New process for treating boron-bearing iron ore by flash reduction coupled with magnetic separation

Qipeng Bao, Lei Guo, Hong Yong Sohn, Haibin Zuo, Feng Liu, Yongliang Gao, Zhancheng Guo

International Journal of Minerals, Metallurgy, and Materials ›› 2024, Vol. 31 ›› Issue (3) : 473-484. DOI: 10.1007/s12613-023-2756-9
Research Article

New process for treating boron-bearing iron ore by flash reduction coupled with magnetic separation

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Abstract

Boron is an important industrial raw material often sourced from minerals containing different compounds that cocrystallize, which makes it difficult to separate the mineral phases through conventional beneficiation. This study proposed a new treatment called flash reduction-melting separation (FRMS) for boron-bearing iron concentrates. In this method, the concentrates were first flash-reduced at the temperature under which the particles melt, and the slag and the reduced iron phases disengaged at the particle scale. Good reduction and melting effects were achieved above 1550°C. The B2O3 content in the separated slag was over 18wt%, and the B content in the iron was less than 0.03wt%. The proposed FRMS method was tested to investigate the effects of factors such as ore particle size and temperature on the reduction and melting steps with and without pre-reducing the raw concentrate. The mineral phase transformation and morphology evolution in the ore particles during FRMS were also comprehensively analyzed.

Keywords

ludwigite / boron-bearing iron concentrate / flash reduction / melting separation / boron

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Qipeng Bao, Lei Guo, Hong Yong Sohn, Haibin Zuo, Feng Liu, Yongliang Gao, Zhancheng Guo. New process for treating boron-bearing iron ore by flash reduction coupled with magnetic separation. International Journal of Minerals, Metallurgy, and Materials, 2024, 31(3): 473‒484 https://doi.org/10.1007/s12613-023-2756-9

References

[[1]]
Fu XJ, Zhao JQ, Chen SY, Liu ZG, Guo TL, Chu MS. Comprehensive utilization of ludwigite ore based on metallizing reduction and magnetic separation. J. Iron Steel Res. Int., 2015, 22(8): 672,
CrossRef Google scholar
[[2]]
Chabak YG, Shimizu K, Efremenko VG, et al.. Microstructure and phase elemental distribution in high-boron multi-component cast irons. Int. J. Miner. Metall. Mater., 2022, 29(1): 78,
CrossRef Google scholar
[[3]]
G.J. Cheng, X.Z. Liu, H. Yang, X.X. Xue, and L.J. Li, Sintering and smelting property investigations of ludwigite, Processes, 10(2022), No. 1, art. No. 159.
[[4]]
Dai B, Long H, Wen Y, Ji Y. Effect of ludwigite (B2O3) on high Al2O3 slag and its mechanism used as a new blast furnace welding flux. Metalurgija, 2020, 59(4): 455
[[5]]
Wang G, Wang JS, Ding YG, Ma S, Xue QG. New separation method of boron and iron from ludwigite based on carbon bearing pellet reduction and melting technology. ISIJ Int., 2012, 52(1): 45,
CrossRef Google scholar
[[6]]
Huang WJ, Jiang T, Liu YJ, Guo TL. Mineralogical properties of ludwigite and the effects of microwave radiation on its particle characteristics and mineral liberation properties. J. Microw. Power Electromagn. Energy, 2022, 56(2): 124
[[7]]
Y.J. Liu, T. Jiang, C.H. Liu, W.J. Huang, J.P. Wang, and X.X. Xue, Effect of microwave pre-treatment on the magnetic properties of Ludwigite and its implications on magnetic separation, Metall. Res. Technol., 116(2019), No. 1, art. No. 107.
[[8]]
Wang G. . Fundamental Research on Comprehensive Utilization of Boron-bearing Iron Concentrate by Coal-Based Reduction and Melting Separation, 2016 Beijing University of Science and Technology Beijing [Dissertation]
[[9]]
Huang WJ, Liu YJ. Effect of microwave radiation on the magnetic properties of ludwigite and iron-boron separation. J. Microw. Power Electromagn. Energy, 2021, 55(2): 93
[[10]]
Liu YJ, Jiang T, Huang WJ, Liu CH, Wang JP, Xue XX. High temperature dielectric properties of ludwigite and its effect on microwave heating process. J. Microw. Power Electromagn. Energy, 2019, 53(3): 195
[[11]]
Fu X, Chu M, Gao L, Liu Z. Mechanism and kinetics studies on non-isothermal decomposition of ludwigite in inert atmosphere. Arch. Metall. Mater., 2018, 63: 1217,
CrossRef Google scholar
[[12]]
Zhu ZP, You JX, Zhang X, et al.. Recycling excessive alkali from reductive soda ash roasted ludwigite ore: Toward a zero-waste approach. ACS Sustainable Chem. Eng., 2020, 8(13): 5317,
CrossRef Google scholar
[[13]]
X. Zhang, G.H. Li, J.X. You, et al., Extraction of boron from ludwigite ore: Mechanism of soda-ash roasting of lizardite and szaibelyite, Minerals, 9(2019), No. 9, art. No. 533.
[[14]]
G.H. Li, L. Fang, X. Zhang, et al., Utilization of the MgO-rich residue originated from ludwigite ore: Hydrothermal synthesis of MHSH whiskers, Minerals, 7(2017), No. 8, art. No. 138.
[[15]]
Liang BJ, Li GH, Rao MJ, Peng ZW, Zhang YB, Jiang T. Water leaching of boron from soda-ash-activated ludwigite ore. Hydrometallurgy, 2017, 167: 101,
CrossRef Google scholar
[[16]]
L. Ye, Z.W. Peng, R. Tian, et al., A novel process for highly efficient separation of boron and iron from ludwigite ore based on low-temperature microwave roasting, Powder Technol., 410(2022), art. No. 117848.
[[17]]
Fu XJ, Chu MS, Gao LH, Liu ZG. Stepwise recovery of magnesium from low-grade ludwigite ore based on innovative and clean technological route. Trans. Nonferrous Met. Soc. China, 2018, 28(11): 2383,
CrossRef Google scholar
[[18]]
Li GH, Liang BJ, Rao MJ, Zhang YB, Jiang T. An innovative process for extracting boron and simultaneous recovering metallic iron from ludwigite ore. Miner. Eng., 2014, 56: 57,
CrossRef Google scholar
[[19]]
Huang GX, Zhen CL, Zhang JC, Liang GQ. Industrial test research of magnesia pellet production with addition of boric magnesium iron concentrate. Sintering Pelletizing, 2016, 41(6): 48
[[20]]
Wang G, Xue QG, Wang JS. Effect of Na2CO3 on reduction and melting separation of ludwigite/coal composite pellet and property of boron-rich slag. Trans. Nonferrous Met. Soc. China, 2016, 26(1): 282,
CrossRef Google scholar
[[21]]
Wang G, Xue QG, Wang JS. Carbothermic reduction characteristics of ludwigite and boron-iron magnetic separation. Int. J. Miner. Metall. Mater., 2018, 25(9): 1000,
CrossRef Google scholar
[[22]]
Wang G, Xue QG, Wang JS. Volume shrinkage of ludwigite/coal composite pellet during isothermal and non-isothermal reduction. Thermochim. Acta, 2015, 621: 90,
CrossRef Google scholar
[[23]]
You JX, Wang J, Rao MJ, et al.. An integrated and efficient process for borax preparation and magnetite recovery from soda-ash roasted ludwigite ore under CO-CO2-N2 atmosphere. Int. J. Miner. Metall. Mater., 2023, 30(11): 2169,
CrossRef Google scholar
[[24]]
Choi ME, Sohn HY. Development of green suspension ironmaking technology based on hydrogen reduction of iron oxide concentrate: Rate measurements. Ironmaking Steelmaking, 2010, 37(2): 81,
CrossRef Google scholar
[[25]]
Guo L, Gao JT, Zhong YW, Guo ZC. Flash suspension reduction of ultra-fine Fe2O3 powders and the kinetic analyzing. ISIJ Int., 2015, 55(9): 1797,
CrossRef Google scholar
[[26]]
Chen ZY, Zeilstra C, van der Stel J, Sietsma J, Yang YX. Reduction mechanism of fine hematite ore particles in suspension. Metall. Mater. Trans. B, 2021, 52(4): 2239,
CrossRef Google scholar
[[27]]
Wang XN, Fu GQ, Li W, Zhu MY. Numerical simulation and optimization of flash reduction of iron ore particles with hydrogen-rich gases. Powder Technol., 2020, 366: 587,
CrossRef Google scholar
[[28]]
B.J. Cheng, J. Xiong, M. Li, Y. Feng, W.Y. Hou, and H.S. Li, Numerical investigation into gas-particle inter-phase combustion and reduction in the flash ironmaking process, Metals, 10(2020), No. 6, art. No. 711.
[[29]]
Abolpour B, Afsahi MM, Soltani Goharrizi A, Azizkarimi M. Investigation of in-flight reduction of magnetite concentrate by hydrogen. Ironmaking Steelmaking, 2019, 46(5): 443,
CrossRef Google scholar
[[30]]
H.J. Lee, C.K. Choi, and S.H. Lee, Local heating effect on thermal Marangoni flow and heat transfer characteristics of an evaporating droplet, Int. J. Heat Mass Transf., 195(2022), art. No. 123206.
[[31]]
Wang CP, Liu XJ, Ohnuma I, Kainuma R, Ishida K. Formation of immiscible alloy powders with egg-type microstructure. Science, 2002, 297(5583): 990,
CrossRef Pubmed Google scholar
[[32]]
Bao QP, Guo L, Guo ZC. A novel direct reduction-flash smelting separation process of treating high phosphorous iron ore fines. Powder Technol., 2021, 377: 149,
CrossRef Google scholar
[[33]]
Yang YR, Bao QP, Guo L, Wang Z, Guo ZC. Numerical simulation of flash reduction in a drop tube reactor with variable temperatures. Int. J. Miner. Metall. Mater., 2022, 29(2): 228,
CrossRef Google scholar

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