Rare earth modified reduced graphene oxide reinforced AgCuTi composite brazing filler for brazing C/C composites

Liang Wu, Yue Li, Jin-wei Chen, Rui Zhang, Qian-kun Zhang, Yi-feng Xiao

Journal of Central South University ›› 2024, Vol. 31 ›› Issue (5) : 1398-1411. DOI: 10.1007/s11771-024-5637-0
Article

Rare earth modified reduced graphene oxide reinforced AgCuTi composite brazing filler for brazing C/C composites

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Abstract

In order to solve the formation of brittle compounds in brazed joints, an innovative rare earth modified reduced graphene oxide reinforced AgCuTi composite brazing filler was designed to achieve brazed joints with Ag-Cu eutectic as the main organization almost free of brittle compounds, and at the same time, the dispersion of graphene in the joint interfaces was improved. Microanalysis and discussion of the brazing fillers with and without Ce modification showed that the Ce modified reduced graphene oxide was more uniformly dispersed in the brazing fillers. The interfacial microstructures of C/C composites-C/C composites joints with and without Ce modified brazing fillers were compared, and the effect of graphene content on the organization and properties of the joints was investigated. The results showed that the shear strength of the joints was significantly enhanced by using Ce modified brazing fillers. When the graphene content was 0.5 wt.%, the average shear strength of the brazed joints obtained by using Ce modified brazing fillers was 31.82 MPa, increased by 50%.

Keywords

rare earth modification / reduced graphene oxide / composite filler / C/C composites / brazing

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Liang Wu, Yue Li, Jin-wei Chen, Rui Zhang, Qian-kun Zhang, Yi-feng Xiao. Rare earth modified reduced graphene oxide reinforced AgCuTi composite brazing filler for brazing C/C composites. Journal of Central South University, 2024, 31(5): 1398‒1411 https://doi.org/10.1007/s11771-024-5637-0

References

[[1]]
Chowdhury P, Sehitoglu H, Rateick R. Damage tolerance of carbon-carbon composites in aerospace application. Carbon, 2018, 126: 382-393, J]
CrossRef Google scholar
[[2]]
Liao J-q, Chen T-f, Huang B-y, et al.. Influence of the pore structure of carbon fibers on the oxidation resistance of C/C composites. Carbon, 2002, 40(4): 617-621, J]
CrossRef Google scholar
[[3]]
Zhang Y-f, Zhou Z-g, Pan S-d, et al.. Comparison on failure behavior of three-dimensional woven carbon/carbon composites joints subjected to out-of-plane loading at room and high temperature. Composites Communications, 2021, 23: 100567, J]
CrossRef Google scholar
[[4]]
Zeng Y, Wang D-n, Xiong X, et al.. Ultra-high-temperature ablation behavior of SiC-ZrC-TiC modified carbon/carbon composites fabricated via reactive melt infiltration. Journal of the European Ceramic Society, 2020, 40(3): 651-659, J]
CrossRef Google scholar
[[5]]
Wang Z-y, Ba J, Qi J-l, et al.. Graphene-coated Cu foam interlayer for brazing C/C composite and Nb. Transactions of the China Welding Institution, 2018, 39(10): 71-74 [J]
[[6]]
Qu C-ming. . Research on high-efficiency resistance brazing technology of C/C composite-T2 copper, 2018 Harbin Harbin Institute of Technology [D]
[[7]]
Guo W, Xue J-l, Zhang H-q, et al.. The role of foam on microstructure and strength of the brazed C/C composites/Ti6Al4V alloy joint. Vacuum, 2020, 179: 109543, J]
CrossRef Google scholar
[[8]]
He Z-jing. . Study on brazing mechanism and joint properties of C/C and SiCf/SiC composites, 2021 Harbin Harbin Institute of Technology [D]
[[9]]
Feng Z-w, Gao T-f, Shao T-w, et al.. Brazing of C/C composite and Ni-based high temperature alloy GH3128. Transactions of the China Welding Institution, 2015, 36(12): 105-108 [J]
[[10]]
Zhang X, Shi X-h, Wang J, et al.. Brazing of C/C composites and GH3044 Ni-based superalloy using Ni71CrSi as the interlayer. Materials China, 2013, 32(11): 665-670 [J]
[[11]]
Li H-l, Wang Z-y, Ahmad Butt H, et al.. Study on the residual stress relieving mechanism of C/C composite-Nb brazed joint by employing a structurally optimized graphene reinforced Cu foam interlayer. Frontiers in Materials, 2021, 8: 761088, J]
CrossRef Google scholar
[[12]]
Li Hang. . Research on the process and mechanism of surface alloying C/SiC and Nb by carbon fiber cloth interlayer-assisted brazing, 2021 Harbin Harbin Institute of Technology [D]
[[13]]
Chang Q, Zhang L-x, Sun Z, et al.. Influence of surface modification by carbon nanotube on C/C composite brazing joints. Journal of Mechanical Engineering, 2020, 56(8): 20, J]
CrossRef Google scholar
[[14]]
Deng L-xia. . Research on interfacial organization and connection mechanism of C/C composite active brazed joints, 2011 Changsha Central South University [D]
[[15]]
Zhao K-h, Liu D, Zhu H-t, et al.. Effect of brazing temperature on the organization and mechanical properties of C/C/AgCuTi+Cf/TC4 joints. Journal of Aeronautics, 2022, 43(4): 471-481 [J]
[[16]]
Wan W-c, Luo W, Wang J, et al.. Research status on relieving the residual stress of Ti(C, N)-based cermets/steels brazing. Journal of Xihua University (Natural Science Edition), 2021, 40(1): 103-108 [J]
[[17]]
Zhang Y, Guo W, Jia Q, et al.. Long-lasting action mechanism of 3D skeleton regulated the residual stress fluctuations in SiCf/SiC heterogeneous joints. Materials Characterization, 2023, 200: 112922, J]
CrossRef Google scholar
[[18]]
Zhou Y-h, Liu D, Niu H-w, et al.. Vacuum brazing of C/C composite to TC4 alloy using nano-Al2O3 strengthened AgCuTi composite filler. Materials & Design, 2016, 93: 347-356, J]
CrossRef Google scholar
[[19]]
Song X-r, Li H-j, Casalegno V, et al.. Microstructure and mechanical properties of C/C composite/Ti6Al4V joints with a Cu/TiCuZrNi composite brazing alloy. Ceramics International, 2016, 42(5): 6347-6354, J]
CrossRef Google scholar
[[20]]
Fan Z, Zhang K, Liu J-y, et al.. Microstructure and mechanical properties of Ti6Al4V alloy and sapphire joint brazed with graphene-AgCuTi. Materials Research Express, 2020, 6(12): 1265k4, J]
CrossRef Google scholar
[[21]]
Liu D, Song Y-y, Zhou Y-h, et al.. Brazing of C/C composite and Ti-6Al-4V with graphene strengthened AgCuTi filler: Effects of graphene on wettability, microstructure and mechanical properties. Chinese Journal of Aeronautics, 2018, 31(7): 1602-1608, J]
CrossRef Google scholar
[[22]]
Guo W, Zhang H-q, Yuan W-q, et al.. The microstructure and mechanical properties of C/C composite/Ti3Al alloy brazed joint with graphene nanoplatelet strengthened Ag-Cu-Ti filler. Ceramics International, 2019, 45(7): 8783-8789, J]
CrossRef Google scholar
[[23]]
Li Y, Zhao Y-r, Li Huan. Preparation and characterization of rare earth-modified graphene oxide. Functional Materials, 2017, 48(10): 10204-10209 [J]
[[24]]
Wang Y, Li Y, Zhu J, et al.. Mechanism of rare earth modification on graphene oxide surface. Materials Engineering, 2018, 46(5): 29-35, J]
CrossRef Google scholar
[[25]]
Zhao Y-r, Li Y, Li Huan. Research progresses of graphene reinforced metal matrix composites. Surface Technology, 2016, 45(5): 33-40 [J]
[[26]]
Zhao Y-ru. . Preparation and organizational properties of rare earth modified graphene oxide reinforced copper matrix composites, 2018 Nanchang Jiangxi University of Science and Technology [D]
[[27]]
Chen Z-lin. . Preparation and lubrication performance study of two modified reduced graphene oxide, 2020 Chengdu Southwest Jiaotong University [D]
[[28]]
Ma T-j, Kang H, Wu Y-q, et al.. Effects of rare earths on Properties of Ti-Zr-Cu-Ni base brazing filler alloys. Proceedings of 2004 International Conference on Rare Earth Research and Application (III), 2004 Beijing The Metallurgical Industry Press 4 [C]
[[29]]
Wu Q-p, Luo Z, Wang Y, et al.. Effect of cerium on wettability of mechanically milled Cu-based brazing alloy powder. Journal of Rare Earths, 2018, 36(11): 1226-1233, J]
CrossRef Google scholar
[[30]]
Song Y-y, Liu D, Hu S-p, et al.. Graphene nanoplatelets reinforced AgCuTi composite filler for brazing SiC ceramic. Journal of the European Ceramic Society, 2019, 39(4): 696-704, J]
CrossRef Google scholar
[[31]]
Shi Y-w, Yu Y, Li Y-p, et al.. Study on the microstructure and wettability of an Al-Cu-Si braze containing small amounts of rare earth erbium. Journal of Materials Engineering and Performance, 2009, 18(3): 278-281, J]
CrossRef Google scholar

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