Theoretical modeling of thin binder interphases in highly filled PBX composites together with the closed form expression of the effective isotropic moduli of a simplified PBX model

Jian-Tao Liu , Mei-Tong Fu

Electronic Research Archive ›› 2025, Vol. 33 ›› Issue (2) : 1045 -1069.

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Electronic Research Archive ›› 2025, Vol. 33 ›› Issue (2) :1045 -1069. DOI: 10.3934/era.2025047
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Theoretical modeling of thin binder interphases in highly filled PBX composites together with the closed form expression of the effective isotropic moduli of a simplified PBX model
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Abstract

Binder interphases inside the highly filled polymer bonded explosives (PBXs) are irregularly distributed and extremely thin, but play an essential role in affecting the overall moduli and explosive performance of such heterogeneous media. In the present paper, a spring-type interface model, which was physically equivalent to these practical layers within a fixed error bound, was briefly derived, at first taking account of the fact that the stiffness of the binder material was much lower than that of the explosive crystals. Hereafter, a simplified PBX model consisting of a spherical explosive particle bonded to an infinite explosive matrix by the spring-type interface is designed, and its effective isotropic moduli were analytically determined via the generalized self-consistent scheme. The upper and lower bounds of these moduli were also derived based on the elasticity extremum principles of minimum potential and minimum complementary energies. These explicit expressions can be applied to predict the preliminary elastic properties of highly filled PBXs as benchmarks to validate numerical evaluations and so forth. Eventually, some discussions were made on the size-dependent effect of PBXs with the aid of the simplified model.

Keywords

spring-type interface / PBX material / multi-scale modeling / effective isotropic moduli / extreme bounds

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Jian-Tao Liu, Mei-Tong Fu. Theoretical modeling of thin binder interphases in highly filled PBX composites together with the closed form expression of the effective isotropic moduli of a simplified PBX model. Electronic Research Archive, 2025, 33 (2) : 1045-1069 DOI:10.3934/era.2025047

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References

[1]

Y. Q. Wu, F. L. Huang, A thermal-mechanical constitutive model for b-HMX single crystal and cohesive interface under dynamic high pressure loading, Sci. China Phys. Mech. Astron., 53 (2010), 218-226. https://doi.org/10.1007/s11433-009-0264-1

[2]

J. J. Xiao, W. R. Wang, J. Chen, G. F. Ji, W. Zhu, H. M. Xiao, Study on structure, sensitivity and mechanical properties of HMX and HMX-based PBXs with molecular dynamics simulation, Comput. Theor. Chem., 999 (2012), 21-27. https://doi.org/10.1016/j.comptc.2012.08.006

[3]

A. Elbeih, S. Zeman, M. Jungova, P. Vávra, Z. Akstein, Effect of different polymeric matrices on some properties of plastic bonded explosives, Propellants Explos. Pyrotech., 37 (2012), 676-684. https://doi.org/10.1002/prep.201200018

[4]

K. D. Dai, Y. L. Liu, P. W. Chen, Y. Tian, Finite element simulation on effective elastic modulus of PBX explosives, Trans. Beijing Inst. Technol., 2012 (2012), 1154-1158.

[5]

H. Tan, C. Liu, Y. Huang, P. H. Geubelle, The cohesive law for the particle/matrix interfaces in high explosives, J. Mech. Phys. Solids, 53 (2005), 1892-1917. https://doi.org/10.1016/j.jmps.2005.01.009

[6]

B. Banerjee, D. O. Adams, On predicting the effective elastic properties of polymer bonded explosives using the recursive cell method, Int. J. Solids Struct., 41 (2004), 481-509. https://doi.org/10.1016/j.ijsolstr.2003.09.016

[7]

H. Tan, Y. Huang, C. Liu, P. H. Geubelle, The Mori-Tanaka method for composite materials with nonlinear interface debonding, Int. J. Plast., 21 (2005), 1890-1918. https://doi.org/10.1016/j.ijplas.2004.10.001

[8]

P. J. Rae, H. T. Goldrein, S. J. P. Palmer, J. E. Field, A. L. Lewis, Quasi-static studies of the deformation and failure of β-HMX based polymer bonded explosives, Proc. R. Soc. London, Ser. A, 458 (2002), 743-762. https://doi.org/10.1098/rspa.2001.0894

[9]

C. Hübner, E. Geibler, P. Elsner, P. Eyerer, The importance of micromechanical phenomena in energetic materials, Propellants Explos. Pyrotech., 24 (1999), 119-125. https://doi.org/10.1002/(SICI)1521-4087(199906)24:03¡119::AID-PREP119¿3.0.CO;2-G

[10]

P. W. Chen, H. M. Xie, F. L. Huang, T. Huang, Y. S. Ding, Deformation and failure of polymer bonded explosives under diametric compression test, Polym. Test., 25 (2006), 333-341. https://doi.org/10.1016/j.polymertesting.2005.12.006

[11]

X. Q. Liu, P. J. Wei, Influences of interfacial damage on the effective wave velocity in composites with reinforced particles, Sci. China Ser. G: Phys. Mech. Astron., 51 (2008), 1126-1133. https://doi.org/10.1007/s11433-008-0094-6

[12]

R. L. Peeters, R. M. Hackett, Constitutive modeling of plastic-bonded explosives, Exp. Mech., 21 (1981), 111-116. https://doi.org/10.1007/BF02326367

[13]

K. S. Yeom, S. Jeong, H. Hun, J. Park, New pseudo-elastic model for polymer-bonded explosive simulants considering the Mullins effect, J. Compos. Mater., 47 (2013), 3401-3411. https://doi.org/10.1177/0021998312466118

[14]

J. Gao, Z. X. Huang, Parameter indentification for viscoelastic damage constitutive model of PBX (in Chinese), Eng. Mech., 30 (2013), 299-304.

[15]

F. Saghir, S. Gohery, F. Mozafari, N. Moslemi, C. Burvill, A. Smith, et al., Mechanical characterization of particulated FRP composite pipes: A comprehensive experimental study, Polym. Test., 93 (2021), 1007001. https://doi.org/10.1016/j.polymertesting.2020.107001

[16]

S. Gohery, S. Sharifi, C. Burvill, S. Mouloodi, M. Izadifar, P. Thissen, Localized failure analysis of internally pressurized laminated ellipsoidal woven GFRP composite domes: Analytical, numerical, and experimental studies, Arch. Civ. Mech. Eng., 19 (2019), 1235-1250. https://doi.org/10.1016/j.acme.2019.06.009

[17]

Q. Z. Xia, Y. Q. Wu, F. L. Huang, Effect of interface behaviour on damage and instability of PBX under combined tension-shear loading, Def. Technol., 23 (2023), 137-151. https://doi.org/10.1016/j.dt.2022.01.010

[18]

P. W. Chen, F. L. Huang, K. D. Dai, Y. S. Ding, Detection and characterization of long-pulse low-velocity impact damage in plastic bonded explosives, Int. J. Impact. Eng., 31 (2005), 497-508. https://doi.org/10.1016/j.ijimpeng.2004.01.008

[19]

Z. W. Liu, H. M. Xie, K. X. Li, P. W. Chen, F. L. Huang, Fracture behavior of PBX simulation subject to combined thermal and mechanical loads, Polym. Test., 28 (2009), 627-635. https://doi.org/10.1016/j.polymertesting.2009.05.011

[20]

A. E. D. M. Heijden, Y. L. M. Creyghton, E. Marino, R. H. B. Bouma, G. J. H. G. Scholtes, W. Duvalois, et al., Energetic materials: Crystallization, characterization and insensitive plastic bonded explosives, Propellants Explos. Pyrotech., 33 (2008), 25-32. https://doi.org/10.1002/prep.200800204

[21]

Z. B. Zhou, P. W. Chen, F. L. Huang, S. Q. Liu, Experimental study on the micromechanical behavior of a PBX simulant using SEM and digital image correlation method, Opt. Lasers Eng., 49 (2011), 366-370. https://doi.org/10.1016/j.optlaseng.2010.11.001

[22]

W. Zhu, J. J. Xiao, W. H. Zhu, H. M. Xiao, Molecular dynamics simulations of RDX and RDX-based plastic-bonded explosives, J. Hazard. Mater., 164 (2009), 1082-1088. https://doi.org/10.1016/j.jhazmat.2008.09.021

[23]

L. Qiu, H. M. Xiao, Molecular dynamics study of binding energies, mechanical properties and detonation performance of bicyclo-HMX-based PBXs, J. Hazard. Mater., 164 (2009), 329-336. https://doi.org/10.1016/j.jhazmat.2008.08.030

[24]

M. M. Li, F. S. Li, R. Q. Shen, X. D. Guo, Molecular dynamics study of the structures and properties of RDX/GAP propellant, J. Hazard. Mater., 186 (2011), 2031-2036. https://doi.org/10.1016/j.jhazmat.2010.12.101

[25]

B. Banerjee, D. O. Adams, Micormechanics-based prediction of thermoelastic properties of high energy materials, preprint, arXiv:1201.2437.

[26]

B. Banerjee, C. M. Cady, D. O. Adams, Micromechanics simulations of glass-estane mock polymer bonded explosives, Modell. Simul. Mater. Sci. Eng., 11 (2003), 457-475. https://doi.org/10.1088/0965-0393/11/4/304

[27]

B. Banerjee, Effective elastic moduli of polymer bonded explosives from finite element simulations, preprint, arXiv:cond-mat/0510367.

[28]

H. Tan, Y. Huang, C. Liu, G. Ravichandran, G. H. Paulino, Constitutive behaviors of composites with interface debonding: the extended Mori-Tanaka method for uniaxial tension, Int. J. Fract., 146 (2007), 139-148. https://doi.org/10.1007/s10704-007-9155-5

[29]

A. Barua, M. Zhou, A Lagrangian framework for analyzing microstructural level response of polymer-bonded explosives, Modell. Simul. Mater. Sci. Eng., 19 (2011), 055001. https://doi.org/10.1088/0965-0393/19/5/055001

[30]

A. Barua, M. Zhou, Computational analysis of temperature rises in microstructures of HMX-Estane PBXs, Comput. Mech., 52 (2013), 151-159. https://doi.org/10.1007/s00466-012-0803-x

[31]

Z. Hashin, Extremum principles for elastic heterogenous media with imperfect interfaces and their application to bounding of effective moduli, J. Mech. Phys. Solids, 40 (1992), 767-781. https://doi.org/10.1016/0022-5096(92)90003-K

[32]

S. T. Gu, Q. C. He, Interfacial discontinuity relations for coupled multified phenomena and their application to the modeling of thin interphases as imperfect interface, J. Mech. Phys. Solids, 59 (2011), 1413-1426. https://doi.org/10.1016/j.jmps.2011.04.004

[33]

J. T. Liu, S. T. Gu, Q. C. He, A computational approach for evaluating the effective elastic moduli of non-spherical particle reinforced composites with interfacial displacement and traction jumps, Int. J. Multiscale Comput. Eng., 13 (2015), 123-143. https://doi.org/10.1615/INTJMULTCOMPENG.2014011640

[34]

S. Gohery, M. Ahmed, Q. Q. Liang, T. Molla, M. Kajtaz, K. M. Tse, et al., Higher-order trigonometric series-based analytical solution to free transverse vibration of suspended laminated composite slabs, Eng. Struct., 296 (2023), 116902. https://doi.org/10.1016/j.engstruct.2023.116902

[35]

S. T. Gu, J. T. Liu, Q. C. He, Size-dependent effective elastic moduli of particulate composites with interfacial displacement and traction discontinuities, Int. J. Solids Struct., 51 (2014), 2283-2296. https://doi.org/10.1016/j.ijsolstr.2014.02.033

[36]

Q. Z. Zhu, S. T. Gu, J. Yvonnet, J. F. Shao, Q. C. He, Three-dimensional numerical modelling by XFEM of spring-layer imperfect curved interfaces with applications to linearly elastic composite materials, Int. J. Numer. Mech. Eng., 88 (2011), 307-328. https://doi.org/10.1002/nme.3175

[37]

H. L. Duan, X. Yi, Z. P. Huang, J. Wang, A unified scheme for prediction of effective moduli of multiphase composites with interface effects. Part I: Theoretical framework, Mech. Mater., 39 (2007), 81-93. https://doi.org/10.1016/j.mechmat.2006.02.009

[38]

H. L. Duan, J. Wang, Z. P. Huang, B. L. Karihaloo, Size-dependent effective elastic constants of solids containing nano-inhomogeneities with interface stress, J. Mech. Phys. Solids, 53 (2005), 1574-1596. https://doi.org/10.1016/j.jmps.2005.02.009

[39]

H. L. Duan, X. Yi, Z. P. Huang, J. Wang, A unified scheme for prediction of effective moduli of multiphase composites with interface effects. Part II: Applicationa and scaling laws, Mech. Mater., 39 (2007), 94-103. https://doi.org/10.1016/j.mechmat.2006.02.010

[40]

S. Nemat-Nasser, M. Lori, Micromechanics: Overall properties of heterogeneous materials, J. Appl. Mech., 63 (1996), 561. https://doi.org/10.1115/1.2788912

[41]

R. M. Christensen, K. H. Lo, Solutions for effective shear properties in three phase sphere and cyliner models, J. Mech. Phys. Solids, 27 (1979), 315-330. https://doi.org/10.1016/0022-5096(79)90032-2

[42]

J. H. Liu, S. J. Liu, M. Huang, H. Z. Li, F. D. Nie, Progress on crystal damage in pressed polymer bonded explosives (in Chinese), Energetic Mater., 21 (2013), 372-378.

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