Solvability and thermal response of cellulose with different crystal configurations

Abstract

Cellulose is a biodegradable and renewable natural material that it is naturally resistant to breaking and modification. Moreover, the crystalline structure of cellulose is a major factor restricting its industrial utilization. In this study, cellulose polymorphs were prepared from natural cellulose, and their solvability and thermal response were investigated. Using liquid- and solid-state NMR signals, the distinct types and dissolving states of cellulose polymorphs were identified. The thermal behavior of the polymorphic forms of cellulose-d was also evaluated, and cellulose II exhibited the poorest thermal stability and a unique exothermic reaction.

Keywords

cellulose / crystal structure / thermal response / XRD / CP/MAS ¹³C NMR

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