Spatial and temporal variations in parameters at the upper boundary of gas hydrate stability zone of the Sea of Okhotsk

Abstract

This study was used oceanographic database in the Sea of Okhotsk between the period from 1929 to 2020 (131286 stations). The paper used gas hydrate dissociation parameters for the “pure methane-seawater” system obtained in the study by Dickens GR and Quinby-Hunt MS. The results have elucidated the spatiotemporal variability of distribution of such parameters at the upper boundary of the gas hydrate stability zone (GHSZ) as water temperature, salinity, and top depth of the stability zone. As the study has shown (based on average long-term spatial distributions), the minimum temperature and depth values of the GHSZ upper boundary in the Sea of Okhotsk occur off the western and southwestern parts of the water area. The maximum temperature and depth values of the GHSZ upper boundary are typical of the southeastern sea area and over the Kamchatka Peninsula slope. This study has also identified an area, where there are no thermobaric conditions for the emergence and stable existence of methane hydrates in the water column. The results presented agree well with the materials of observations conducted during expeditions and the previous data of predictive simulations for the Sea of Okhotsk.

Keywords

Methane hydrates / Thermobaric conditions / Stability zone / Upper boundary / Water column / Spatiotemporal variability / Sea of Okhotsk

CRediT authorship contribution statement

The authors made equal contributions at all stages of preparation of the paper (objective setting, calculations, analysis of results, and writing of text). All authors discussed the results obtained from the study and contributed to the final version of this article.

Declaration of competing interest

The authors declare no conflicts of interest.

Acknowledgments

The authors express their sincere gratitude to the reviewers for the constructive comments. This study is a contribution to fulfilling the goals of the GEOMIR project within the framework of the national action plan for the United Nations Decade of Ocean Sciences for Sustainable Development (2021-2030) and the WESTPAC Working Group on Gas Hydrates and Methane Fluxes in the IndoPacific Region. The study was carried out in accordance with the state budget topic for the POI FEB RAS, entitled "Study of the Structure and Dynamics of World's Oceans Waters in Conditions of Current Climate Change" (reg. no. 124022100079-4).

References

[1] Alfultis MA, Martin S. 1987. Satellite passive microwave studies of the Sea of Okhotsk ice cover and its relation to oceanic processes, 1978-1982. Journal of Geophysical Research: Oceans, 92(C12), 13013-13028. doi: 10.1029/jc092ic12p13013.

[2] Biastoch A, Treude T, Rüpke LH, Riebesell U, Roth C, Burwicz EB, Park W, Latif M, Böning CW, Madec G, Wallmann K. 2011. Rising Arctic Ocean temperatures cause gas hydrate destabilization and ocean acidification. Geophysical Research Letters, 38(8), L08602. doi: 10.1029/2011g1047222.

[3] Bogoyavlensky V, Kishankov A, Yanchevskaya A, Bogoyavlensky I. 2018a. Forecast of gas hydrates distribution zones in the Arctic Ocean and adjacent offshore areas. Geosciences, 8(12), 453. doi: 10.3390/geosciences8120453.

[4] Bogoyavlensky VI, Yanchevskaya AS, Bogoyavlensky IV, Kishankov AV. 2018b. Gas hydrates in the Circum-Arctic Region aquatories. Arctic: Ecology and Economy, 3(31), 42-55 (in Russian with English abstract). doi: 10.25283/2223-4594-2018-3-42-55.

[5] Chen ZA, Bai WM, Xu WY. 2005. Prediction of stability zones and occurrence zones of Multiple composition natural gas hydrate in marine sediment. Chinese Journal of Geophysics, 48(4), 939-945. doi: 10.1002/cjg2.733.

[6] Chen ZA, Bai WM, Xu WY, Jin ZH. 2010. An analysis on stability and deposition zones of natural gas hydrate in Dongsha Region, north of South China Sea. Journal of Thermodynamics, 185639. doi: 10.1155/2010/185639.

[7] Dickens GR, Quinby-Hunt MS. 1994. Methane hydrate stability in seawater. Geophysical Research Letters, 21(19), 2115-2118. doi: 10.1029/94g101858.

[8] Eliseev AV. 2018. Global methane cycle: A review. Fundamental and Applied Climatology, 1, 52-70. doi: 10.21513/2410-8758-2018-1-52-70.

[9] Fayman PA, Prants SV, Budyansky MV, Uleysky MY. 2021. Simulated pathways of the northwestern Pacific water in the Okhotsk Sea. Izvestiya, Atmospheric and Oceanic Physics, 57(3), 329-340. doi: 10.1134/s000143382103004x.

[10] Figurkin AL. 2011. Variability of temperature and salinity from bottom waters in the northern Okhotsk Sea. Izvestiya TINRO, 166, 255-274 (in Russian with English abstract).

[11] Ginsburg GD, Gramberg IS, Soloviev VA. 1990. Geology of submarine gas hydrates. Sovietskaya Geologiya, 11, 12-19 (in Russian).

[12] Giustiniani M, Tinivella U, Jakobsson M, Rebesco M. 2013. Arctic ocean gas hydrate stability in a changing climate. Journal of Geological Research, 783969. doi: 10.1155/2013/783969.

[13] Gladyshev S, Talley L, Kantakov G, Khen G, Wakatsuchi M. 2003. Distribution, formation, and seasonal variability of Okhotsk Sea mode water. Journal of Geophysical Research: Oceans, 108(C6), 3186. doi: 10.1029/2001jc000877.

[14] Granin NG, Makarov MM, Kucher KM, Gnatovsky RY. 2010. Gas seeps in Lake Baikal-detection, distribution, and implications for water column mixing. Geo-Marine Letters, 30(3-4), 399-409. doi: 10.1007/s00367-010-0201-3.

[15] Holder GD, Malone RD, Lawson WF. 1987. Effects of gas composition and geothermal properties on the thickness and depth of natural-gashydrate zones. Journal of Petroleum Technology, 39(9), 1147-1152. doi: 10.2118/13595-pa.

[16] Istomin VA, Yakushev VS. 1992. Gas hydrates in natural conditions. Nedra, Moscow, 236 (in Russian).

[17] Itoh M, Ohshima KI, Wakatsuchi M. 2003. Distribution and formation of Okhotsk Sea intermediate water: An analysis of isopycnal climatological data. Journal of Geophysical Research: Oceans, 108(C8), 3258. doi: 10.1029/2002jc001590.

[18] Jin YK, Shoji H, Obzhirov A, Baranov B. 2013. Operation report of Sakhalin slope gas hydrate project 2012, R/V Akademik MA Lavrentyev, Cruise 59. Korea Polar Research Institute, 163.

[19] Jin YK, Minami H, Baranov B, Nikolaeva N, Obzhirov A. 2015. Operation Report of Sakhalin Slope Gas Hydrate Project II, 2014, R/V Akademik MA Lavrentyev, Cruise 67. Korea Polar Research Institute, 121.

[20] Kitani K. 1973. An oceanographic study of the Okhotsk Sea-particularly in regard to cold waters. Bull. Far Seas Fisheries Research Laboratory, 9, 45-77.

[21] Luchin VA. 1982. Diagnostic calculation of water circulation in the Sea of Okhotsk in a summer season. Trudy DVNIGMI, 96, 69-77 (in Russian).

[22] Luchin VA. 1987. The Sea of Okhotsk circulation and features of its interannual variability as referred from diagnostic calculations, Trudy DVNIGMI, 36, 3-13 (in Russian).

[23] Luchin VA. 2007. Seasonal variations in water temperature in the active layer of Far East Seas, in Dal'nevostochnye morya Rossii (Far East Seas of Russia), Book 1, Nauka, Moscow, 232-252 (in Russian).

[24] Luchin VA, Zhigalov IA. 2006. Types of water temperature distribution in active layer of the Okhotsk Sea and possibility of its prediction. Izvestiya TINRO, 147, 183-204 (in Russian with English abstract).

[25] Luchin VA, Kruts AA. 2016. Properties of cores of the water masses in the Okhotsk Sea. Izvestiya TINRO, 184(1), 204-218. doi: 10.26428/1606-9919-2016-184-204-218.

[26] Makogon YF. 2003. Natural gas hydrates: Distribution, models of formation, resources. Russian Chemistry Journal, 47(3), 70-79 (in Russian).

[27] Makogon YF. 2010. Gas hydrates, History of development and prospects of study. Geology and mineral resources of World Ocean, 2, 5-21 (in Russian).

[28] Martin S, Drucker R, Yamashita K. 1998. The production of ice and dense shelf water in the Okhotsk Sea polynyas. Journal of Geophysical Research: Oceans, 103(C12), 27771-27782. doi: 10.1029/98jc02242.

[29] McGinnis DF, Greinert J, Artemov Y, Beaubien SE, Wüest A. 2006. Fate of rising methane bubbles in stratified waters: How much methane reaches the atmosphere? Journal of Geophysical Research:Oceans, 111(C9), C09007. doi: 10.1029/2005jc003183.

[30] Mehta AP, Sloan ED. 1996. Improved thermodynamic parameters for prediction of structure H hydrate equilibria. AIChE Journal, 42(7), 2036-2046. doi: 10.1002/aic.690420724.

[31] Bondur VG, Mokhov II, Macosko AA. 2022. Methane and climate change: Scientific problems and technological aspects. Russian Academy of Sciences, Moscow, 388 (in Russian).

[32] Minami H, Jin YK, Baranov B, Nikolaeva N, Obzhirov A. 2016. Operation Report of Sakhalin Slope Gas Hydrate Project II, 2015, R/V Akademik MA Lavrentyev, Cruise 70. Kitami Institute of Technology, 119.

[33] Moroshkin KV. 1966. Water masses of the Sea of Okhotsk. Nauka, Moscow, 70 (in Russian).

[34] Nakanowatari T, Ohshima KI, Wakatsuchi M. 2007. Warming and oxygen decrease of intermediate water in the northwestern North Pacific, originating from the Sea of Okhotsk, 1955-2004. Geophysical Research Letters, 34(4), L04602. doi: 10.1029/2006gl028243.

[35] Obzhirov AI. 2018. Gasgeochemical precursors of seismic activity, earthquakes, volcanic episodes on the Kamchatka and Sea of Okhotsk

[36] ( to use information of the Kamchatka scientific conferences 2017). Geosystems of Transition Zones, 2(1), 57-68 (in Russian with English abstract ) . doi: 10.30730/2541-8912.2018.2.1.057-068.

[37] Obzhirov AI, Shakirov RB. 2012. Gas hydrate complex geological and geophysical investigation in the Okhotsk Sea. Geology and geoecology of Eurasian continental margins, 4, Special issue, Geology and mineral resources of the Eurasian marginal seas, GEOS, Moscow, 122-136 (in Russian).

[38] Obzhirov AI, Shakirov RB. 2013. Sources of hydrocarbon gases, conditions of gas hydrate formation, and their relation with petroleum reservoirs in the Sea of Okhotsk. Oceanographic studies of the Far Eastern Seas and North-Western Pacific, Book 2, Dalnauka, Vladivostok, 149-161 (in Russian).

[39] Ohshima KI, Nakanowatari T, Riser S, Wakatsuchi M. 2010. Seasonal variation in the in- and outflow of the Okhotsk Sea with the North Pacific. Deep Sea Research Part II: Topical Studies in Oceanography, 57(13-14), 1247-1256. doi: 10.1016/j.dsr2.2009.12.012.

[40] Ono K, Ohshima KI, Kono T, Itoh M, Katsumata K, Volkov YN, Wakatsuchi M. 2007. Water mass exchange and diapycnal mixing at Bussol' Strait revealed by water mass properties. Journal of Oceanography, 63(2), 281-291. doi: 10.1007/s10872-007-0028-3.

[41] Reagan MT, Moridis GJ. 2007. Oceanic gas hydrate instability and dissociation under climate change scenarios. Geophysical Research Letters, 34(22), L22709. doi: 10.1029/2007g1031671.

[42] Reagan MT, Moridis GJ, Elliott SM, Maltrud M. 2011. Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes. Journal of Geophysical Research, 116(C9), C09014. doi: 10.1029/2011jc007189.

[43] Shcherbina AY, Talley LD, Rudnick DL. 2003. Direct observations of North Pacific ventilation: Brine rejection in the Okhotsk Sea. Science, 302(5652), 1952-1955. doi: 10.1126/science.1088692.

[44] Shoji H, Jin YK, Baranov B, Nikolaeva N, Obzhirov A. 2014. Operation Report of Sakhalin Slope Gas Hydrate Project II, 2013, R/V Akademik MA Lavrentyev, Cruise 62. Environmental and Energy Resources Research Center, Kitami Institute of Technology, Kitami, 111.

[45] Sloan ED. 1998. Off shore hydrate engineering handbook. Center for Hydrate Research, Colorado School of Mines. Golden, Colorado.

[46] Sloan ED, Sparks KA, Johnson JJ. 1987. Two-phase liquid hydrocarbonhydrate equilibrium for ethane and propane. Industrial & Engineering Chemistry Research, 26(6), 1173-1179. doi: 10.1021/ie00066a019.

[47] Sloan ED, Koh CA. 2008. Clathrate Hydrates of Natural Gases. CRC Press, Boca Raton, Fla, USA, 3rd edition, 752. doi: 10.1201/9781420008494.

[48] Smyshlyaev SP, Mareev EA, Galin VY, Blakitnaya PA. 2015. Modeling the influence of methane emissions from Arctic gas hydrates on regional variations in composition of the lower atmosphere. Izvestiya, Atmospheric and Oceanic Physics, 51(4), 412-422. doi: 10.1134/s000143381504012x.

[49] Talley LD. 1991. An Okhotsk Sea water anomaly: Implications for ventilation in the North Pacific. Deep Sea Research Part A. Oceanographic Research Papers, 38(1), S171-S190. doi: 10.1016/ S0198- 0149(12)80009-4.

[50] Trofimuk AA, Cherskiy NV, Tsarev VP. 1973. Accumulation of natural gases in zones of hydrate formation in the hydrosphere. Doklady Akademii Nauk SSSR, 212(4), 931-934 (in Russian).

[51] Veselov OV, Gordienko VV, Kudelkin VV. 2006. Thermobaric conditions of gas hydrate formation in the Sea of Okhotsk. Geology and Mineral Resources of World Ocean, 3(5), 62-68 (in Russian).

[52] Vorobiov AE, Malyukov VP. 2009. Gas hydrates. Technologies of influence on unconventional hydrocarbons: Manual, the revised & added 2nd edition, Peoples' friendship Russian University (RUDN), Moscow, 289 (in Russian).

[53] Wong CS, Matear RJ, Freeland HJ, Whitney FA, Bychkov AS. 1998. WOCE line P1W in the Sea of Okhotsk: 2. CFCs and the formation rate of intermediate water. Journal of Geophysical Research: Oceans, 103(C8), 15625-15642. doi: 10.1029/98jc01008.

[54] Yakutseni VP. 2013. Gas hydrates-unconventional gas sources, their formation, properties, distribution and geological resources. Petroleum Geology - Theoretical and Applied Studies, 8(4), 1-24 (in Russian with English abstract).

[55] Yasuda I. 1997. The origin of the North Pacific intermediate water. Journal of Geophysical Research: Oceans, 102(C1), 893-909. doi: 10.1029/96jc02938.