Recent progresses in the development of tubular segmented-in-series solid oxide fuel cells: Experimental and numerical study

Abstract

Solid oxide fuel cells (SOFCs) have attracted a great deal of interest because they have the highest efficiency without using any noble metal as catalysts among all the fuel cell technologies. However, traditional SOFCs suffer from having a higher volume, current leakage, complex connections, and difficulty in gas sealing. To solve these problems, Rolls-Royce has fabricated a simple design by stacking cells in series on an insulating porous support, resulting in the tubular segmented-in-series solid oxide fuel cells (SIS-SOFCs), which achieved higher output voltage. This work systematically reviews recent advances in the structures, preparation methods, performances, and stability of tubular SIS-SOFCs in experimental and numerical studies. Finally, the challenges and future development of tubular SIS-SOFCs are also discussed. The findings of this work can help guide the direction and inspire innovation of future development in this field.

Keywords

solid oxide fuel cell / segmented-in-series / tubular / experimental study / numerical study

References

[1] Zhang Y, Chen B, Guan DQ, et al.. Thermal-expansion offset for high-performance fuel cell cathodes. Nature, 2021, 591(7849): 246,

[2] A. Hauch, R. Küngas, P. Blennow, et al., Recent advances in solid oxide cell technology for electrolysis, Science, 370(2020), art. No. eaba6118.

[3] Wei T, Zhou YY, Sun C, et al.. Prestoring lithium into SnO₂ coated 3D carbon fiber cloth framework as dendrite-free lithium metal anode. Particuology, 2024, 84: 89,

[4] T. Wei, Y.Y. Zhou, C. Sun, et al., An intermittent lithium deposition model based on CuMn-bimetallic MOF derivatives for composite lithium anode with ultrahigh areal capacity and current densities, Nano Res., (2023). Doi: https://doi.org/10.1007/112274-023-6187-8.

[5] Wei T, Lu JH, Wang MT, et al.. MOF-derived materials enabled lithiophilic 3D hosts for lithium metal anode—A review. Chin. J. Chem., 2023, 41(15): 1861,

[6] T. Wei, J.H. Lu, P. Zhang, et al., Metal–organic framework-derived Co₃O₄ modified nickel foam-based dendrite-free anode for robust lithium metal batteries, Chin. Chem. Lett., 34(2023), No. 8, art. No. 107947.

[7] T. Wei, J.H. Lu, P. Zhang, et al., An intermittent lithium deposition model based on bimetallic MOFs derivatives for dendrite-free lithium anode with ultrahigh areal capacity, Chin. Chem. Lett., (2023), art. No. 109122.

[8] X.C. Ge, H.X. Li, J. Li, et al., High-entropy doping boosts ion/electronic transport of Na₄Fe₃(PO₄)₂(P₂O₇)/C cathode for superior performance sodium-ion batteries, Small, 19(2023), No. 37, art. No. e2302609.

[9] W.J. Meng, Z.Z. Dang, D.S. Li, and L. Jiang, Long-cycle-life sodium-ion battery fabrication via a unique chemical bonding interface mechanism, Adv. Mater., 35(2023), No. 30, art. No. e2301376.

[10] Wei T, Zhang Q, Wang SJ, et al.. A gel polymer electrolyte with IL@UiO-66-NH₂ as fillers for high-performance all-solid-state lithium metal batteries. Int. J. Miner. Metall. Mater., 2023, 30(10): 1897,

[11] Q. Zhang, S.J. Wang, Y. Liu, M.T. Wang, R.T. Chen, Z.Y. Zhu, X.Y. Qiu, S.D. Xu, and T. Wei, UiO - 66 - NH₂@67 core–shell metal–organic framework as fillers in solid composite electrolytes for high - performance all - solid - state lithium metal batteries, Energy Technol., 11(2023), No. 4, art. No. 2201438.

[12] Zhang ZH, Wei T, Lu JH, et al.. Practical development and challenges of garnet-structured Li₇La₃Zr₂O₁₂ electrolytes for all-solid-state lithium-ion batteries: A review. Int. J. Miner. Metall. Mater., 2021, 28(10): 1565,

[13] Lu JH, Wang ZM, Zhang Q, et al.. The effects of amino groups and open metal sites of MOFs on polymer-based electrolytes for all-solid-state lithium metal batteries. Chin. J. Chem. Eng., 2023, 60: 80,

[14] Q. Zhang, T. Wei, J.H. Lu, et al., The effects of PVB additives in MOFs-based solid composite electrolytes for all-solid-state lithium metal batteries, J. Electroanal. Chem., 926(2022), No. 9, art. No. 116935.

[15] Wei T, Zhang ZH, Zhang Q, et al.. Anion-immobilized solid composite electrolytes based on metal-organic frameworks and superacid ZrO₂ fillers for high-performance all solid-state lithium metal batteries. Int. J. Miner. Metall. Mater., 2021, 28(10): 1636,

[16] Wei T, Zhang ZH, Wang ZM, et al.. Ultrathin solid composite electrolyte based on Li_6.4La₃Zr_1.4Ta_0.6O₁₂/PVDF-HFP/LiTF-SI/succinonitrile for high-performance solid-state lithium metal batteries. ACS Appl. Energy Mater., 2020, 3(9): 9428,

[17] A.G. Olabi, T. Wilberforce, and M. Ali Abdelkareem, Fuel cell application in the automotive industry and future perspective, Energy, 214(2021), art. No. 118955.

[18] Dhimish M, Vieira RG, Badran G. Investigating the stability and degradation of hydrogen PEM fuel cell. Int. J. Hydrogen Energy, 2021, 46(74): 37017,

[19] Yang X, Du ZH, Zhang Q, et al.. Effects of operating conditions on the performance degradation and anode microstructure evolution of anode-supported solid oxide fuel cells. Int. J. Miner. Metall. Mater., 2023, 30(6): 1181,

[20] Yusoff W N AW, Baharuddin N A, Somalu M R, Muchtar A, Brandon N P, Fan HQ. Recent advances and influencing parameters in developing electrode materials for symmetrical solid oxide fuel cells. Int. J. Miner. Metall. Mater., 2023, 30(10): 1933,

[21] Liang FY, Yang JR, Wang HQ, Wu JW. Fabrication of Gd₂O₃-doped CeO₂ thin films through DC reactive sputtering and their application in solid oxide fuel cells. Int. J. Miner. Metall. Mater., 2023, 30(6): 1190,

[22] Liu GY, Hou FG, Peng SL, Wang XD, Fang BZ. Process and challenges of stainless steel based bipolar plates for proton exchange membrane fuel cells. Int. J. Miner. Metall. Mater., 2022, 29(5): 1099,

[23] Song J, Birdja YY, Pant D, Chen ZY, Vaes J. Recent progress in the structure optimization and development of proton-conducting electrolyte materials for low-temperature solid oxide cells. Int. J. Miner. Metall. Mater., 2022, 29(4): 848,

[24] J.X. Peng, J. Huang, X.L. Wu, Y.W. Xu, H.C. Chen, and X. Li, Solid oxide fuel cell (SOFC) performance evaluation, fault diagnosis and health control: A review, J. Power Sources, 505(2021), art. No. 230058.

[25] Malik V, Srivastava S, Bhatnagar MK, Vishnoi M. Comparative study and analysis between Solid Oxide Fuel Cells (SOFC) and Proton Exchange Membrane (PEM) fuel cell–A review. Mater. Today Proc., 2021, 47: 2270,

[26] Dwivedi S. Solid oxide fuel cell: Materials for anode, cathode and electrolyte. Int. J. Hydrogen Energy, 2020, 45(44): 23988,

[27] Singh M, Zappa D, Comini E. Solid oxide fuel cell: Decade of progress, future perspectives and challenges. Int. J. Hydrogen Energy, 2021, 46(54): 27643,

[28] D.F. Chen, Y.L. Zhu, S. Han, L. Anatoly, M. Andrey, and L. Lu, Investigate the effect of a parallel-cylindrical flow field on the solid oxide fuel cell stack performance by 3D multiphysics simulating, J. Energy Storage, 60(2023), art. No. 106587.

[29] Singhal SC. Progress in tubular solid oxide fuel cell technology. Proc. Vol., 1999, 1999–19(1): 39,

[30] Chen DF, Xu Y, Hu B, Yan C, Lu L. Investigation of proper external air flow path for tubular fuel cell stacks with an anode support feature. Energy Convers. Manag., 2018, 171: 807,

[31] Dong LX, Zheng Q, Huang Y, Tian ZP, Liu JP, Wang C, Liang B, Lei LB. Research progress on cutting-edge technology of tubular solid oxide fuel cells. Energy Stor. Mater., 2022, 12(1): 131

[32] Park BK, Lee JW, Lee SB, et al.. A flat-tubular solid oxide fuel cell with a dense interconnect film coated on the porous anode support. J. Power Sources, 2012, 213: 218,

[33] Othman MHD, Droushiotis N, Wu ZT, Kelsall G, Li K. High-performance, anode-supported, microtubular SOFC prepared from single-step-fabricated, dual-layer hollow fibers. Adv. Mater., 2011, 23(21): 2480,

[34] Li CJ, Chen X, Zhang SL, Li CX, Yang GJ. The characteristics of cermet-supported tubular solid oxide fuel cells manufactured by thermal spraying. ECS Trans., 2019, 91(1): 285,

[35] Li C, Li C, Xing Y, Gao M, Yang G. Influence of YSZ electrolyte thickness on the characteristics of plasma-sprayed cermet supported tubular SOFC. Solid State Ion., 2006, 177(19–25): 2065,

[36] Li CX, Li CJ, Guo LJ. Effect of composition of NiO/YSZ anode on the polarization characteristics of SOFC fabricated by atmospheric plasma spraying. Int. J. Hydrogen Energy, 2010, 35(7): 2964,

[37] Li CJ, Li CX, Long HG, Xing YZ, Yang GJ. Performance of tubular solid oxide fuel cell assembled with plasma-sprayed Sc₂O₃-ZrO₂ electrolyte. Solid State Ionics, 2008, 179(27–32): 1575,

[38] O. Hodjati-Pugh, A. Dhir, and R. Steinberger-Wilckens, The development of current collection in micro-tubular solid oxide fuel cells—A review, Appl. Sci., 11(2021), No. 3, art. No. 1077.

[39] Khan MZ, Iltaf A, Ishfaq H, et al.. Flat-tubular solid oxide fuel cells and stacks: A review. J. Asian Ceram. Soc., 2021, 9(3): 745,

[40] Jamil SM, Othman MHD, Rahman MA, Jaafar J, Ismail AF, Li K. Recent fabrication techniques for micro-tubular solid oxide fuel cell support: A review. J. Eur. Ceram. Soc., 2015, 35(1): 1,

[41] Gardner FJ, Day MJ, Brandon NP, Pashley MN, Cassidy M. SOFC technology development at Rolls-Royce. J. Power Sources, 2000, 86(1–2): 122,

[42] An YT, Ji MJ, Seol KH, Hwang HJ, Park E, Choi BH. Characteristics of flat-tubular ceramic supported segmented-in-series solid oxide fuel cell on all sides laminating using decalcomania method. J. Power Sources, 2014, 262: 323,

[43] An YT, Ji MJ, Hwang HJ, Eugene Park S, Choi BH. Effect of cell-to-cell distance in segmented-in-series solid oxide fuel cells. Int. J. Hydrogen Energy, 2015, 40(5): 2320,

[44] An YT, Ji MJ, Hwang HJ, Park SE, Choi BH. Effect of cell length on the performance of segmented-in-series solid oxide fuel cells fabricated using decalcomania method. J. Ceram. Soc. Jpn, 2015, 123(1436): 178,

[45] Mukerjee S, Leah R, Selby M, Stevenson G, Brandon NP. . Solid Oxide Fuel Cell Lifetime and Reliability, 2017 London Academic Press 173,

[46] Miyamoto K, Mihara M, Oozawa H, et al.. Recent progress of SOFC combined cycle system with segmented-in-series tubular type cell stack at MHPS. ECS Trans., 2015, 68(1): 51,

[47] H. Yoshida, T. Seyama, T. Sobue, and S. Yamashita, Development of residential SOFC CHP system with flatten tubular segmented-in-series cells stack, ECS Trans., 35(2011), No. 1, art. No. 97.

[48] Mushtaq U, Kim DW, Yun UJ, et al.. Effect of cathode geometry on the electrochemical performance of flat tubular segmented-in-series (SIS) solid oxide fuel cell. Int. J. Hydrogen Energy, 2015, 40(18): 6207,

[49] Ding J, Liu J. A novel design and performance of cone-shaped tubular anode-supported segmented-in-series solid oxide fuel cell stack. J. Power Sources, 2009, 193(2): 769,

[50] Matsuzaki Y, Nakamura K, Somekawa T, et al.. Multimodal assessment of durability and reliabilityof flattened tubular SIS stacks. ECS Trans., 2013, 57(1): 325,

[51] Y.H. Tang, Y.K. Lin, D.M. Ford, et al., A review on models and simulations of membrane formation via phase inversion processes, J. Membr. Sci., 640(2021), art. No. 119810.

[52] Ren C, Liu T, Mao YT, et al.. Effect of casting slurry composition on anode support microstructure and cell performance of MT-SOFCs by phase inversion method. Electrochim. Acta, 2014, 149: 159,

[53] Yang CH, Jin C, Chen FL. Micro-tubular solid oxide fuel cells fabricated by phase-inversion method. Electrochem. Commun., 2010, 12(5): 657,

[54] Han ZY, Wang YH, Yang ZB, Han MF. Electrochemical properties of tubular SOFC based on a porous ceramic support fabricated by phase-inversion method. J. Mater. Sci. Technol., 2016, 32(7): 681,

[55] Mat A, Canavar M, Timurkutluk B, Kaplan Y. Investigation of micro-tube solid oxide fuel cell fabrication using extrusion method. Int. J. Hydrogen Energy, 2016, 41(23): 10037,

[56] Zhang SL, Li CX, Liu S, et al.. Thermally sprayed large tubular solid oxide fuel cells and its stack: Geometry optimization, preparation, and performance. J. Therm. Spray Technol., 2017, 26(3): 441,

[57] Somalu M, Muchtar A, Wan Daud W, Brandon N. Screen-printing inks for the fabrication of solid oxide fuel cell films: A review. Renewable Sustainable Energy Rev., 2017, 75: 426,

[58] Yang ZB, Zhu TL, Han MF. Tubular SOFC with hollow fiber ceramic support and inner coating. ECS Trans., 2015, 68(1): 2267,

[59] Ghatee M, Salari F. Electrical and mechanical properties of 5YSZ tubular thin film prepared by screen printing method. Int. J. Appl. Ceram. Technol., 2016, 13(2): 373,

[60] Kim DW, Yun UJ, Lee JW, et al.. Fabrication and operating characteristics of a flat tubular segmented-in-series solid oxide fuel cell unit bundle. Energy, 2014, 72: 215,

[61] Xu YJ, Wang SR, Liu RZ, Wen TL, Wen ZY. A novel bilayered Sr_0.6La_0.4TiO₃/La_0.8Sr_0.2MnO₃ interconnector for anode-supported tubular solid oxide fuel cell via slurry-brushing and co-sintering process. J. Power Sources, 2011, 196(3): 1338,

[62] Yun UJ, Lee JW, Lee SB, et al.. Fabrication and operation of tubular segmented-In-series (SIS) solid oxide fuel cells (SOFC). Fuel Cells, 2012, 12(6): 1099,

[63] Bai YH, Liu J, Wang CL. Performance of cone-shaped tubular anode-supported segmented-in-series solid oxide fuel cell stack fabricated by dip coating technique. Int. J. Hydrogen Energy, 2009, 34(17): 7311,

[64] Ding J, Zhou XY, Liu QH, Yin GQ. Development of tubular anode-supported solid oxide fuel cell cell and 4-cell-stack based on lanthanum gallate electrolyte membrane for mobile application. J. Power Sources, 2018, 401: 336,

[65] Wei T, Liu XJ, Yuan C, Gao QY, Xin XS, Wang SR. A modified liquid-phase-assisted sintering mechanism for La_0.8Sr_0.2Cr_1−xFe _xO_3−δ—A high density, redox-stable perovskite interconnect for solid oxide fuel cells. J. Power Sources, 2014, 250: 152,

[66] Xu YJ, Wang SR, Shao L, Wen TL, Wen ZY. Performance of an anode-supported tubular solid oxide fuel cells stack with two single cells connected by a co-sintered ceramic interconnector. Int. J. Hydrogen Energy, 2011, 36(10): 6194,

[67] Park BK, Kim DW, Song RH, et al.. Design of a dual-layer ceramic interconnect based on perovskite oxides for segmented-in-series solid oxide fuel cells. J. Power Sources, 2015, 300: 318,

[68] Y.Z. Hu, J.T. Gao, C.X. Li, and C.J. Li, Thermally sprayed MCO/FeCr24 interconnector with improved stability for tubular segmented-in-series SOFCs, Appl. Surf. Sci., 587(2022), art. No. 152861.

[69] Pianko-Oprych P, Palus M. Numerical analysis of a serial connection of two staged SOFC stacks in a CHP system fed by methane using Aspen TECH. Pol. J. Chem. Technol., 2019, 21(1): 33,

[70] T.S. Lai, J. Liu, and S.A. Barnett, Effect of cell width on segmented-in-series SOFCs, Electrochem. Solid-State Lett., 7(2004), No. 4, art. No. A78.

[71] Lai TS, Barnett SA. Design considerations for segmented-in-series fuel cells. J. Power Sources, 2005, 147(1–2): 85,

[72] Lai TS, Barnett SA. Effect of cathode sheet resistance on segmented-in-series SOFC power density. J. Power Sources, 2007, 164(2): 742,

[73] D.A. Cui, Y.L. Ji, C. Chang, Z. Wang, X. Xiao, and Y.T. Li, Influence of structure size on voltage uniformity of flat tubular segmented-in-series solid oxide fuel cell, J. Power Sources, 460(2020), art. No. 228092.

[74] J.H. Fan, J.X. Shi, R.Y. Zhang, Y.Q. Wang, and Y.X. Shi, Numerical study of a 20-cell tubular segmented-in-series solid oxide fuel cell, J. Power Sources, 556(2023), art. No. 232449.

[75] A.D. Shi, Y.P. Kong, Z. Li, Y.H. Wang, S.L. Fan, and Z.L. Jin, Performance analysis of series connected cathode supported tubular SOFCs, Int. J. Electrochem. Sci., 18(2023), No. 5, art. No. 100126.

[76] O. Hodjati-Pugh, J. Andrews, A. Dhir, and R. Steinberger-Wilckens, Analysis of current collection in micro-tubular solid oxide fuel cells: An empirical and mathematical modelling approach for minimised ohmic polarisation, J. Power Sources, 494(2021), art. No. 229780.

[77] Liu B, Matsui T, Muroyama H, Tomida K, Kabata T, Eguchi K. Impedance analysis of practical segmented-in-series tubular solid oxide fuel cells. ECS Trans., 2011, 35(1): 637,

[78] B. Liu, H. Muroyama, T. Matsui, K. Tomida, T. Kabata, and K. Eguchi, Analysis of impedance spectra for segmented-in-series tubular solid oxide fuel cells, J. Electrochem. Soc., 157(2010), No. 12, art. No. B1858.

[79] B. Liu, H. Muroyama, T. Matsui, K. Tomida, T. Kabata, and K. Eguchi, Gas transport impedance in segmented-in-series tubular solid oxide fuel cell, J. Electrochem. Soc., 158(2011), No. 2, art. No. B215.

[80] Liu B, Muroyama H, Matsui T, Tomida K, Kabata T, Eguchi K. Dynamic behavior of segmented-in-series tubular solid oxide fuel cell upon discharge. J. Electrochem. Soc., 2012, 159(3): B324,

[81] Fujita K, Somekawa T, Hatae T, Matsuzaki Y. Residual stress and redox cycling of segmented-in-series solid oxide fuel cells. J. Power Sources, 2011, 196(21): 9022,

[82] Somekawa T, Horiuchi K, Matsuzaki Y. A study of electrically insulated oxide substrates for flat-tube segmented-in-series solid oxide fuel cells. J. Power Sources, 2012, 202: 114,

[83] Choudhury A, Chandra H, Arora A. Application of solid oxide fuel cell technology for power generation—A review. Renewable Sustainable Energy Rev., 2013, 20: 430,

[84] Huang K, Singhal SC. Cathode-supported tubular solid oxide fuel cell technology: A critical review. J. Power Sources, 2013, 237: 84,

[85] K. Horiuchi, K. Nakamura, Y. Matsuzaki, et al., Durability tests of flatten tubular segmented-in-series type SOFC stacks for intermediate temperature operation, ECS Trans., 35(2011), No. 1, art. No. 217.

[86] Kobayashi Y, Tomida K, Tsukuda H, Shiratori Y, Taniguchi S, Sasaki K. Durability of a segmented-in-series tubular SOFC with a (Ce,Sm)O₂ cathode interlayer: Influence of operating conditions. J. Electrochem. Soc., 2014, 161(3): F214,