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Abstract
Searching for low-cost, high-capacity, high-power, high-stability, high-tapdensity, and inherently safe materials for developing cheap, safe, and highperformance batteries has always been a research hotspot. Herein, an inherently safe, low-cost, and low-strain KTiOPO4 (KTOP) submicron single crystals with a uniform thin layer carbon coating are developed using a ball-mill assisted solid-state method. Uniform solid electrolyte interphase, carbon coating, and inherently stable structure synergistically help compact KTOP submicron single crystals achieve an exceptional anodic K-ion storage performance. The carbon-coated KTOP single crystals obtained under the carbonization temperature of 400°C (KTOP-C-400) can deliver an exceptional potassium ion storage performance of 253.3, 224.0, 175.5, and 131.1mA h g–1 at the current density of 100, 200, 500, and 1000 mA g–1, respectively, in the electrolyte of 5M potassium bis(fluorosulfonyl)imide (KFSI) in DIGLYME electrolytes. Even after being cycled at 1000 mA g–1 for 1000 cycles, the capacity was maintained at 182.5 mAh g–1 with a coulombic efficiency of 99.9%.
Keywords
anode materials
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ball-milling assisted solid-state method
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polyanionic compounds
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potassium-ion batteries
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potassium titanium oxide phosphate
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Ling Bai, Su Jin, Qian Liu, Wenjuan Xu, Ziquan Li, Zhen-Dong Huang.
Uniform carbon coating and solid electrolyte interphase synergistically enhanced exceptional anodic K-ion storage properties of stable KTiOPO4 single crystals.
Carbon Neutralization, 2024, 3(6): 1131-1139 DOI:10.1002/cnl2.167
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2024 The Author(s). Carbon Neutralization published by Wenzhou University and John Wiley & Sons Australia, Ltd.
