Evaluation of environmental geochemical signatures due to RO rejects on arid agricultural farms and tangible solutions

Harish Bhandary, Chidambaram Sabarathinam, Adnan Akber, Tariq Rashid, Dhanu Radha Samayamanthula, Yogeesha Jayaramu, Bedour Alsabti

Geoscience Frontiers ›› 2024, Vol. 15 ›› Issue (6) : 101929.

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Geoscience Frontiers ›› 2024, Vol. 15 ›› Issue (6) : 101929. DOI: 10.1016/j.gsf.2024.101929

Evaluation of environmental geochemical signatures due to RO rejects on arid agricultural farms and tangible solutions

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Abstract

The impact of reverse osmosis (RO) rejects in the groundwater presents a significant challenge in arid regions. This study collected groundwater samples, product water, and reverse osmosis brine (ROB) from evaporation ponds and analyzed them for major ions and trace elements. Test boreholes were drilled near the ROB site along the flow direction, and borehole sediment samples were collected. The samples were predominantly gravelly sand, and the depth to water level fluctuated around 30 m below ground level (bgl), with minerals mainly consisting of calcite, gypsum, and quartz. Data loggers reflected a rise in water level (<22 m bgl) corresponding to higher electrical conductivity (>16 mS/cm) during the cropping period in many locations, confirming the impact of ROB in groundwater. The results were further supported by enriched signatures of δ18O (∼ +1.5‰) and δ2H (∼ +15‰). The saturation index of the minerals reflected that carbonate minerals (Calcite > Dolomite) were saturated in the ROB relative to the groundwater. The vertical variation of mineral assemblages in the boreholes indicated gypsum precipitation in the capillary zone along with calcite and dolomite. The assemblage varies as the groundwater moves from the disposal site. The speciation of different compounds along the groundwater path indicated higher carbonate and sulfate species (CaCO3 > CaHCO3> CaSO4 > NaSO4 > MgSO4) near the disposal site, with variations along the flow direction. Considering the significant variation in temperature in the region (5 to 50 ℃), the water sample composition was modeled using PHREEQC, suggesting that the increase in temperature led to supersaturation of epsomite and gypsum compositions. The ROB was theoretically mixed with groundwater and product water in different proportions, and an optimum composition (10:90) for safe disposal was derived and tested fit for reuse in agriculture.

Keywords

Brine disposal / Groundwater / Geochemistry / Monitoring / Modeling / Recommendation

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Harish Bhandary, Chidambaram Sabarathinam, Adnan Akber, Tariq Rashid, Dhanu Radha Samayamanthula, Yogeesha Jayaramu, Bedour Alsabti. Evaluation of environmental geochemical signatures due to RO rejects on arid agricultural farms and tangible solutions. Geoscience Frontiers, 2024, 15(6): 101929 https://doi.org/10.1016/j.gsf.2024.101929

CRediT authorship contribution statement

Mohammed Musah: Conceptualization, Data curation, Formal analysis, Methodology. Stephen Taiwo Onifade: Conceptualization, Methodology, Supervision, Writing – original draft, Writing – review & editing. Elma Satrovic: Data curation, Writing – original draft, Visualization. Joseph Akwasi Nkyi: Writing – original draft.

Declaration of interests

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Appendix.

CS-ARDL model specifications

The study’s CS-ARDL models augmented with the lags of the cross-sectional averages of the input and output variables to account for cross-sectional dependence are specified as;
Interactive Model:(A1)lnEFPit=wi+j=1pyλijlnEFPit-j+j=0pxβ1jlnFGit-j+j=0pxβ2jlnGIit-j+j=0pxβ3jlnYit-j+j=0pxβ4jlnY2it-j+j=0pxβ5jlnNRRit-j+j=0pxδ1jlnFGGIit-j+j=0pγ1jlnEFP¯t-j+j=0pγ2jlnFG¯t-j+j=0pγ3jlnGI¯t-j+j=0pγ4jlnY¯t-j+j=0pγ5jlnY2¯t-j+j=0pγ6jlnNRR¯t-j+j=0pγ7jlnGIFG¯t-j+εitlnEFPit=wi+j=1pyλijlnEFPit-j+j=0pxβ1jlnFGit-j+j=0pxβ2jlnGIit-j+j=0pxβ3jlnYit-j+j=0pxβ4jlnY2it-j+j=0pxβ5jlnNRRit-j+j=0pxδ1jlnFGGIit-j+j=0pγ1jlnEFP¯t-j+j=0pγ2jlnFG¯t-j+j=0pγ3jlnGI¯t-j+j=0pγ4jlnY¯t-j+j=0pγ5jlnY2¯t-j+j=0pγ6jlnNRR¯t-j+j=0pγ7jlnGIFG¯t-j+εit
Nonlinear Model:(A2)lnEFPit=wi+j=1pyλijlnEFPit-j+j=0pxβ1jlnFGit-j+j=0pxβ2jlnGIit-j+j=0pxβ3jlnYit-j+j=0pxβ4jlnY2it-j+j=0pxβ5jlnNRRit-j+j=0pxπ1jlnFG2it-j+j=0pγ1jlnEFP¯t-j+j=0pγ2jlnFG¯t-j+j=0pγ3jlnGI¯t-j+j=0pγ4jlnY¯t-j+j=0pγ5jlnY2¯t-j+j=0pγ6jlnNRR¯t-j+j=0pγ7jlnFG2¯t-j+εitlnEFPit=wi+j=1pyλijlnEFPit-j+j=0pxβ1jlnFGit-j+j=0pxβ2jlnGIit-j+j=0pxβ3jlnYit-j+j=0pxβ4jlnY2it-j+j=0pxβ5jlnNRRit-j+j=0pxπ1jlnFG2it-j+j=0pγ1jlnEFP¯t-j+j=0pγ2jlnFG¯t-j+j=0pγ3jlnGI¯t-j+j=0pγ4jlnY¯t-j+j=0pγ5jlnY2¯t-j+j=0pγ6jlnNRR¯t-j+j=0pγ7jlnFG2¯t-j+εitwhere lnEFP¯lnEFP¯, lnFG¯lnFG¯, lnGI¯lnGI¯, lnY¯lnY¯, lnY2¯,lnNRR¯lnY2¯,lnNRR¯, lnGIFG¯lnGIFG¯, and lnFG2¯lnFG2¯ are the cross-sectional means of the endogenous and exogenous series correspondingly.

CCEMG model specifications

In the CCEMG procedure, the estimated model is augmented with cross-sectional averages of the regressors to account for cross-sectional correlations. Our study’s augmented CCEMG models to control for cross-sectional dependence are specified as;
Interactive Model:(A3)lnEFPit=α0+β1lnFGit+β2lnGIit+β3lnYit+β4lnY2it+β5lnNRRit+δ1lnGIFGit+ψ1lnFGit¯+ψ2lnGIit¯+ψ3lnYit¯+ψ4lnY2it¯+ψ5lnNRRit¯+ψ6lnGIFGit¯+εitlnEFPit=α0+β1lnFGit+β2lnGIit+β3lnYit+β4lnY2it+β5lnNRRit+δ1lnGIFGit+ψ1lnFGit¯+ψ2lnGIit¯+ψ3lnYit¯+ψ4lnY2it¯+ψ5lnNRRit¯+ψ6lnGIFGit¯+εit
Nonlinear Model:(A4)lnEFPit=α0+β1lnFGit+β2lnGIit+β3lnYit+β4lnY2it+β5lnNRRit+π1lnFG2it+Ω1lnFGit¯+Ω2lnGIit¯+Ω3lnYit¯+Ω4lnY2it¯+Ω5lnNRRit¯+Ω6lnFG2it¯+εitlnEFPit=α0+β1lnFGit+β2lnGIit+β3lnYit+β4lnY2it+β5lnNRRit+π1lnFG2it+Ω1lnFGit¯+Ω2lnGIit¯+Ω3lnYit¯+Ω4lnY2it¯+Ω5lnNRRit¯+Ω6lnFG2it¯+εitFrom the above equations lnFGit¯lnFGit¯, lnGIit¯lnGIit¯, lnYit¯lnYit¯, lnY2it,¯lnY2it,¯ lnNRRit¯lnNRRit¯, lnGIFGit¯lnGIFGit¯, and lnFG2it¯lnFG2it¯ denote the cross-sectional averages of the input variables.

AMG model specifications

The AMG approach follows a two-staged process. At the first stage, Eqs. (1), (2), and (3) are specified in a T−1 dummies and first differenced form as;
Interactive Model:(A5)ΔlnEFPit=α0+β1ΔlnFGit+β2ΔlnGIit+β3ΔlnYit+β4ΔlnY2it+β5ΔlnNRRit+δ1lnGIFGit+t=2TtΔDt+εitΔlnEFPit=α0+β1ΔlnFGit+β2ΔlnGIit+β3ΔlnYit+β4ΔlnY2it+β5ΔlnNRRit+δ1lnGIFGit+t=2TtΔDt+εit
Nonlinear Model:(A6)ΔlnEFPit=α0+β1ΔlnFGit+β2ΔlnGIit+β3ΔlnYit+β4ΔlnY2it+β5ΔlnNRRit+π1lnFG2it+t=2TtΔDt+εitΔlnEFPit=α0+β1ΔlnFGit+β2ΔlnGIit+β3ΔlnYit+β4ΔlnY2it+β5ΔlnNRRit+π1lnFG2it+t=2TtΔDt+εitFrom the equations above, ΔDtΔDt is the first difference order of T−1 dummies, and tt is its coefficient.
In the second stage, common dynamic processes are formed by transforming tt to PtPt(tt = PtPt) as;
Interactive Model:(A7)ΔlnEFPit=αi+β1ΔlnFGit+β2ΔlnGIit+β3ΔlnYit+β4ΔlnY2it+β5ΔlnNRRit+Ptdt+δ1lnGIFGit+εitΔlnEFPit=αi+β1ΔlnFGit+β2ΔlnGIit+β3ΔlnYit+β4ΔlnY2it+β5ΔlnNRRit+Ptdt+δ1lnGIFGit+εit(A8)ΔlnEFPit-Ptdt=αi+β1ΔlnFGit+β2ΔlnGIit+β3ΔlnYit+β4ΔlnY2it+β5ΔlnNRRit+δ1lnGIFGit+εitΔlnEFPit-Ptdt=αi+β1ΔlnFGit+β2ΔlnGIit+β3ΔlnYit+β4ΔlnY2it+β5ΔlnNRRit+δ1lnGIFGit+εit
Nonlinear Model:(A9)ΔlnEFPit=αi+β1ΔlnFGit+β2ΔlnGIit+β3ΔlnYit+β4ΔlnY2it+β5ΔlnNRRit+Ptdt+π1lnFG2it+εitΔlnEFPit=αi+β1ΔlnFGit+β2ΔlnGIit+β3ΔlnYit+β4ΔlnY2it+β5ΔlnNRRit+Ptdt+π1lnFG2it+εit(A10)ΔlnEFPit-Ptdt=αi+β1ΔlnFGit+β2ΔlnGIit+β3ΔlnYit+β4ΔlnY2it+β5ΔlnNRRit+π1lnFG2it+εitΔlnEFPit-Ptdt=αi+β1ΔlnFGit+β2ΔlnGIit+β3ΔlnYit+β4ΔlnY2it+β5ΔlnNRRit+π1lnFG2it+εitwhere dtdt is the dynamic process.
After the transformations, the elasticities of the predictors are respectively computed as;
Interactive Model:(A11)β1,AMG=1Ni=1Nβ1i,β2,AMG=1Ni=1Nβ2i,β3,AMG=INi=1Nβ3i,β4,AMG=INi=1Nβ4i,β5,AMG=INi=1Nβ5i,δ1,AMG=INi=1Nδ1i,β1,AMG=1Ni=1Nβ1i,β2,AMG=1Ni=1Nβ2i,β3,AMG=INi=1Nβ3i,β4,AMG=INi=1Nβ4i,β5,AMG=INi=1Nβ5i,δ1,AMG=INi=1Nδ1i,
Nonlinear Model:(A12)β1,AMG=1Ni=1Nβ1i,β2,AMG=1Ni=1Nβ2i,β3,AMG=INi=1Nβ3i,β4,AMG=INi=1Nβ4i,β5,AMG=INi=1Nβ5i,π1,AMG=INi=1Nπ1i,β1,AMG=1Ni=1Nβ1i,β2,AMG=1Ni=1Nβ2i,β3,AMG=INi=1Nβ3i,β4,AMG=INi=1Nβ4i,β5,AMG=INi=1Nβ5i,π1,AMG=INi=1Nπ1i,

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