Customization of FeNi alloy nanosheet arrays inserted with biomass-derived carbon templates for boosted electromagnetic wave absorption

Abstract

Electromagnetic wave (EMW)-absorbing materials have considerable capacity in the military field and the prevention of EMW radiation from harming human health. However, obtaining lightweight, high-performance, and broadband EMW-absorbing material remains an overwhelming challenge. Creating dielectric/magnetic composites with customized structures is a strategy with great promise for the development of high-performance EMW-absorbing materials. Using layered double hydroxides as the precursors of bimetallic alloys and combining them with porous biomass-derived carbon materials is a potential way for constructing multi-interface heterostructures as efficient EMW-absorbing materials because they have synergistic losses, low costs, abundant resources, and light weights. Here, FeNi alloy nanosheet array/Lycopodium spore-derived carbon (FeNi/LSC) was prepared through a simple hydrothermal and carbonization method. FeNi/LSC presents ideal EMW-absorbing performance by benefiting from the FeNi alloy nanosheet array, sponge-like structure, capability for impedance matching, and improved dielectric/magnetic losses. As expected, FeNi/LSC exhibited the minimum reflection loss of −58.3 dB at 1.5 mm with 20wt% filler content and a widely effective absorption bandwidth of 4.92 GHz. FeNi/LSC composites with effective EMW-absorbing performance provide new insights into the customization of biomass-derived composites as high-performance and lightweight broadband EMW-absorbing materials.

Keywords

spore-derived carbon / FeNi alloy nanosheet array / multi-interface heterostructures / synergistic effect / efficient electromagnetic wave absorption

References

[[1]] H.L. Lv, Z.H. Yang, H.G. Pan, and R.B. Wu, Electromagnetic absorption materials: Current progress and new frontiers, Prog. Mater. Sci., 127(2022), art. No. 100946.

[[2]] Z.D. Zhang, Y.M. Zhao, G.H. Fan, et al., Paper-based flexible metamaterial for microwave applications, EPJ Appl. Metamater., 8(2021), art. No. 6.

[[3]] Srivastava SK, Manna K. Recent advancements in the electromagnetic interference shielding performance of nano-structured materials and their nanocomposites: A review. J. Mater. Chem. A, 2022, 10(14): 7431,

[[4]] Wu F, Yang K, Li Q, et al.. Biomass-derived 3D magnetic porous carbon fibers with a helical/chiral structure toward superior microwave absorption. Carbon, 2021, 173: 918,

[[5]] Zhu HH, Liang J, Chen JF, et al.. Rational construction of yolk-shell structured Co₃Fe₇/FeO@carbon composite and optimization of its microwave absorption. J. Colloid Interface Sci., 2022, 626: 775,

[[6]] B.L. Wang, Y.G. Fu, J. Li, Q. Wu, X.Y. Wang, and T. Liu, Construction of Co@C nanocapsules by one-step carbon reduction of single-crystal Co₃O₄ nanoparticles: Ultra-wideband microwave absorber verified via coaxial and arch methods, Chem. Eng. J., 445(2022), art. No. 136863.

[[7]] W. Tian, J.Y. Li, Y.F. Liu, et al. Atomic-scale layer-by-layer deposition of FeSiAl@ZnO@Al₂O₃ hybrid with threshold anticorrosion and ultra-high microwave absorption properties in low-frequency bands, Nano Micro Lett., 13(2021), No. 1, art. No. 161.

[[8]] H.H. Niu, X.Y. Tu, S. Zhang, et al., Engineered core–shell SiO₂@Ti₃C₂T_x composites: Towards ultra-thin electromagnetic wave absorption materials, Chem. Eng. J., 446(2022), art. No. 137260.

[[9]] Liu TH, Shang KX, Miao C, Ouyang J. Multiple interface coupling in halloysite/reduced graphene oxide/cobalt nickel composites for high-performance electromagnetic wave absorption. J. Colloid Interface Sci., 2022, 628: 858,

[[10]] X.X. Wang, F.F. You, X.Y. Wen, K.R. Wang, G.X. Tong, and W.H. Wu, Doping Ce(OH)CO₃ laminated dendrites with Fe, Co and Ni for defect steered wide-frequency microwave absorption, Chem. Eng. J., 445(2022), art. No. 136431.

[[11]] Zhou Q, Shi TT, Xue B, et al.. Gradient carbonyl-iron/carbon-fiber reinforced composite metamaterial for ultra-broadband electromagnetic wave absorption by multi-scale integrated design. Int. J. Miner. Metall. Mater., 2023, 30(6): 1198,

[[12]] Zhang R, Mu CP, Wang BC, et al.. Composites of In/C hexagonal nanorods and graphene nanosheets for high-performance electromagnetic wave absorption. Int. J. Miner. Metall. Mater., 2023, 30(3): 485,

[[13]] Wen B, Yang GR, Zhou XY, Ding SJ. Intelligent diffusion regulation induced in situ growth of cobalt nanoclusters on carbon nanotubes for excellent electromagnetic wave absorption. J. Colloid Interface Sci., 2023, 634: 74,

[[14]] Wang YC, Yao LH, Zheng Q, Cao MS. Graphene-wrapped multiloculated nickel ferrite: A highly efficient electromagnetic attenuation material for microwave absorbing and green shielding. Nano Res., 2022, 15(7): 6751,

[[15]] S.K. Hou, Y. Wang, F. Gao, et al., In situ growing fusiform SnO₂ nanocrystals film on carbon fiber cloth as an efficient and flexible microwave absorber, Mater. Des., 225(2023), art. No. 111576.

[[16]] Jin X, Al-Qatatsheh A, Subhani K, Salim NV. An ultralight, elastic carbon nanofiber aerogel with efficient energy storage and sorption properties. Nanoscale, 2022, 14(18): 6854,

[[17]] Wang DD, Zhang MY, Guo Y, et al.. Facile preparation of a cellulose derived carbon/BN composite aerogel for superior electromagnetic wave absorption. J. Mater. Chem. C, 2022, 10(13): 5311,

[[18]] Lv H, Xiao ZY, Zhai SR, Wang XT, Hao JA, An QD. Designed formation of C/Fe₃O₄@Ni(OH)₂ cathode with enhanced pseudocapacitance for asymmetric supercapacitors. J. Colloid Interface Sci., 2023, 635: 176,

[[19]] H. Lv, Z.Y. Xiao, S.R. Zhai, et al., Ni₃S₂ nanoparticles encapsulated in S-doped biomass-derived hierarchically porous carbon as an advanced electrode for excellent hybrid supercapacitors performance, Ind. Crops Prod., 194(2023), art. No. 116320.

[[20]] H. Lv, Z.Y. Xiao, S.R. Zhai, X.T. Wang, J.G. Hao, and Q.D. An, Cu_xS particles loaded on S-doped 3D hierarchical porous carbon as an efficient electrode for superior asymmetric super-capacitors, J. Alloys Compd., 945(2023), art. No. 169332.

[[21]] H.D. Sun, L.L. Zheng, Y.R. Xi, S.R. Zhai, Q.D. An, and Z.Y. Xiao, Nickel-iron sulfide nanoparticles supported on biomass-derived N-doped hierarchical porous carbon as a robust electrode for supercapacitors, Electrochim. Acta, 466(2023), art. No. 143053.

[[22]] Lu ZX, Ren F, Guo ZZ, et al.. Facile construction of core-shell Carbon@CoNiO₂ derived from yeast for broadband and high-efficiency microwave absorption. J. Colloid Interface Sci., 2022, 625: 415,

[[23]] Yusuf JY, Soleimani H, Yahya N, et al.. Eletromagnetic wave absorption of coconut fiber-derived porous activated carbon. Bol. Soc. Esp. Ceram. Vidrio, 2022, 61(5): 417,

[[24]] Zhai NX, Luo JH, Xiao MW, Zhang YC, Yan WX, Xu Y. In situ construction of Co@nitrogen-doped carbon/Ni nanocomposite for broadband electromagnetic wave absorption. Carbon, 2023, 203: 416,

[[25]] Li J, Wang L, Zhang D, et al.. Reduced graphene oxide modified mesoporous FeNi alloy/carbon microspheres for enhanced broadband electromagnetic wave absorbers. Mater. Chem. Front., 2017, 1(9): 1786,

[[26]] Pan JJ, Tu WJ, Ma SH, et al.. Improvement of multiple attenuation characteristics of two-dimensional lamellar ferrocobalt@carbon nanocomposites as excellent electromagnetic wave absorbers. Dalton Trans., 2022, 51(25): 9793,

[[27]] Li Y, Qin YS, Wu GL, Zheng YC, Ban QF. Metal-co-ordination-driven self-assembly synthesis of porous iron/carbon composite for high-efficiency electromagnetic wave absorption. J. Colloid Interface Sci., 2022, 623: 1002,

[[28]] Wu P, Wang ZY, Bolan NS, Wang HL, Wang YJ, Chen WF. Visualizing the development trend and research frontiers of biochar in 2020: A scientometric perspective. Biochar, 2021, 3(4): 419,

[[29]] D.M. Zhang, W. He, G.Q. Quan, et al., Sterculia lychnophora seed-derived porous carbon@CoFe₂O₄ composites with efficient microwave absorption performance, Appl. Surf. Sci., 607(2023), art. No. 155027.

[[30]] Lv JJ, Wang LM, Li RS, et al.. Constructing a hetero-interface composed of oxygen vacancy-enriched Co₃O₄ and crystalline–amorphous NiFe-LDH for oxygen evolution reaction. ACS Catal., 2021, 11(23): 14338,

[[31]] Jin YY, Tian K, Wei L, Zhang XY, Guo X. Hierarchical porous microspheres of activated carbon with a high surface area from spores for electrochemical double-layer capacitors. J. Mater. Chem. A, 2016, 4(41): 15968,

[[32]] Cui C, Bai WH, Jiang S, et al.. FeNi LDH/loofah sponge-derived magnetic FeNi alloy nanosheet array/porous carbon hybrids with efficient electromagnetic wave absorption. Ind. Eng. Chem. Res., 2022, 61(28): 10078,

[[33]] Wang T, Xu YB, Li YF, et al.. Sodium-mediated bimetallic Fe–Ni catalyst boosts stable and selective production of light aromatics over HZSM-5 zeolite. ACS Catal., 2021, 11(6): 3553,

[[34]] Shi SQ, Hao SJ, Yang C, Chen YB, Chu HR, Dai SL. Enhanced microwave absorption properties of reduced graphene oxide/TiO₂ nanowire composites synthesized via simultaneous carbonation and hydrogenation. J. Mater. Chem. C, 2022, 10(25): 9586,

[[35]] Shi YN, Ding XY, Pan KC, Gao ZH, Du J, Qiu J. A novel multi-dimensional structure of graphene-decorated composite foam for excellent stealth performance in microwave and infrared frequency bands. J. Mater. Chem. A, 2022, 10(14): 7705,

[[36]] Y.L. Huang, W.J. Wang, X.W. Hou, et al., Salt-templated synthesis of CuO/Carbon nanosheets for efficient microwave absorption, Appl. Surf. Sci., 598(2022), art. No. 153779.

[[37]] Wei TC, Zhu XZ, Xu JN, Kan CX, Shi DN. Porous molybdenum compound design for strong microwave absorption. Langmuir, 2023, 39(2): 890,

[[38]] H. Wang, X.H. Zhang, Y.H. Tang, et al., Using silk-derived magnetic carbon nanocomposites as highly efficient Nanozymes and electromagnetic absorbing agents, Chin. Chem. Lett., 34(2023), No. 9, art. No. 108084.

[[39]] Su XG, Han MJ, Liu YN, Wang J, Liang CB, Liu YQ. In-situ construction of nitrogen-doped reduced graphene oxide@carbon nanofibers towards the synergetic enhancement of their microwave absorption properties via integrating point defects and structure engineering. J. Colloid Interface Sci., 2022, 628: 984, Part B

[[40]] Deng WB, Li TH, Li H, et al.. Controllable graphitization degree of carbon foam bulk toward electromagnetic wave attenuation loss behavior. J. Colloid Interface Sci., 2022, 618: 129,

[[41]] J.K. Liu, Z.R. Jia, W.H. Zhou, et al., Self-assembled MoS₂/magnetic ferrite CuFe₂O₄ nanocomposite for high-efficiency microwave absorption, Chem. Eng. J., 429(2022), art. No. 132253.

[[42]] J. Dong, W.H. Xu, S.B. Liu, et al., Lignin-derived biochar to support CoFe₂O₄: Effective activation of peracetic acid for sulfamethoxazole degradation, Chem. Eng. J., 430(2022), art. No. 132868.

[[43]] T.T. Zheng, Y. Zhang, Z.R. Jia, J.H. Zhu, G.L. Wu, and P.F. Yin, Customized dielectric-magnetic balance enhanced electromagnetic wave absorption performance in Cu_xS/CoFe₂O₄ composites, Chem. Eng. J., 457(2023), art. No. 140876.

[[44]] Q.J. Wang, J.N. Wang, Y.Z. Zhao, et al., NiO/NiFe₂0₄@N-doped reduced graphene oxide aerogel towards the wideband electromagnetic wave absorption: Experimental and theoretical study, Chem. Eng. J., 430(2022), art. No. 132814.

[[45]] X.H. Liang, Z.M. Man, B. Quan, et al., Environment-stable Co_xNi_y encapsulation in stacked porous carbon nanosheets for enhanced microwave absorption, Nano Micro Lett., 12(2020), No. 1, art. No. 102.

[[46]] Zhang S, Wang CJ, Gao TH, et al.. Optimizing electromagnetic interference shielding of ultrathin nanoheterostructure textiles through interfacial engineering. ACS Appl. Mater. Interfaces, 2023, 15(12): 15965,

[[47]] Z. Su, S. Yi, W.Y. Zhang, et al., Magnetic-dielectric complementary Fe–Co–Ni alloy/carbon composites for high-attenuation C-band microwave absorption via carbothermal reduction of solid-solution precursor, Adv. Electron. Mater., 9(2023), No. 2, art. No. 2201159.

[[48]] Y.C. Sun, T.T. Wang, C.H. Han, et al., Facile synthesis of Fe-modified lignin-based biochar for ultra-fast adsorption of methylene blue: Selective adsorption and mechanism studies, Bioresour. Technol., 344(2022), art. No. 126186.

[[49]] Y.P. Zhao, X.Q. Zuo, Y. Guo, et al., Structural engineering of hierarchical aerogels comprised of multi-dimensional gradient carbon nanoarchitectures for highly efficient microwave absorption, Nano Micro Lett., 13(2021), No. 1, art. No. 144.

[[50]] Wang YJ, Pang ZB, Xu H, et al.. High-performance electromagnetic wave absorption of NiCoFe/N-doped carbon composites with a Prussian blue analog (PBA) core at 2–18 GHz. J. Colloid Interface Sci., 2022, 620: 107,

[[51]] Zhang XY, Jia ZR, Zhang F, et al.. MOF-derived NiFe₂S₄/Porous carbon composites as electromagnetic wave absorber. J. Colloid Interface Sci., 2022, 610: 610,

[[52]] Fei Y, Wang XY, Yuan MS, Liang M, Chen Y, Zou HW. Co nanoparticles encapsulated in carbon nanotubes decorated carbon aerogels toward excellent microwave absorption. Ind. Eng. Chem. Res., 2022, 61(4): 1684,

[[53]] M. Zhang, S.N. Song, Y.M. Liu, Z.X. Hou, W.Y. Tang, and S.N. Li, Microstructural design of necklace-like Fe₃O₄/multi-wall carbon nanotube (MWCNT) composites with enhanced microwave absorption performance, Materials (Basel), 14(2021), No. 17, art. No. 4783.

[[54]] J.R. Yao, L. Zhang, F. Yang, et al., Superhydrophobic Ti₃C₂T_x MXene/aramid nanofiber films for high-performance electromagnetic interference shielding in thermal environment, Chem. Eng. J., 446(2022), art. No. 136945.

[[55]] Y.J. Zou, X.Z. Huang, B.H. Fan, J.L. Yue, and Y. Liu, Enhanced low-frequency microwave absorption performance of FeNi alloy coated carbon foam assisted by SiO₂ layer, Appl. Surf. Sci., 600(2022), art. No. 154046.

[[56]] X.Y. Deng, S. Gao, Y. Liu, Y.L. Bao, Y.F. Zhu, and Y.Q. Fu, Cellular-like sericin-derived carbon decorated reduced graphene oxide for tunable microwave absorption, Appl. Surf. Sci., 599(2022), art. No. 154063.

[[57]] Y.L. Hou, Z.Z. Sheng, C. Fu, J. Kong, and X.T. Zhang, Hygroscopic holey graphene aerogel fibers enable highly efficient moisture capture, heat allocation and microwave absorption, Nat. Commun., 13(2022), No. 1, art. No. 1227.

[[58]] Fang JF, Lv HL, Zhao B, et al.. Selective assembly of magnetic nano-antenna for electromagnetic dissipation. J. Mater. Chem. A, 2022, 10(20): 10909,

[[59]] Liu Y, Jia ZR, Zhan QQ, Dong YH, Xu QM, Wu GL. Magnetic manganese-based composites with multiple loss mechanisms towards broadband absorption. Nano Res., 2022, 15(6): 5590,

[[60]] Mao WJ, Wang XT, Hu XL, Lin ZH, Su ZM. Activation of peroxymonosulfate by co-metal–organic frameworks as catalysts for degradation of organic pollutants. Ind. Eng. Chem. Res., 2021, 60(36): 13223,

[[61]] Wang Y, Gao YN, Yue TN, Chen XD, Che RC, Wang M. Liquid metal coated copper micro-particles to construct core-shell structure and multiple heterojunctions for high-efficiency microwave absorption. J. Colloid Interface Sci., 2022, 607: 210,

[[62]] J.N. Hu, C.Y. Liang, J.D. Li, et al., Flexible reduced graphene oxide@Fe₃O₄/silicone rubber composites for enhanced microwave absorption, Appl. Surf. Sci., 570(2021), art. No. 151270.

[[63]] L. Chai, Y.Q. Wang, Z.R. Jia, et al., Tunable defects and interfaces of hierarchical dandelion-like NiCo₂O₄ via Ostwald ripening process for high-efficiency electromagnetic wave absorption, Chem. Eng. J., 429(2022), art. No. 132547.

[[64]] X. Luo, H.F. Li, J.H. Sun, et al., EM waves absorption properties of nitrogenous porous carbon derived from PANI fiber clusters carbonization, Microporous Mesoporous Mater., 339(2022), art. No. 112000.

[[65]] Wang YY, Zhu JL, Li N, et al.. Carbon aerogel microspheres with in situ mineralized TiO₂ for efficient microwave absorption. Nano Res., 2022, 15(8): 7723,

[[66]] Liang J, Li CW, Cao X, et al.. Hollow hydrangea-like nitrogen-doped NiO/Ni/carbon composites as lightweight and highly efficient electromagnetic wave absorbers. Nano Res., 2022, 15(8): 6831,

[[67]] J. Liu, Y.S. Gu, L.L. Gao, et al., Hollow multi-shell SiC@C@PANI nanoparticles with broadband microwave absorption performance, Appl. Surf. Sci., 613(2023), art. No. 156098.

[[68]] Li ZX, Yang W, Jiang B, et al.. Engineering of the core-shell boron Nitride@Nitrogen-doped carbon heterogeneous interface for efficient heat dissipation and electromagnetic wave absorption. ACS Appl. Mater. Interfaces, 2023, 15(5): 7578,

[[69]] Zhai NX, Luo JH, Shu PC, Mei J, Li XP, Yan WX. 1D/2D CoTe₂@MoS₂ composites constructed by CoTe₂ nanorods and MoS₂ nanosheets for efficient electromagnetic wave absorption. Nano Res., 2023, 16(7): 10698,