Ice-phobic properties of MoS2-loaded rice straw biogas residue biochar-based photothermal and anti-corrosion coating with low oxygen to carbon ratio
Zhiyuan Liu, Yan Li, Zhiyuan He
Biochar ›› 2023, Vol. 5 ›› Issue (1) : 0.
Ice-phobic properties of MoS2-loaded rice straw biogas residue biochar-based photothermal and anti-corrosion coating with low oxygen to carbon ratio
1. A biochar-based ice-phobic coating was prepared from rice straw biogas residue.
2. Low O/C ratio promoted superhydrophobicity and low ice adhesion of the coating.
3. The icing wind tunnel test proved the coating has good anti-icing performance.
4. The MoS2 loading endowed the material with photothermal and anti-corrosion effects.
Icing of wind turbine blades will seriously hinder the development of the wind power industry, and the use of biomass resources to solve the icing problem is conducive to promoting the synergistic development of biomass and wind energy. In this study, ice-phobic coatings with photothermal and anti-corrosion properties were prepared by surface modification pyrolysis and hydrothermal reaction with rice straw biogas residue as raw material. The erosion of KOH and the surface modification of MoS2 produced a rough structure of the material, and the high-temperature pyrolysis and hydrothermal reaction promoted the dehydrogenation and decarboxylation reactions, which reduced the number of oxygen-containing functional groups and decreased the surface energy of the material. The ice-phobic coating has superhydrophobic properties with a contact angle of 158.32°. Due to the small surface area in contact with water, the coating was able to significantly reduce the icing adhesion strength to 53.23 kPa. The icing wind tunnel test results showed that the icing area and mass were reduced by 10.54% and 30.08%, respectively, when the wind speed was 10 m s−1 and the temperature was − 10 °C. Photothermal performance tests showed that the MoS2-loaded material had light absorption properties, and the coating could rapidly warm up to 58.3 ℃ under xenon lamp irradiation with photothermal cycle stability. The loading of MoS2 acts as a physical barrier, reducing the contact of corrosive media with the substrate, thus improving the anti-corrosion of the coating. This study has practical application value and significance for the development of the anti-icing field under complex environmental conditions.
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