Solid-electrolyte interphases for all-solid-state batteries

Yu Xia; Xu Han; Yue Ji; Simeng Zhang; Saiqi Wei; Yue Gong; Junyi Yue; Yueyue Wang; Xiaona Li; Zhiqiang Fang; Changtai Zhao; Jianwen Liang

doi:10.1016/j.chphma.2024.09.006

ChemPhysMater ›› 2025, Vol. 4 ›› Issue (1) : 9 -29. DOI: 10.1016/j.chphma.2024.09.006

Research article

research-article

Solid-electrolyte interphases for all-solid-state batteries

Yu Xia ^a^,^b^,^c^,^d^,^#
, Xu Han ^a^,^b^,^c^,^d^,^#
, Yue Ji ^a^,^b^,^c^,^d
, Simeng Zhang ^b^,^e
, Saiqi Wei ^b^,^f
, Yue Gong ^b^,^g^,^h
, Junyi Yue ^b^,^e
, Yueyue Wang ^a^,^b^,^c^,^d
, Xiaona Li ^e
, Zhiqiang Fang ^a^,^b^,^c^,^d^,^*
, Changtai Zhao ^a^,^b^,^c^,^d^,^*
, Jianwen Liang ^a^,^b^,^c^,^d^,^*

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Abstract

Interfacial engineering, particularly the design of artificial solid-electrolyte interphases (SEIs), has been successfully applied in all-solid-state batteries (ASSLBs) for industrial applications. However, a fundamental understanding of the synthesis and mechanism models of artificial SEIs in all-solid-state Li-ion batteries remains limited. In this review, recent advances in designing and synthesizing artificial SEIs for ASSLBs to solve interfacial issues are thoroughly discussed, covering three main preparation methods and their technical routes: 1) atomic layer deposition, 2) sol-gel methods, and 3) mechanical ball-milling methods. Moreover, advanced ex-situ characterization techniques for artificial SEIs are comprehensively summarized. Finally, this review provides perspectives on techniques for the interface engineering of artificial SEIs for ASSLBs, with focus on promising methods for industrial applications.

Keywords

All-solid-state lithium batteries / Interfacial engineering / Solid-electrolyte interphase / Atomic layer deposition / Sol-gel / Mechanical ball-milling

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Yu Xia, Xu Han, Yue Ji, Simeng Zhang, Saiqi Wei, Yue Gong, Junyi Yue, Yueyue Wang, Xiaona Li, Zhiqiang Fang, Changtai Zhao, Jianwen Liang. Solid-electrolyte interphases for all-solid-state batteries. ChemPhysMater, 2025, 4(1): 9-29 DOI:10.1016/j.chphma.2024.09.006

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Declaration of Competing Interest

The authors declare the following personal relationships which may be considered as competing interests: Yu Xia, Xu Han, Yue Ji, Yueyue Wang, Zhiqiang Fang, Changtai Zhao, Jianwen Liang are currently employed by GRINM Group Co., Ltd. and China Automotive Battery Research Institute Co., Ltd.; Yue Gong is currently employed by China FAW Corporation Limited. Other authors declare that there are no competing interests.

CRediT authorship contribution statement

Yu Xia: Writing - review & editing, Writing - original draft. Xu Han: Writing - review & editing, Investigation. Yue Ji: Writing - review & editing. Simeng Zhang: Writing - review & editing, Visualization. Saiqi Wei: Writing - review & editing. Yue Gong: Writing - review & editing. Junyi Yue: Writing - review & editing. Yueyue Wang: Writing - review & editing. Xiaona Li: Writing - review & editing, Visualization, Supervision. Zhiqiang Fang: Writing - review & editing, Visualization, Supervision. Changtai Zhao: Writing - review & editing, Visualization, Supervision, Investigation, Conceptualization. Jianwen Liang: Writing - review & editing, Project administration, Funding acquisition, Conceptualization.

Acknowledgements

This research was supported by the National Key R&D Program of China (2022YFB3506300), National Natural Science Foundation of China (No. 52176185), Guangdong-Foshan Joint Fund (2023A1515140091), Guangdong High-level Innovation Institute project (2021B090905000), Ningbo Yongjiang Talent Introduction Program (2023A-184-G), and Eastern Institute of Technology, Ningbo.

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