Zeolite-confined Fe-site Catalysts for the Hydrogenation of CO₂ to Produce High-value Chemicals

Abstract

Zeolite-confined Fe-site catalysts (ZFCs) have emerged as superior materials for sustainably producing high-value chemicals through CO₂ hydrogenation, owing to their adaptable framework, customizable composition, and thermal robustness. They excel in activating, adsorbing, and converting CO₂ with remarkable efficiency and consistency in performance. This has sparked a surge in research interest in recent years. The review delves into the latest advancements in CO₂ catalytic hydrogenation to olefins, alcohols, aromatics, and other liquid hydrocarbons, examining the synthesis, modification tactics, and the correlation between structure and performance across various ZFCs. Additionally, it underscores the pivotal factors affecting performance and sheds light on the mechanisms behind selectivity control in the CO₂ hydrogenation process facilitated by ZFCs. To conclude, it presents pressing challenges and strategic recommendations to inspire the development of high-performance, durable ZFCs for CO₂ hydrogenation applications.

Keywords

Zeolite-confined Fe-site catalyst / CO₂ hydrogenation / Modification strategy / High-value chemical

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