Mechanical and thermal properties of steel slag/stone-wood plastic composites reinforced with calcium sulfate whisker

Hao Zhang , Qian Wang , Ling Zhao , Liangjun Chen , Xiaojian Ren , Zhifang Zong , Xiaoyan Du

International Journal of Minerals, Metallurgy, and Materials ›› 2026, Vol. 33 ›› Issue (4) : 1176 -1186.

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International Journal of Minerals, Metallurgy, and Materials ›› 2026, Vol. 33 ›› Issue (4) :1176 -1186. DOI: 10.1007/s12613-025-3199-2
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Mechanical and thermal properties of steel slag/stone-wood plastic composites reinforced with calcium sulfate whisker
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Abstract

The development of steel slag/stone-wood plastic composites reinforced with calcium sulfate whisker is beneficial for reducing costs in the stone-wood plastic industry and promoting the resource utilization of industrial waste. Steel slag powder (SSP) composited with calcium sulfate whisker (CSW) was investigated as a replacement for a portion of talc powder (TP) in the creation of calcium sulfate whisker-reinforced steel slag/stone-wood plastic composites (CSW-SSP/SPCs). The reinforcement effect and thermal stability mechanism of CSW within these composites were examined by assessing their mechanical properties, mineral composition, structural composition, thermal stability, crystallinity, and microstructure. The results showed that the tensile strength, flexural strength, and impact strength of CSW-SSP/SPCs were increased by 28.13%, 25.02%, and 45.55%, respectively, which were significantly better than those of the pure TP sample. The SSP composited with CSW effectively replaced part of the TP, where CSW significantly reinforced the composites through its bridging, micro-filling, and synergistic effects with the SSP. Meanwhile, the MgO, Al2O3, and Fe2O3 in the SSP crosslinked with the carbon layer skeleton and residual materials to form a more stable carbon layer, which inhibited the combustion reaction and further enhanced the thermal stability and retarded the thermal degradation process.

Keywords

steel slag / calcium sulfate whisker / stone-wood plastic composites / mechanical properties / thermal stability

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Hao Zhang, Qian Wang, Ling Zhao, Liangjun Chen, Xiaojian Ren, Zhifang Zong, Xiaoyan Du. Mechanical and thermal properties of steel slag/stone-wood plastic composites reinforced with calcium sulfate whisker. International Journal of Minerals, Metallurgy, and Materials, 2026, 33(4): 1176-1186 DOI:10.1007/s12613-025-3199-2

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References

[1]

C.L. Fan, R.F. Wei, T. Cheng, R. Sun, H. Zhang, and H.M. Long, The positive contributions of steel slag in reducing carbon dioxide emissions in the steel industry: Waste heat recovery, carbon sequestration, and resource utilization, Chem. Eng. J., 498(2024), art. No. 155379.

[2]

W.H. Gao, W.T. Zhou, X.J. Lyu, X. Liu, H.L. Su, C.M. Li, and H. Wang, Comprehensive utilization of steel slag: A review, Powder Technol., 422(2023), art. No. 118449.

[3]

Yan ZH, Zhao Q, Han CZ, Mei XH, Liu CJ, Jiang MF. Effects of iron oxide on crystallization behavior and spatial distribution of spinel in stainless steel slag. Int. J. Miner. Metall. Mater., 2024, 31(2): 292

[4]

C. Yang, Z.W. Huang, S.P. Wu, et al., Recycling steel slag as aggregate in developing an ultra-thin friction course with high comprehensive road performance, Constr. Build. Mater., 449(2024), art. No. 138539.

[5]

Wu QS, Huang ZC. Preparation and performance of lightweight porous ceramics using metallurgical steel slag. Ceram. Int., 2021, 47(18): 25169

[6]

Wang D, Lu JS, Xie B, Liu ZY, Guo K. Whitening and purification of calcined talc powders from black talc by the milling and reactive calcination with magnesium precursors. J. Therm. Anal. Calorim., 2023, 148(21): 11619

[7]

L. Jing, Y.X. Wang, J. Li, et al., Innovative plasticization technique for talc-powder reinforced wheat-starch biomass composite plastics with enhanced mechanical strength, Int. J. Biol. Macromol., 269(2024), art. No. 131894.

[8]

L. Zhao, C. Su, Q. Wang, et al., Fabrication modified pressurized-hot steel slag using stearic acid coupling agent to enhance the mechanical properties of wood-plastic composites, Constr. Build. Mater., 458(2025), art. No. 139571.

[9]

Zhao L, Zhao K, Shen ZW, et al. . Novel wood–plastic composite fabricated via modified steel slag: Preparation, mechanical and flammability properties. Int. J. Miner. Metall. Mater., 2024, 31(9): 2110

[10]

Kengkhetkit N, Amornsakchai T. A new approach to “Greening” plastic composites using pineapple leaf waste for performance and cost effectiveness. Mater. Des., 2014, 55: 292

[11]

I.O. Oladele, S.O. Aliu, A.S. Taiwo, and N.I. Agbeboh, Comparative investigation of the influence of stone-dust particles and bagasse fiber on the mechanical and physical properties of reinforced recycled high-density polyethylene bio-composites, Compos. Adv. Mater., 31(2022), art. No. 26349833221077701.

[12]

Y.H. Qi, J.X. Wu, S.C. Qin, et al., Characterization and mechanism of natural rubber composites reinforced by modified calcium sulfate whisker, J. Appl. Polym. Sci., 140(2023), No. 27, art. No. e53911.

[13]

Lu YH, Jiang N, Li XW, Xu SA. Effect of inorganic–organic surface modification of calcium sulfate whiskers on mechanical and thermal properties of calcium sulfate whisker/poly(vinyl chloride) composites. RSC Adv., 2017, 7(73): 46486

[14]

Aakriti, A. Bhardwaj, S. Maiti, N. Jain, A. Pathak, and R.R. Gupta, Calcium sulphate whiskers (CSW) an innovative material for civil engineering applications: A critical review of its preparation, characterization, current trends, and prospects, Constr. Build. Mater., 420(2024), art. No. 135624.

[15]

K. Cao, G. Liu, H. Li, and Z. Huang, Mechanical properties and microstructure of calcium sulfate whisker-reinforced cement-based composites, Materials, 15(2022), No. 3, art. No. 947.

[16]

F.T. Ma, C. Chen, and Y.B. Wang, Mechanical behavior of calcium sulfate whisker-reinforced paraffin/gypsum composites, Constr. Build. Mater., 305(2021), art. No. 124795.

[17]

Zheng WC, Zhao L, Xu WC, et al. . Utilization of shield powder as a novel reinforcing and compatibilizing filler in styrene–butadiene rubber (SBR) composites. J. Mater. Cycles Waste Manage., 2023, 25(4): 2113

[18]

Li BP, Long HM, Liu ZM, Zhang YH, Zhang H. Preparation of high strength–wear resistant styrene butadiene rubber composite materials with steel slag ultrafine powder replacing partial carbon black and study on their properties. Mod. Chem. Ind., 2021, 41(1): 149

[19]

Wei RF, Zhu YL, Zhou D, Wang YF, Long HM. Impurity removal and hydrothermal heterogeneous cryogenic rapid oxidation of semi-dry desulfurization ash from iron ore sintering flue gas. Chin. J. Process. Eng., 2021, 21(8): 95

[20]

D. Friedrich, Consumer behaviour towards wood-polymer packaging in convenience and shopping goods: A comparative analysis to conventional materials, Resour. Conserv. Recycl., 163(2020), art. No. 105097.

[21]

Y. Guo, S.L. Zhu, Y.X. Chen, and D.G. Li, Thermal properties of wood-plastic composites with different compositions, Materials, 12(2019), No. 6, art. No. 881.

[22]

D.M. Wang, C. Chen, Y.B. Wang, S.W. Jiu, and Y.X. Chen, Influence of modified calcium sulfate hemihydrate whisker on the physical, mechanical, and microscopic properties of gypsum matrix composites, Constr. Build. Mater., 394(2023), art. No. 132280.

[23]

Y. Hailu, V.A. Maidannyk, E.G. Murphy, and N.A. McCarthy, Improving the physical and wettability properties of skim milk powders through agglomeration and lecithination, J. Food Eng., 357(2023), art. No. 111597.

[24]

P.Y. Ma, H.Y. Chen, Q.J. Zhang, J. Wang, and L. Xiang, Preparation of hierarchical CaSO4 whisker and its reinforcing effect on PVC composites, J. Nanomater., 2018(2018), No. 1, art. No. 7803854.

[25]

Q.B. Li, H. Liu, C.C. Nie, et al., PMMA-grafted calcium sulfate whiskers for applications as fillers in PVC, Polymers, 14(2022), No. 19, art. No. 4199.

[26]

Zhang QJ, Ma PY, Yang YR, Pan XF, Zhang JF, Xiang L. Reinforcement of recycled paint slag hybrid-filled lightweight calcium sulphate whisker/PVC foam composites. J. Environ. Chem. Eng., 2018, 6(1): 520

[27]

Zhao L, Ma WK, Zhang H, Long HM. Use of melt blending to synthesize wood plastic composites containing modified steel slag: A study. Mater. Manuf. Process., 2024, 39(8): 1052

[28]

Q. Liu, Z.T. Chen, and Y.Z. Yang, Model of the charged mosaic surface of the cement particle based on the adsorption behavior of surfactants using ATR-FTIR spectroscopy, Composites Part B: Eng., 215(2021), art. No. 108802.

[29]

Mamilla JLK, Novak U, Grilc M, Likozar B. Natural deep eutectic solvents (DES) for fractionation of waste lignocellulosic biomass and its cascade conversion to value-added bio-based chemicals. Biomass Bioenergy, 2019, 120: 417

[30]

Xie BS, Ma H, Li CC, Chen J. Enhanced properties of stone coal-based composite phase change materials for thermal energy storage. Int. J. Miner. Metall. Mater., 2024, 31(1): 206-215

[31]

Saona LER, Allendorf ME. Use of FTIR for rapid authentication and detection of adulteration of food. Annu. Rev. Food Sci. Technol., 2011, 2: 467

[32]

Zhang L, Ren GL, Su P, Zhang JH, Fang YQ. Study on DOPO derivatives/octaaminopropyl POSS flame-retardant wood-plastic composites. J. Southwest For. Univ. Nat. Sci., 2023, 43(3): 136

[33]

R.Z. Huang, X. Zhang, Z.L. Chen, M.L. Wan, and Q.L. Wu, Thermal stability and flame resistance of the coextruded wood-plastic composites containing talc-filled plastic shells, Int. J. Polym. Sci., 2020(2020), art. No. 1435249.

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