Development and progress in polymer materials for anti-corrosion and anti-fouling applications: A review

Abstract

Corrosion has always been a difficult problem that troubles and restricts the application and development of engineering materials. By endowing coatings on metal surfaces with polymer material, it is possible to protect other materials from factors including acid and alkali, water vapor, bacteria. Therefore, it is necessary to summarize the research progress of polymer materials in the field of pollution and corrosion prevention in recent years. This article summarizes four types of polymer materials with good weather resistance: polyurethane (PU), polydimethylsiloxane (PDMS), polyvinylidene fluoride (PVDF), and polyvinylidene chloride (PVDC). These four polymer materials are suitable for making polymer anti-corrosion or anti-fouling materials and each has its own characteristics. PU can firmly adhere to various substrates, effectively protecting and extending their lifespan, but the environmentally friendly varieties currently used, namely water-borne polyurethanes (WPU), generally have poor mechanical properties. PDMS is non-toxic and has excellent hydrophobicity, but its static anti-fouling ability is insufficient when applied in the field of anti-fouling. PVDF has good chemical resistance and high mechanical properties, good UV resistance making it suitable for outdoor use like in the marine environment. However, PVDF lacks flexibility after molding and its manufacturing cost is relatively high. PVDC has excellent water vapor barrier properties, but poor adhesion to metal material surfaces. Therefore, researchers need to modify these four polymers when using them to solve the problem of corrosion or biofouling. The article will review the research progress of four types of polymers in recent years from the perspectives of anti-corrosion, anti-fouling, and a strategy named as self-healing that is beneficial for protecting polymer surfaces from mechanical damage, and summarize the modification methods adopted by researchers when applying these materials. Finally, a summary of the application and the prospects of these polymer materials are presented.

References

[1] JinH-c, TianL-m, BingW, et al. . Bioinspired marine antifouling coatings: Status, prospects, and future [J]. Progress in Materials Science, 2022, 124: 100889

[2] LiZ, DingS-q, KongL-j, et al. . Nano TiO₂-engineered anti-corrosion concrete for sewage system [J]. Journal of Cleaner Production, 2022, 337: 130508

[3] GittensR A, Olivares-NavarreteR, TannenbaumR, et al. . Electrical implications of corrosion for osseointegration of titanium implants [J]. Journal of Dental Research, 2011, 90(12): 1389-1397

[4] RobergeP R, KlassenR D, HaberechtP W. Atmospheric corrosivity modeling—A review [J]. Materials & Design, 2002, 23(3): 321-330

[5] YanM-d, WeiB-x, XuJ, et al. . Insight into sulfate-reducing bacteria corrosion behavior of X80 pipeline steel welded joint in a soil solution [J]. Journal of Materials Research and Technology, 2023, 24: 5839-5863

[6] ZhouX-p, DuE-b, WangY-teng. Chemo-mechanical coupling bond-based peridynamic model for electrochemical corrosion and stress chemical corrosion [J]. Engineering Analysis with Boundary Elements, 2023, 151: 360-369

[7] Al-AmieryA A, IsahakW N R W, Al-AzzawiW K. Corrosion inhibitors: Natural and synthetic organic inhibitors [J]. Lubricants, 2023, 11(4): 174

[8] VaghefinazariB, WierzbickaE, VisserP, et al. . Chromate-free corrosion protection strategies for magnesium alloys-a review: Part III—corrosion inhibitors and combining them with other protection strategies [J]. Materials, 2022, 15(23): 8489

[9] PrzybyszewskiB, BoczkowskaA, KozeraR, et al. . Hydrophobic and icephobic behaviour of polyurethane-based nanocomposite coatings [J]. Coatings, 2019, 9(12): 811

[10] ShaJ-n, YuJ, ChenR-r, et al. . Eco-friendly self-polishing antifouling coating via eugenol ester hydrolysis [J]. Progress in Organic Coatings, 2022, 172: 107077

[11] WangY, LiQ-z, ShaoT-r, et al. . Fabrication of anti-fouling and anti-bacterial hydrophilic coating through enzymatically-synthesized cellooligomers [J]. Applied Surface Science, 2022, 600: 154133

[12] AbolhasaniH, FarziG, DavoodiA, et al. . Development of self-healable acrylic water-based environmental-friendly coating as an alternative to chromates coatings [J]. Progress in Organic Coatings, 2023, 176: 107402

[13] SamadzadehM, BouraS H, PeikariM, et al. . Tung oil: An autonomous repairing agent for self-healing epoxy coatings [J]. Progress in Organic Coatings, 2011, 70(4): 383-387

[14] HuangJ-r, GongZ, ChenY-kun. A stretchable elastomer with recyclability and shape memory assisted self-healing capabilities based on dynamic disulfide bonds [J]. Polymer, 2022, 242: 124569

[15] BianW-c, WangW-x, YangYing. A self-healing and electrical-tree-inhibiting epoxy composite with hydrogen-bonds and SiO₂ particles [J]. Polymers, 2017, 9(9): 431

[16] BaijuS K, MartinB J, FredericksR, et al. . Anti-fouling properties of phosphonium ionic liquid coatings in the Marine Environment [J]. Polymers, 2023, 15(18): 3677

[17] DianatG, SeidelS, de LunaM M, et al. . Vapor phase fabrication of hydrophilic and hydrophobic asymmetric polymer membranes [J]. Macromolecular Materials and Engineering, 2016, 301(9): 1037-1043

[18] KumarS S A, BashirS, RameshK, et al. . New perspectives on graphene/graphene oxide based polymer nanocomposites for corrosion applications: The relevance of the graphene/polymer barrier coatings [J]. Progress in Organic Coatings, 2021, 154: 106215

[19] ZhangX, RenP-f, YangH-c, et al. . Co-deposition of tannic acid and diethlyenetriamine for surface hydrophilization of hydrophobic polymer membranes [J]. Applied Surface Science, 2016, 360: 291-297

[20] YuanR-x, LiuH, ChenY-g, et al. . Design ambient-curable superhydrophobic/electroactive coating toward durable pitting corrosion resistance [J]. Chemical Engineering Journal, 2019, 374: 840-851

[21] ZhangT, ZhangL-zhi. A self-healing PVDF-ZnO/MXene membrane with universal fouling resistance for real seawater desalination [J]. Water Research, 2022, 216: 118349

[22] StaráH, StarýZ, MünstedtH. Silver nanoparticles in blends of polyethylene and a superabsorbent polymer: Morphology and silver ion release [J]. Macromolecular Materials and Engineering, 2011, 296(5): 423-427

[23] MondrzykA, FischerJ, RitterH. Antibacterial materials: Structure-bioactivity relationship of epoxy – amine resins containing quaternary ammonium compounds covalently attached [J]. Polymer International, 2014, 63(7): 1192-1196

[24] RahmanM, AliA, SjöholmE, et al. . Significance of polymers with “allyl” functionality in biomedicine: An emerging class of functional polymers [J]. Pharmaceutics, 2022, 14(4): 798

[25] MarquitanM, RuffA, BraminiM, et al. . Polymer/enzyme-modified HF-etched carbon nanoelectrodes for single-cell analysis [J]. Bioelectrochemistry, 2020, 133: 107487

[26] AiF-j, YinX-z, HuR-c, et al. . Research into the super-absorbent polymers on agricultural water [J]. Agricultural Water Management, 2021, 245: 106513

[27] PernigoniL, GrandeA M. Development of a supramolecular polymer based self-healing multilayer system for inflatable structures [J]. Acta Astronautica, 2020, 177: 697-706

[28] LubisM A R, SariF P, LaksanaR P B, et al. . Ambient curable natural rubber latex adhesive cross-linked with polymeric isocyanate for bonding wood [J]. Polymer Bulletin, 2022, 79(8): 6745-6757

[29] ZhuL-l, ShiT-j, ZhangL-y, et al. . Preparation and characteristics of poly(benzoxazine-urethane)/graphene oxide composites: Toughness, mechanical and thermal properties [J]. Journal of Macromolecular Science, Part A, 2017, 54(12): 967-977

[30] ChangC C, HuangC L, ChangC L. Poly(urethane)-based solar absorber coatings containing nanogold [J]. Solar Energy, 2013, 91: 350-357

[31] WangJ, ShiZ, YuanG, et al. . A flexible modulated pesticide release platform through poly(urethane-urea) microcapsules: Effect of different crosslinkers compositions [J]. Pest Management Science, 2024, 80(8): 3707-3716

[32] HussainH K, ZhangL Z, LiuG W. An experimental study on strengthening reinforced concrete T-beams using new material poly-urethane-cement (PUC) [J]. Construction and Building Materials, 2013, 40: 104-117

[33] AvrahamL, SanguramathR A, CohenO, et al. . Polysaccharide-based, emulsion-templated, porous poly (urethane urea)s: Composition, catalysis, cell growth [J]. European Polymer Journal, 2022, 169: 111140

[34] WangY-y, ZhuL-n, WangY, et al. . Ultrasensitive GSH-responsive ditelluride-containing poly (ether-urethane) nanoparticles for controlled drug release [J]. ACS Applied Materials & Interfaces, 2016, 8(51): 35106-35113

[35] LyuL, WangZ-g, JiJ, et al. . Investigating rheological and healing properties of asphalt binder modified by disulfide-crosslinked poly(urea-urethane) elastomer [J]. Construction and Building Materials, 2022, 347: 128546

[36] WołoszD, FageA M, ParzuchowskiP G, et al. . Sustainable associative thickeners based on hydrophobically modified ethoxylated poly(hydroxy-urethane)s end-capped by long alkyl chains [J]. Progress in Organic Coatings, 2023, 179: 107514

[37] LuS, ZhaoP-q, LiangC, et al. . Utilization of Polydimethylsiloxane (PDMS) in polymer cement-based coating to improve marine environment service performance [J]. Construction and Building Materials, 2023, 367: 130359

[38] FuC-h, CaiD, HuS, et al. . Ethanol fermentation integrated with PDMS composite membrane: An effective process [J]. Bioresource Technology, 2016, 200: 648-657

[39] NAVAEE F, KHORNIAN N, LONGET D, et al. A Three-dimensional engineered cardiac in vitro model: Controlled alignment of cardiomyocytes in 3D microphysiological systems [J]. Cells, 2023, 12(4). DOI: https://doi.org/10.3390/cells12040576.

[40] CuiH-y, CuiY, TangQ, et al. . PDMS-TiO₂ composite films combined with LC-MS/MS for determination of phospholipids of urine in non-small cell lung cancer patients with traditional Chinese medicine syndromes [J]. Journal of Pharmaceutical and Biomedical Analysis, 2023, 233: 115472

[41] ZhangJ, ZhangX-d, LiuZ-y, et al. . Study on preparation and anticorrosive performance of a new high hydrophobic anticorrosive coating [J]. Journal of Applied Polymer Science, 2023, 140(6): e53459

[42] LiQ, HeP, WangH-h, et al. . Enhanced adhesive and mechanically robust silicone-based coating with excellent marine anti-fouling and anti-corrosion performances [J]. Chemistry—A European Journal, 2024, 30(21): e202303096

[43] YangB, ShangY-y, WuM-e, et al. . Statistical characteristics of naturally aged PVDF-coated fabrics’ mechanical properties and structural reliability index [J]. Polymer Testing, 2019, 80: 106143

[44] SugimotoT, OnoK, AndoA, et al. . PVDF-driven flexible and transparent loudspeaker [J]. Applied Acoustics, 2009, 70(8): 1021-1028

[45] PangZ-y, LiY, ZhengH-b, et al. . Microscopic mechanism of electrical aging of PVDF cable insulation material [J]. Polymers, 2023, 15(5): 1286

[46] ShiZ-l, ZhaoG-q, ZhangL, et al. . Ultralight and hydrophobic PVDF/PMMA open-cell foams with outstanding heat-insulation and oil-adsorption performances fabricated by CO₂ molten foaming [J]. Journal of CO2 Utilization, 2022, 63: 102108

[47] JiJ, LiuF, HashimN A, et al. . Poly(vinylidene fluoride) (PVDF) membranes for fluid separation [J]. Reactive and Functional Polymers, 2015, 86: 134-153

[48] TerakadoO, TakahahsiY, HirasawaM. Influence of metal oxide on the fixation of chlorine in thermal decomposition of poly (vinylidene chloride co vinyl chloride) [J]. High Temperature Materials and Processes, 2009, 28(3): 133-140

[49] ShanthiM, MathewC M, UlaganathanM, et al. . FT-IR and DSC studies of poly(vinylidene chloride-co-acrylonitrile) complexed with LiBF₄ [J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2013, 109: 105-109

[50] YangJ, BaoY-z, PanP-ju. Preparation of hierarchical porous carbons from amphiphilic poly (vinylidene chloride-co-methyl acrylate)-b-poly(acrylic acid) copolymers by self-templating and one-step carbonization method [J]. Microporous and Mesoporous Materials, 2014, 196: 199-207

[51] IbrahimA, CottetH. Characterization of hydrosoluble fraction and oligomers in poly(vinylidene chloride) latexes by capillary electrophoresis using electrophoretic mobility modeling [J]. Journal of Chromatography A, 2019, 1598: 223-231

[52] VelasquezE, RiegerJ, StoffelbachF, et al. . Study of the solution and aqueous emulsion copolymerization of vinylidene chloride with methyl acrylate in the presence a poly(ethylene oxide) macromolecular RAFT agent [J]. Polymer, 2013, 54(24): 6547-6554

[53] IreniN G, NarayanR, BasakP, et al. . Poly (thiourethane-urethane)-urea as anticorrosion coatings with impressive optical properties [J]. Polymer, 2016, 97: 370-379

[54] WangY-x, LiC, ZhangX-p, et al. . Poly (vinylidene chloride)/Poly(chlorotrifluoroethylene-co-acrylates) composite latex coating cured at room temperature showing an excellent corrosion resistance [J]. ChemistrySelect, 2020, 5(21): 6278-6284

[55] SiyanbolaT O, SasidharK, AnjaneyuluB, et al. . Anti-microbial and anti-corrosive poly (ester amide urethane) siloxane modified ZnO hybrid coatings from Thevetia peruviana seed oil [J]. Journal of Materials Science, 2013, 48(23): 8215-8227

[56] ZhangB-b, YanJ-y, XuW-c, et al. . Robust, scalable and fluorine-free superhydrophobic anticorrosion coating with shielding functions in marine submerged and atmospheric zones [J]. Materials & Design, 2022, 223: 111246

[57] WangH-h, QinS-d, YangX-f, et al. . A waterborne uniform graphene-poly(urethane-acrylate) complex with enhanced anticorrosive properties enabled by ionic interaction [J]. Chemical Engineering Journal, 2018, 351: 939-951

[58] XiaoY-k, JiW-f, ChangK S, et al. . Sandwich-structured rGO/PVDF/PU multilayer coatings for anticorrosion application [J]. RSC Advances, 2017, 7(54): 33829-33836

[59] YangX-n, TianL-m, WangW, et al. . Bio-inspired superhydrophobic self-healing surfaces with synergistic anticorrosion performance [J]. Journal of Bionic Engineering, 2020, 17(6): 1196-1208

[60] Mehri GhahfarokhiN, Shayegh BroujenyB, HakimizadA, et al. . Plasma electrolytic oxidation (PEO) coating to enhance in vitro corrosion resistance of AZ91 magnesium alloy coated with polydimethylsiloxane (PDMS) [J]. Applied Physics A, 2022, 128(2): 112

[61] RahmanM M, ChunH H, ParkH. Waterborne polysiloxane-urethane-urea for potential marine coatings [J]. Journal of Coatings Technology and Research, 2011, 8(3): 389-399

[62] VanithakumariS C, JohnsonC C, PhilipJ. Facile fabrication of superhydrophobic steel surfaces with self-cleaning ability using nickel myristate/PDMS bilayer coating [J]. Surface and Coatings Technology, 2023, 467: 129712

[63] MohamedA M A, HasanH, SelemanM M E S, et al. . Performance of sprayed PVDF-Al₂O₃ composite coating for industrial and civil applications [J]. Materials, 2021, 14(21): 6358

[64] JiJ, LiangL, XuH, et al. . Facile solvent evaporation synthesis of core-shell structured Al@PVDF nanoparticles with excellent corrosion resistance and combustion properties [J]. Combustion and Flame, 2022, 238: 111925

[65] YuY, YangY, YuL, et al. . Modification of polyvinylidene fluoride membrane by silver nanoparticles-graphene oxide hybrid nanosheet for effective membrane biofouling mitigation [J]. Chemosphere, 2021, 268: 129187

[66] LinX D, YangM, JeongH, et al. . Durable superhydrophilic coatings formed for anti-biofouling and oil-water separation [J]. Journal of Membrane Science, 2016, 506: 22-30

[67] LiuL-f, WuH, LiR-h, et al. . Modification of poly (amide-urethane-imide) (PAUI) thin film composite reverse osmosis membrane with nano-silver particles [J]. RSC Advances, 2018, 8(66): 37817-37827

[68] NasiriardaliM, BoroujenyB S, DoostmohammadiA, et al. . Improvement of biological and corrosion behavior of 316 L stainless steel using PDMS-Ag doped Willemite nanocomposite coating [J]. Progress in Organic Coatings, 2022, 165: 106733

[69] AlnairatN, Abu DaloM, Abu-ZuraykR, et al. . Green synthesis of silver nanoparticles as an effective antibiofouling material for polyvinylidene fluoride (PVDF) ultrafiltration membrane [J]. Polymers, 2021, 13(21): 3683

[70] MpalaT J, Serepa-DlaminiM H, EtaleA, et al. . Cellulose nanocrystal-mediated synthesis of silver nanoparticles via microwave assisted method for biofouling control in membrane distillation [J]. Materials Today Communications, 2023, 34: 105028

[71] GharibiR, YeganehH, KazemiS. Green and non-leaching anti-bacterial and cytocompatible coating with build-in quaternary ammonium salt derived from methoxysilane functionalized soybean oil [J]. Materials Science and Engineering C, 2019, 99: 887-899

[72] PingM, ZhangX-r, LiuM-x, et al. . Surface modification of polyvinylidene fluoride membrane by atom-transfer radical-polymerization of quaternary ammonium compound for mitigating biofouling [J]. Journal of Membrane Science, 2019, 570: 286-293

[73] ZhaiY-x, ZhangX-r, WuZ-c, et al. . Modification of polyvinylidene fluoride membrane by quaternary ammonium compounds loaded on silica nanopollens for mitigating biofouling [J]. Journal of Membrane Science, 2020, 597: 117679

[74] ZhangX-r, WangZ-w, ChenM, et al. . Membrane biofouling control using polyvinylidene fluoride membrane blended with quaternary ammonium compound assembled on carbon material [J]. Journal of Membrane Science, 2017, 539: 229-237

[75] LiJ, XieB, XiaK, et al. . Facile synthesis and characterization of cross-linked chitosan quaternary ammonium salt membrane for antibacterial coating of piezoelectric sensors [J]. International Journal of Biological Macromolecules, 2018, 120: 745-752

[76] LiuC, YanB-h, SunJ-w, et al. . Cu@C core-shell nanoparticles modified polydimethylsiloxane-based coatings with improved static antifouling performance [J]. Progress in Organic Coatings, 2022, 171: 107026

[77] KamaludinR, Abdul MajidL, OthmanM H D, et al. . Polyvinylidene difluoride (PVDF) hollow fiber membrane incorporated with antibacterial and anti-fouling by zinc oxide for water and wastewater treatment [J]. Membranes, 2022, 12(2): 110

[78] SeoE, LeeJ W, LeeD, et al. . Eco-friendly erucamide-polydimethylsiloxane coatings for marine anti-biofouling [J]. Colloids and Surfaces B: Biointerfaces, 2021, 207: 112003

[79] SeoE, SeongM R, LeeJ W, et al. . Anti-biofouling features of eco-friendly oleamide-PDMS copolymers [J]. ACS Omega, 2020, 5(20): 11515-11521

[80] RathS K, ChavanJ G, GhorpadeT K, et al. . Structure - property correlations of foul release coatings based on low hard segment content poly(dimethylsiloxane-urethane-urea) [J]. Journal of Coatings Technology and Research, 2018, 15(1): 185-198

[81] WangF-j, LeiS, OuJ-f, et al. . Effect of PDMS on the waterproofing performance and corrosion resistance of cement mortar [J]. Applied Surface Science, 2020, 507: 145016

[82] QiaoM-y, JiG-j, LuY, et al. . Sustainable corrosion-resistant superhydrophobic composite coating with strengthened robustness [J]. Journal of Industrial and Engineering Chemistry, 2023, 121: 215-227

[83] JinZ-p, MeiH, PanL-k, et al. . Superhydrophobic self-cleaning hierarchical micro/nanocomposite coating with high corrosion resistance and durability [J]. ACS Sustainable Chemistry & Engineering, 2021, 9(11): 4111-4121

[84] SalehS M, AlminderejF M, MohamedA M A. Superhydrophobic and corrosion behaviour of PVDF-CeO₂ composite coatings [J]. Materials, 2022, 15(23): 8674

[85] PakhiraM, GhoshS, GhoshS, et al. . Development of poly(vinylidene fluoride) graft random copolymer membrane for antifouling and antimicrobial applications [J]. Journal of Industrial and Engineering Chemistry, 2022, 112: 171-181

[86] LiJ-w, HongC-y, ZhangH, et al. . Fabrication of self-cross-linking silicified polyvinylidene chloride emulsions with core-shell structure and its film properties [J]. Polymer Bulletin, 2024, 81(2): 1651-1673

[87] LiuH-l, ChenK-k, ChenX, et al. . Structure and performance of poly(vinylidene chloride-co-vinyl chloride) porous membranes with different additives [J]. Chemical Engineering & Technology, 2019, 42(1): 215-224

[88] LiZ-r, DengH-y, XiaoP-s, et al. . Ultrasonically sprayed poly(vinylidene chloride) coating on polyurea as moisture barrier [J]. Materials Chemistry and Physics, 2022, 292: 126803

[89] LiW-y, YangH-m, XueS, et al. . A simple strategy towards construction of fluorine-free superhydrophobic aluminum alloy surfaces: Self-cleaning, anti-corrosion and anti-frost [J]. Applied Physics A, 2022, 128(7): 626

[90] LiuZ-j, WangH-y, ZhangX-g, et al. . Durable and self-healing superhydrophobic polyvinylidene fluoride (PVDF) composite coating with in situ gas compensation function [J]. Surface and Coatings Technology, 2017, 327: 18-24

[91] ShuY-x, LuX-y, LuW-s, et al. . Mechanically robust superhydrophobic copper surface with self-cleaning, anti-icing, and corrosion resistance [J]. Surface and Coatings Technology, 2023, 455: 129216

[92] ZhangX-f, ChenY-q, HuJ-ming. Robust superhydrophobic SiO₂/polydimethylsiloxane films coated on mild steel for corrosion protection [J]. Corrosion Science, 2020, 166: 108452

[93] XiaR-h, Zhangb, DongK-s, et al. . HD-SiO₂/SiO₂ sol@PDMS superhydrophobic coating with good durability and anti-corrosion for protection of Al sheets [J]. Materials, 2023, 16(9): 3532

[94] ShenY-z, LiK-l, ChenH-f, et al. . Superhydrophobic F-SiO₂@PDMS composite coatings prepared by a two-step spraying method for the interface erosion mechanism and anti-corrosive applications [J]. Chemical Engineering Journal, 2021, 413: 127455

[95] QianZ-q, LiuZ, WangS-d, et al. . A durable PVDF/PFOTES-SiO₂ superhydrophobic coating on AZ31B Mg alloy with enhanced abrasion resistance performance and anti-corrosion properties [J]. Applied Sciences, 2021, 11(23): 11172

[96] VanithakumariS C, ThinaharanC, PhilipJ. Polyvinylidene difluoride-SiO₂-silane based superhydrophobic coatings on carbon steel with enhanced corrosion resistance and self-cleaning property [J]. Journal of Materials Engineering and Performance, 2023, 32(13): 6028-6041

[97] HouY-y, ShangJ, YuS, et al. . Bio-inspired organic-inorganic hybrid superhydrophobic PVDF@SiO₂ particles for corrosion protection [J]. Journal of Materials Science, 2023, 58(19): 8061-8075

[98] YangJ, ZhangY-f, JiaX-h, et al. . A mechanically robust slippery coating for anti-corrosion, Photothermal deicing, and anti-sticking applications [J]. Surface and Coatings Technology, 2022, 438: 128395

[99] YangJ, LiJ-y, JiaX-h, et al. . Fabrication of robust and transparent slippery coating with hot water repellency, antifouling property, and corrosion resistance [J]. ACS Applied Materials & Interfaces, 2020, 12(25): 28645-28654

[100] WancuraM, NkansahA, ChwatkoM, et al. . Interpenetrating network design of bioactive hydrogel coatings with enhanced damage resistance [J]. Journal of Materials Chemistry B, 2023, 11(24): 5416-5428

[101] DueramaeI, NishidaM, Nakaji-HirabayashiT, et al. . Biodegradable shape memory polymers functionalized with anti-biofouling interpenetrating polymer networks [J]. Journal of Materials Chemistry B, 2016, 4(32): 5394-5404

[102] TongZ-m, SongL-n, ChenS-f, et al. . Hagfish-inspired smart SLIPS marine antifouling coating based on supramolecular: Lubrication modes responsively switching and self-healing properties [J]. Advanced Functional Materials, 2022, 32(27): 2201290

[103] LiuJ-h, LiQ, GuiT-j, et al. . Carp-inspired self-regulating marine antifouling coating: Featuring robust controlled release of eugenol and high-efficiency self-healing performance [J]. Chemical Engineering Journal, 2024, 486: 149929

[104] LiuJ-h, TongZ-m, GaoF, et al. . Pearl-inspired intelligent marine hetero nanocomposite coating based on “Brick&Mortar” strategy: Anticorrosion durability and switchable antifouling [J]. Advanced Materials, 2024, 36(26): 2401982

[105] XiangT-f, RenH-w, ZhangY-l, et al. . Rational design of PDMS/paraffin infused surface with enhanced corrosion resistance and interface erosion mechanism [J]. Materials & Design, 2022, 215: 110450

[106] CuiX, YanY-g, HuangJ, et al. . A substrate-independent isocyanate-modified polydimethylsiloxane coating harvesting mechanical durability, self-healing ability and low surface energy with anti-corrosion/biofouling potential [J]. Applied Surface Science, 2022, 579: 152186

[107] ZeimaranE, PourshahrestaniS, KadriN A, et al. . Self-healing polyester urethane supramolecular elastomers reinforced with cellulose nanocrystals for biomedical applications [J]. Macromolecular Bioscience, 2019, 19(10): 1900176

[108] MiH-y, JingX, YalmazG, et al. . In situ synthesis of polyurethane scaffolds with tunable properties by controlled crosslinking of tri-block copolymer and polycaprolactone triol for tissue regeneration [J]. Chemical Engineering Journal, 2018, 348: 786-798

[109] JooJ, KangM, MoonH S, et al. . Design and experimental studies of self-healable anti-corrosion coating: Passivation of metal surfaces by silicone oil impregnated porous oxides [J]. Surface and Coatings Technology, 2020, 404: 126595

[110] TangY, WuF, FangL, et al. . Effect of deposition sequence of MgAl-LDH and SiO₂@PDMS layers on the corrosion resistance of robust superhydrophobic/self-healing multifunctional coatings on magnesium alloy [J]. Progress in Organic Coatings, 2023, 174: 107299

[111] SunJ-w, DuanJ-z, LiuX-j, et al. . Environmentally benign smart self-healing silicone-based coating with dual antifouling and anti-corrosion properties [J]. Applied Materials Today, 2022, 28: 101551

[112] KimY J, HuhP H, KimB K. Synthesis of self-healing polyurethane urea-based supramolecular materials [J]. Journal of Polymer Science Part B: Polymer Physics, 2015, 53(7): 468-474

[113] ZhangG-w, PeiJ-z, LiR, et al. . The preparation and characterization of a novel self-healing based on the dynamic translocation of disulfide bonds [J]. Materials Research Express, 2018, 5(10): 105301

[114] LiY-h, GuoW-j, LiW-j, et al. . Tuning hard phase towards synergistic improvement of toughness and self-healing ability of poly(urethane urea) by dual chain extenders and coordinative bonds [J]. Chemical Engineering Journal, 2020, 393: 124583

[115] DengS W, TongL B, LiX J, et al. . Enhanced anti-corrosion/wear properties of Mg alloy through a hierarchical bio-inspired self-healing composite coating [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, 658: 130770

[116] ZhangK-m, SunJ-w, SongJ-y, et al. . Self-healing Ti₃C₂ MXene/PDMS supramolecular Elastomers based on small biomolecules modification for wearable sensors [J]. ACS Applied Materials & Interfaces, 2020, 12(40): 45306-45314

[117] MartinR, RekondoA, de LuzuriagaA R, et al. . Dynamic sulfur chemistry as a key tool in the design of self-healing polymers [J]. Smart Materials and Structures, 2016, 25(8): 084017

[118] NevejansS, BallardN, FernándezM, et al. . The challenges of obtaining mechanical strength in self-healing polymers containing dynamic covalent bonds [J]. Polymer, 2019, 179: 121670

[119] ShengY-m, WangM-h, ZhangK-p, et al. . An “inner soft external hard”, scratch-resistant, self-healing waterborne poly(urethane-urea) coating based on gradient metal coordination structure [J]. Chemical Engineering Journal, 2021, 426: 131883

[120] Da ViaF, SurianoR, BoumezganeO, et al. . Self-healing behavior in blends of PDMS-based polyurethane ionomers [J]. Polymers for Advanced Technologies, 2022, 33(2): 556-565

[121] KhanA, HuangK, SarwarM G, et al. . Self-healing and self-cleaning clear coating [J]. Journal of Colloid and Interface Science, 2020, 577: 311-318

[122] LeeJ M, ParkJ, KoJ, et al. . Autonomous self-healable scratch-free bilayer anti-corrosion film [J]. Applied Surface Science, 2023, 631: 157484

[123] LiQ, ZhangX-d, BenS, et al. . Bio-inspired superhydrophobic magnesium alloy surfaces with active anti-corrosion and self-healing properties [J]. Nano Research, 2023, 16(2): 3312-3319