High-strength and thermally stable TiB2-modified Al–Mn–Mg–Er–Zr alloy fabricated via selective laser melting

Jiang Yu, Yaoxiang Geng, Yongkang Chen, Xiao Wang, Zhijie Zhang, Hao Tang, Junhua Xu, Hongbo Ju, Dongpeng Wang

International Journal of Minerals, Metallurgy, and Materials ›› 2024, Vol. 31 ›› Issue (10) : 2221-2232. DOI: 10.1007/s12613-024-2879-7
Research Article

High-strength and thermally stable TiB2-modified Al–Mn–Mg–Er–Zr alloy fabricated via selective laser melting

Author information +
History +

Abstract

To increase the processability and plasticity of the selective laser melting (SLM) fabricated Al–Mn–Mg–Er–Zr alloys, a novel TiB2-modified Al–Mn–Mg–Er–Zr alloy with a mixture of Al–Mn–Mg–Er–Zr and nano-TiB2 powders was fabricated by SLM. The processability, microstructure, and mechanical properties of the alloy were systematically investigated by density measurement, microstructure characterization, and mechanical properties testing. The alloys fabricated at 250 W displayed higher relative densities due to a uniformly smooth top surface and appropriate laser energy input. The maximum relative density value of the alloy reached (99.7 ± 0.1)%, demonstrating good processability. The alloy exhibited a duplex grain microstructure consisting of columnar regions primarily and equiaxed regions with TiB2, Al6Mn, and Al3Er phases distributed along the grain boundaries. After directly aging treatment at a high temperature of 400°C, the strength of the SLM-fabricated TiB2/Al–Mn–Mg–Er–Zr alloy increased due to the precipitation of the secondary Al6Mn phases. The maximum yield strength and ultimate tensile strength of the aging alloy were measured to be (374 ± 1) and (512 ± 13) MPa, respectively. The SLM-fabricated TiB2/Al–Mn–Mg–Er–Zr alloy demonstrates exceptional strength and thermal stability due to the synergistic effects of the inhibition of grain growth, the incorporation of TiB2 nanoparticles, and the precipitation of secondary Al6Mn nanoparticles.

Keywords

selective laser melting / aluminum alloy / processability / mechanical properties / thermal stability

Cite this article

Download citation ▾
Jiang Yu, Yaoxiang Geng, Yongkang Chen, Xiao Wang, Zhijie Zhang, Hao Tang, Junhua Xu, Hongbo Ju, Dongpeng Wang. High-strength and thermally stable TiB2-modified Al–Mn–Mg–Er–Zr alloy fabricated via selective laser melting. International Journal of Minerals, Metallurgy, and Materials, 2024, 31(10): 2221‒2232 https://doi.org/10.1007/s12613-024-2879-7

References

[[1]]
N.T. Aboulkhair, M. Simonelli, L. Parry, I. Ashcroft, C. Tuck, and R. Hague, 3D printing of aluminium alloys: Additive manufacturing of aluminium alloys using selective laser melting, Prog. Mater. Sci., 106(2019), art. No. 100578.
[[2]]
Geng YX, Tang H, Xu JH, et al.. Influence of process parameters and aging treatment on the microstructure and mechanical properties of AlSi8Mg3 alloy fabricated by selective laser melting. Int. J. Miner. Metall. Mater., 2022, 29(9): 1770,
CrossRef Google scholar
[[3]]
Y.X. Geng, Q. Wang, Y.M. Wang, et al., Microstructural evolution and strengthening mechanism of high-strength AlSi8.1Mg1.4 alloy produced by selective laser melting, Mater. Des., 218(2022), art. No. 110674.
[[4]]
L.Y. Chen, S.X. Liang, Y.J. Liu, and L.C. Zhang, Additive manufacturing of metallic lattice structures: Unconstrained design, accurate fabrication, fascinated performances, and challenges, Mater. Sci. Eng. R, 146(2021), art. No. 100648.
[[5]]
L. Zhao, L.B. Song, J.G. Santos Macias, et al., Review on the correlation between microstructure and mechanical performance for laser powder bed fusion AlSi10Mg, Addit. Manuf., 56(2022), art. No. 102914.
[[6]]
Schmidtke K, Palm F, Hawkins A, Emmelmann C. Process and mechanical properties: Applicability of a scandium modified Al-alloy for laser additive manufacturing. Phys. Procedia, 2011, 12: 369,
CrossRef Google scholar
[[7]]
Jia QB, Rometsch P, Kürnsteiner P, et al.. Selective laser melting of a high strength AlMnSc alloy: Alloy design and strengthening mechanisms. Acta Mater., 2019, 171: 108,
CrossRef Google scholar
[[8]]
Li RD, Wang MB, Li ZM, Cao P, Yuan TC, Zhu HB. Developing a high-strength Al–Mg–Si–Sc–Zr alloy for selective laser melting: Crack-inhibiting and multiple strengthening mechanisms. Acta Mater., 2020, 193: 83,
CrossRef Google scholar
[[9]]
Geng YX, Tang H, Xu JH, Zhang ZJ, Xiao YK, Wu Y. Strengthening mechanisms of high-performance Al–Mn–Mg–Sc–Zr alloy fabricated by selective laser melting. Sci. China Mater., 2021, 64(12): 3131,
CrossRef Google scholar
[[10]]
Tang H, Geng YX, Bian SN, Xu JH, Zhang ZJ. An ultra-high strength over 700 MPa in Al–Mn–Mg–Sc–Zr alloy fabricated by selective laser melting. Acta Metall. Sin. Engl. Lett., 2022, 35(3): 466,
CrossRef Google scholar
[[11]]
Tang H, Geng YX, Luo JJ, Xu JH, Ju HB, Yu LH. Mechanical properties of high Mg-content Al–Mg–Sc–Zr alloy fabricated by selective laser melting. Met. Mater. Int., 2021, 27(8): 2592,
CrossRef Google scholar
[[12]]
Croteau JR, Griffiths S, Rossell MD, et al.. Microstructure and mechanical properties of Al–Mg–Zr alloys processed by selective laser melting. Acta Mater., 2018, 153: 35,
CrossRef Google scholar
[[13]]
Zhou L, Hyer H, Park S, et al.. Microstructure and mechanical properties of Zr-modified aluminum alloy 5083 manufactured by laser powder bed fusion. Addit. Manuf., 2019, 28: 485
[[14]]
Y.X. Geng, C.G. Jia, J.H. Xu, et al., Selective laser melting of a novel high-strength Er- and Zr-modified Al–Mn–Mg alloy, Mater. Lett., 313(2022), art. No. 131762.
[[15]]
Yu J, Geng YX, Zhang ZJ, Ju HB. Densification, microstructural, and mechanical properties of Al–Mn–Mg–Er–Zr alloy fabricated by laser powder bed fusion. Met. Mater. Int., 2023, 29(11): 3235,
CrossRef Google scholar
[[16]]
J. Yu, Y.X. Geng, H.B. Ju, Z.J. Zhang, and J.H. Xu, Selective laser melted Al–Mn–Mg–Er–Zr–Si alloy: Crack elimination and strength enhancement by alloying with Si, Trans. Nonferrous Met. Soc. China, 2023. https://kns.cnki.net/kcms2/detail/43.1239.TG.20230727.1754.038.html.
[[17]]
S.Y. Zhou, Y. Su, H. Wang, J. Enz, T. Ebel, and M. Yan, Selective laser melting additive manufacturing of 7xxx series Al–Zn–Mg–Cu alloy: Cracking elimination by co-incorporation of Si and TiB2, Addit. Manuf., 36(2020), art. No. 101458.
[[18]]
Sun TT, Wang HZ, Gao ZY, et al.. The role of in-situ nano-TiB2 particles in improving the printability of noncastable 2024Al alloy. Mater. Res. Lett., 2022, 10(10): 656,
CrossRef Google scholar
[[19]]
Q.Z. Wang, X. Lin, N. Kang, et al., Effect of laser additive manufacturing on the microstructure and mechanical properties of TiB2 reinforced Al-Cu matrix composite, Mater. Sci. Eng. A, 840(2022), art. No. 142950.
[[20]]
Zhang H, Wang Y, Wang JJ, et al.. Achieving superior mechanical properties of selective laser melted AlSi10Mg via direct aging treatment. J. Mater. Sci. Technol., 2022, 108: 226,
CrossRef Google scholar
[[21]]
Weingarten C, Buchbinder D, Pirch N, Meiners W, Wissenbach K, Poprawe R. Formation and reduction of hydrogen porosity during selective laser melting of AlSi10Mg. J. Mater. Process. Technol., 2015, 221: 112,
CrossRef Google scholar
[[22]]
Geng YX, Tang H, Xu JH, et al.. Formability and mechanical properties of high-strength Al–(Mn, Mg)–(Sc, Zr) alloy produced by selective laser melting. Acta Metall. Sin., 2021, 58(8): 1044
[[23]]
Y.Q. Xue, Z.Y. Lou, Q.T. Hao, et al., Insight into the precipitation behavior and mechanical properties of Sc-Zr micro-alloying TiB2/Al-4.5Cu composites, J. Alloys Compd., 929(2022), art. No. 167209.
[[24]]
M.L. Qu, Q.L. Guo, L.I. Escano, A. Nabaa, Z.A. Young, and L.Y. Chen, Controlling process instability for defect lean metal additive manufacturing, Nat. Commun., 13(2022), No. 1, art. No. 1079.
[[25]]
L. Du, L.D. Ke, M.L. Xiao, et al., Densification, microstructure and properties of Sc and Zr modified Al-Mn alloy prepared by selective laser melting, Opt. Laser Technol., 148(2022), art. No. 107703.
[[26]]
Aboulkhair NT, Everitt NM, Ashcroft I, Tuck C. Reducing porosity in AlSi10Mg parts processed by selective laser melting. Addit. Manuf., 2014, 1: 77
[[27]]
Wang LZ, Wang S, Wu JJ. Experimental investigation on densification behavior and surface roughness of AlSi10Mg powders produced by selective laser melting. Opt. Laser Technol., 2017, 96: 88,
CrossRef Google scholar
[[28]]
Y.K. Xiao, Q. Yang, Z.Y. Bian, et al., Microstructure, heat treatment and mechanical properties of TiB2/Al–7Si–Cu–Mg alloy fabricated by selective laser melting, Mater. Sci. Eng. A, 809(2021), art. No. 140951.
[[29]]
Z. Feng, H. Tan, Y.B. Fang, X. Lin, and W.D. Huang, Selective laser melting of TiB2/AlSi10Mg composite: Processability, microstructure and fracture behavior, J. Mater. Process. Technol., 299(2022), art. No. 117386.
[[30]]
Yang HY, Cai ZJ, Zhang Q, et al.. Comparison of the effects of Mg and Zn on the interface mismatch and compression properties of 50vol% TiB2/Al composites. Ceram. Int., 2021, 47(15): 22121,
CrossRef Google scholar
[[31]]
Fan Z, Wang Y, Zhang Y, et al.. Grain refining mechanism in the Al/Al-Ti-B system. Acta Mater., 2015, 84: 292,
CrossRef Google scholar
[[32]]
J.H. Li, F.S. Hage, Q.M. Ramasse, and P. Schumacher, The nucleation sequence of α-Al on TiB2 particles in Al–Cu alloys, Acta Mater., 206(2021), art. No. 116652.
[[33]]
P. Mair, L. Kaserer, J. Braun, N. Weinberger, I. Letofsky-Papst, and G. Leichtfried, Microstructure and mechanical properties of a TiB2-modified Al–Cu alloy processed by laser powder-bed fusion, Mater. Sci. Eng. A, 799(2021), art. No. 140209.
[[34]]
Vlach M, Stulikova I, Smola B, et al.. Precipitation in cold-rolled Al–Sc–Zr and Al–Mn–Sc–Zr alloys prepared by powder metallurgy. Mater. Charact., 2013, 86: 59,
CrossRef Google scholar
[[35]]
Q. Wang, Z. Li, S.J. Pang, X.N. Li, C. Dong, and P.K. Liaw, Coherent precipitation and strengthening in compositionally complex alloys: A review, Entropy, 20(2018), No. 11, art. No. 878.
[[36]]
B. Tang, Y.J. Hu, J. Lu, et al., Energy transfer and wavelength tunable lasing of single perovskite alloy nanowire, Nano Energy, 71(2020), art. No. 104641.
[[37]]
Lee IS, Hsu CJ, Chen CF, Ho NJ, Kao PW. Particle-reinforced aluminum matrix composites produced from powder mixtures via friction stir processing. Compos. Sci. Technol., 2011, 71(5): 693,
CrossRef Google scholar
[[38]]
Hu J, Shi YN, Sauvage X, Sha G, Lu K. Grain boundary stability governs hardening and softening in extremely fine nanograined metals. Science, 2017, 355(6331): 1292,
CrossRef Pubmed Google scholar
[[39]]
S.M. Ma, Y. Li, W.B. Kan, et al., Enhancement of grain refinement and heat resistance in TiB2-reinforced Al–Cu–Mg–Fe–Ni matrix composite additive manufactured by electron beam melting, J. Alloys Compd., 924(2022), art. No. 166395.

Accesses

Citations

Detail

Sections
Recommended

/