Recent advances and perspectives of zinc metal-free anodes for zinc ion batteries

Abstract

Zinc-ion batteries (ZIBs) are recognized as potential energy storage devices due to their advantages of low cost, high energy density, and environmental friendliness. However, zinc anodes are subject to unavoidable zinc dendrites, passivation, corrosion, and hydrogen evolution reactions during the charging and discharging of batteries, becoming obstacles to the practical application of ZIBs. Appropriate zinc metal-free anodes provide a higher working potential than metallic zinc anodes, effectively solving the problems of zinc dendrites, hydrogen evolution, and side reactions during the operation of metallic zinc anodes. The improvement in the safety and cycle life of batteries creates conditions for further commercialization of ZIBs. Therefore, this work systematically introduces the research progress of zinc metal-free anodes in “rocking chair” ZIBs. Zinc metal-free anodes are mainly discussed in four categories: transition metal oxides, transition metal sulfides, MXene (two dimensional transition metal carbide) composites, and organic compounds, with discussions on their properties and zinc storage mechanisms. Finally, the outlook for the development of zinc metal-free anodes is proposed. This paper is expected to provide a reference for the further promotion of commercial rechargeable ZIBs.

Keywords

zinc ion batteries / anode / zinc metal-free anode / recent advances / perspectives

References

[[1]] Dunn B, Kamath H, Tarascon JM. Electrical energy storage for the grid: A battery of choices. Science, 2011, 334(6058): 928,

[[2]] Winter M, Brodd RJ. What are batteries, fuel cells, and su-percapacitors?. Chem. Rev., 2004, 104(10): 4245,

[[3]] Larcher D, Tarascon JM. Towards greener and more sustainable batteries for electrical energy storage. Nat. Chem., 2015, 7(1): 19,

[[4]] Goodenough JB, Kim Y. Challenges for rechargeable Li batteries. Chem. Mater., 2010, 22(3): 587,

[[5]] Tarascon JM, Armand M. Issues and challenges facing rechargeable lithium batteries. Nature, 2001, 414(6861): 359,

[[6]] X. Guo, J. Zhou, C.L. Bai, X.K. Li, G.Z. Fang, and S.Q. Liang, Zn/MnO₂ battery chemistry with dissolution-deposition mechanism, Mater. Today Energy, 16(2020), art. No. 100396.

[[7]] Wen RY, Gao ZH, Luo L, et al.. Sandwich-structured electrospun all-fluoropolymer membranes with thermal shut-down function and enhanced electrochemical performance. Nanocomposites, 2022, 8(1): 64,

[[8]] Chao DL, Zhou WH, Ye C, et al.. An electrolytic Zn–MnO₂ battery for high-voltage and scalable energy storage. Angew. Chem. Int. Ed., 2019, 58(23): 7823,

[[9]] Wang F, Borodin O, Gao T, et al.. Highly reversible zinc metal anode for aqueous batteries. Nat. Mater., 2018, 17(6): 543,

[[10]] Song Y, Ruan PC, Mao CW, et al.. Metal-organic frameworks functionalized separators for robust aqueous zinc-ion batteries. Nano Micro Lett., 2022, 14(1): 1,

[[11]] Qin HG, Chen LL, Wang LM, Chen X, Yang ZH. V₂O₅ hollow spheres as high rate and long life cathode for aqueous rechargeable zinc ion batteries. Electrochim. Acta, 2019, 306: 307,

[[12]] M.Y. Yan, P. He, Y. Chen, et al., Water-lubricated intercalation in V₂O₅nH₂O for high-capacity and high-rate aqueous rechargeable zinc batteries, Adv. Mater., 30(2018), No. 1, art. No. 1703725.

[[13]] Zhang N, Chen XY, Yu M, Niu ZQ, Cheng FY, Chen J. Materials chemistry for rechargeable zinc-ion batteries. Chem. Soc. Rev., 2020, 49(13): 4203,

[[14]] K.Y. Zhu, T. Wu, and K. Huang, NaCa_0.6V₆O_1.6·3H₂O as an ultra-stable cathode for Zn-ion batteries: The roles of pre-inserted dual-cations and structural water in V₃O₈ layer, Adv. Energy Mater., 9(2019), No. 38, art. No. 1901968.

[[15]] L. Cheng, J.W. Chen, Y. Yan, et al., Metal organic frameworks derived active functional groups decorated manganese monoxide for aqueous zinc ion battery, Chem. Phys. Lett., 778(2021), art. No. 138772.

[[16]] S.Y. Li, D.X. Yu, L.N. Liu, et al., In-situ electrochemical induced artificial solid electrolyte interphase for MnO@C nano-composite enabling long-lived aqueous zinc-ion batteries, Chem. Eng. J., 430(2022), art. No. 132673.

[[17]] W.J. Li, X. Gao, Z.Y. Chen, et al., Electrochemically activated MnO cathodes for high performance aqueous zinc-ion battery, Chem. Eng. J., 402(2020), art. No. 125509.

[[18]] T.S. Zhang, Y. Tang, G.Z. Fang, et al., Electrochemical activation of manganese-based cathode in aqueous zinc-ion electrolyte, Adv. Funct. Mater., 30(2020), No. 30, art. No. 2002711.

[[19]] X.H. Chen, P.C. Ruan, X.W. Wu, S.Q. Liang, and J.A. Zhou, Crystal structures, reaction mechanisms, and optimization strategies of MnO₂ cathode for aqueous rechargeable zinc batteries, Acta Phys. Chim. Sin., 38(2022), No. 12, art. No. 2111003.

[[20]] Selvakumaran D, Pan AQ, Liang SQ, Cao GZ. A review on recent developments and challenges of cathode materials for rechargeable aqueous Zn-ion batteries. J. Mater. Chem. A, 2019, 7(31): 18209,

[[21]] Zampardi G, La Mantia F. Prussian blue analogues as aqueous Zn-ion batteries electrodes: Current challenges and future perspectives. Curr. Opin. Electrochem., 2020, 21: 84,

[[22]] Zeng YX, Lu XF, Zhang SL, Luan DY, Li S, Lou XW. Construction of Co–Mn Prussian blue analog hollow spheres for efficient aqueous Zn-ion batteries. Angew. Chem. Int. Ed, 2021, 60(41): 22189,

[[23]] L.N. Chen, Q.Y. An, and L.Q. Mai, Recent advances and prospects of cathode materials for rechargeable aqueous zinc-ion batteries, Adv. Mater. Interfaces, 6(2019), No. 17, art. No. 1900387.

[[24]] Geng YF, Pan L, Peng ZY, et al.. Electrolyte additive engineering for aqueous Zn ion batteries. Energy Storage Mater., 2022, 51: 733,

[[25]] Li B, Zhang XT, Wang TT, et al.. Interfacial engineering strategy for high-performance Zn metal anodes. Nano Micro Lett., 2021, 14(1): 1,

[[26]] Wang TT, Li CP, Xie XS, et al.. Anode materials for aqueous zinc ion batteries: Mechanisms, properties, and perspectives. ACS Nano, 2020, 14(12): 16321,

[[27]] Zhang Q, Luan JY, Tang YG, Ji XB, Wang HY. Interfacial design of dendrite-free zinc anodes for aqueous zinc-ion batteries. Angew. Chem. Int. Ed., 2020, 59(32): 13180,

[[28]] H.M. Yu, Y.J. Chen, H. Wang, et al., Engineering multi-functionalized molecular skeleton layer for dendrite-free and durable zinc batteries, Nano Energy, 99(2022), art. No. 107426.

[[29]] Hong L, Wu XM, Wang LY, et al.. Highly reversible zinc anode enabled by a cation-exchange coating with Zn-ion selective channels. ACS Nano, 2022, 16(4): 6906,

[[30]] Du WC, Ang EH, Yang Y, Zhang YF, Ye MH, Li CC. Challenges in the material and structural design of zinc anode towards high-performance aqueous zinc-ion batteries. Energy Environ. Sci., 2020, 13(10): 3330,

[[31]] N. Guo, W.J. Huo, X.Y. Dong, et al., A review on 3D zinc anodes for zinc ion batteries, Small Methods, 6(2022), No. 9, art. No. e2200597.

[[32]] Li RT, Du YX, Li YH, et al.. Alloying strategy for high-performance zinc metal anodes. ACS Energy Lett., 2023, 8(1): 457,

[[33]] B.T. Liu, S.J. Wang, Z.L. Wang, H. Lei, Z.T. Chen, and W.J. Mai, Novel 3D nanoporous Zn–Cu alloy as long-life anode toward high-voltage double electrolyte aqueous zinc-ion batteries, Small, 16(2020), No. 22, art. No. e2001323.

[[34]] Liu C, Luo Z, Deng WT, et al.. Liquid alloy interlayer for aqueous zinc-ion battery. ACS Energy Lett., 2021, 6(2): 675,

[[35]] Zhang Q, Luan JY, Fu L, et al.. The three-dimensional dendrite-free zinc anode on a copper mesh with a zinc-oriented poly-acrylamide electrolyte additive. Angew. Chem. Int. Ed., 2019, 58(44): 15841,

[[36]] Zhang YM, Howe JD, Ben-Yoseph S, Wu YT, Liu N. Unveiling the origin of alloy-seeded and nondendritic growth of Zn for rechargeable aqueous Zn batteries. ACS Energy Lett., 2021, 6(2): 404,

[[37]] Sun P, Ma L, Zhou WH, et al.. Simultaneous regulation on solvation shell and electrode interface for dendrite-free Zn ion batteries achieved by a low-cost glucose additive. Angew. Chem. Int. Ed., 2021, 60(33): 18247,

[[38]] H.J. Ji, Z.Q. Han, Y.H. Lin, et al., Stabilizing zinc anode for high-performance aqueous zinc ion batteries via employing a novel inositol additive, J. Alloys Compd., 914(2022), art. No. 165231.

[[39]] C.P. Li, X.S. Xie, H. Liu, et al., Integrated’ all-in-one’ strategy to stabilize zinc anodes for high-performance zinc-ion batteries, Natl. Sci. Rev., 9(2021), No. 3, art. No. nwab177.

[[40]] Xing ZY, Wang S, Yu AP, Chen ZW. Aqueous intercalation-type electrode materials for grid-level energy storage: Beyond the limits of lithium and sodium. Nano Energy, 2018, 50: 229,

[[41]] Kaveevivitchai W, Manthiram A. High-capacity zinc-ion storage in an open-tunnel oxide for aqueous and nonaqueous Zn-ion batteries. J. Mater. Chem. A, 2016, 4(48): 18737,

[[42]] Chae MS, Heo JW, Lim SC, Hong ST. Electrochemical zinc-ion intercalation properties and crystal structures of ZnMo₆S₈ and Zn₂Mo₆S₈ chevrel phases in aqueous electrolytes. Inorg. Chem., 2016, 55(7): 3294,

[[43]] W. Li, K.L. Wang, S.J. Cheng, and K. Jiang, An ultrastable presodiated titanium disulfide anode for aqueous “rocking-chair” zinc ion battery, Adv. Energy Mater., 9(2019), No. 27, art. No. 1900993.

[[44]] Yan LJ, Zeng XM, Li ZH, et al.. An innovation: Dendrite free quinone paired with ZnMn₂O₄ for zinc ion storage. Mater. Today Energy, 2019, 13: 323,

[[45]] Y. Yang, J.F. Xiao, J.Y. Cai, et al., Mixed-valence copper selenide as an anode for ultralong lifespan rocking-chair Zn-ion batteries: An insight into its intercalation/extraction kinetics and charge storage mechanism, Adv. Funct. Mater., 31(2021), No. 3, art. No. 2005092.

[[46]] W. Li, Y.S. Ma, P. Li, X.Y. Jing, K. Jiang, and D.H. Wang, Electrochemically activated Cu_2–xTe as an ultraflat discharge plateau, low reaction potential, and stable anode material for aqueous Zn-ion half and full batteries, Adv. Energy Mater., 11(2021), No. 42, art. No. 2102607.

[[47]] J. Cao, D.D. Zhang, Y.L. Yue, et al., Strongly coupled tungsten oxide/carbide heterogeneous hybrid for ultrastable aqueous rocking-chair zinc-ion batteries, Chem. Eng. J., 426(2021), art. No. 131893.

[[48]] B. Wang, J.P. Yan, Y.F. Zhang, M.H. Ye, Y. Yang, and C.C. Li, In situ carbon insertion in laminated molybdenum dioxide by interlayer engineering toward ultrastable “rocking-chair” zinc-ion batteries, Adv. Funct. Mater., 31(2021), No. 30, art. No. 2102827.

[[49]] Zhang Q, Duan TF, Xiao MJ, et al.. BiOI nanopaper As a high-capacity, long-life and insertion-type anode for a flexible quasi-solid-state Zn-ion battery. ACS Appl. Mater. Interfaces, 2022, 14(22): 25516,

[[50]] X. Wang, Y.M. Wang, Y.P. Jiang, et al., Tailoring ultrahigh energy density and stable dendrite-free flexible anode with Ti₃C₂T_x MXene nanosheets and hydrated ammonium vanadate nanobelts for aqueous rocking-chair zinc ion batteries, Adv. Funct. Mater., 31(2021), No. 35, art. No. 2103210.

[[51]] Xiong T, Zhang YX, Wang YM, Lee WSV, Xue JM. Hexagonal MoO₃ as a zinc intercalation anode towards zinc metal-free zinc-ion batteries. J. Mater. Chem. A, 2020, 8(18): 9006,

[[52]] Zhu YP, Cui Y, Alshareef HN. An anode-free Zn-MnO₂ battery. Nano Lett., 2021, 21(3): 1446,

[[53]] Y.Q. Jiang, K. Ma, M.L. Sun, Y.Y. Li, and J.P. Liu, All-climate stretchable dendrite-free Zn-ion hybrid supercapacitors enabled by hydrogel electrolyte engineering, Energy Environ. Mater., 6(2023), No. 2, art. No. e12357.

[[54]] K. Mao, J.J. Shi, Q.X. Zhang, Y et al., High-capacitance MXene anode based on Zn-ion pre-intercalation strategy for de-gradable micro Zn-ion hybrid supercapacitors, Nano Energy, 103(2022), art. No. 107791.

[[55]] Hao JN, Li XL, Zeng XH, Li D, Mao JF, Guo ZP. Deeply understanding the Zn anode behaviour and corresponding improvement strategies in different aqueous Zn-based batteries. Energy Environ. Sci., 2020, 13(11): 3917,

[[56]] H. Jia, Z.Q. Wang, B. Tawiah, et al., Recent advances in zinc anodes for high-performance aqueous Zn-ion batteries, Nano Energy, 70(2020), art. No. 104523.

[[57]] Lu WJ, Xie CX, Zhang HM, Li XF. Inhibition of zinc dendrite growth in zinc-based batteries. ChemSusChem, 2018, 11(23): 3996,

[[58]] Li CP, Xie XS, Liang SQ, Zhou J. Issues and future perspective on zinc metal anode for rechargeable aqueous zinc-ion batteries. Energy Environ. Mater., 2020, 3(2): 146,

[[59]] Z.Y. Xing, Y.Y. Sun, X.S. Xie, et al., Zincophilic electrode interphase with appended proton reservoir ability stabilizes Zn metal anodes, Angew. Chem. Int. Ed., 62(2023), No. 5, art. No. e202215324.

[[60]] Chen XF, Huang RS, Ding MY, He HB, Wang F, Yin SB. Hexagonal WO₃/3D porous graphene as a novel zinc intercalation anode for aqueous zinc-ion batteries. ACS Appl. Mater. Interfaces, 2022, 14(3): 3961,

[[61]] Yang BB, Qin T, Du YY, et al.. Rocking-chair proton battery based on a low-cost “water in salt” elecroolyte. Chem. Commun., 2022, 58(10): 1550,

[[62]] Cheng YW, Luo LL, Zhong L, et al.. Highly reversible zinc-ion intercalation into chevrel phase Mo6S8 nanocubes and applications for advanced zinc-ion batteries. ACS Appl. Mater. Interfaces, 2016, 8(22): 13673,

[[63]] M.S. Chae and S.T. Hong, Prototype system of rocking-chair Zn-ion battery adopting zinc chevrel phase anode and rhombo-hedral zinc hexacyanoferrate cathode, Batteries, 5(2019), No. 1, art. No. 3.

[[64]] Lv Z, Wang B, Ye M, Zhang Y, Yang Y, Li CC. Activating the stepwise intercalation-conversion reaction of layered copper sulfide toward extremely high capacity zinc-metal-free anodes for rocking-chair zinc-ion batteries. ACS Appl. Mater. Interfaces, 2022, 14(1): 1126,

[[65]] L. Wen, Y.N. Wu, S.L. Wang, et al., A novel TiSe₂ (de)inter-calation type anode for aqueous zinc-based energy storage, Nano Energy, 93(2022), art. No. 106896.

[[66]] Du YQ, Zhang BY, Kang RK, et al.. Practical conversion-type titanium telluride anodes for high-capacity long-lifespan rechargeable aqueous zinc batteries. J. Mater. Chem. A, 2022, 10(32): 16976,

[[67]] B.T. Zhao, S.L. Wang, Q.T. Yu, et al., A flexible, heat-resistant and self-healable “rocking-chair” zinc ion microbattery based on MXene-TiS₂ (de)intercalation anode, J. Power Sources, 504(2021), art. No. 230076.

[[68]] N.N. Liu, X. Wu, Y. Zhang, et al., Building high rate capability and ultrastable dendrite-free organic anode for rechargeable aqueous zinc batteries, Adv. Sci., 7(2020), No. 14, art. No. 2000146.

[[69]] Y. Liu, X.M. Zhou, X. Wang, et al., Hydrated titanic acid as an ultralow-potential anode for aqueous zinc-ion full batteries, Chem. Eng. J., 420(2021), art. No. 129629.

[[70]] S.L. Leng, X.Y. Sun, Y.C. Yang, and R.H. Zhang, Borophene as an anode material for Zn-ion batteries: A first-principles investigation, Mater. Res. Express, 6(2019), No. 8, art. No. 085504.