Research Progress on the Application of MOF Materials in Lithium-Ion Batteries

Abstract

Lithium-ion batteries (LIBs) have established themselves as the preferred power sources for both pure electric and hybrid vehicles, attributable to their exceptional characteristics, including prolonged cycle life, elevated energy density, and minimal self-discharge rates. Metal-organic frameworks (MOFs), as innovative functional molecular crystal materials, exhibit promising application prospects in LIBs. This paper provides a comprehensive overview of the latest advancements in the synthesis techniques and structural modulation of MOFs and their derivative materials. It particularly emphasizes a thorough exploration of the utilization of MOFs and their derivatives in the anode, cathode, and separators of LIBs. Additionally, this paper delves into the current obstacles encountered by MOFs in LIB applications and offers insights into their potential future development.

Keywords

anode / cathode / lithium-ion batteries / metal-organic frameworks / separators

References

[1] M. Li, J. Lu, Z. Chen, and K. Amine, “30 Years of Lithium-Ion Batteries,” Advanced Materials 30 (2018):1800561.

[2] A. Yoshino, “The Birth of the Lithium-Ion Battery,” Angewandte Chemie International Edition 51 (2012):5798–5800.

[3] C. Zhou, C. Dong, W. Wang, et al., “An Ultrathin and Crack-Free Metal-Organic Framework Film for Effective Polysulfide Inhibition in Lithium–Sulfur Batteries,” Interdisciplinary Materials 3 (2024):306–315.

[4] X. Jian, X. Liu, C. Yang, et al., “In Situ Construction of Inorganics-Rich Cathode-Electrolyte Interface Toward Long-Life Prussian White Cathode,” Small 20 (2024):2400709.

[5] Y. Zhang, X. Zhou, C. Yang, et al., “Air-Stable Prussian White Cathode Materials for Sodium-Ion Batteries Enabled by ZnO Surface Modification,” ACS Applied Materials &Interfaces 16 (2024):15649–15656.

[6] L. Chen, Z. Liu, W. Yang, et al., “Micro-Mesoporous Cobalt Phosphosulfide (Co₃S₄/CoP/NC) Nanowires for Ultrahigh Rate Capacity and Ultrastable Sodium Ion Battery,” Journal of Colloid and Interface Science 666 (2024):416–423.

[7] Y. L. Heng, Z. Y. Gu, J. Z. Guo, and X. L. Wu, “Research Progresses on Vanadium-Based Cathode Materials for Aqueous Zinc-Ion Batteries,” Acta Physico-Chimica Sinica 37 (2021):2005013.

[8] Z.-Y. Gu, X.-T. Wang, Y.-L. Heng, et al., “Prospects and Perspectives on Advanced Materials for Sodium-Ion Batteries,” Science Bulletin 68 (2023):2302–2306.

[9] C. Xiao, X. Tang, J. Peng, and Y. Ding, “Graphene-Like BSi as a Promising Anode Material for Li-and Mg-Ion Batteries: A First Principle Study,” Applied Surface Science 563 (2021):150278.

[10] E. Fan, L. Li, Z. Wang, et al., “Sustainable Recycling Technology for Li-Ion Batteries and Beyond: Challenges and Future Prospects,” Chemical Reviews 120 (2020):7020–7063.

[11] X. Cai, L. Lai, Z. Shen, and J. Lin, “Graphene and Graphene-Based Composites as Li-Ion Battery Electrode Materials and Their Application in Full Cells,” Journal of Materials Chemistry A 5 (2017):15423–15446.

[12] H. Aghamohammadi, R. Eslami-Farsani, and E. Castillo-Martinez, “Recent Trends in the Development of MXenes and MXene-Based Composites as Anode Materials for Li-Ion Batteries,” Journal of Energy Storage 47 (2022):103572.

[13] H. Chen, W. Zhang, X.-Q. Tang, et al., “First Principles Study of P-Doped Borophene as Anode Materials for Lithium Ion Batteries,” Applied Surface Science 427 (2018):198–205.

[14] W. Zhang, F. Li, J. Hu, et al., “Strain Engineering on Transmission Carriers of Monolayer Phosphorene,” Journal of Physics: Condensed Matter 29 (2017):465501.

[15] C. Xiao, X. Tang, J. Peng, and Y. Ding, “Graphene-Like BSi as a Promising Anode Material for Li-and Mg-Ion Batteries: A First Principle Study,” Applied Surface Science 563 (2021):150278.

[16] S. Xu, X. Fan, J. Liu, D. J. Singh, Q. Jiang, and W. Zheng, “Adsorption of Li on Single-Layer Silicene for Anodes of Li-Ion Batteries,” Physical Chemistry Chemical Physics 20 (2018):8887–8896.

[17] M. Wu and Z. Zhou, “Covalent Organic Frameworks as Electrode Materials for Rechargeable Metal-Ion Batteries,” Interdisciplinary Materials 2 (2023):231–259.

[18] S. Wang, Q. Wang, P. Shao, et al., “Exfoliation of Covalent Organic Frameworks Into Few-Layer Redox-Active Nanosheets as Cathode Materials for Lithium-Ion Batteries,” Journal of the American Chemical Society 139 (2017):4258–4261.

[19] A. K. Thakur, M. Majumder, S. P. Patole, K. Zaghib, and M. V. Reddy, “Metal–Organic Framework-Based Materials: Advances, Exploits, and Challenges in Promoting Post Li-Ion Battery Technologies,” Materials Advances 2 (2021):2457–2482.

[20] R. Freund, O. Zaremba, G. Arnauts, et al., “The Current Status of MOF and COF Applications,” Angewandte Chemie International Edition 60 (2021):23975–24001.

[21] Q. Wang and D. Astruc, “State of the Art and Prospects in Metal–Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis,” Chemical Reviews 120 (2020):1438–1511.

[22] B.-J. Xin and X.-L. Wu, “Research Progresses on Metal-Organic Frameworks for Sodium/Potassium-Ion Batteries,” Battery Energy 3 (2024):20230074.

[23] L. Chai, J. Pan, Y. Hu, J. Qian, and M. Hong, “Rational Design and Growth of MOF-on-MOF Heterostructures,” Small 17 (2021):2100607.

[24] M. Rubio-Martinez, C. Avci-Camur, A. W. Thornton, I. Imaz, D. Maspoch, and M. R. Hill, “New Synthetic Routes Towards MOF Production at Scale,” Chemical Society Reviews 46 (2017):3453–3480.

[25] M. Y. Masoomi, A. Morsali, A. Dhakshinamoorthy, and H. Garcia, “Mixed-Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design,” Angewandte Chemie 131 (2019):15330–15347.

[26] M. O’Keeffe and O. M. Yaghi, “Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials Into Their Underlying Nets,” Chemical Reviews 112 (2012):675–702.

[27] M. Eddaoudi, J. Kim, N. Rosi, et al., “Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage,” Science 295 (2002):469–472.

[28] Y. Peng, J. Xu, J. Xu, et al., “Metal-Organic Framework (MOF) Composites as Promising Materials for Energy Storage Applications,” Advances in Colloid and Interface Science 307 (2022):102732.

[29] L. Chen, X. Zhang, X. Cheng, Z. Xie, Q. Kuang, and L. Zheng, “The Function of Metal–Organic Frameworks in the Application of MOF-Based Composites,” Nanoscale Advances 2 (2020):2628–2647.

[30] X. Zhang, A. Chen, M. Zhong, et al., “Metal–Organic Frameworks (MOFs) and MOF-Derived Materials for Energy Storage and Conversion,” Electrochemical Energy Reviews 2 (2019):29–104.

[31] J. Ren, Y. Huang, H. Zhu, et al., “Recent Progress on MOF-Derived Carbon Materials for Energy Storage,” Carbon Energy 2 (2020):176–202.

[32] D. Sud and G. Kaur, “A Comprehensive Review on Synthetic Approaches for Metal-Organic Frameworks: From Traditional Solvothermal to Greener Protocols,” Polyhedron 193 (2021):114897.

[33] H. Li, M. Eddaoudi, M. O’Keeffe, and O. M. Yaghi, “Design and Synthesis of an Exceptionally Stable and Highly Porous Metal-Organic Framework,” Nature 402 (1999):276–279.

[34] Q. Chen, Y. Ying, L. Wang, et al., “A Heterometallic MOF Based on Monofunctional Linker by “One-Pot” Solvothermal Method for Highly Selective Gas Adsorption,” Zeitschrift für anorganische und allgemeine Chemie 646 (2020):437–443.

[35] M. Y. Zorainy, M. Sheashea, S. Kaliaguine, M. Gobara, and D. C. Boffito, “Facile Solvothermal Synthesis of a MIL-47(V) Metal–Organic Framework for a High-Performance Epoxy/MOF Coating With Improved Anticorrosion Properties,” RSC Advances 12 (2022):9008–9022.

[36] E. M. C Morales, M. A. Méndez-Rojas, L. M. Torres-Martínez, et al., “Ultrafast Synthesis of HKUST-1 Nanoparticles by Solvothermal Method: Properties and Possible Applications,” Polyhedron 210 (2021):115517.

[37] T. J. Azbell, T. A. Pitt, R. T. Jerozal, R. M. Mandel, and P. J. Milner, “Simplifying the Synthesis of Metal–Organic Frameworks,” Accounts of Materials Research 4 (2023):867–878.

[38] T. J. Azbell, T. A. Pitt, M. M. Bollmeyer, C. Cong, K. M. Lancaster, and P. J. Milner, “Ionothermal Synthesis of Metal-Organic Frameworks Using Low-Melting Metal Salt Precursors,” Angewandte Chemie International Edition 62 (2023): e202218252.

[39] M. Teixeira, R. A. Maia, S. Shanmugam, B. Louis, and S. A. Baudron, “Impact of Urea-Based Deep Eutectic Solvents on Mg-MOF-74 Morphology and Sorption Properties,” Microporous and Mesoporous Materials 343 (2022):112148.

[40] Z. Zheng, H. L. Nguyen, N. Hanikel, et al., “High-Yield, Green and Scalable Methods for Producing MOF-303 for Water Harvesting From Desert Air,” Nature Protocols 18 (2023):136–156.

[41] Z. Zhao, H. Li, K. Zhao, L. Wang, and X. Gao, “Microwave-Assisted Synthesis of MOFs: Rational Design via Numerical Simulation,” Chemical Engineering Journal 428 (2022):131006.

[42] S. Głowniak, B. Szczęśniak, J. Choma, and M. Jaroniec, “Mechanochemistry: Toward Green Synthesis of Metal–Organic Frameworks,” Materials Today 46 (2021):109–124.

[43] J. Beamish-Cook, K. Shankland, C. A. Murray, and P. Vaqueiro, “Insights Into the Mechanochemical Synthesis of MOF-74,” Crystal Growth &Design 21 (2021):3047–3055.

[44] T. Gao, H.-J. Tang, S.-Y. Zhang, et al., “Mechanochemical Synthesis of Three-Component Metal-Organic Frameworks for Large Scale Production,” Journal of Solid State Chemistry 303 (2021):122547.

[45] Y. Chen, H. Wu, Y. Yuan, et al., “Highly Rapid Mechanochemical Synthesis of a Pillar-Layer Metal-Organic Framework for Efficient CH4/N2 Separation,” Chemical Engineering Journal 385 (2020):123836.

[46] Z. Guo, Q. Zhang, Z. Cheng, et al., “Air-Flow Impacting Synthesis of Metal Organic Frameworks: A Continuous, Highly Efficient, Large-Scale Mechanochemical Synthetic Method,” ACS Sustainable Chemistry & Engineering 8 (2020):4037–4043.

[47] P. He, Z. Hu, Z. Dai, et al., “Mechanochemistry Milling of Waste Poly(Ethylene Terephthalate) Into Metal–Organic Frameworks,” Chemsuschem 16 (2023): e202201935.

[48] N. Zhao, K. Cai, and H. He, “The Synthesis of Metal–Organic Frameworks With Template Strategies,” Dalton Transactions 49 (2020):11467–11479.

[49] K. Li, J. Yang, and J. Gu, “Hierarchically Porous MOFs Synthesized by Soft-Template Strategies,” Accounts of Chemical Research 55 (2022):2235–2247.

[50] E. Doustkhah, R. Hassandoost, A. Khataee, R. Luque, and M. H. N. Assadi, “Hard-Templated Metal–Organic Frameworks for Advanced Applications,” Chemical Society Reviews 50 (2021):2927–2953.

[51] N. Wang, Y. Wei, M. Chang, J. Liu, and J.-X. Wang, “Macro-Meso-Microporous Metal–Organic Frameworks: Template-Assisted Spray Drying Synthesis and Enhanced Catalysis,” ACS Applied Materials &Interfaces 14 (2022):10712–10720.

[52] L. Meng, B. Yu, and Y. Qin, “Templated Interfacial Synthesis of Metal-Organic Framework (MOF) Nano-and Micro-Structures With Precisely Controlled Shapes and Sizes,” Communications Chemistry 4 (2021):82.

[53] K. Zhou, C. Zhang, Z. Xiong, et al., “Template-Directed Growth of Hierarchical MOF Hybrid Arrays for Tactile Sensor,” Advanced Functional Materials 30 (2020):2001296.

[54] A. Kumar and R. Kataria, “MOFs as Versatile Scaffolds to Explore Environmental Contaminants Based on Their Luminescence Bustle,” Science of the Total Environment 926 (2024):172129.

[55] V. M. V. M. and G. Nageswaran, “Review—Direct Electrochemical Synthesis of Metal Organic Frameworks,” Journal of the Electrochemical Society 167 (2020):155527.

[56] H. Ren and T. Wei, “Electrochemical Synthesis Methods of Metal-Organic Frameworks and Their Environmental Analysis Applications: A Review,” ChemElectroChem 9 (2022): e202200196.

[57] S. Zhou, O. Shekhah, J. Jia, et al., “Electrochemical Synthesis of Continuous Metal–Organic Framework Membranes for Separation of Hydrocarbons,” Nature Energy 6 (2021):882–891.

[58] A. Asghar, N. Iqbal, T. Noor, B. M. Kariuki, L. Kidwell, and T. L. Easun, “Efficient Electrochemical Synthesis of a Manganese-Based Metal–Organic Framework for H₂ and CO₂ Uptake,” Green Chemistry 23 (2021):1220–1227.

[59] Y. Liu, Y. Wei, M. Liu, et al., “Electrochemical Synthesis of Large Area Two-Dimensional Metal–Organic Framework Films on Copper Anodes,” Angewandte Chemie International Edition 60 (2021):2887–2891.

[60] I. Jahan, T. H. Rupam, M. Palash, K. A. Rocky, and B. B. Saha, “Energy Efficient Green Synthesized MOF-801 for Adsorption Cooling Applications,” Journal of Molecular Liquids 345 (2022):117760.

[61] A. Bakhshi, H. Saravani, G. Sargazi, and M. Shahbakhsh, “Ultrasound-Assisted Efficient Synthesis of a Novel Nd–MOF Polymer as a New Candidate for Electrocatalytic Activity in Hydrogen Storage,” Journal of Applied Electrochemistry 51 (2021):399–410.

[62] C. Xie, H. Li, B. Niu, H. Guo, and X. Lin, “Comparison of Ultrasonic vs Mechanochemistry Methods for Fabrication of Mixed-Ligand Zn-Based MOFs for Electrochemical Determination of Luteolin,” Journal of Alloys and Compounds 989 (2024):174363.

[63] V. Safarifard and A. Morsali, “Facile Preparation of Nanocubes Zinc-Based Metal-Organic Framework by an Ultrasound-Assisted Synthesis Method;Precursor for the Fabrication of Zinc Oxide Octahedral Nanostructures,” Ultrasonics Sonochemistry 40 (2018):921–928.

[64] G. Sargazi, D. Afzali, and A. Mostafavi, “A Novel Synthesis of a New Thorium (IV) Metal Organic Framework Nanostructure With Well Controllable Procedure Through Ultrasound Assisted Reverse Micelle Method,” Ultrasonics Sonochemistry 41 (2018):234–251.

[65] T. R. M. Nezhad and F. Manteghi, “Applying Benzene Tetracarboxylic Acid as a Linker in the Synthesis a Porous Ba (II)-Based MOF by Ultrasonic Method,” Proceedings 41 (2019):61.

[66] Z. Ma, D. Wu, X. Han, et al., “Ultrasonic Assisted Synthesis of Zn-Ni Bi-Metal MOFs for Interconnected Ni-N-C Materials With Enhanced Electrochemical Reduction of CO2,” Journal of CO₂ Utilization 32 (2019):251–258.

[67] F. Bigdeli, F. Rouhani, A. Morsali, and A. Ramazani, “Ultrasonic-Assisted Synthesis of the Nanostructures of a Co(II) Metal Organic Framework as a Highly Sensitive Fluorescence Probe of Phenol Derivatives,” Ultrasonics Sonochemistry 62 (2020):104862.

[68] T. Yan, Y. Huo, and W.-G. Pan, “Optimization Strategies of the Design and Preparation of Metal–Organic Framework Nanostructures for Water Sorption: A Review,” ACS Applied Nano Materials 6 (2023):10903–10924.

[69] F. Carraro, J. D. Williams, M. Linares-Moreau, et al., “Continuous-Flow Synthesis of ZIF-8 Biocomposites With Tunable Particle Size,” Angewandte Chemie International Edition 59 (2020):8123–8127.

[70] H. Reinsch, S. Waitschat, S. M. Chavan, K. P. Lillerud, and N. Stock, “A Facile “Green” Route for Scalable Batch Production and Continuous Synthesis of Zirconium MOFs,” European Journal of Inorganic Chemistry 2016 (2016):4490–4498.

[71] M. Rubio-Martinez, M. P. Batten, A. Polyzos, et al., “Versatile, High Quality and Scalable Continuous Flow Production of Metal-Organic Frameworks,” Scientific Reports 4 (2014):5443.

[72] J. Kim, S.-H. Kim, S.-T. Yang, and W.-S. Ahn, “Bench-Scale Preparation of Cu₃(BTC)₂ by Ethanol Reflux: Synthesis Optimization and Adsorption/Catalytic Applications,” Microporous and Mesoporous Materials 161 (2012):48–55.

[73] C. Fan, L. Wang, Y. Luo, Y. Song, T. Xu, and X. Zhang, “Cost-Effective Screening of Antimicrobial Performance of Multiple Metal–Organic Frameworks via a Droplet-Based Batch Synthesis Platform,” ACS Sustainable Chemistry & Engineering 10 (2022):6476–6482.

[74] W. Zheng, X. Hao, L. Zhao, and W. Sun, “Controllable Preparation of Nanoscale Metal–Organic Frameworks by Ionic Liquid Microemulsions,” Industrial & Engineering Chemistry Research 56 (2017):5899–5905.

[75] Q. Zhang, S. Yan, X. Yan, and Y. Lv, “Recent Advances in Metal-Organic Frameworks: Synthesis, Application and Toxicity,” Science of the Total Environment 902 (2023):165944.

[76] M. Moharramnejad, A. Ehsani, M. Shahi, et al., “MOF as Nanoscale Drug Delivery Devices: Synthesis and Recent Progress in Biomedical Applications,” Journal of Drug Delivery Science and Technology 81 (2023):104285.

[77] M. P. Bondarde, R. Jain, J. S. Sohn, et al., “Carbon-Based Anode Materials for Lithium-Ion Batteries,” Lithium-Sulfur Batteries (Elsevier, 2022), 521–545.

[78] F. Yao, B. Li, K. So, et al., “A Strategy to Overcome the Limits of Carbon-Based Materials as Lithium-Ion Battery Anodes,” Carbon 79 (2014):563–571.

[79] X. Liu, Y. Jiang, K. Li, F. Xu, P. Zhang, and Y. Ding, “Electrospun Free-Standing N-Doped C@SnO₂ Anode Paper for Flexible Li-Ion Batteries,” Materials Research Bulletin 109 (2019):41–48.

[80] J. Asenbauer, T. Eisenmann, M. Kuenzel, A. Kazzazi, Z. Chen, and D. Bresser, “The Success Story of Graphite as a Lithium-Ion Anode Material—Fundamentals, Remaining Challenges, and Recent Developments Including Silicon (Oxide) Composites,” Sustainable Energy & Fuels 4 (2020):5387–5416.

[81] J. Sun, L. Ye, X. Zhao, P. Zhang, and J. Yang, “Electronic Modulation and Structural Engineering of Carbon-Based Anodes for Low-Temperature Lithium-Ion Batteries: A Review,” Molecules 28 (2023):2108.

[82] B. Jin, F. Gao, Y. F. Zhu, et al., “Facile Synthesis of Non-Graphitizable Polypyrrole-Derived Carbon/Carbon Nanotubes for Lithium-Ion Batteries,” Scientific Reports 6 (2016):19317.

[83] Z. Li, G. Li, J. Ouyang, et al., “Defective Lithium Storage Boosts High Rate and Long-Life Span of Carbon Fibers,” ChemistrySelect 4 (2019):5768–5775.

[84] F. Li, C. Deng, X. Liu, Y. Ding, and J. Peng, “SiOx-Modified Biocarbon Materials Derived From Shaddock Peel for Li–Ion Batteries,” ChemistrySelect 4 (2019):8614–8620.

[85] W. Lai, J. H. Lee, L. Shi, et al., “High Mechanical Strength Si Anode Synthesis With Interlayer Bonded Expanded Graphite Structure for Lithium-Ion Batteries,” Journal of Energy Chemistry 93 (2024):253–263.

[86] Y.-H. Ding, P. Zhang, H.-M. Ren, Q. Zhuo, Z.-M. Yang, and Y. Jiang, “Preparation of graphene/TiO₂ Anode Materials for Lithium-Ion Batteries by a Novel Precipitation Method,” Materials Research Bulletin 46 (2011):2403–2407.

[87] Y. Zhang, Y. Tang, W. Li, and X. Chen, “Nanostructured TiO₂-Based Anode Materials for High-Performance Rechargeable Lithium-Ion Batteries,” ChemNanoMat 2 (2016):764–775.

[88] X. Liu, Y. Jiang, K. Li, F. Xu, P. Zhang, and Y. Ding, “Electrospun Free-Standing N-Doped C@SnO₂ Anode Paper for Flexible Li-Ion Batteries,” Materials Research Bulletin 109 (2019):41–48.

[89] Z. Li, J. Huang, B. Yann Liaw, V. Metzler, and J. Zhang, “A Review of Lithium Deposition in Lithium-Ion and Lithium Metal Secondary Batteries,” Journal of Power Sources 254 (2014):168–182.

[90] B. Zhao, R. Ran, M. Liu, and Z. Shao, “A Comprehensive Review of Li₄Ti5O₁₂-based Electrodes for Lithium-Ion Batteries: The Latest Advancements and Future Perspectives,” Materials Science and Engineering: R: Reports 98 (2015):1–71.

[91] Y. Ding, C. Deng, and J. Peng, “A New Strategy for Preparation of Copper Oxides Composites as Anode Materials for Li-Ion Storage,” Solid State Ionics 394 (2023):116195.

[92] W. Zhang, J. Yin, P. Zhang, X. Tang, and Y. Ding, “Two-Dimensional Phosphorus Carbide as a Promising Anode Material for Lithium-Ion Batteries,” Journal of Materials Chemistry A 6 (2018):12029–12037.

[93] W. Jiang, Y. Jiang, S. Zhao, et al., “Novel Sepiolite-Based Materials for Lithium-and Sodium-Ion Storage,” Energy Technology 8 (2020):1901262.

[94] Y. Yue, Y. Li, Z. Bi, et al., “A POM-Organic Framework Anode for Li-Ion Battery,” Journal of Materials Chemistry A 3 (2015):22989–22995.

[95] S. Sun, L. Cui, K. Yu, et al., “3D Porous Metal–Organic Skeleton Based on Polyoxometalate Nanoclusters as an Anode in a Lithium-Ion Battery,” ACS Applied Nano Materials 7 (2024):1310–1318.

[96] Y. Y. Hu, R. X. Han, L. Mei, et al., “Design Principles of MOF-Related Materials for Highly Stable Metal Anodes in Secondary Metal-Based Batteries,” Materials Today Energy 19 (2021):100608.

[97] X. Li, C. He, J. Zheng, et al., “Preparation of Promising Anode Materials With Sn-MOF as Precursors for Superior Lithium and Sodium Storage,” Journal of Alloys and Compounds 842 (2020):155605.

[98] R. Gao, J. Tang, X. Yu, et al., “In Situ Synthesis of MOF-Derived Carbon Shells for Silicon Anode With Improved Lithium-Ion Storage,” Nano Energy 70 (2020):104444.

[99] X. Li, J. Zheng, C. He, et al., “MOF-Derived Cu–C Loaded With SnO_x as a Superior Anode Material for Lithium-Ion Batteries,” Electrochimica Acta 326 (2019):134960.

[100] K. Chu, Z. Li, S. Xu, et al., “MOF-Derived Hollow NiCo₂O₄ Nanowires as Stable Li-Ion Battery Anodes,” Dalton Transactions 49 (2020):10808–10815.

[101] K. Liu, C. Li, L. Yan, et al., “MOFs and Their Derivatives as Sn-Based Anode Materials for Lithium/Sodium Ion Batteries,” Journal of Materials Chemistry A 9 (2021):27234–27251.

[102] Y. Liu, S. Dong, L. Wang, et al., “Bimetal Cobalt-Zinc MOF and Its Derivatives as Anode Materials for Lithium-Ion Batteries,” Journal of Solid State Electrochemistry 26 (2022):2301–2313.

[103] L. Wu, Y. Liu, H. Zhao, et al., “Study of MOF-Derived Double Hemispherical Nano-Co₃O₄/C Composite as Anode Material for Lithium-Ion Batteries,” ChemistrySelect 9 (2024):8.

[104] W. Du, Y. Zheng, X. Liu, et al., “Oxygen-Enriched Vacancy Spinel MFe₂O₄/carbon (M = Ni, Mn, Co) Derived From Metal-Organic Frameworks Toward Boosting Lithium Storage,” Chemical Engineering Journal 451 (2023):138626.

[105] W. Zhang, L. Wang, G. Ding, et al., “Bimetallic CoNiSe₂/C Nanosphere Anodes Derived From Ni-Co-Metal-Organic Framework Precursor Towards Higher Lithium Storage Capacity,” Chinese Chemical Letters 34 (2023):107328.

[106] P. Jia, J. Liang, H. Wang, X. Wang, C. Liang, and K. Yu, “BiMMOF-Derived ZnS/Co₉S₈ Heterojunctions Decorated Hollow Carbon Nanospheres as Advanced Anode Materials for Lithium-Ion Batteries,” Journal of Alloys and Compounds 976 (2024):173121.

[107] X. Liu, F. Liu, X. Zhao, and L. Z. Fan, “Constructing MOF-Derived CoP-NC@MXene Sandwich-Like Composite by In-Situ Intercalation for Enhanced Lithium and Sodium Storage,” Journal of Materiomics 8 (2022):30–37.

[108] J. Yan, C. Gao, S. Qi, et al., “Encapsulation of Nano-Si Into MOF Glass to Enhance Lithium-Ion Battery Anode Performances,” Nano Energy 103 (2022):107779.

[109] S. Javadian, Z. Parviz, P. Salimi, et al., “Engineering Cobalt-Based Nanoparticles Encapsulated in Hierarchical Porous N-Doped Carbon as an Efficient Electrode for Li Storage,” Journal of Alloys and Compounds 898 (2022):162849.

[110] J. Hou, Y. Guo, Y. Zhang, et al., “Facile Green and Sustainable Synthesis of MnO@rGO as Electrochemically Stable Anode for Lithium-Ion Batteries,” Materials Letters 325 (2022):132761.

[111] Z. Jia, H. Lyu, W. Wang, X. Qi, and S. Guo, “Hierarchical Nickel Cobalt Sulfide Nanoparticles Encapsulated in Rose-Shaped Carbon Spheres as High-Performance Anode Materials for Lithium-Ion Batteries,” Solid State Ionics 389 (2023):116097.

[112] G. Nagaraju, P. Santhoshkumar, S. C. Sekhar, et al., “Metal Organic Framework-Derived MnO@Carbon Composites for Highly Durable Li-Ion Batteries and Hybrid Electrochemical Cells,” Journal of Power Sources 549 (2022):232113.

[113] G. Ou, J. Chen, M. Lu, et al., “A Metal-Organic Framework Approach to Engineer ZnO/Co₃ZnC/N-doped Carbon Composite as Anode Material for Boosting Lithium Storage,” Journal of Alloys and Compounds 923 (2022):166436.

[114] Y. Chen, J. Chen, J. Liu, et al., “Metal-Organic Framework-Derived Mixed-Phase Anatase/Rutile TiO₂ Towards Boosted Lithium Storage: Surface Engineering and Design Strategy Through Crystal Phase Transition,” Materials Today Nano 20 (2022):100265.

[115] L. Zhu, T. Han, Y. Ding, J. Long, X. Lin, and J. Liu, “A Metal-Organic-Framework Derived NiFe₂O₄@NiCo-LDH Nanocube as High-Performance Lithium-Ion Battery Anode Under Different Temperatures,” Applied Surface Science 599 (2022):153953.

[116] H. Huang, M. Cheng, J. Yin, J. Zhang, L. Kong, and X. H. Bu, “MIL-101(Fe)-derived Iron Oxide/Carbon Anode for Lithium-Ion Batteries: Derivation Process Study and Performance Optimization,” Electrochimica Acta 426 (2022):140794.

[117] Y. An, Y. Tian, J. Feng, and Y. Qian, “MXenes for Advanced Separator in Rechargeable Batteries,” Materials Today 57 (2022):146–179.

[118] F. Li, L. Chen, L. He, et al., “MOF Derived Pomegranate-Like NiSb/C Composites for Li-Ion Batteries,” Materials Letters 350 (2023):134970.

[119] R. Guan, G. Dong, Z. Li, and S. Yang, “MOF-Derived Co₃O₄/C Microspheres as High-Performance Anode Materials for Lithium-Ion Batteries,” Russian Journal of Physical Chemistry A 96 (2022): S175-S182.

[120] T. Li, D. Zhao, M. Shi, et al., “MOF-Derived N,S Co-Doped Carbon Matrix-Encapsulated Cu₂S Nanoparticles as High-Performance Lithium-Ion Battery Anodes: A Joint Theoretical and Experimental Study,” Journal of Materials Chemistry A 11 (2023):1461–1472.

[121] Y. Yang, J. W. Zhu, P. Y. Wang, et al., “NH₂-MIL-125 (Ti) Derived Flower-Like Fine TiO₂ Nanoparticles Implanted in N-Doped Porous Carbon as an Anode With High Activity and Long Cycle Life for Lithium-Ion Batteries,” Acta Physico-Chimica Sinica 38 (2022):9.

[122] J. E. Zhou, H. Zhong, Y. Zhang, et al., “An Oxygen-Deficient Strategy to Boost Lithium Storage of Metal-Organic Framework-Derived ZnTiO₃/TiO₂/C Composite Anodes,” Chemical Engineering Journal 450 (2022):137448.

[123] C. S. Kim, J. S. Lee, R. Saroha, et al., “Porous Nitrogen-Doped Graphene Nanofibers Comprising Metal Organic Framework-Derived Hollow and Ultrafine Layered Double Metal Oxide Nanocrystals as High-Performance Anodes for Lithium-Ion Batteries,” Journal of Power Sources 523 (2022):231030.

[124] X. D. Chen, J. Q. Jian, P. Yan, P. F. Liu, X. H. Cao, and J. H. Liu, “Preparation and Lithium Storage Properties of Fe-CrSe/C Anode Material Derived From Bimetallic Organic Framework,” Chinese Journal of Inorganic Chemistry 38 (2022):1752–1758.

[125] H. Xu, D. Liu, W. Wang, and G. Yu, “Selenium-Doped Amorphous Black Phosphorus@TiO₂/C Heterostructures for High-Performance Li/Na/K Ion Batteries,” Inorganic Chemistry 61 (2022):3121–3131.

[126] M. Maniyazagan, P. Naveenkumar, H. Zuhaib, H. W. Yang, W. S. Kang, and S. J. Kim, “Sulfur-Doped SnO₂ Nanoparticles Encased in Porous Carbon Derived From a Metal-Organic Framework for Lithium-Ion Battery Anodes,” Solid State Sciences 136 (2023):107091.

[127] J. Li, C. Li, J. Ren, et al., “Synergistic Effect of Organic-Inorganic Hybrid Electrolyte for Ultra-Long Zn–I₂ Batteries,” International Journal of Hydrogen Energy 48 (2023):21985–21995.

[128] Y. Chen, F. H. Du, J. B. Lian, et al., “W-Based MOF Derived ZnWO₄/ZnO@C Hierarchical Nanoflakes With Superior Lithium Storage Performance,” Ceramics International 50 (2024):10363–10373.

[129] N. Buğday, M. N. Ates, O. Duygulu, et al., “ZIF-12-Derived N-Doped Fe/Co/S/@C Nanoparticles as High-Performance Composite Anode Electrode Materials for Lithium-Ion Batteries,” Journal of Alloys and Compounds 928 (2022):167037.

[130] G. Férey, F. Millange, M. Morcrette, et al., “Mixed-Valence Li/Fe-Based Metal–Organic Frameworks With Both Reversible Redox and Sorption Properties,” Angewandte Chemie International Edition 46 (2007):3259–3263.

[131] M. Nagarathinam, K. Saravanan, E. J. H. Phua, M. V. Reddy, B. V. R. Chowdari, and J. J. Vittal, “Redox-Active Metal-Centered Oxalato Phosphate Open Framework Cathode Materials for Lithium Ion Batteries,” Angewandte Chemie International Edition 51 (2012):5866–5870.

[132] C. Cong and H. Ma, “Advances of Electroactive Metal–Organic Frameworks,” Small 19 (2023):2207547.

[133] S. Gu, Z. Bai, S. Majumder, B. Huang, and G. Chen, “Conductive Metal–Organic Framework With Redox Metal Center as Cathode for High Rate Performance Lithium Ion Battery,” Journal of Power Sources 429 (2019):22–29.

[134] A. Nazir, H. T. T. Le, A.-G. Nguyen, and C.-J. Park, “Graphene Analogue Metal Organic Framework With Superior Capacity and Rate Capability as an Anode for Lithium Ion Batteries,” Electrochimica Acta 389 (2021):138750.

[135] W. Yan, J. Su, Z. M. Yang, S. Lv, Z. Jin, and J. L. Zuo, “High-Performance Lithium-Ion Capacitors Based on Porosity-Regulated Zirconium Metal−Organic Frameworks,” Small 17 (2021):2005209.

[136] C. Gao, P. Wang, Z. Wang, S. K. Kær, Y. Zhang, and Y. Yue, “The Disordering-Enhanced Performances of the Al-MOF/Graphene Composite Anodes for Lithium Ion Batteries,” Nano Energy 65 (2019):104032.

[137] D. Rambabu, A. E. Lakraychi, J. Wang, et al., “An Electrically Conducting Li-Ion Metal–Organic Framework,” Journal of the American Chemical Society 143 (2021):11641–11650.

[138] Y.-S. Hsiao, J.-H. Huang, T.-H. Cheng, et al., “Cr-Doped LiNi_0.5Mn_1.5O₄ Derived From Bimetallic Ni/Mn Metal-Organic Framework as High-Performance Cathode for Lithium-Ion Batteries,” Journal of Energy Storage 68 (2023):107686.

[139] K. Wang, X. Huang, T. Zhou, H. Wang, H. Xie, and Y. Ren, “Boosted Electrochemical Properties of Porous Li₂FeSiO₄/C Based on Fe-MOFs Precursor for Lithium Ion Batteries,” Vacuum 171 (2020):108997.

[140] Q.-Q. Qiao, G.-R. Li, Y.-L. Wang, and X.-P. Gao, “To Enhance the Capacity of Li-Rich Layered Oxides by Surface Modification With Metal–Organic Frameworks (MOFs) as Cathodes for Advanced Lithium-Ion Batteries,” Journal of Materials Chemistry A 4 (2016):4440–4447.

[141] P. Qi, Y. Han, J. Zhou, et al., “MOF Derived Composites for Cathode Protection: Coatings of LiCoO₂ From UiO-66 and MIL-53 as Ultra-Stable Cathodes,” Chemical Communications 51 (2015):12391–12394.

[142] S. Li, X. Fu, J. Zhou, et al., “An Effective Approach to Improve the Electrochemical Performance of LiNi_0.6Co_0.2Mn_0.2O₂ Cathode by an MOF-Derived Coating,” Journal of Materials Chemistry A 4 (2016):5823–5827.

[143] Y. Xie, S. Chen, Z. Lin, W. Yang, H. Zou, and R. W.-Y. Sun, “Enhanced Electrochemical Performance of Li-Rich Layered Oxide, Li_1.2Mn_0.54Co_0.13Ni_0.13O₂, by Surface Modification Derived From a MOF-Assisted Treatment,” Electrochemistry Communications 99 (2019):65–70.

[144] X. Zhang, W. Zi, J. Zhou, L. Zhou, J. Zhang, and X. Xuan, “Li-Mn Bimetallic Metal-Organic Framework and Its Derivative as a Cathode for Lithium-Ion Batteries,” Inorganic Chemistry 62 (2023):9501–9507.

[145] L. Xiong, X. Zeng, S. Zhou, et al., “Porous Li₄Ti₅O₁₂-Induced Cathode Electrolyte Interphases Enable Sustainable Single-Crystalline NCM Cathodes,” Applied Surface Science 613 (2023):156043.

[146] R. Shan, X. Lu, Y. Xu, et al., “A Ternary MOF Derived Single Crystalline LiNi_1/3Mn_1/3Co_1/3O₂ as High-Voltage Cathodes for Lithium-Ion Batteries,” Chemical Engineering Science 268 (2023):118416.

[147] Y. S. Hsiao, J. H. Huang, T. H. Cheng, et al., “Cr-Doped LiNi_0.5Mn_1.5O₄ Derived From Bimetallic Ni/Mn Metal-Organic Framework as High-Performance Cathode for Lithium-Ion Batteries,” Journal of Energy Storage 68 (2023):107686.

[148] S. Zhai, W. Liu, Y. Hu, et al., “Kinetic Acceleration of Lithium Polysulfide Conversion via a Copper-Iridium Alloying Catalytic Strategy in Li-S Batteries,” ACS Applied Materials & Interfaces 14 (2022):50932–50946.

[149] J. Lin, Y. H. Sun, and X. Lin, “Metal-Organic Framework-Derived LiFePO₄ Cathode Encapsulated in O,F-Codoped Carbon Matrix Towards Superior Lithium Storage,” Nano Energy 91 (2022):106655.

[150] Z. Li, J. Wu, P. Chen, et al., “A New Metallic Composite Cathode Originated From Hyperbranched Polymer Coated MOF for High-Performance Lithium-Sulfur Batteries,” Chemical Engineering Journal 435 (2022):135125.

[151] H. Li, W. Dong, C. Li, et al., “Boosting Reaction Kinetics and Shuttle Effect Suppression by Single Crystal MOF-Derived N-Doped Ordered Hierarchically Porous Carbon for High Performance Li-Se Battery,” Science China Materials 65 (2022):2975–2988.

[152] C. Wen, X. Du, F. Wu, L. Wu, J. Li, and G. Liu, “Conductive Al-Doped Zno Framework Embedded With Catalytic Nanocages as a Multistage-Porous Sulfur Host in Lithium-Sulfur Batteries,” ACS Applied Materials & Interfaces 13 (2021):44389–44400.

[153] C. Qi, H. Li, J. Wang, et al., “Metal-Organic-Framework-Derived Porous Carbon Embedded With TiO₂ Nanoparticles as a Cathode for Advanced Lithium-Sulfur Batteries,” ChemElectroChem 8 (2021):90–95.

[154] H. Peng, T. Zhang, W. Shao, S. Liu, and F. Hu, “All MOF-Derived-Carbon Material-Based Integrated Electrode Constructed by Carbon Nanosheet Sulfur Host and Fe Microparticles With Carbon Nanofiber Network Interlayer for Lithium-Sulfur Batteries,” Applied Surface Science 569 (2021):150935.

[155] C. Huang, Z. Wang, Z. Q. Fang, S. X. Zhao, and L. Ci, “Achieving High Initial Coulombic Efficiency and Low Voltage Dropping in Li-Rich Mn-Based Cathode Materials by Metal-Organic Frameworks-Derived Coating,” Journal of Power Sources 499 (2021):229967.

[156] C. Shen, Y. Li, M. Gong, et al., “Ultrathin Cobalt Phthalocyanine@Graphene Oxide Layer-Modified Separator for Stable Lithium–Sulfur Batteries,” ACS Applied Materials & Interfaces 13 (2021):60046–60053.

[157] F. Zou, K. Liu, C. Cheng, Y. Ji, and Y. Zhu, “Metal-Organic Frameworks (MOFs) Derived Carbon-Coated NiS Nanoparticles Anchored on Graphene Layers for High-Performance Li-S Cathode Material,” Nanotechnology 31 (2020):485404.

[158] F. Zhou, Z. Qiao, Y. Zhang, et al., “Bimetallic MOF-Derived CNTs-Grafted Carbon Nanocages as Sulfur Host for High-Performance Lithium–Sulfur Batteries,” Electrochimica Acta 349 (2020):136378.

[159] L. Zhao, Z. Guan, Z. Ullah, et al., “Significantly Stable Organic Cathode for Lithium-Ion Battery Based on Nanoconfined Poly(Anthraquinonyl Sulfide)@MOF-Derived Microporous Carbon,” Electrochimica Acta 335 (2020):135681.

[160] J. Yao, M. Zhang, G. Han, X. Wang, Z. Wang, and J. Wang, “Reduced Graphene Oxide Coated Fe-SOC as a Cathode Material for High-Performance Lithium-Sulfur Batteries,” Ceramics International 46 (2020):24155–24161.

[161] G. Liu, K. Feng, H. Cui, J. Li, Y. Liu, and M. Wang, “Mof Derived In-Situ Carbon-Encapsulated Fe₃O₄@C to Mediate Polysulfides Redox for Ultrastable Lithium-Sulfur Batteries,” Chemical Engineering Journal 381 (2020):122652.

[162] Y. Chen, L. Qiu, X. Ma, et al., “Electrospun PMIA and PVDF-HFP Composite Nanofibrous Membranes With Two Different Structures for Improved Lithium-Ion Battery Separators,” Solid State Ionics 347 (2020):115253.

[163] G. Han, X. Wang, J. Yao, M. Zhang, and J. Wang, “The Application of Indium Oxide@CPM-5-C-600 Composite Material Derived From MOF in Cathode Material of Lithium Sulfur Batteries,” Nanomaterials 10 (2020):177.

[164] Q. Cheng, Y. Pan, Y. Chen, et al., “Nanostructured Iron Fluoride Derived From Fe-Based Metal-Organic Framework for Lithium Ion Battery Cathodes,” Inorganic Chemistry 59 (2020):12700–12710.

[165] Z. Wang, P. Pang, Z. Ma, H. Chen, and J. Nan, “A Four-Layers Hamburger-Structure PVDF-HFP/Al2O3/PE/PVDF-HFP Composite Separator for Pouch Lithium-Ion Batteries With Enhanced Safety and Reliability,” Journal of the Electrochemical Society 167 (2020):090507.

[166] J.-L. Yang, X.-X. Zhao, W. Zhang, et al., “‘Pore-Hopping’Ion Transport in Cellulose-Based Separator Towards High-Performance Sodium-Ion Batteries,” Angewandte Chemie (International ed. in English) 62 (2023): e202300258.

[167] L. Zhou, H. Pan, G. Yin, et al., “Tailoring the Function of Battery Separators via the Design of MOF Coatings,” Advanced Functional Materials 34 (2024):2314246.

[168] L.-Y. Yang, J.-H. Cao, W.-H. Liang, Y.-K. Wang, and D.-Y. Wu, “Effects of the Separator MOF-Al₂O₃ Coating on Battery Rate Performance and Solid–Electrolyte Interphase Formation,” ACS Applied Materials & Interfaces 14 (2022):13722–13732.

[169] P. Chen, H. Ren, L. Yan, et al., “Metal–Organic Frameworks Enabled High-Performance Separators for Safety-Reinforced Lithium Ion Battery,” ACS Sustainable Chemistry & Engineering 7 (2019):16612–16619.

[170] L. Deng, C. Cai, Y. Huang, and Y. Fu, “In-Situ MOFs Coating on 3D-channeled Separator With Superior Electrolyte Uptake Capacity for Ultrahigh Cycle Stability and Dendrite-Inhibited Lithium-Ion Batteries,” Microporous and Mesoporous Materials 329 (2022):111544.

[171] A. Valverde, R. Gonçalves, M. M. Silva, et al., “Metal–Organic Framework Based PVDF Separators for High Rate Cycling Lithium-Ion Batteries,” ACS Applied Energy Materials 3 (2020):11907–11919.

[172] H. B. Son, S. Cho, K. Baek, et al., “All-Impurities Scavenging, Safe Separators With Functional Metal-Organic-Frameworks for High-Energy-Density Li-Ion Battery,” Advanced Functional Materials 33 (2023):2302563.

[173] W. Jiang, Y. Han, and Y. Ding, “Sepiolite and ZIF-67 Co-Modified PAN/PVDF-HFP Nanofiber Separators for Advanced Li-Ion Batteries,” Nanotechnology 33 (2022):425601.

[174] A. Valverde, R. Gonçalves, M. M. Silva, et al., “Metal-Organic Framework Based PVDF Separators for High Rate Cycling Lithium-Ion Batteries,” ACS Applied Energy Materials 3 (2020):11907–11919.

[175] J. Li, L. Chen, F. Wang, et al., “Anionic Metal-Organic Framework Modified Separator Boosting Efficient Li-Ion Transport,” Chemical Engineering Journal 451 (2023):138536.

[176] S. Zhang, J. Luo, M. Du, F. Zhang, and X. He, “Highly Porous Zeolitic Imidazolate Framework-8@bacterial Cellulose Composite Separator With Enhanced Electrolyte Absorption Capability for Lithium-Ion Batteries,” Cellulose 29 (2022):5163–5176.

[177] S. Zhang, J. Luo, F. Zhang, et al., “A Porous, Mechanically Strong and Thermally Stable Zeolitic Imidazolate Framework-8@bacterial Cellulose/Aramid Nanofibers Composite Separator for Advanced Lithium-Ion Batteries,” Journal of Membrane Science 652 (2022):120461.

[178] J. C. Barbosa, R. Gonçalves, A. Valverde, et al., “Metal Organic Framework Modified Poly(Vinylidene Fluoride-Co-Hexafluoropropylene) Separator Membranes to Improve Lithium-Ion Battery Capacity Fading,” Chemical Engineering Journal 443 (2022):136329.

[179] W. Ren, J. Liang, M. Huang, et al., “Thermally-Stable and Flame-Retardant Metal-Organic Framework-Based Separator for High-Performance Lithium-Ion Batteries,” Chemical Engineering Journal 498 (2024):155811.

[180] Y. Gao, Q.-S. Liu, M.-C. Long, et al., “Nano-Interfacial Supramolecular Adhesion of Metal-Organic Framework-Based Separator Enables High-Safety and Wide-Temperature-Range Lithium Batteries,” Small 20 (2024):2400980.

[181] C. Kim, W. Jeong, H. R. Shin, K.-N. Jung, and J.-W. Lee, “Robust Metal-Organic Framework Monoliths for Long-Term Cycling Lithium Metal Batteries,” Journal of Materials Chemistry A 12 (2024):10686–10694.

[182] D. Li, Y. Ouyang, Y. Xiao, et al., “Core-Shell Structured Flame-Retardant Separator Mediated With Metal-Organic Framework Armor Enables Self-Acceleration Mechanism for Dendrite-Free and Safer Lithium Metal Batteries,” Advanced Functional Materials 34 (2024):2314296.

[183] L. Zuo, Q. Ma, P. Xiao, et al., “Upgrading the Separators Integrated With Desolvation and Selective Deposition Toward the Stable Lithium Metal Batteries,” Advanced Materials 36 (2024):2311529.

[184] G. Yin, L. Zhou, Y. Xiang, et al., “Flame Retardant Encapsulation in MOFs: A Promising Universal Approach for Enhancing Battery Performance,” Journal of Energy Storage 76 (2024):109786.

[185] Y. Ding, C. Zhang, H. Zheng, and Y. Han, “Zeolitic Imidazolate Framework-8 Modified Poly(Vinylidene Fluoride-Co-Hexafluoropropylene)/Polyacrylonitrile Composite Separators for Li-Ion Batteries,” Chinese Journal of Chemical Engineering 62 (2023):291–296.

[186] K. Yang, L. Sheng, D. Zhu, et al., “Water Harvesting MOF Enables Stable Cycling of Nickel-Rich Batteries,” Advanced Functional Materials 34 (2024):2307746.

RIGHTS & PERMISSIONS

2024 The Author(s). Battery Energy published by Xijing University and John Wiley & Sons Australia, Ltd.