Growth kinetics of titanium carbide coating by molten salt synthesis process on graphite sheet surface

Abstract

The synthesis of carbide coatings on graphite substrates using molten salt synthesis (MSS), has garnered significant interest due to its cost-effective nature. This study investigates the reaction process and growth kinetics involved in MSS, shedding light on key aspects of the process. The involvement of Ti powder through liquid-phase mass transfer is revealed, where the diffusion distance and quantity of Ti powder play a crucial role in determining the reaction rate by influencing the C content gradient on both sides of the carbide. Furthermore, the growth kinetics of the carbide coating are predominantly governed by the diffusion behavior of C within the carbide layer, rather than the chemical reaction rate. To analyze the kinetics, the thickness of the carbide layer is measured with respect to heat treatment time and temperature, unveiling a parabolic relationship within the temperature range of 700–1300°C. The estimated activation energy for the reaction is determined to be 179283 J·mol⁻¹. These findings offer valuable insights into the synthesis of carbide coatings via MSS, facilitating their optimization and enhancing our understanding of their growth mechanisms and properties for various applications.

Keywords

titanium carbide / graphite / molten salt / kinetic analysis

References

[[1]] Wang PP, Chen GQ, Li WJ, et al.. Microstructural evolution and thermal conductivity of diamond/Al composites during thermal cycling. Int. J. Miner. Metall. Mater., 2021, 28(11): 1821,

[[2]] Zhang HD, Zhang JJ, Liu Y, Zhang F, Fan TX, Zhang D. Unveiling the interfacial configuration in diamond/Cu composites by using statistical analysis of metallized diamond surface. Scripta Mater., 2018, 152: 84,

[[3]] Hu ZF, Tong YC, Wang M, Xu JB, Yang C. Rapid and low-cost carbon/carbon composites by using graphite slurry impregnated prepregs. J. Eur. Ceram. Soc., 2023, 43(10): 4363,

[[4]] Chand S. Review carbon fibers for composites. J. Mater. Sci., 2000, 35(6): 1303,

[[5]] Das TK, Ghosh P, Das NC. Preparation, development, outcomes, and application versatility of carbon fiber-based polymer composites: A review. Adv. Compos. Hybrid Mater., 2019, 2(2): 214,

[[6]] Zhang S, Lee WE. Carbon containing castables: Current status and future prospects. Br. Ceram. Trans., 2002, 101(1): 1,

[[7]] de Oliveira IR, Studart AR, Pandolfelli VC, Menegazzo BA. Zero-cement refractory castables. Am. Ceram. Soc. Bull., 2002, 81(12): 27

[[8]] Harussani MM, Sapuan SM, Nadeem G, Rafin T, Kirubaanand W. Recent applications of carbon-based composites in defence industry: A review. Def. Technol., 2022, 18(8): 1281,

[[9]] M. Yang, Y. Liu, T.X. Fan, and D. Zhang, Metal-graphene interfaces in epitaxial and bulk systems: A review, Prog. Mater. Sci., 110(2020), art. No. 100652.

[[10]] Fan TX, Liu Y, Yang KM, Song J, Zhang D. Recent progress on interfacial structure optimization and their influencing mechanism of carbon reinforced metal matrix composites. Acta Metall. Sin., 2019, 55(1): 16

[[11]] J. Song, S.S. Yao, Q. Li, et al., Reorientation mechanisms of graphene coated copper{001 surfaces}, Metals, 13(2023), No. 5, art. No. 910.

[[12]] Verdon C, Szwedek O, Jacques S, Allemand A, Le Petitcorps Y. Hafnium and silicon carbide multilayer coatings for the protection of carbon composites. Surf. Coat. Technol., 2013, 230: 124,

[[13]] Bacos MP. Carbon-carbon composites: Oxidation behavior and coatings protection. J. Phys. IV, 1993, 3(C7): C7-1895

[[14]] Friedrich C, Gadow R, Speicher M. Protective multilayer coatings for carbon-carbon composites. Surf. Coat. Technol., 2002, 151–152: 405,

[[15]] Liu ZL, Deng CJ, Yu C, Ding J, Zhu HX. Improving the anti-oxidation and water wettability of graphite through the design of coating structure for the preparation of Al₂O₃–SiC–C castables. Ceram. Int., 2023, 49(17): 29104,

[[16]] Kuang CL, Wang X, Liu ZL, et al.. Nanocrystalline ZrC coated graphite and its effect on mechanical properties and thermal shock resistance of low-carbon Al₂O₃–C refractories. Ceram. Int., 2022, 48(22): 33926,

[[17]] Yang X, Huang QZ, Su ZA, et al.. Resistance to oxidation and ablation of SiC coating on graphite prepared by chemical vapor reaction. Corros. Sci., 2013, 75: 16,

[[18]] Zhu P, Wang PP, Shao PZ, et al.. Research progress in interface modification and thermal conduction behavior of diamond/metal composites. Int. J. Miner. Metall. Mater., 2022, 29(2): 200,

[[19]] Liu XY, Sun FY, Wang W, et al.. Effect of chromium inter-layer thickness on interfacial thermal conductance across copper/diamond interface. Int. J. Miner. Metall. Mater., 2022, 29(11): 2020,

[[20]] Liu GY, Hou FG, Peng SL, Wang XD, Fang BZ. Process and challenges of stainless steel based bipolar plates for proton exchange membrane fuel cells. Int. J. Miner. Metall. Mater., 2022, 29(5): 1099,

[[21]] Z. Liu, W. Cheng, D.K. Mu, et al., Influences of early-stage C diffusion on growth microstructures in solid-state interface reaction between CVD diamond and sputtered Cr, Mater. Charact., 196(2023), art. No. 112603.

[[22]] Wang HQ, Wang LT, Zhang HY. The study of TiC/C composite fiber by chemical vapor deposition. Appl. Mech. Mater., 2011, 69: 99,

[[23]] Rubshtein AP, Vladimirov AB, Korkh YV, Ponosov YS, Plotnikov SA. The composition, structure and surface properties of the titanium-carbon coatings prepared by PVD technique. Surf. Coat. Technol., 2017, 309: 680,

[[24]] Chen NQ, Li Q, Ma YC, et al.. Significant strengthening of copper-based composites using boron nitride nanotubes. Int. J. Miner. Metall. Mater., 2023, 30(9): 1764,

[[25]] Y. Huang, J.M. Ni, X.Y. Shi, et al. Two-step thermal transformation of multilayer graphene using polymeric carbon source assisted by physical vapor deposited copper, Meterials, 16(2023), No. 16, art. No. 5603.

[[26]] Liu X, Zhang S. Low-temperature preparation of titanium carbide coatings on graphite flakes from molten salts. J. Am. Ceram. Soc., 2008, 91(2): 667,

[[27]] Liu XG, Wang ZF, Zhang SW. Molten salt synthesis and characterization of titanium carbide-coated graphite flakes for refractory castable applications. Int. J. Appl. Ceram. Technol., 2011, 8(4): 911,

[[28]] Ding J, Guo D, Deng CJ, Zhu HX, Yu C. Low-temperature synthesis of nanocrystalline ZrC coatings on flake graphite by molten salts. Appl. Surf. Sci., 2017, 407: 315,

[[29]] Masoudifar S, Bavand-Vandchali M, Golestani-Fard F, Nemati A. Molten salt synthesis of a SiC coating on graphite flakes for application in refractory castables. Ceram. Int., 2016, 42(10): 11951,

[[30]] Dong ZJ, Li XK, Yuan GM, et al.. Fabrication of protective tantalum carbide coatings on carbon fibers using a molten salt method. Appl. Surf. Sci., 2008, 254(18): 5936,

[[31]] S. Suasmoro, F.A.R. Wati, and N. Muhaimin, Ti-Zr coating on graphite through powder immersion reaction-assisted coating (PIRAC) and its oxidation kinetics at T =1000°C, Bull. Mater. Sci., 42(2019), No. 3, art. No. 126.

[[32]] L.H. Wang, J.W. Li, L.Y. Gao, et al., Gradient interface formation in Cu–Cr/diamond(Ti) composites prepared by gas pressure infiltration, Vacuum, 206(2022), art. No. 111549.

[[33]] L. Constantin, L. Fan, M. Pouey, et al., Spontaneous formation of multilayer refractory carbide coatings in a molten salt media, PNAS, 118(2021), No. 18, art. No. e2100663118.

[[34]] Behboudi F, Kakroudi MG, Vafa NP, Faraji M, Milani SS. Molten salt synthesis of in situ TiC coating on graphite flakes. Ceram. Int., 2021, 47(6): 8161,

[[35]] Xi XL, Feng M, Zhang LW, Nie ZR. Applications of molten salt and progress of molten salt electrolysis in secondary metal resource recovery. Int. J. Miner. Metall. Mater., 2020, 27(12): 1599,

[[36]] J.T. Wang, X.Q. Kan, Z.L. Liu, et al., Low-temperature and efficient preparation of starfish-like Mo₂C/C composites from waste biomass, J. Phys. Chem. Solids, 181(2023), art. No. 111522.

[[37]] M.E. Straumanis, S.T. Shih, and A.W. Schlechten, The mechanism of deposition of titanium coatings from fused salt baths, J. Electrochem. Soc., 104(1957), No. 1, art. No. 17.

[[38]] Miriyev A, Sinder M, Frage N. Thermal stability and growth kinetics of the interfacial TiC layer in the Ti alloy/carbon steel system. Acta Mater., 2014, 75: 348,

[[39]] De Barros MI, Rats D, Vandenbulcke L, Farges G. Influence of internal diffusion barriers on carbon diffusion in pure titanium and Ti–6Al–4V during diamond deposition. Diam. Relat. Mater., 1999, 8(6): 1022,

[[40]] Kōyama K, Hashimoto Y, Ōmori SI. Diffusion of carbon in TiC. Trans. JIM, 1975, 16(4): 211,