inorg Chem2019;58:2717-28

[258] Wang W,Chen S,He M.Microwave-assisted fabrication of a mixed-ligand [Cu₄(μ₃-OH)₂]-cluster-based metal-organic framework with coordinatively unsaturated metal sites for carboxylation of terminal alkynes with carbon dioxide.Appl Organomet Chem2021;35

[259] Kong Y,Zhang J.Microwave-assisted rapid synthesis of nanoscale MOF-303 for hydrogel composites with superior proton conduction at ambient-humidity conditions.ACS Appl Energy Mater2021;4:14681-8

[260] Firmino AD,Antunes MM.Robust multifunctional yttrium-based metal-organic frameworks with breathing effect.Inorg Chem2017;56:1193-208

[261] Kukkar P,Kukkar D.Recent advances in the synthesis techniques for zeolitic imidazolate frameworks and their sensing applications.Coord Chem Rev2021;446:214109

[262] Cherbański R.Modelling of microwave heating of water in a monomode applicator - influence of operating conditions.Int J Therm Sci2013;74:214-29

[263] Zhao Z,Zhao K,Gao X.Microwave-assisted synthesis of MOFs: rational design via numerical simulation.Chem Eng J2022;428:131006

[264] Chang HY,Chen WC.Water-induced self-assembly of amphiphilic discotic molecules for adaptive artificial water channels.ACS Nano2021;15:14885-90

[265] Mohammadi P,Nonappa ,Miserez A.Bioinspired functionally graded composite assembled using cellulose nanocrystals and genetically engineered proteins with controlled biomineralization.Adv Mater2021;33:e2102658

[266] Morris RE.Exploiting chemically selective weakness in solids as a route to new porous materials.Nat Chem2015;7:381-8

[267] Huang H,Wang K.An in situ self-assembly template strategy for the preparation of hierarchical-pore metal-organic frameworks.Nat Commun2015;6:8847 PMCID:PMC4667608

[268] Feng L,Powell J.Controllable synthesis of metal-organic frameworks and their hierarchical assemblies.Matter2019;1:801-24

[269] Wang Z,Zhang G.The controllable synthesis of urchin-shaped hierarchical superstructure MOFs with high catalytic activity and stability.Chem Commun2021;57:8758-61

[270] Zhao X,Liu J.Metal-organic framework-derived ZnO/ZnS heteronanostructures for efficient visible-light-driven photocatalytic hydrogen production.Adv Sci2018;5:1700590 PMCID:PMC5908348

[271] Hu SJ,Zhou LP.Guest-driven self-assembly and chiral induction of photofunctional lanthanide tetrahedral cages.J Am Chem Soc2022;144:4244-53

[272] Alivand MS,Wu Y.Engineered assembly of water-dispersible nanocatalysts enables low-cost and green CO₂ capture.Nat Commun2022;13:1249 PMCID:PMC8913730

[273] Avci C,Carné-Sánchez A.Self-assembly of polyhedral metal-organic framework particles into three-dimensional ordered superstructures.Nat Chem2017;10:78-84

[274] Rosi NL,Eddaoudi M.Hydrogen storage in microporous metal-organic frameworks.Science2003;300:1127-9

[275] Rowsell JL.Strategies for hydrogen storage in metal - organic frameworks.Angew Chem Int Ed Engl2005;44:4670-9

[276] Ren J,North BC.Review on processing of metal-organic framework (MOF) materials towards system integration for hydrogen storage: review on processing of MOF materials towards system integration.Int J Energy Res2015;39:607-20

[277] Vilela SMF,Micheron L,Yot PG.A robust monolithic metal-organic framework with hierarchical porosity.Chem Commun2018;54:13088-91

[278] Lim GJH,Shah BB.3D-printing of pure metal-organic framework monoliths.ACS Mater Lett2019;1:147-53

[279] Sumida K,Reboul J,Furukawa S.Sol-gel processing of metal-organic frameworks.Chem Mater2017;29:2626-45

[280] Lee J,Kim J.Fiber-based gas filter assembled via in situ synthesis of ZIF-8 metal organic frameworks for an optimal adsorption of SO₂: experimental and theoretical approaches.ACS Appl Mater Interfaces2021;13:1620-31

[281] Asaro F,Freris I,Savko N.Evolution of the nonionic inverse microemulsion-acid-TEOS system during the synthesis of nanosized silica via the sol-gel process.Langmuir2010;26:12917-25

[282] Lorignon F,Carboni M.Hierarchically porous monolithic MOFs: an ongoing challenge for industrial-scale effluent treatment.Chem Eng J2020;393:124765

[283] Tian T,Vulpe D.A sol-gel monolithic metal-organic framework with enhanced methane uptake.Nat Mater2018;17:174-9

[284] Connolly BM,Gandara-Loe J.Tuning porosity in macroscopic monolithic metal-organic frameworks for exceptional natural gas storage.Nat Commun2019;10:2345 PMCID:PMC6538620

[285] Bueken B,Willhammar T.Gel-based morphological design of zirconium metal-organic frameworks.Chem Sci2017;8:3939-48 PMCID:PMC5433495

[286] Hou J,Bennett TD.Metal-organic framework gels and monoliths.Chem Sci2020;11:310-23 PMCID:PMC7021205

[287] Avrami M.Kinetics of phase change. I general theory.J Chem Phys1939;7:1103-12

[288] Gualtieri AF.Synthesis of sodium zeolites from a natural halloysite.Phys Chem Miner2001;28:719-28

[289] Chen X,Zhou C.Unraveling the physiochemical nature of colloidal motion waves among silver colloids.Sci Adv2022;8:eabn9130 PMCID:PMC9132452

[290] Pang M,Liu Y,Zeng HC.Synthesis and integration of Fe-soc-MOF cubes into colloidosomes via a single-step emulsion-based approach.J Am Chem Soc2013;135:10234-7

[291] Pang M,Liu Y,Zeng HC.Highly monodisperse M(III)-based soc-MOFs (M = In and Ga) with cubic and truncated cubic morphologies.J Am Chem Soc2012;134:13176-9

[292] Zheng S,Xue H,Huang W.Dual-ligand and hard-soft-acid-base strategies to optimize metal-organic framework nanocrystals for stable electrochemical cycling performance.Natl Sci Rev2022;9:nwab197 PMCID:PMC9362764

[293] di Gregorio MC,Wen Q.Molecular cannibalism: sacrificial materials as precursors for hollow and multidomain single crystals.Nat Commun2021;12:957 PMCID:PMC7878748

[294] Li H,Yang X,Li Y.Growth pattern control and nanoarchitecture engineering of metal-organic framework single crystals by confined space synthesis.ACS Cent Sci2022;8:718-28 PMCID:PMC9228561

[295] Wang Y,Zhang L,Pang H.Core-shell-type ZIF-8@ZIF-67@POM hybrids as efficient electrocatalysts for the oxygen evolution reaction.Inorg Chem Front2019;6:2514-20

[296] Chen L,Li C.Bimetallic metal-organic frameworks and their derivatives.Chem Sci2020;11:5369-403 PMCID:PMC8159423

[297] Chuang C.Metal-organic frameworks toward electrochemical sensors: challenges and opportunities.Electroanalysis2020;32:1885-95

[298] Guo C,Wang B.Metal-organic frameworks-based composites and their photothermal applications.Acta Chimica Sinica2021;79:967

[299] Xu Y,Wan J.Reduced graphene oxide-supported metal organic framework as a synergistic catalyst for enhanced performance on persulfate induced degradation of trichlorophenol.Chemosphere2020;240:124849

[300] Wu Y,He D.Decorated traditional zeolites with subunits of metal-organic frameworks for CH₄/N₂ separation.Angew Chem Int Ed Engl2019;58:10241-4

[301] Xiong Y,Qiao X.Co-MOF-74 derived Co₃O₄/graphene heterojunction nanoscrolls for ppb-level acetone detection.Sens Actuators B Chem2019;300:127011

[302] Zhou T,Wang X,Zeng D.Catalytic activation of cobalt doping sites in ZIF-71-coated ZnO nanorod arrays for enhancing gas-sensing performance to acetone.ACS Appl Mater Interfaces2020;12:48948-56

[303] Zhao Q,Fu K,Song C.Oxidation of acetone over Co-based catalysts derived from hierarchical layer hydrotalcite: influence of Co/Al molar ratios and calcination temperatures.Chemosphere2018;204:257-66

[304] Lan L,Zhang Q.Defects lead to a massive enhancement in the UV-Vis-IR driven thermocatalytic activity of Co₃O₄ mesoporous nanorods.J Mater Chem A2018;6:7194-205

[305] Zhang Y.Facile construction of MoO₃@ZIF-8 core-shell nanorods for efficient photoreduction of aqueous Cr (VI).Appl Catal B: Environ2019;240:92-101

[306] Abdollahi N,Morsali A.High capacity Hg(II) and Pb(II) removal using MOF-based nanocomposite: cooperative effects of pore functionalization and surface-charge modulation.J Hazard Mater2020;387:121667

[307] Zheng S,Xue H,Xu Q.A highly alkaline-stable metal oxide@metal-organic framework composite for high-performance electrochemical energy storage.Natl Sci Rev2020;7:305-14

[308] Li QY,Xu YX,Xue H.Smart yolk/shell ZIF-67@POM hybrids as efficient electrocatalysts for the oxygen evolution reaction.ACS Sustain Chem Eng2019;7:5027-33

[309] Xiao X,Xu Y.A new strategy for the controllable growth of MOF@PBA architectures.J Mater Chem A2019;7:17266-71

[310] Shan Y,Bai Y,Guo X.Design and synthesis of transition metal oxide/zeolitic imidazolate framework-67 composites.Chem Eng J2022;429:132146

[311] Radhakrishnan S. Chapter 8 - graphene-carbon nanotubes modified electrochemical sensors. In: editor^editors, editor. Graphene-based electrochemical sensors for biomolecules. Elsevier; 2019. p.187-205.

[312] Venkadesh A,Radhakrishnan S.Voltammetric sensing of caffeine in food sample using Cu-MOF and graphene.Electroanalysis2021;33:1007-13

[313] Khiarak BN,Mojaddami M,Simchi A.In situ synthesis of quasi-needle-like bimetallic organic frameworks on highly porous graphene scaffolds for efficient electrocatalytic water oxidation.Chem Commun2020;56:3135-8

[314] Wang W,Zhou W.Recent progress in metal-organic frameworks for applications in electrocatalytic and photocatalytic water splitting.Adv Sci2017;4:1600371 PMCID:PMC5396165

[315] Huang H,Chen Z,Hu Y.Electrochemical sensor based on Ce-MOF/carbon nanotube composite for the simultaneous discrimination of hydroquinone and catechol.J Hazard Mater2021;416:125895

[316] Quan X,Xu J.Construction of an aminated MIL-53(Al)-functionalized carbon nanotube for the efficient removal of bisphenol AF and metribuzin.Inorg Chem2020;59:2667-79

[317] Lin KY.Ultra-high adsorption capacity of zeolitic imidazole framework-67 (ZIF-67) for removal of malachite green from water.Chemosphere2015;139:624-31

[318] Del Rio M, Turnes Palomino G, Palomino Cabello C. Metal-organic framework@carbon hybrid magnetic material as an efficient adsorbent for pollutant extraction.ACS Appl Mater Interfaces2020;12:6419-25

[319] Qiu J,Li M.Metal nanoparticles decorated MIL-125-NH2 and MIL-125 for efficient photocatalysis.Mater Res Bull2019;112:297-306

[320] Sun D.Double-solvent method to Pd nanoclusters encapsulated inside the cavity of NH₂-Uio-66(Zr) for efficient visible-light-promoted suzuki coupling reaction.J Phys Chem C2016;120:19744-50

[321] Wang Y,Hou CC,Xu Q.Multiple catalytic sites in MOF-based hybrid catalysts for organic reactions.Org Biomol Chem2020;18:8508-25

[322] Guan J,Zhang F.Water oxidation on a mononuclear manganese heterogeneous catalyst.Nat Catal2018;1:870-7

[323] Li X,Wu L.Semiconducting quantum dots for artificial photosynthesis.Nat Rev Chem2018;2:160-73

[324] Chung HT,Higgins D.Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst.Science2017;357:479-84

[325] Fang X,Wang Y.Single Pt atoms confined into a metal-organic framework for efficient photocatalysis.Adv Mater2018;30:1705112

[326] He T,Ni B.Zirconium-porphyrin-based metal-organic framework hollow nanotubes for immobilization of noble-metal single atoms.Angew Chem Int Ed Engl2018;57:3493-8

[327] Abdel-Mageed AM,Parlinska-Wojtan M,Yaghi OM.Highly active and stable single-atom Cu catalysts supported by a metal-organic framework.J Am Chem Soc2019;141:5201-10

[328] Zuo Q,Chen C.Ultrathin metal-organic framework nanosheets with ultrahigh loading of single Pt atoms for efficient visible-light-driven photocatalytic H₂ evolution.Angew Chem Int Ed Engl2019;58:10198-203

[329] Qiu J,Xie K.Noble metal nanoparticle-functionalized Zr-metal organic frameworks with excellent photocatalytic performance.J Colloid Interface Sci2019;538:569-77

[330] Chen S,Jin J.Individually encapsulated frame-in-frame structure.ACS Materials Lett2020;2:685-90

[331] Kalaj M,Ayala S Jr.MOF-polymer hybrid materials: from simple composites to tailored architectures.Chem Rev2020;120:8267-302

[332] Iizuka T,Uemura T.Enhanced mechanical properties of a metal-organic framework by polymer insertion.Chem Commun2019;55:691-4

[333] DeCoste JB,Peterson GW,Cohen SM.Enhanced aging properties of HKUST-1 in hydrophobic mixed-matrix membranes for ammonia adsorption.Chem Sci2016;7:2711-6 PMCID:PMC5477018

[334] Kalaj M,Bentz KC,Cohen SM.Nylon-MOF composites through postsynthetic polymerization.Angew Chem Int Ed Engl2019;58:2336-40

[335] Fu D,Zheng X.Polymer-metal-organic framework hybrids for bioimaging and cancer therapy.Coord Chem Rev2022;456:214393

[336] Tan C,Wu X.Epitaxial growth of hybrid nanostructures.Nat Rev Mater2018;3

[337] Liu C,Wan J.MOF-on-MOF hybrids: synthesis and applications.Coord Chem Rev2021;432:213743

[338] Chai L,Hu Y,Hong M.Rational design and growth of MOF-on-MOF heterostructures.Small2021;17:e2100607

[339] Deng X,Huang H.Shape-defined hollow structural Co-MOF-74 and metal nanoparticles@Co-MOF-74 composite through a transformation strategy for enhanced photocatalysis performance.Small2019;15:e1902287

[340] Feng L,Yan TH.Modular programming of hierarchy and diversity in multivariate polymer/metal-organic framework hybrid composites.J Am Chem Soc2019;141:10342-9

[341] Zhu K,Wu J.MOF-on-MOF membrane with cascading functionality for capturing dichromate ions and p-arsanilic acid turn-on sensing.ACS Appl Mater Interfaces2020;12:58239-51

[342] Choi S,Ji H,Oh M.Isotropic and anisotropic growth of metal-organic framework (MOF) on MOF: logical inference on MOF structure based on growth behavior and morphological feature.J Am Chem Soc2016;138:14434-40

[343] Pan Y,Liu S.Core-shell ZIF-8@ZIF-67-derived CoP nanoparticle-embedded N-doped carbon nanotube hollow polyhedron for efficient overall water splitting.J Am Chem Soc2018;140:2610-8

[344] Zhan G.Hydrogen spillover through Matryoshka-type (ZIFs@)(n-1)ZIFs nanocubes.Nat Commun2018;9:3778 PMCID:PMC6141604

[345] Lee HJ,Cho W.Controlled isotropic or anisotropic nanoscale growth of coordination polymers: formation of hybrid coordination polymer particles.ACS Nano2013;7:491-9

[346] Chernikova V,Spanopoulos I,Eddaoudi M.Liquid phase epitaxial growth of heterostructured hierarchical MOF thin films.Chem Commun2017;53:6191-4

[347] Yang X,Zou L.One-step synthesis of hybrid core-shell metal-organic frameworks.Angew Chem Int Ed Engl2018;57:3927-32

[348] Kim D,Oh S.Unbalanced MOF-on-MOF growth for the production of a lopsided core-shell of MIL-88B@MIL-88A with mismatched cell parameters.Chem Commun2018;55:43-6

[349] Lee S,Oh M.Atypical hybrid metal-organic frameworks (MOFs): a combinative process for MOF-on-MOF growth, etching, and structure transformation.Angew Chem Int Ed Engl2020;59:1327-33

[350] Zha Q,Qin G.Cobalt-based MOF-on-MOF two-dimensional heterojunction nanostructures for enhanced oxygen evolution reaction electrocatalytic activity.Inorg Chem2020;59:1295-305

[351] Zhao M,Chen B.Selective epitaxial growth of oriented hierarchical metal-organic framework heterostructures.J Am Chem Soc2020;142:8953-61

[352] Haldar R.Hierarchical assemblies of molecular frameworks - MOF-on-MOF epitaxial heterostructures.Nano Res2021;14:355-68

[353] Abdollahzadeh M,Hosseini E.Designing angstrom-scale asymmetric MOF-on-MOF cavities for high monovalent ion selectivity.Adv Mater2022;34:e2107878

[354] Lee G,Oh S,Oh M.Tip-to-middle anisotropic MOF-On-MOF growth with a structural adjustment.J Am Chem Soc2020;142:3042-9

[355] Gu Z,Pan T.Anisotropic MOF-on-MOF growth of isostructural multilayer metal-organic framework heterostructures.Research2021;2021:9854946 PMCID:PMC8613540

[356] Van Vleet MJ, Weng T, Li X, Schmidt JR. In situ, time-resolved, and mechanistic studies of metal-organic framework nucleation and growth.Chem Rev2018;118:3681-721

[357] Pienack N.In-situ monitoring of the formation of crystalline solids.Angew Chem Int Ed Engl2011;50:2014-34