Construction of enhanced multi-polarization and high performance electromagnetic wave absorption by self-growing ZnFe₂O₄ on Cu₉S₅

Abstract

The development of 3D structural composites with electromagnetic (EM) wave absorption could attenuate EM waves. Herein, magnetized flower-like Cu₉S₅/ZnFe₂O₄ composites were fabricated through a multistep hydrothermal method. The crystallographic and surface phase chemical information, morphological structure, and magnetic and EM parameters of the composites were analyzed. The prepared Cu₉S₅/ZnFe₂O₄ composites have multiple loss paths for EM waves and present an overall 3D flower-like structure. The Cu₉S₅/ZnFe₂O₄ composites exhibit a minimum reflection loss of −54.38 dB and a broad effective absorption bandwidth of 5.92 GHz. Through magnetization, ZnFe₂O₄ particles are self-assembled and grown on the surfaces of Cu₉S₅. Such a modification is conducive to the generation of additional cross-linking contact sites and the effective introduction of a large number of phase interfaces, crystalline defects, special three-dimensional flower-like structures, and magneto–electrical coupling loss effects. Moreover, the synergistic effect of multiple loss strategies effectively improves EM wave absorption by the material. This work can provide a strategy for the use of magnetization-modified sulfide composite functional materials in EM wave absorption.

Keywords

self-assembled material / electromagnetic wave absorption / enhanced multi-polarization effect / Cu₉S₅/ZnFe₂O₄ composites / radar cross-section

References

[[1]] Yang X, Duan YP, Li SQ, et al.. Constructing three-dimensional reticulated carbonyl iron/carbon foam composites to achieve temperature-stable broadband microwave absorption performance. Carbon, 2022, 188: 376,

[[2]] Wang L, Huang MQ, Yu XF, et al.. Engineering polarization surface of hierarchical ZnO microspheres via spray-annealing strategy for wide-frequency electromagnetic wave absorption. J. Mater. Sci. Technol., 2022, 131: 231,

[[3]] J. Cheng, C. Li, Y. Xiong, et al., Recent advances in design strategies and multifunctionality of flexible electromagnetic interference shielding materials, Nano-Micro Lett., 14(2022), No. 1, art. No. 80.

[[4]] Sun HD, Zhang Y, Wu Y, et al.. Broadband absorption of macro pyramid structure based flame retardant absorbers. J. Mater. Sci. Technol., 2022, 128: 228,

[[5]] Liu JY, Duan YP, Zhang T, Huang LX, Pang HF. Dual-polarized and real-time reconfigurable metasurface absorber with infrared-coded remote-control system. Nano Res., 2022, 15(8): 7498,

[[6]] L. Wang, M.Q. Huang, X. Qian, et al., Confined magnetic-dielectric balance boosted electromagnetic wave absorption, Small, 17(2021), No. 30, art. No. e2100970.

[[7]] Zhang M, Cao MS, Wang QQ, et al.. A multifunctional stealthy material for wireless sensing and active camouflage driven by configurable polarization. J. Mater. Sci. Technol., 2023, 132: 42,

[[8]] Y. Zheng, C.Y. Li, L.H. Qi, et al., Reduced graphene oxide-supported boron and nitrogen co-doped carbon nanotubes with embedded cobalt nanoparticles for absorption of electromagnetic wave, J. Alloys Compd., 865(2021), art. No. 158967.

[[9]] Darboe AK, Qi X, Gong X, et al.. Constructing MoSe₂/MoS₂ and MoS₂/MoSe₂ inner and outer-interchangeable flower-like heterojunctions: A combined strategy of interface polarization and morphology configuration to optimize microwave absorption performance. J. Colloid Interface Sci., 2022, 624: 204,

[[10]] Shi B, Liang HS, Xie ZJ, Chang Q, Wu HJ. Dielectric loss enhancement induced by the microstructure of CoFe₂O₄ foam to realize broadband electromagnetic wave absorption. Int. J. Miner. Metall. Mater., 2023, 30(7): 1388,

[[11]] Wang L, Qian YT, Du JM, et al.. Facile synthesis of cactus-shaped CdS–Cu₉S₅ heterostructure on copper foam with enhanced photoelectrochemical performance. Appl. Surf. Sci., 2019, 492: 849,

[[12]] L. Chen, Y.B. Li, B. Zhao, et al., Multiprincipal element M₂FeC (M = Ti, V, Nb, Ta, Zr) MAX phases with synergistic effect of dielectric and magnetic loss, Adv. Sci., 10(2023), No. 10, art. No. 2206877.

[[13]] Y.P. Duan, H.F. Pang, and H. Zhang, Structure and composition design on ternary CNT@ZnFe₂O₄@ZnO composite utilized as enhanced microwave absorbing materials, Diam. Relat. Mater., 120(2021), art. No. 108701.

[[14]] Wu GL, Wu HJ, Jia ZR. Editorial for special issue on electromagnetic wave absorbing materials. Int. J. Miner. Metall. Mater., 2023, 30(3): 401,

[[15]] Tao F, Green M, Tran ATV, Zhang Y, Yin Y, Chen X. Plasmonic Cu₉S₅ nanonets for microwave absorption. ACS Appl. Nano Mater., 2019, 2(6): 3836,

[[16]] Liao J, Ye MQ, Han AJ, Guo JM, Liu QZ, Yu GQ. Boosted electromagnetic wave absorption performance from multiple loss mechanisms in flower-like Cu₉S₅/RGO composites. Carbon, 2021, 177: 115,

[[17]] J.T. Zhou, B. Wei, M.Q. Wang, et al., Three dimensional flower like ZnFe₂O₄ ferrite loaded graphene: Enhancing microwave absorption performance by constructing microcircuits, J. Alloys Compd., 889(2021), art. No. 161734.

[[18]] Li GM, Xue XJ, Mao LT, et al.. Recycling and utilization of coal gasification residues for fabricating Fe/C composites as novel microwave absorbents. Int. J. Miner. Metall. Mater., 2023, 30(3): 591,

[[19]] C.Y. Xu, P.B. Liu, Z.C. Wu, et al., Customizing heterointerfaces in multilevel hollow architecture constructed by magnetic spindle arrays using the polymerizing-etching strategy for boosting microwave absorption, Adv. Sci., 9(2022), No. 17, art. No. 2200804.

[[20]] R. Cai, W. Zheng, P.A. Yang, et al., Microstructure, electromagnetic properties, and microwave absorption mechanism of SiO_2–MnO–Al₂O₃ based manganese ore powder for electromagnetic protection, Molecules, 27(2022), No. 12, art. No. 3758.

[[21]] J.R. Di, Y.P. Duan, H.F. Pang, X.R. Ma, and J. Liu, Sintering-regulated two-dimensional plate@shell basalt@NiO heterostructure for enhanced microwave absorption, Appl. Surf. Sci., 574(2022), art. No. 151590.

[[22]] M.Q. Huang, L. Wang, W.B. You, and R.C. Che, Single zinc atoms anchored on MOF-derived N-doped carbon shell cooperated with magnetic core as an ultrawideband microwave absorber, Small, 17(2021), No. 30, art. No. e2101416.

[[23]] Z. Zhang, J.Y. Sun, S.D. Mo, et al., Constructing a highly efficient CuS/Cu₉S₅ heterojunction with boosted interfacial charge transfer for near-infrared photocatalytic disinfection, Chem. Eng. J., 431(2022), art. No. 134287.

[[24]] D.M. Xu, Y.F. Yang, K. Le, et al., Bifunctional Cu₉S₅/C octahedral composites for electromagnetic wave absorption and supercapacitor applications, Chem. Eng. J., 417(2021), art. No. 129350.

[[25]] Liao J, Ye MQ, Han AJ, Guo JM, Chen CL. Nanosheet architecture of Cu₉S₅ loaded with Fe₃O₄ microspheres for efficient electromagnetic wave absorption. Ceram. Int., 2021, 47(7): 8803,

[[26]] Wu GL, Zhang HX, Luo XX, Yang LJ, Lv HL. Investigation and optimization of Fe/ZnFe₂O₄ as a wide-band electromagnetic absorber. J. Colloid Interface Sci., 2019, 536: 548,

[[27]] Shu RW, Xu J, Wan ZL, Cao X. Synthesis of hierarchical porous nitrogen-doped reduced graphene oxide/zinc ferrite composite foams as ultrathin and broadband microwave absorbers. J. Colloid Interface Sci., 2022, 608: 2994,

[[28]] L.H. Bai, H.L. Xing, and X.L. Ji, Zinc aluminate nanoparticles modified with (D-xylose, adenine)-derived nitrogen-doped carbon nanosheet composites as high-efficiency microwave absorbents, Diam. Relat. Mater., 127(2022), art. No. 109150.

[[29]] Jia ZR, Kong MY, Yu BW, Ma YZ, Pan JY, Wu GL. Tunable Co/ZnO/C@MWCNTs based on carbon nanotube-coated MOF with excellent microwave absorption properties. J. Mater. Sci. Technol., 2022, 127: 153,

[[30]] H.X. Jia, H.L. Xing, X.L. Ji, and S.T. Gao, Self-template and in situ polymerization strategy to lightweight hollow MnO₂@polyaniline core–shell heterojunction with excellent microwave absorption properties, Appl. Surf. Sci., 537(2021), art. No. 147857.

[[31]] Liu H, Xing HL, Shi R, Ji XL. Facial synthesis of Al@MnO₂ with enhanced microwave absorption and low infrared emissivity. J. Mater. Sci.: Mater. Electron., 2020, 31: 18791

[[32]] Hao HM, Wang LM, Xu LH, Pan H, Cao LQ, Chen KQ. Synthesis of hollow core–shell ZnFe₂O₄@C nanospheres with excellent microwave absorption properties. RSC Adv, 2022, 12(17): 10573, pmcid: 8987361

[[33]] Bai LH, Xing HL, Ji XL, Yang P. D-xylose-derived carbon microspheres modified by CuFe₂O₄ nanoparticles with excellent microwave absorption properties. J. Mater. Sci. Mater. Electron., 2021, 32(22): 26726,

[[34]] Deng LL, Zhang JB, Shu RW. Fabrication of three-dimensional nitrogen-doped reduced graphene oxide/tin oxide composite aerogels as high-performance electromagnetic wave absorbers. J. Colloid Interface Sci., 2021, 602: 282,

[[35]] Di XC, Wang Y, Fu YQ, Wu XM, Wang P. Wheat flour-derived nanoporous carbon@ZnFe₂O₄ hierarchical composite as an outstanding microwave absorber. Carbon, 2021, 173: 174,

[[36]] D.M. Xu, Y.F. Yang, L.F. Lyu, et al., One-dimensional MnO@N-doped carbon nanotubes as robust dielectric loss electromagnetic wave absorbers, Chem. Eng. J., 410(2021), art. No. 128295.

[[37]] X.C. Zhang, M.J. Liu, J. Xu, et al., Flexible and waterproof nitrogen-doped carbon nanotube arrays on cotton-derived carbon fiber for electromagnetic wave absorption and electric-thermal conversion, Chem. Eng. J., 433(2022), art. No. 133794.

[[38]] S.T. Gao, Y.C. Zhang, H.L. Xing, and H.X. Li, Controlled reduction synthesis of yolk–shell magnetic@void@C for electromagnetic wave absorption, Chem. Eng. J., 387(2020), art. No. 124149.

[[39]] Chang L, Wang YZ, Zhang XC, Li L, Zhai HZ, Cao MS. Toward high performance microwave absorber by implanting La_0.8CoO₃ nanoparticles on rGO. J. Mater. Sci. Technol., 2024, 174: 176,

[[40]] Huang B, Yue JL, Fan BH, Liu Y, Huang XZ. Vertical carbon nanotubes arrays with controlled morphology on silicon carbide fibers for electromagnetic wave absorption. Ceram. Int., 2022, 48(13): 19375,

[[41]] Gong CC, Jiang JJ, Ding JW, et al.. Graphene oxide supported yolk–shell ZnS/Ni3S4 with the adjustable air layer for high performance of electromagnetic wave absorber. J. Colloid Interface Sci., 2022, 617: 620,

[[42]] Xing HL, Xie JX, Hu MQ. Sheet-like NiCo₂O₄-interconnected multiwalled carbon nanotubes with high-performance electromagnetic wave absorption. J. Mater. Sci. - Mater. Electron., 2022, 33(1): 306,

[[43]] Wang JL, Zhou M, Xie ZC, et al.. Enhanced interfacial polarization of biomass-derived porous carbon with a low radar cross-section. J. Colloid Interface Sci., 2022, 612: 146,

[[44]] R. Zhou, Y.S. Wang, Z.Y. Liu, Y.Q. Pang, J.X. Chen, and J. Kong, Digital light processing 3D-printed ceramic metamaterials for electromagnetic wave absorption, Nano-Micro Lett., 14(2022), No. 1, art. No. 122.

[[45]] Zhao J, Wei Y, Zhang Y, Zhang QG. 3D flower-like hollow CuS@PANI microspheres with superb X-band electromagnetic wave absorption. J. Mater. Sci. Technol., 2022, 126: 141,

[[46]] Wang SP, Liu ZY, Liu QC, et al.. Promoting the microwave absorption performance of hierarchical CF@NiO/Ni composites via phase and morphology evolution. Int. J. Miner. Metall. Mater., 2023, 30(3): 494,

[[47]] X. Yang, Y.P. Duan, S.Q. Li, et al., Bio-inspired microwave modulator for high-temperature electromagnetic protection, infrared stealth and operating temperature monitoring, Nano-Micro Lett., 14(2021), No. 1, art. No. 28.

[[48]] Cheng JB, Zhao HB, Zhang AN, Wang YQ, Wang YZ. Porous carbon/Fe composites from waste fabric for high-efficiency electromagnetic wave absorption. J. Mater. Sci. Technol., 2022, 126: 266,

[[49]] T. Zhu, W. Shen, X.Y. Wang, Y.F. Song, and W. Wang, Paramagnetic CoS₂@MoS₂ core–shell composites coated by reduced graphene oxide as broadband and tunable high-performance microwave absorbers, Chem. Eng. J., 378(2019), art. No. 122159.

[[50]] X.J. Liu, Y.P. Duan, Y. Guo, et al., Microstructure design of high-entropy alloys through a multistage mechanical alloying strategy for temperature-stable megahertz electromagnetic absorption, Nano-Micro Lett., 14(2022), No. 1, art. No. 142.

[[51]] Ren LG, Wang YQ, Zhang X, He QC, Wu GL. Efficient microwave absorption achieved through in situ construction of core–shell CoFe₂O₄@mesoporous carbon hollow spheres. Int. J. Miner. Metall. Mater., 2023, 30(3): 504,

[[52]] Gao ZG, Yang K, Zhao ZH, et al.. Design principles in MOF-derived electromagnetic wave absorption materials: Review and perspective. Int. J. Miner. Metall. Mater., 2023, 30(3): 405,

[[53]] L.M. Song, C.W. Wu, Q. Zhi, et al., Multifunctional SiC aerogel reinforced with nanofibers and nanowires for high-efficiency electromagnetic wave absorption, Chem. Eng. J., 467(2023), art. No. 143518.

[[54]] Q.Q. Huang, Y. Zhao, Y. Wu, et al., A dual-band transceiver with excellent heat insulation property for microwave absorption and low infrared emissivity compatibility, Chem. Eng. J., 446(2022), art. No. 137279.

[[55]] Chen XT, Zhou M, Zhao Y, et al.. Correction: Morphology control of eco-friendly chitosan-derived carbon aerogels for efficient microwave absorption at thin thickness and thermal stealth. Green Chem., 2022, 24(15): 6036,