Design of narrow bandgap Fe₂O₃/MoO₃ heterostructure for boosting triethylamine sensing performance

Abstract

To achieve the rapid and real-time detection of triethylamine (TEA) gas, this study synthesized a gas sensor based on heterostructures of Fe₂O₃/MoO₃ using a hydrothermal method. Fe₂O₃/MoO₃ composites with a narrow bandgap (1.1 eV) were successfully synthesized by constructing heterostructures. The rapid and efficient detection of triethylamine was achieved at 220 °C. The response and response/recovery times of the Fe₂O₃/MoO₃ sensor with 50 × 10⁻⁶ triethylamine were 132 s and 5 s/10 s, respectively. The Fe₂O₃/MoO₃ sensor maintained a good response to triethylamine gas, even at 80% relative humidity. The sensing mechanism of the Fe₂O₃/MoO₃ sensor can be described in terms of adsorption energy and electronic behavior of the sensing layer using density functional theory (DFT). The results are consistent with the excellent selectivity and rapid response/recovery of the Fe₂O₃/MoO₃ gas sensor for triethylamine. Therefore, the construction of heterostructures to facilitate electron transmission is an effective strategy to achieve rapid detection of triethylamine and is worthy of further exploration and investigation.

Keywords

Fe₂O₃/MoO₃ / Heterostructure / Triethylamine / DFT / Narrow bandgap

Declaration of Competing Interests

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

CRediT authorship contribution statement

Shuai Zhang: Writing - original draft, Investigation, Formal analysis, Data curation. Qi Wang: Validation, Resources. Peng Song: Writing - review & editing, Funding acquisition.

Acknowledgements

This work was financially supported by National Natural Science Foundation of China (Nos. 61102006 and 51803109) and Natural Science Foundation of Shandong Province, China (ZR2022MF234 and No. ZR2018LE006).

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