Core-Sheath CNT@MXene Fibers Toward Absorption-Dominated Electromagnetic Interference Shielding Fabrics

Abstract

Absorption-dominated electromagnetic interference (EMI) shielding fabrics are urgently needed to address the increasingly severe electromagnetic radiation pollution, especially the secondary radiation problem. In this study, we design novel core-sheath CNT@MXene fibers with a gradient conductive structure and corresponding fabrics to realize absorption-dominated EMI shielding performances. This coaxial structure utilizes carbon nanotubes (CNTs) as the sheath and MXene as the core and is constructed through a wet spinning technique. By virtue of the core-sheath structure, the conductive gradient structure in the fibers is easily optimized by adjusting the core MXene and sheath CNT content. This gradient conductive network of fiber effectively facilitates the incidence of electromagnetic waves and strong interactions between electromagnetic waves and the composites, resulting in excellent EMI absorption ability. Within the X-band frequency range, the fabric exhibits an electromagnetic interference shielding effectiveness of 23.40 dB and an absorption coefficient of 0.63. Due to the protection of polymer, the fiber’s electrical conductivity remains stable under conditions such as multi-cycle bending, stretching, and ultrasonic treatment, and in high relative humidity environments. Additionally, the fabric also demonstrates EMI shielding stability in indoor environments. This work indicates the great potential of the gradient structured fibers to achieve an absorption-dominated mechanism for next-generation eco-friendly EMI shielding fabrics.

Keywords

Electromagnetic interference shielding / Fabrics / Low reflections / Wet spinning / MXene

References

[1] Zou LH, Sun YY, Dou TT, Yao M, Xu ZZ, Lan CT. Low-temperature treated polypyrrole coated cotton fabrics for efficient electromagnetic interference shielding. Cellulose, 2023, 30: 3283,

[2] Zou LH, Lan CT, Zhang SL, Zheng XH, Xu ZZ, Li CL, Yang L, Ruan FT, Tan SC. Near-instantaneously self-healing coating toward stable and durable electromagnetic interference shielding. Nanomicro Lett, 2021, 13: 190

[3] Lan CT, Jia H, Qiu MH, Fu SH. Ultrathin MXene/polymer coatings with an alternating structure on fabrics for enhanced electromagnetic interference shielding and fire-resistant protective performances. ACS Appl Mater Interf, 2021, 13: 38761,

[4] Lan CT, Guo M, Li CL, Qiu YP, Ma Y, Sun JQ. Axial alignment of carbon nanotubes on fibers to enable highly conductive fabrics for electromagnetic interference shielding. ACS Appl Mater Interf, 2020, 12: 7477,

[5] Lu X, Ye YS, Shang WH, Huang SM, Wang HF, Gan TS, Chen GK, Deng LB, Wu QX, Zhou XC. Ultrastrong, flame-retardant, intrinsically weldable, and highly conductive metallized Kevlar fabrics. J Mater Chem A, 2022, 10: 21379,

[6] Lin FB, Li W, Du XD, Chen NL, Wu YB, Tang YS, Jiang JH. Electrically conductive silver/polyimide fabric composites fabricated by spray-assisted electroless plating. Appl Surf Sci, 2019, 493: 1,

[7] Zhang YH, Shen GD, Lam SS, Ansar S, Jung SC, Ge SB, Hou L, Fan ZK, Wang F, Fan W. A waste textiles-based multilayer composite fabric with superior electromagnetic shielding, infrared stealth and flame retardance for military applications. Chem Eng J, 2023, 471: 144679,

[8] Hu L, Kang ZX. Enhanced flexible polypropylene fabric with silver/magnetic carbon nanotubes coatings for electromagnetic interference shielding. Appl Surf Sci, 2021, 568: 150845,

[9] Qian JJ, Shui A, Du B, Cai M, He C, Zeng SH, Zhong XR, Lou JY. Synthesis and tunable electromagnetic shielding and absorption performance of the three-dimensional SiC nanowires/carbon fiber composites. J Eur Ceram Soc, 2022, 42: 4154,

[10] Gonzalez M, Pozuelo J, Baselga J. Electromagnetic shielding materials in GHz range. Chem Rec, 2018, 18: 1000,

[11] Xia YX, Gao WW, Gao C. A review on graphene-based electromagnetic functional materials: electromagnetic wave shielding and absorption. Adv Funct Mater, 2022, 32: 2204591,

[12] Yang YF, Han MR, Liu W, Wu N, Liu JR. Hydrogel-based composites beyond the porous architectures for electromagnetic interference shielding. Nano Res, 2022, 15: 9614,

[13] Wang C, Murugadoss V, Kong J, He ZF, Mai XM, Shao Q, Chen YJ, Guo L, Liu CT, Angaiah S, Guo ZH. Overview of carbon nanostructures and nanocomposites for electromagnetic wave shielding. Carbon, 2018, 140: 696,

[14] Zheng SF, Wang YY, Wang XS, Lu H. Research progress on high-performance electromagnetic interference shielding materials with well-organized multilayered structures. Mater Today Phys, 2024, 40: 101330,

[15] Gao Y-N, Wang Y, Yue T-N, Zhao B, Che R, Wang M. Superstructure silver micro-tube composites for ultrahigh electromagnetic wave shielding. Chem Eng J, 2022, 430: 132949,

[16] Wang ZY, Fu XY, Zhang ZD, Jiang YL, Waqar M, Xie PT, Bi K, Liu Y, Yin XW, Fan RH. Paper-based metasurface: turning waste-paper into a solution for electromagnetic pollution. J Clean Prod, 2019, 234: 588,

[17] Lan CT, Zou LH, Wang N, Qiu YP, Ma Y. Multi-reflection-enhanced electromagnetic interference shielding performance of conductive nanocomposite coatings on fabrics. J Colloid Interf Sci, 2021, 590: 467,

[18] Eom W, Shin H, Ambade RB, Lee SH, Lee KH, Kang DJ, Han TH. Large-scale wet-spinning of highly electroconductive MXene fibers. Nat Commun, 2020, 11: 2825,

[19] Wang KZ, Chao YF, Chen ZQ, Sayyar S, Wang CY, Wallace G. Wet spinning of hollow graphene fibers with high capacitance. Chem Eng J, 2023, 453: 139920,

[20] Du YZ, Liu YC, Wang A, Kong J. Research progress and future perspectives on electromagnetic wave absorption of fibrous materials. iScience, 2023, 26: 107873,

[21] Zhang F, Song BY, Li YL, Zhou YY, Wang YB, Xu QN, Ma JZ. Breathability and moisture permeability of cellulose nanocrystals hollow microsphere coatings for PET fabrics. Polymers, 2022, 14: 5345,

[22] Lee S, Nguyen NK, Kim M, Park P, Nah J. Conductivity-controlled polyvinylidene fluoride nanofiber stack for absorption-dominant electromagnetic interference shielding materials. ACS Appl Mater Interf, 2023, 15: 33180,

[23] Sun BB, Sun SJ, He P, Mi H-Y, Dong BB, Liu CT, Shen CY. Asymmetric layered structural design with segregated conductive network for absorption-dominated high-performance electromagnetic interference shielding. Chem Eng J, 2021, 416: 129083,

[24] Wan Y-J, Rajavel K, Li X-M, Wang X-Y, Liao S-Y, Lin Z-Q, Zhu P-L, Sun R, Wong C-P. Electromagnetic interference shielding of Ti₃C₂T MXene modified by ionic liquid for high chemical stability and excellent mechanical strength. Chem Eng J, 2021, 408: 127303,

[25] Hu JN, Liang CY, Li JD, Lin CW, Liang YJ, Dong DW. Ultrastrong and hydrophobic sandwich-structured MXene-based composite films for high-efficiency electromagnetic interference shielding. ACS Appl Mater Interf, 2022, 14: 33817,

[26] Yan Z, Ding YL, Huang MR, Li JF, Han QX, Yang MQ, Li WM. MXene/CNTs/Aramid aerogels for electromagnetic interference shielding and joule heating. ACS Appl Nano Mater, 2023, 6: 6141,

[27] Wang YF, Liang LY, Du ZR, Wang YM, Liu CT, Shen CY. Biodegradable PLA/CNTs/Ti₃C₂T_x MXene nanocomposites for efficient electromagnetic interference shielding. J Mater Sci Mater El, 2021, 32: 25952,

[28] Li HY, Ru XH, Song Y, Wang HP, Yang CH, Zheng SR, Gong L, Zhang XG, Duan HJ, Liu ZG, Zhang QY, Chen YH. Flexible sandwich-structured silicone rubber/MXene/Fe₃O₄ composites for tunable electromagnetic interference shielding. Ind Eng Chem Res, 2022, 61: 11766,

[29] Liu Y, Wu N, Zheng SN, Yang YF, Li B, Liu W, Liu JR, Zeng ZH. From MXene Trash to ultraflexible composites for multifunctional electromagnetic interference shielding. ACS Appl Mater Interf, 2022, 14: 50120,

[30] Li ZY, Sun Y, Zhou B, Feng YZ, Liu CT, Shen CY. Flexible thermoplastic polyurethane/MXene foams for compressible electromagnetic interference shielding. Mater Today Phys, 2023, 32: 101017,

[31] Wei YY, Dai ZH, Zhang YF, Zhang WW, Gu J, Hu CS, Lin XY. Multifunctional waterproof MXene-coated wood with high electromagnetic shielding performance. Cellulose, 2022, 29: 5883,

[32] Wei YY, Liang DD, Zhou HY, Huang SJ, Zhang WW, Gu J, Hu CS, Lin XY. Facile preparation of MXene-decorated wood with excellent electromagnetic interference shielding performance. Compos Part A Appl S, 2022, 153: 106739,

[33] Zhai JY, Cui C, Li A, Guo RH, Cheng C, Ren EH, Xiao HY, Zhou M, Zhang JW. Waste cotton Fabric/MXene composite aerogel with heat generation and insulation for efficient electromagnetic interference shielding. Ceram Int, 2022, 48: 13464,

[34] Fan ZM, Wang DL, Yuan Y, Wang YS, Cheng ZJ, Liu YY, Xie ZM. A lightweight and conductive MXene/graphene hybrid foam for superior electromagnetic interference shielding. Chem Eng J, 2020, 381: 122696,

[35] Yang YF, Li B, Wu N, Liu W, Zhao SY, Zhang CF, Liu JR, Zeng ZH. Biomimetic porous MXene-based hydrogel for high-performance and multifunctional electromagnetic interference shielding. Acs Mater Lett, 2022, 4: 2352,

[36] Wang W, Peng ZL, Ma ZP, Zhang L, Wang XZ, Xu ZM, Feng YB, Liu CL, Liang DW, Li QL. High-efficiency electromagnetic interference shielding from highly aligned MXene porous composites via controlled directional freezing. ACS Appl Mater Interf, 2023, 15: 47566,

[37] Sun YL, Li B, Zheng HF, Rong K, Fan W, Li DY. MXene-decorated carbonized jute composite for high-performance electromagnetic interference shielding. J Mater Res Technol, 2023, 22: 658,

[38] He JZ, Li JJ, Zhang JL, Yi P, Sun X, Han GY, Li XF, Zhang RB, Liu XF, Yu RH. Metal ions-assisted construction of SiO₂/MXene/Fe₃O₄ aerogel as multifunctional electromagnetic wave absorbing material. Carbon, 2023, 214: 118266,

[39] Ghaffarkhah A, Hashemi SA, Rostami S, Amini M, Ahmadijokani F, Pournaghshband Isfahani A, Mhatre SE, Rojas OJ, Kamkar M, Wuttke S, Soroush M, Arjmand M. Ultra-flyweight cryogels of MXene/graphene oxide for electromagnetic interference shielding. Adv Funct Mater, 2023, 33: 2304748,

[40] Zhan YH, Meng YY, Xie Q. Simple approach to fabricate MXene/cellulose paper for electromagnetic interference shielding applications. J Appl Polym Sci, 2021, 138: 50597,

[41] Liu L-X, Chen W, Zhang H-B, Zhang Y, Tang PP, Li DY, Deng ZM, Ye LX, Yu Z-Z. Tough and electrically conductive Ti₃C₂T MXene–based core–shell fibers for high–performance electromagnetic interference shielding and heating application. Chem Eng J, 2022, 430: 133074,

[42] Liu L-X, Chen W, Zhang H-B, Ye LX, Wang ZG, Zhang Y, Min P, Yu Z-Z. Super-tough and environmentally stable aramid. Nanofiber@MXene coaxial fibers with outstanding electromagnetic interference shielding efficiency. Nanomicro Lett, 2022, 14: 111

[43] Yin G, Wu J, Ye LX, Liu LX, Yu YX, Min P, Yu ZZ, Zhang H-B. Dynamic adaptive wrinkle‐structured silk fibroin/MXene composite fibers for switchable electromagnetic interference shielding. Adv Funct Mater. 2024;2314425.

[44] Ye LX, Liu L-X, Yin G, Liu YF, Deng ZM, Qi C-Z, Zhang H-B, Yu Z-Z. Highly conductive, hydrophobic, and acid/alkali-resistant MXene@PVDF hollow core-shell fibers for efficient electromagnetic interference shielding and Joule heating. Mater Today Phys, 2023, 35: 101100,

[45] Lee S, Kim M, Cao V, Park J, Yoon I-J, Park P, Nah J. High performance flexible electromagnetic interference shielding material realized using ZnO nanorod decorated polyvinylidene fluoride (PVDF)-MXene composite nanofibers. J Mater Chem C, 2023, 11: 1522,

[46] Zheng XH, Tang JH, Wang P, Wang ZQ, Zou LH, Li CL. Interfused core-shell heterogeneous graphene/MXene fiber aerogel for high-performance and durable electromagnetic interference shielding. J Colloid Interf Sci, 2022, 628: 994,

[47] Zhao GX, Sui C, Miao LL, Li JJ, Wen L, Cheng G, Zhao CX, Hao WZ, Sang YN, Li JX, Zhang ZC, Zhao YS, Wang F, Liu R, He XD, Wang C. Strong and continuous MXene/sodium alginate composite fibers prepared by immersion rotary jet spinning process with outstanding electromagnetic interference shielding performance. Chem Eng J, 2023, 469: 143983,

[48] Hu Y, Chen JZ, Yang GY, Li YJ, Dong M, Zhang H, Bilotti E, Jiang JJ, Papageorgiou DG. Highly conductive and mechanically robust MXene@CF core-shell composites for in-situ damage sensing and electromagnetic interference shielding. Compos Sci Technol, 2024, 246: 110356,

Funding

The National Natural Science Foundation of China(No.52173274); The National Natural Science Foundation of China(No.52102045)