Compositing halide perovskites for multifunctionalities beyond optoelectronics

Abstract

Metal halide perovskites (MHPs) have emerged as highly promising optoelectronic materials due to their high absorption coefficients, tunable bandgaps, long carrier diffusion lengths, and low exciton binding energies. In addition, their unique polar structures enable electric polarization-related properties, such as ferroelectricity, opening new avenues for integrating light-responsive and ferroelectric functionalities in next-generation electronic devices. Despite the exciting progress achieved in MHPs-based optoelectronic devices, compositing MHPs with polymers or metal-organic frameworks not only improves their mechanical flexibility, stability, and optoelectronic performance, but also extends their functions to multi-energy harvesting and multifunctional sensing. Herein, we highlight the structural diversity, tunability, and rich physics of MHPs, and focus on strategies for structural design, optimization of optical and ferroelectric properties, as well as functional implementation across diverse applications of MHPs-based composites in sensors, energy harvesters, solar cells, and photocatalysts. Finally, we conclude with perspectives on the prospects of MHPs-based composites, emphasizing their significant potential to advance the development of highly stable, efficient, low-cost, and multifunctional flexible optoelectronic devices.

Keywords

Metal halide perovskite / composite / multifunction

References

[1] Han Y,Cui BB.Low-dimensional metal halide perovskite crystal materials: structure strategies and luminescence applications.Adv Sci2021;8:e2004805 PMCID:PMC8336498

[2] Dong H,Liu X,Zhao YS.Materials chemistry and engineering in metal halide perovskite lasers.Chem Soc Rev2020;49:951-82

[3] Fu Y,Chen J,Zhu XY.Metal halide perovskite nanostructures for optoelectronic applications and the study of physical properties.Nat Rev Mater2019;4:169-88

[4] Filip MR,Snaith HJ.Steric engineering of metal-halide perovskites with tunable optical band gaps.Nat Commun2014;5:5757

[5] Xiong Z,Cai K.Homogenized chlorine distribution for >27% power conversion efficiency in perovskite solar cells.Science2025;390:638-42

[6] Zhou Q,Wang J.Aromatic interaction-driven out-of-plane orientation for inverted perovskite solar cells with improved efficiency.Nat Energy2025;10:1371-81

[7] He D,Zhang J.Universal ion migration suppression strategy based on supramolecular host-guest interaction for high-performance perovskite solar cells.Adv Mater2025;37:e2505115

[8] Pandey R,Yun J.Mutual insight on ferroelectrics and hybrid halide perovskites: a platform for future multifunctional energy conversion.Adv Mater2019;31:e1807376

[9] Zhang T,Li J.Ferroelectric hybrid organic-inorganic perovskites and their structural and functional diversity.Natl Sci Rev2023;10:nwac240 PMCID:PMC9935996

[10] Zheng W,Zhang X.Emerging halide perovskite ferroelectrics.Adv Mater2023;35:e2205410

[11] Li X,Guo X,Wei J.Constructing heterojunctions by surface sulfidation for efficient inverted perovskite solar cells.Science2022;375:434-7

[12] Bai Y,Shao Y.Enhancing stability and efficiency of perovskite solar cells with crosslinkable silane-functionalized and doped fullerene.Nat Commun2016;7:12806 PMCID:PMC5059465

[13] Wang R,Meng L.Caffeine improves the performance and thermal stability of perovskite solar cells.Joule2019;3:1464-77

[14] Wang Y,Chen H.Ultrastable, highly luminescent organic-inorganic perovskite-polymer composite films.Adv Mater2016;28:10710-7

[15] Qin J,Guo X.A polymer strategy toward high-performance multifunctional perovskite optoelectronics: from polymer matrix to device applications.Adv Opt Mater2023;11:2202809

[16] Zhang C,Li L.Metal halide perovskite nanocrystals in metal-organic framework host: not merely enhanced stability.Angew Chem Int Ed2021;60:7488-501

[17] Khare S,Gohel JV.Advanced materials to overcome the challenges in the fabrication of stable and efficient perovskite solar cells by additive engineering: a review.J Mater Sci2023;58:16565-90

[18] He Y,Liang S.Dual-protected metal halide perovskite nanosheets with an enhanced set of stabilities.Angew Chem Int Ed2021;60:7259-66

[19] Zhang Z,Meng K,Chen G.Rationalization of passivation strategies toward high-performance perovskite solar cells.Chem Soc Rev2023;52:163-95

[20] Wu S,Li MQ.2D metal-organic framework for stable perovskite solar cells with minimized lead leakage.Nat Nanotechnol2020;15:934-40

[21] Liu Y,Wei Z.Confined flash printing and synthesis of stable perovskite nanofilms under ambient conditions.Adv Mater2024;36:e2409592

[22] Li Z,Wan Z.Boosting mechanical durability under high humidity by bioinspired multisite polymer for high-efficiency flexible perovskite solar cells.Nat Commun2025;16:1771 PMCID:PMC11840045

[23] Zhou Y,Uddin MA,Ni Z.Self-powered perovskite photon-counting detectors.Nature2023;616:712-8 PMCID:PMC11565494

[24] Yang X,Xiang Y.Buried interfaces in halide perovskite photovoltaics.Adv Mater2021;33:e2006435

[25] Wang Y,Cheng Z.Halide perovskite inducing anomalous nonvolatile polarization in poly(vinylidene fluoride)-based flexible nanocomposites.Nat Commun2024;15:3943 PMCID:PMC11087492

[26] Chen Z,Hu Y,Gu H.Ultrahigh energy harvesting ability of PVDF incorporated with 2D halide perovskite nanosheets via interface effect.Chem Eng J2024;497:154558

[27] Park SY,Kim J.2D perovskite nanosheet-driven polymeric nanocomposites as gate dielectrics for flexible negative-capacitance applications.Adv Funct Mater2024;34:2404466.

[28] Sun X,Zhang L.Enhanced electromechanical conversion via in situ grown CsPbBr₃ nanoparticle/poly(vinylidene fluoride) fiber composites for physiological signal monitoring.Soft Sci2022;2:1

[29] Zain Karimy NH,Lee HB.Highly efficient 3D-printed PVDF-based triboelectric nanogenerators featuring polymorphic perovskite nanofillers.Adv Funct Mater2025;35:2424271.

[30] Zhao X.Large-area near-infrared perovskite light-emitting diodes.Nat Photonics2020;14:215-18.

[31] Li X,Yuan S.Stretchable luminescent perovskite-polymer hydrogels for visual-digital wearable strain sensor textiles.Adv Fiber Mater2023;5:1671-84

[32] Kong ZC,Dong YJ.Core@shell CsPbBr₃@zeolitic imidazolate framework nanocomposite for efficient photocatalytic CO₂ reduction.ACS Energy Lett2018;3:2656-62.

[33] Xu CY,Wang G.Coordinated optical matching of a texture interface made from demixing blended polymers for high-performance inverted perovskite solar cells.ACS Nano2020;14:196-203

[34] Hou J,Shukla A.Liquid-phase sintering of lead halide perovskites and metal-organic framework glasses.Science2021;374:621-5

[35] Xia P,Guo H.Luminescent solar concentrator with advanced structure for reabsorption loss suppression and synergistic energy harvesting.Adv Funct Mater2024;34:2401121

[36] Green MA,Snaith HJ.The emergence of perovskite solar cells.Nat Photonics2014;8:506-14

[37] Goldschmidt VM.Die gesetze der krystallochemie.Naturwissenschaften1926;14:477-85

[38] Liu Y,Zheng H.Structurally dimensional engineering in perovskite photovoltaics.Adv Energy Mater2023;13:2300188.

[39] Zhou C,Wang M.Low-dimensional organic tin bromide perovskites and their photoinduced structural transformation.Angew Chem Int Ed2017;56:9018-22

[40] Mao L,Kanatzidis MG.Two-dimensional hybrid halide perovskites: principles and promises.J Am Chem Soc2019;141:1171-90

[41] Quan LN,Comin R.Ligand-stabilized reduced-dimensionality perovskites.J Am Chem Soc2016;138:2649-55

[42] You YM,Zhao D.An organic-inorganic perovskite ferroelectric with large piezoelectric response.Science2017;357:306-9

[43] Sun S,Gao X.0D perovskites: unique properties, synthesis, and their applications.Adv Sci2021;8:e2102689 PMCID:PMC8693037

[44] Zhao X,Loo YL.Advancing 2D perovskites for efficient and stable solar cells: challenges and opportunities.Adv Mater2022;34:e2105849

[45] Yu S,Wang S,Dong X.Hydrazinium cation mixed FAPbI₃-based perovskite with 1D/3D hybrid dimension structure for efficient and stable solar cells.Chem Eng J2021;403:125724

[46] Kong T,Zhang Y.Perovskitoid-templated formation of a 1D@3D perovskite structure toward highly efficient and stable perovskite solar cells.Adv Energy Mater2021;11:2101018

[47] Tian T,Fang Y.Large-area waterproof and durable perovskite luminescent textiles.Nat Commun2023;14:234 PMCID:PMC9842651

[48] Liu Z,Peng X.Perovskite light-emitting diodes with EQE exceeding 28% through a synergetic dual-additive strategy for defect passivation and nanostructure regulation.Adv Mater2021;33:e2103268

[49] Li X,Wang YC,Wang HQ.In-situ cross-linking strategy for efficient and operationally stable methylammoniun lead iodide solar cells.Nat Commun2018;9:3806 PMCID:PMC6143610

[50] Peng J,Liu W.A universal double-side passivation for high open-circuit voltage in perovskite solar cells: role of carbonyl groups in poly(methyl methacrylate).Adv Energy Mater2018;8:1801208

[51] Qiao GY,Yuan S.Perovskite quantum dots encapsulated in a mesoporous metal-organic framework as synergistic photocathode materials.J Am Chem Soc2021;143:14253-60

[52] Liu S,Su Y.Optimizing printed quasi-2D luminescent perovskite films via delaminated metal-organic framework modulation.Adv Mater2025;37:e2501939

[53] He H,Li B.Confinement of perovskite-QDs within a single MOF crystal for significantly enhanced multiphoton excited luminescence.Adv Mater2019;31:e1806897

[54] Hou J,Chen P,Cheetham AK.Intermarriage of halide perovskites and metal-organic framework crystals.Angew Chem Int Ed2020;59:19434-49

[55] Fang X,Sharshir S.Lead halide perovskite nanocrystals in metal-organic frameworks: synthesis, properties, and applications.Adv Sci2025;12:e05407 PMCID:PMC12499464

[56] Zhou Q,Lu WG,Zou B.In situ fabrication of halide perovskite nanocrystal-embedded polymer composite films with enhanced photoluminescence for display backlights.Adv Mater2016;28:9163-8

[57] Hu X,Li F.Nacre-inspired crystallization and elastic “brick-and-mortar” structure for a wearable perovskite solar module.Energy Environ Sci2019;12:979-87

[58] Li Z,Wan Z.Hyperbranched polymer functionalized flexible perovskite solar cells with mechanical robustness and reduced lead leakage.Nat Commun2023;14:6451 PMCID:PMC10576085

[59] Li M,Wang ZK.Perovskite grains embraced in a soft fullerene network make highly efficient flexible solar cells with superior mechanical stability.Adv Mater2019;31:e1901519

[60] Jeong B,Choi YJ.All-inorganic CsPbI₃ perovskite phase-stabilized by poly(ethylene oxide) for red-light-emitting diodes.Adv Funct Mater2018;28:1706401

[61] Kim M,Sorrentino R.Enhanced solar cell stability by hygroscopic polymer passivation of metal halide perovskite thin film.Energy Environ Sci2018;11:2609-19

[62] Cao Q,Zhang H.Efficient and stable inverted perovskite solar cells with very high fill factors via incorporation of star-shaped polymer.Sci Adv2021;7:eabg0633 PMCID:PMC8262814

[63] Wang S,Li MX,Hu JS.Polymers for perovskite solar cells.JACS Au2024;4:3400-12 PMCID:PMC11423326

[64] Li M,Chang J.Orientated crystallization of FA-based perovskite via hydrogen-bonded polymer network for efficient and stable solar cells.Nat Commun2023;14:573 PMCID:PMC9895431

[65] Yuan Y,Yang B.Arising applications of ferroelectric materials in photovoltaic devices.J Mater Chem A2014;2:6027-41

[66] Zhang CC,Yuan S.Polarized ferroelectric polymers for high-performance perovskite solar cells.Adv Mater2019;31:e1902222

[67] Yuan Y,Sharma P.Efficiency enhancement in organic solar cells with ferroelectric polymers.Nat Mater2011;10:296-302

[68] Cheng J,Zhang S.Enhanced electric field minimizing quasi-fermi level splitting deficit for high-performance tin-lead perovskite solar cells.Adv Mater2024;36:e2410298

[69] Li Z,Wu S.An effective and economical encapsulation method for trapping lead leakage in rigid and flexible perovskite photovoltaics.Nano Energy2022;93:106853

[70] Chen B,Chen S,Xiao X.Recycling lead and transparent conductors from perovskite solar modules.Nat Commun2021;12:5859 PMCID:PMC8494795

[71] Dong H,Fang H.Internal encapsulation strategy using a polymer enables efficient, stable, and lead-safe inverted perovskite solar cells.Adv Funct Mater2024;34:2402394

[72] Xu Y,Lin Z.Perovskite films regulation via hydrogen-bonded polymer network for efficient and stable perovskite solar cells.Angew Chem Int Ed2023;62:e202306229

[73] Jiang Y,Juarez-Perez EJ.Reduction of lead leakage from damaged lead halide perovskite solar modules using self-healing polymer-based encapsulation.Nat Energy2019;4:585-93

[74] Zhang J,Guo F.Thermally crosslinked F-rich polymer to inhibit lead leakage for sustainable perovskite solar cells and modules.Angew Chem Int Ed2023;62:e202305221

[75] Fu H.Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics.Nature2000;403:281-3

[76] Choi KJ,Li YL.Enhancement of ferroelectricity in strained BaTiO₃ thin films.Science2004;306:1005-9

[77] Kingon AI.Lead zirconate titanate thin films directly on copper electrodes for ferroelectric, dielectric and piezoelectric applications.Nat Mater2005;4:233-37

[78] Huangfu G,Wang B.Giant electric field-induced strain in lead-free piezoceramics.Science2022;378:1125-30

[79] Pan Q,Zhou RJ.The past 10 years of molecular ferroelectrics: structures, design, and properties.Chem Soc Rev2024;53:5781-861

[80] Guo Z,Mao L.Dynamic control of halide perovskite structures for tailored ferroelectric and second-order nonlinear optical functionalities.Chem Soc Rev2025;54:8845-87

[81] Quarti C,De Angelis F.Interplay of orientational order and electronic structure in methylammonium lead iodide: implications for solar cell operation.Chem Mater2014;26:6557-69

[82] Wilson JN,Wallace SK.Dielectric and ferroic properties of metal halide perovskites.APL Mater2019;7:010901

[83] Ali W,Tian H,Feng Z.Tuning lattice structure of ferroelastic twin-domains achieving efficient perovskite solar cells.ACS Energy Lett2023;8:5070-78

[84] Li PF,Tang YY,Zhang Y.Unprecedented ferroelectric-antiferroelectric-paraelectric phase transitions discovered in an organic-inorganic hybrid perovskite.J Am Chem Soc2017;139:8752-7

[85] Yang CK,Ding YT.The first 2D homochiral lead iodide perovskite ferroelectrics: [R- and S-1-(4-chlorophenyl)ethylammonium]₂PbI₄.Adv Mater2019;31:e1808088

[86] Leguy AM,McMahon AP.The dynamics of methylammonium ions in hybrid organic-inorganic perovskite solar cells.Nat Commun2015;6:7124 PMCID:PMC4458867

[87] Rossi D,der Maur MA.On the importance of ferroelectric domains for the performance of perovskite solar cells.Nano Energy2018;48:20-6

[88] Liu HY,Chen XG.Molecular design principles for ferroelectrics: ferroelectrochemistry.J Am Chem Soc2020;142:15205-18

[89] Shi K,Zou H.Interface induced performance enhancement in flexible BaTiO₃/PVDF-TrFE based piezoelectric nanogenerators.Nano Energy2021;80:105515

[90] Chen B,Dong Q.Large electrostrictive response in lead halide perovskites.Nat Mater2018;17:1020-6

[91] He W,Zhao YB.Self-supporting smart air filters based on PZT/PVDF electrospun nanofiber composite membrane.Chem Eng J2021;423:130247

[92] Tian G,Gao Y.Rich lamellar crystal baklava-structured PZT/PVDF piezoelectric sensor toward individual table tennis training.Nano Energy2019;59:574-81.

[93] Shi K,Huang X.Synergistic effect of graphene nanosheet and BaTiO₃ nanoparticles on performance enhancement of electrospun PVDF nanofiber mat for flexible piezoelectric nanogenerators.Nano Energy2018;52:153-62.

[94] Luo S,Yu S.Significantly enhanced electrostatic energy storage performance of flexible polymer composites by introducing highly insulating-ferroelectric microhybrids as fillers.Adv Energy Mater2019;9:1803204.

[95] Dunlap-Shohl WA,Padture NP.Synthetic approaches for halide perovskite thin films.Chem Rev2019;119:3193-295

[96] Sultana A,Alam MM.Methylammonium lead iodide incorporated poly(vinylidene fluoride) nanofibers for flexible piezoelectric-pyroelectric nanogenerator.ACS Appl Mater Interfaces2019;11:27279-87

[97] Jiang F,Lv J.Stretchable, breathable, and stable lead-free perovskite/polymer nanofiber composite for hybrid triboelectric and piezoelectric energy harvesting.Adv Mater2022;34:e2200042

[98] Kumar P,Sahoo A.Harnessing self-powered and photoresponsive biomechanical activity sensors by exploring the piezo-phototronic effect in lead-free layered halide perovskite/PVDF composites.J Mater Chem A2025;13:18420-35

[99] Chai B,Wang Y.Integrated piezoelectric/pyroelectric sensing from organic-inorganic perovskite nanocomposites.ACS Nano2024;18:25216-25

[100] Salesh M,Mridha N,Mural PKS.Multifunctional lead-free halide perovskite-based nanogenerator for enhanced energy harvesting and information-encrypted transmission.ACS Appl Mater Interfaces2025;17:38481-92

[101] Wu Y,Jin X.High-performance flexible molecular-based piezoelectric composites for wireless microelectronics.Chem Eng J2025;515:163755

[102] Garain S,Monluc H,Bai J.Halide-tunable bond engineering for high-performance multi-responsive piezoelectric sensors via enhanced electrostatic polarization in in situ perovskite-embedded PVDF nanofibers.Small2025;21:e2504787 PMCID:PMC12410901

[103] Wu S,Yeap RY.Cesium lead halide perovskite decorated polyvinylidene fluoride nanofibers for wearable piezoelectric nanogenerator yarns.ACS Nano2023;17:1022-35 PMCID:PMC9878976

[104] Zhao Z,Li S.Selection rules of triboelectric materials for direct-current triboelectric nanogenerator.Nat Commun2021;12:4686 PMCID:PMC8333059

[105] Musiienko A,Praus P.Deciphering the effect of traps on electronic charge transport properties of methylammonium lead tribromide perovskite.Sci Adv2020;6:eabb6393 PMCID:PMC7486106

[106] Chen Y.Defects chemistry in high-efficiency and stable perovskite solar cells.J Appl Phys2020;128:060903

[107] Su L,Li HY.High-performance organolead halide perovskite-based self-powered triboelectric photodetector.ACS Nano2015;9:11310-6

[108] Wang Y,Yang X,Zhao L.The unique dielectricity of inorganic perovskites toward high-performance triboelectric nanogenerators.Nano Energy2020;69:104418

[109] Yu A,Wang W.Progress in triboelectric materials: toward high performance and widespread applications.Adv Funct Mater2019;29:1900098.

[110] He Y,Sha Z,Wang CH.Enhancing output performance of PVDF-HFP fiber-based nanogenerator by hybridizing silver nanowires and perovskite oxide nanocrystals.Nano Energy2022;98:107343

[111] Cheon S,Kim H.High-performance triboelectric nanogenerators based on electrospun polyvinylidene fluoride-silver nanowire composite nanofibers.Adv Funct Mater2018;28:1703778.

[112] Jiang F,Lee JP.Self-healable and stretchable perovskite-elastomer gas-solid triboelectric nanogenerator for gesture recognition and gripper sensing.Sci Adv2024;10:eadq5778 PMCID:PMC11468913

[113] Kojima A,Shirai Y.Organometal halide perovskites as visible-light sensitizers for photovoltaic cells.J Am Chem Soc2009;131:6050-1

[114] Luo J,Grater L.Vapour-deposited perovskite light-emitting diodes.Nat Rev Mater2024;9:282-94.

[115] Wen J,Chen C.Present status of and future opportunities for all-perovskite tandem photovoltaics.Nat Energy2025;10:681-96

[116] Prince KJ,Gaulding EA.Sustainability pathways for perovskite photovoltaics.Nat Mater2025;24:22-33

[117] Han J,Tan S.Perovskite solar cells.Nat Rev Methods Primers2025;5:3

[118] Chen Z,Zhang C.Recombination dynamics study on nanostructured perovskite light-emitting devices.Adv Mater2018;30:e1801370

[119] Tian Y,Worku M.Highly efficient spectrally stable red perovskite light-emitting diodes.Adv Mater2018;30:e1707093

[120] Tsai H,Vilá RA.Bright and stable light-emitting diodes made with perovskite nanocrystals stabilized in metal-organic frameworks.Nat Photonics2021;15:843-49

[121] Li G,Canil L.Highly efficient p-i-n perovskite solar cells that endure temperature variations.Science2023;379:399-403

[122] Dong Y,Zhang H.Multifunctional MOF@COF nanoparticles mediated perovskite films management toward sustainable perovskite solar cells.Nanomicro Lett2024;16:171 PMCID:PMC11009200

[123] Wu Y,Shen Y.Stereoscopic polymer network for developing mechanically robust flexible perovskite solar cells with an efficiency approaching 25.Adv Mater2024;36:e2403531

[124] Wu LY,Guo XX.Encapsulating perovskite quantum dots in iron-based metal-organic frameworks (MOFs) for efficient photocatalytic CO₂ reduction.Angew Chem Int Ed2019;58:9491-5

[125] Xia Z,Zhu W,Lü C.Binary hybridization strategy toward stable porphyrinic Zr-MOF encapsulated perovskites as high-performance heterogeneous photocatalysts for red to NIR light-induced PET-RAFT polymerization.Adv Funct Mater2022;32:2207655

[126] Yin Z,Liang G,Zhao C.Facile construction of a double-heterojunction perovskite quantum dot system for efficient photocatalytic Cr⁶⁺ reduction.ACS Appl Mater Interfaces2024;16:39506-16

[127] Cao F,Meng L,Li L.Ultrahigh-performance flexible and self-powered photodetectors with ferroelectric P(VDF-TrFE)/perovskite bulk heterojunction.Adv Funct Mater2019;29:1808415

[128] Guan S,Ning Y,Qin B.Effect of metal-organic frameworks with different ligand structures (ZIF-11 & ZIF-23) on the optoelectronic performance of perovskite photodetectors.ACS Appl Mater Interfaces2024;16:41341-50

[129] Yang Y,Liu X.Flexible photo-responsive nanofiber composites coupled triboelectric-photovoltaic effect for energy harvesting.Compos Part B2025;307:112879.

[130] Guo Q,Wang Y,Duan J.Dielectric hole collector toward boosting charge transfer of CsPbBr₃ hybrid nanogenerator by coupling triboelectric and photovoltaic effects.Adv Funct Mater2021;31:2101348

[131] Sultana A,Sadhukhan P.Organo-lead halide perovskite regulated green light emitting poly(vinylidene fluoride) electrospun nanofiber mat and its potential utility for ambient mechanical energy harvesting application.Nano Energy2018;49:380-92

[132] Lin H,Yao H.Robustly stable perovskite-based triboelectric nanogenerators via grain-boundary manipulation for light-assisted energy harvesting and wireless control of smart windows.Nano Energy2025;144:111355

[133] Kim M,Cao VA,Nah J.Performance enhancement of triboelectric nanogenerators via photo-generated carriers using a polymer-perovskite composite.Nano Energy2023;112:108474

[134] Wu W,Li M,Long H.A flexible bimodal self-powered optoelectronic skin for comprehensive perception of multiplexed sensoring signals.Nano Energy2024;125:109593.

[135] Venkatesan M,Cho CJ.Enhanced piezoelectric and photocatalytic performance of flexible energy harvester based on CsZn_0.75Pb_0.25I₃/CNC-PVDF composite nanofibers.Chem Eng J2022;433:133620

[136] Zuo L,deQuilettes DW.Polymer-modified halide perovskite films for efficient and stable planar heterojunction solar cells.Sci Adv2017;3:e1700106 PMCID:PMC5567759

[137] Han TH,Choi C.Perovskite-polymer composite cross-linker approach for highly-stable and efficient perovskite solar cells.Nat Commun2019;10:520 PMCID:PMC6355927

[138] Ma L,Zhou X.A polymer controlled nucleation route towards the generalized growth of organic-inorganic perovskite single crystals.Nat Commun2021;12:2023 PMCID:PMC8016843

[139] Yuan Y,Huang J.Achieving high efficiency laminated polymer solar cell with interfacial modified metallic electrode and pressure induced crystallization.Appl Phys Lett2011;98:063306

[140] Yuan Y,Xiao Z.Understanding the effect of ferroelectric polarization on power conversion efficiency of organic photovoltaic devices.Energy Environ Sci2012;5:8558-63

[141] Han TH,Dong Y,Sargent EH.A roadmap for the commercialization of perovskite light emitters.Nat Rev Mater2022;7:757-77.

[142] Xi Y,Shen Y.et al. Aspect ratio dependent photocatalytic enhancement of CsPbBr₃ in CO₂ reduction with two-dimensional metal organic framework as a cocatalyst.Appl Catal B2021;297:120411

[143] Wan S,Zhong Q.Perovskite-type CsPbBr₃ quantum dots/UiO-66(NH₂) nanojunction as efficient visible-light-driven photocatalyst for CO₂ reduction.Chem Eng J2019;358:1287-95

[144] Yang T,Li Z.Recent advances in wearable tactile sensors: materials, sensing mechanisms, and device performance.Mater Sci Eng R2017;115:1-37.

[145] Wu C,Ding W,Wang ZL.Triboelectric nanogenerator: a foundation of the energy for the new era.Adv Energy Mater2019;9:1802906.

[146] Xia P,Xu S.Luminescent solar concentrators with dual functions of photovoltaic and piezoelectric properties for wireless self-powered speed measurement.Adv Energy Mater2023;13:2301332

[147] Cao X,Sun J,Sun Q.Piezoelectric nanogenerators derived self-powered sensors for multifunctional applications and artificial intelligence.Adv Funct Mater2021;31:2102983

[148] Ma X,Wei R.Bimodal tactile sensor without signal fusion for user-interactive applications.ACS Nano2022;16:2789-97

[149] Son D,Qiao S.Multifunctional wearable devices for diagnosis and therapy of movement disorders.Nat Nanotechnol2014;9:397-404

[150] Wang W,Zhong D.Neuromorphic sensorimotor loop embodied by monolithically integrated, low-voltage, soft e-skin.Science2023;380:735-42

[151] Peng W,Wang X.Temperature dependence of pyro-phototronic effect on self-powered ZnO/perovskite heterostructured photodetectors.Nano Res2016;9:3695-704

[152] Chen TW,Chen SM,Ramachandran K.Graphene and perovskite-based nanocomposite for both electrochemical and gas sensor applications: an overview.Sensors2020;20:6755 PMCID:PMC7731062

[153] Li W,Sun X,Ye T.A light/pressure bifunctional electronic skin based on a bilayer structure of PEDOT:PSS-coated cellulose paper/CsPbBr₃ QDs film.Polymers2023;15:2136 PMCID:PMC10181253

[154] Khan AA,Huang G.Maximizing piezoelectricity by self-assembled highly porous perovskite-polymer composite films to enable the internet of things.J Mater Chem A2020;8:13619-29

[155] Min J,Sempionatto JR.An autonomous wearable biosensor powered by a perovskite solar cell.Nat Electron2023;6:630-41 PMCID:PMC10923186