Dynamic color-tunable ultra-long room temperature phosphorescence polymers with photo-chromism and water-stimuli response for multilevel anti-counterfeiting

Xiao Ma; Tian-Jiao Ye; Han-Jiang Yang; Guang-Kun Ling; Danfeng Wang; Jia-Shu Li; Peiyang Gu; Liang-Jin Xu; Tian-Lu Sheng; Fu-Rong Lin; Run-Fu Shen; Qichun Zhang

doi:10.1002/agt2.579

Aggregate ›› 2024, Vol. 5 ›› Issue (5) : e579 DOI: 10.1002/agt2.579

RESEARCH ARTICLE

Dynamic color-tunable ultra-long room temperature phosphorescence polymers with photo-chromism and water-stimuli response for multilevel anti-counterfeiting

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Abstract

Developing dynamic color-tunable ultra-long room temperature phosphorescence (URTP) polymers with afterglow of over 1 s, photo-chromism, and multi-stimuli response for practical anti-counterfeiting and information security applications is attractive but very challenging. Herein, by doping multicolor phosphorescence pyridinium bromide L block or viologen-based photo-chromic V block into polyvinyl alcohol matrixes, the water-stimuli-responsive color-tunable URTP polymer films with afterglow of up to 8 s and the reversible viologen-based photochromic polymer films have been developed. More significantly, a series of dynamic color-tunable URTP polymer films with ultra-long afterglow of over 6 s, photo-chromism, and water-stimuli response have been successfully exploited by integrating L and V blocks into one polymer system. Mechanistic investigations have revealed that their photo-chromism mainly comes from the photo-generated viologen free radicals. Furthermore, their dynamic multilevel anti-counterfeiting applications have been demonstrated. These results pave the way to develop smarter multifunctional URTP materials for anti-counterfeiting and optical sensing.

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anti-counterfeiting / phosphorescence / photochromism / stimuli response / ultralong viologen

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Xiao Ma, Tian-Jiao Ye, Han-Jiang Yang, Guang-Kun Ling, Danfeng Wang, Jia-Shu Li, Peiyang Gu, Liang-Jin Xu, Tian-Lu Sheng, Fu-Rong Lin, Run-Fu Shen, Qichun Zhang. Dynamic color-tunable ultra-long room temperature phosphorescence polymers with photo-chromism and water-stimuli response for multilevel anti-counterfeiting. Aggregate, 2024, 5(5): e579 DOI:10.1002/agt2.579

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