Allying interfacial engineering of 2D carbon nanosheet-, graphene-, and graphdiyne-based heterostructured electrocatalysts toward hydrogen evolution and overall water splitting

Abstract

Electrochemical hydrogen evolution reaction (HER) and overall water splitting (OWS) for renewable energy generation have recently become a highly promising and sustainable strategy to tackle energy crisis and global warming arising from our overreliance on fossil fuels. Previously, tremendous research breakthroughs have been made in 2D carbon-based heterostructured electrocatalysts in this field. Such heterostructures are distinguished by their remarkable electrical conductivity, exposed active sites, and mechanical stability. Herein, with fundamental mechanisms of electrocatalytic OWS summarized, our review critically emphasized on state-of-the-art 2D carbon nanosheet-, graphene-, and graphdiyne-based heterostructured electrocatalysts in HER and OWS since 2018. Particularly, the three emerging carbonaceous substrates tend to be incorporated with metal carbides, phosphides, dichalcogenides, nitrides, oxides, nanoparticles, single atom catalysts, or layered double hydroxides. Meanwhile, fascinating structural engineering and facile synthesis strategies were also unraveled to establish the structure–activity relationship, which will enlighten future electrocatalyst developments toward ameliorated HER and OWS activities. Additionally, computational results from density functional theory simulations were highlighted as well to better comprehend the synergistic effects within the heterostructures. Finally, current stages and future recommendations of this brand-new electrocatalyst type were concluded and discussed for advanced catalyst designs and future practical applications.

Keywords

2D carbon-based heterostructures / electrocatalysis / hydrogen evolution reaction / interfacial engineering / overall water splitting

References

[1] ChuS, Majumdar A. Opportunities and challenges for a sustainable energy future. Nature. 2012;488(7411):294-303.

[2] SchlapbachL, Züttel A. Hydrogen-storage materials for mobile applications. Nature. 2001;414(6861):353-358.

[3] AkhtarMS, KhanH, LiuJJ, Na J. Green hydrogen and sustainable development –a social LCA perspective highlighting social hotspots and geopolitical implications of the future hydrogen economy. J Clean Prod. 2023;395:136438.

[4] MondalA, Vomiero A. 2D transition metal dichalcogenides-based electrocatalysts for hydrogen evolution reaction. Adv Funct Mater. 2022;32(52):2208994.

[5] YounisMA, LyuS, ZhaoQ, et al. Noble metal-free two dimensional carbon-based electrocatalysts for water splitting. BMC Mater. 2019;1:6. https://doi.org/10.1186/s42833-019-0006-2

[6] ChenZ, HaY, JiaH, et al. Water splitting: oriented transformation of Co-LDH into 2D/3D ZIF-67 to achieve Co–N–C hybrids for efficient overall water splitting (Adv. Energy Mater. 19/2019). Adv Energy Mater. 2019;9(19):1803918.

[7] ZhangJ, ZhangQ, FengX. Support and interface effects in water-splitting electrocatalysts. Adv Mater. 2019;31:1808167.

[8] GnanasekarP, Periyanagounder D, KulandaivelJ. Vertically aligned MoS₂ nanosheets on graphene for highly stable electrocatalytic hydrogen evolution reactions. Nanoscale. 2019;11(5):2439-2446.

[9] SongA, SongS, DuanmuM, et al. Recent progress of non-noble metallic heterostructures for the electrocatalytic hydrogen evolution. Small Sci. 2023;3:2300036.

[10] AliA, ShenPK. Recent progress in graphene-based nanostructured electrocatalysts for overall water splitting. Electrochem Energy Rev. 2020;3(2):370-394.

[11] SunY, ZhangT, LiC, XuK, LiY. Compositional engineering of sulfides, phosphides, carbides, nitrides, oxides, and hydroxides for water splitting. J Mater Chem A. 2020;8(27):13415-13436.

[12] LeiC, ZhouW, FengQ, et al. Charge engineering of Mo₂C@Defect-Rich N-doped carbon nanosheets for efficient electrocatalytic H2 evolution. Nanomicro Lett. 2019;11(1):45.

[13] ZengM, ChenY, LiJ, et al. 2D WC single crystal embedded in graphene for enhancing hydrogen evolution reaction. Nano Energy. 2017;33:356-362.

[14] LiuY, ZhuY, ShenJ, Huang J, YangX, LiC. CoP nanoparticles anchored on N, P-dual-doped graphene-like carbon as a catalyst for water splitting in non-acidic media. Nanoscale. 2018;10(5):2603-2612.

[15] MaJ, WangM, LeiG, et al. Polyaniline derived N-doped carbon-coated cobalt phosphide nanoparticles deposited on N-doped graphene as an efficient electrocatalyst for hydrogen evolution reaction. Small. 2018;14(2):1702895.

[16] ZhangD, MouH, LuF, SongC, WangD. A novel strategy for 2D/2D NiS/graphene heterostructures as efficient bifunctional electrocatalysts for overall water splitting. Appl Catal, B. 2019;254:471-478.

[17] YuH, XueY, HuiL, et al. Controlled growth of MoS₂ nanosheets on 2D N-doped graphdiyne nanolayers for highly associated effects on water reduction. Adv Funct Mater. 2018;28(19):1707564.

[18] YuX, ZhaoG, GongS, et al. Design of MoS₂/graphene van der Waals heterostructure as highly efficient and stable electrocatalyst for hydrogen evolution in acidic and alkaline media. ACS Appl Mater Interfaces. 2020;12(22):24777-24785.

[19] ZhangX, JiaF, SongS. Recent advances in structural engineering of molybdenum disulfide for electrocatalytic hydrogen evolution reaction. Chem Eng J. 2021;405:127013.

[20] NajafiL, Bellani S, Oropesa-NuñzR, et al. Engineered MoSe2-based heterostructures for efficient electrochemical hydrogen evolution reaction. Adv Energy Mater. 2018;8(16):1703212.

[21] ZhangL, CaoX, FengC, et al. Interfacial Mo–N–C bond endowed hydrogen evolution reaction on MoSe₂@N-doped carbon hollow nanoflowers. Inorg Chem. 2021;60(16):12377-12385.

[22] ChenZ, HaY, LiuY, et al. In situ formation of cobalt nitrides/graphitic carbon composites as efficient bifunctional electrocatalysts for overall water splitting. ACS Appl Mater Interfaces. 2018;10(8):7134-7144.

[23] FangY, XueY, HuiL, et al. In situ growth of graphdiyne based heterostructure: toward efficient overall water splitting. Nano Energy. 2019;59:591-597.

[24] ZouH, LiG, DuanL, Kou Z, WangJ. In situ coupled amorphous cobalt nitride with nitrogen-doped graphene aerogel as a trifunctional electrocatalyst towards Zn-air battery deriven full water splitting. Appl Catal, B. 2019;259:118100.

[25] YaoY, ZhuY, PanC, et al. Interfacial sp C–O–Mo hybridization originated high-current density hydrogen evolution. J Am Chem Soc. 2021;143(23):8720-8730.

[26] HuangT, ChenY, LeeJ-M. Two-dimensional cobalt/N-doped carbon hybrid structure derived from metal–organic frameworks as efficient electrocatalysts for hydrogen evolution. ACS Sustain Chem Eng. 2017;5(7):5646-5650.

[27] JinQ, RenB, LiD, CuiH, WangC. Plasma-assisted synthesis of self-supporting porous CoNPs@C nanosheet as efficient and stable bifunctional electrocatalysts for overall water splitting. ACS Appl Mater Interfaces. 2017;9(37):31913-31921.

[28] ShiG, XieY, DuL, et al. Stabilization of cobalt clusters with graphdiyne enabling efficient overall water splitting. Nano Energy. 2020;74:104852.

[29] LiuX, LiW, ZhaoX, Liu Y, NanC-W, FanL-Z. Two birds with one stone: metal–organic framework derived micro-/nanostructured Ni₂P/Ni hybrids embedded in porous carbon for electrocatalysis and energy storage. Adv Funct Mater. 2019;29(35):1901510.

[30] CaoB, ChengY, HuM, et al. Efficient and durable 3D self-supported nitrogen-doped carbon-coupled nickel/cobalt phosphide electrodes: stoichiometric ratio regulated phaseand morphology-dependent overall water splitting performance. Adv Funct Mater. 2019;29(44):1906316.

[31] SuoN, HanX, ChenC, et al. Engineering vanadium phosphide by iron doping as bifunctional electrocatalyst for overall water splitting. Electrochim Acta. 2020;333:135531.

[32] MondalA, SinhaK, PaulA, Srivastava DN, PandaAB. Large scale synthesis of Mo₂C nanoparticle incorporated carbon nanosheet (Mo₂C–C) for enhanced hydrogen evolution reaction. Int J Hydrogen Energy. 2020;45(37):18623-18634.

[33] TangC, HuQ, LiF, et al. Coupled molybdenum carbide and nitride on carbon nanosheets: an efficient and durable hydrogen evolution electrocatalyst in both acid and alkaline media. Electrochim Acta. 2018;280:323-331.

[34] WuC, LiJ. Unique hierarchical Mo₂C/C nanosheet hybrids as active electrocatalyst for hydrogen evolution reaction. ACS Appl Mater Interfaces. 2017;9(47):41314-41322.

[35] MolnárÁ, Papp A. Catalyst recycling—a survey of recent progress and current status. Coord Chem Rev. 2017;349:1-65.

[36] WangXX, TanZH, ZengM, Wang JN. Carbon nanocages: a new support material for Pt catalyst with remarkably high durability. Sci Rep. 2014;4(1):4437.

[37] LiC-F, ZhaoJ-W, XieL-j, Wu J-Q, LiG-R. Water adsorption and dissociation promoted by Co*-/N-C*-biactive sites of metallic Co/N-doped carbon hybrids for efficient hydrogen evolution. Appl Catal, B. 2021;282:119463.

[38] LiY, WangH, XieL, LiangY, HongG, Dai H. MoS₂ nanoparticles grown on graphene: an advanced catalyst for the hydrogen evolution reaction. J Am Chem Soc. 2011;133:7296-7299.

[39] XueY, HuangB, YiY, et al. Anchoring zero valence single atoms of nickel and iron on graphdiyne for hydrogen evolution. Nat Commun. 2018;9:1460. https://doi.org/10.1038/s41467-018-03896-4

[40] PengS, LiL, HanX, et al. Cobalt sulfide nanosheet/graphene/carbon nanotube nanocomposites as flexible electrodes for hydrogen evolution. Angew Chem Int Ed. 2014;53(46):12594-12599.

[41] YanY, ThiaL, XiaBY, et al. Construction of efficient 3D gas evolution electrocatalyst for hydrogen evolution: porous FeP nanowire arrays on graphene sheets. Adv Sci. 2015;2(8):1500120.

[42] YangJ, VoiryD, AhnSJ, et al. Two-dimensional hybrid nanosheets of tungsten disulfide and reduced graphene oxide as catalysts for enhanced hydrogen evolution. Angew Chem Int Ed. 2013;52(51):13751-13754.

[43] YangL, ZhouW, LuJ, et al. Hierarchical spheres constructed by defect-rich MoS₂/carbon nanosheets for efficient electrocatalytic hydrogen evolution. Nano Energy. 2016;22:490-498.

[44] ZhengY, JiaoY, ZhuY, et al. Hydrogen evolution by a metal-free electrocatalyst. Nat Commun. 2014;5(1):3783.

[45] ChenLX, ChenZW, ZhangY, Yang CC, JiangQ. Insight into the excellent catalytic activity of (CoMo)S₂/graphene for hydrogen evolution reaction. Appl Catal, B. 2019;258:118012.

[46] LiuM, YangL, LiuT, et al. Fe₂P/reduced graphene oxide/Fe₂P sandwich-structured nanowall arrays: a high-performance non-noble-metal electrocatalyst for hydrogen evolution. JJ Mater Chem A. 2017;5(18):8608-8615.

[47] PengK, WangH, GaoH, WanP, MaM, LiX. Emerging hierarchical ternary 2D nanocomposites constructed from montmorillonite, graphene and MoS₂ for enhanced electrochemical hydrogen evolution. Chem Eng J. 2020;393:124704.

[48] FengY, OuYangY, PengL, Qiu H, WangH, WangY. Quasigraphene-envelope Fe-doped Ni₂P sandwiched nanocomposites for enhanced water splitting and lithium storage performance. J Mater Chem A. 2015;3(18):9587-9594.

[49] HosseiniH, Roushani M. Rational design of hollow core-double shells hybrid nanoboxes and nanopipes composed of hierarchical Cu-Ni-Co selenides anchored on nitrogendoped carbon skeletons as efficient and stable bifunctional electrocatalysts for overall water splitting. Chem Eng J. 2020;402:126174.

[50] HuiL, XueY, HuangB, et al. Overall water splitting by graphdiyne-exfoliated and -sandwiched layered doublehydroxide nanosheet arrays. Nat Commun. 2018;9(1):5309.

[51] QiL, ZhengZ, XingC, et al. 1D Nanowire heterojunction electrocatalysts of MnCo₂O₄/GDY for efficient overall water splitting. Adv Funct Mater. 2021:2107179. https://doi.org/10.1002/adfm.202107179

[52] WanW, WeiS, LiJ, TrianaCA, ZhouY, Patzke GR. Transition metal electrocatalysts encapsulated into N-doped carbon nanotubes on reduced graphene oxide nanosheets: efficient water splitting through synergistic effects. J Mater Chem A. 2019;7(25):15145-15155.

[53] XueY, ZuoZ, LiY, LiuH, LiY. Graphdiyne-Supported NiCo₂S₄ nanowires: a highly active and stable 3D bifunctional electrode material. Small. 2017;13(31):1700936.

[54] ZhangS, YuX, YanF, LiC, ZhangX, Chen Y. N-Doped graphene-supported Co@CoO core–shell nanoparticles as high-performance bifunctional electrocatalysts for overall water splitting. J Mater Chem A. 2016;4(31):12046-12053.

[55] ZhangX, LiuS, ZangY, et al. Co/Co₉S₈@S,N-doped porous graphene sheets derived from S, N dual organic ligands assembled Co-MOFs as superior electrocatalysts for full water splitting in alkaline media. Nano Energy. 2016;30:93-102.

[56] ZhouF, ZhangX, SaR, ZhangS, WenZ, WangR. The electrochemical overall water splitting promoted by MoS₂ in coupled nickel–iron (oxy)hydride/molybdenum sulfide/graphene composite. Chem Eng J. 2020;397:125454.

[57] ZhangX, ZhuZ, LiangX, et al. Encapsulating dual-phased Mo₂C-WC nanocrystals into ultrathin carbon nanosheet assemblies for efficient electrocatalytic hydrogen evolution. Chem Eng J. 2021;408:127270.

[58] LiuB, HuoL, GaoZ, ZhiG, ZhangG, Zhang J. Graphene decorated with uniform ultrathin (CoP)_x-(FeP)_1-x nanorods: a robust non-noble-metal catalyst for hydrogen evolution. Small. 2017;13(21):1700092.

[59] JeongGH, Sasikala SP, YunT, LeeGY, LeeWJ, KimSO. Nanoscale assembly of 2D materials for energy and environmental applications. Adv Mater. 2020;32(35):1907006.

[60] ZhaoG, RuiK, DouSX, Sun W. Heterostructures for electrochemical hydrogen evolution reaction: a review. Adv Funct Mater. 2018;28(43):1803291.

[61] AliA, ShenPK. Nonprecious metal’s graphene-supported electrocatalysts for hydrogen evolution reaction: fundamentals to applications. Carbon Energy. 2020;2(1):99-121.

[62] ZouX, ZhangY. Noble metal-free hydrogen evolution catalysts for water splitting. Chem Soc Rev. 2015;44(15):5148-5180.

[63] ChenP, ZhouT, ChenM, et al. Enhanced catalytic activity in nitrogen-anion modified metallic cobalt disulfide porous nanowire arrays for hydrogen evolution. ACS Catal. 2017;7(11):7405-7411.

[64] Naresh KumarT, Chandrasekaran N, Lakshminarasimha PhaniK. Structural and electronic modification of MoS₂ nanosheets using S-doped carbon for efficient electrocatalysis of the hydrogen evolution reaction. Chem Commun. 2015;51(24):5052-5055.

[65] DickensC, KirkC, Nøskov J. Insights into the electrochemical oxygen evolution reaction with ab initio calculations and microkinetic modeling: beyond the limiting potential volcano. J Phys Chem C. 2019;123(31):18960-18977.

[66] ReierT, NongHN, TeschnerD, Schlöl R, StrasserP. Electrocatalytic oxygen evolution reaction in acidic environments –reaction mechanisms and catalysts. Adv Energy Mater. 2017;7(1):1601275.

[67] RossmeislJ, QuZW, ZhuH, KroesGJ, NøskovJK. Electrolysis of water on oxide surfaces. J Electroanal Chem. 2007;607(1-2):83-89.

[68] ZhuY-P, XuX, SuH, LiuY-P, ChenT, Yuan Z-Y. Ultrafine metal phosphide nanocrystals in situ decorated on highly porous heteroatom-doped carbons for active electrocatalytic hydrogen evolution. ACS Appl Mater Interfaces. 2015;7(51):28369-28376.

[69] ZhaoX, YinF, HeX, ChenB, LiG. Efficient overall water splitting over a Mo(IV)-doped Co₃O₄/NC electrocatalyst. Int J Hydrogen Energy. 2021;46(40):20905-20918.

[70] Cilpa-KarhuG, Pakkanen OJ, LaasonenK. Hydrogen evolution reaction on the single-shell carbon-encapsulated iron nanoparticle: a density functional theory insight. J Phys Chem C. 2019;123(22):13569-13577.

[71] ShinagawaT, Garcia-Esparza AT, TakanabeK. Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion. Sci Rep. 2015;5(1):13801.

[72] ZhangS, WeiN, YaoZ, ZhaoX, DuM, ZhouQ. Oxygen vacancy-based ultrathin Co₃O₄ nanosheets as a highefficiency electrocatalyst for oxygen evolution reaction. Int J Hydrogen Energy. 2021;46(7):5286-5295.

[73] FangY, LvY, CheR, et al. Two-dimensional mesoporous carbon nanosheets and their derived graphene nanosheets: synthesis and efficient lithium ion storage. J Am Chem Soc. 2013;135(4):1524-1530.

[74] LiH, ShenL, YinK, et al. Facile synthesis of N-doped carboncoated Li₄Ti₅O₁₂ microspheres using polydopamine as a carbon source for high rate lithium ion batteries. J Mater Chem A. 2013;1(24):7270-7276.

[75] RenJ-T, ChenL, YangD-D, Yuan Z-Y. Molybdenum-based nanoparticles (Mo₂C, MoP and MoS₂) coupled heteroatoms-doped carbon nanosheets for efficient hydrogen evolution reaction. Appl Catal, B. 2020;263:118352.

[76] ZhangB, QinH, PanY, et al. Graphite carbon nanosheetcoated cobalt-doped molybdenum carbide nanoparticles for efficient alkaline hydrogen evolution reaction. ACS Appl Nano Mater. 2021;4(1):372-380.

[77] QuK, WangY, VasileffA, Jiao Y, ChenH, ZhengY. Polydopamine-inspired nanomaterials for energy conversion and storage. J Mater Chem A. 2018;6(44):21827-21846.

[78] WangH, XuX, NiB, LiH, BianW, Wang X. 3D self-assembly of ultrafine molybdenum carbide confined in N-doped carbon nanosheets for efficient hydrogen production. Nanoscale. 2017;9(41):15895-15900.

[79] XiongJ, LiJ, ShiJ, et al. Metallic 1T-MoS₂ nanosheets in-situ entrenched on N,P,S-codoped hierarchical carbon microflower as an efficient and robust electro-catalyst for hydrogen evolution. Appl Catal, B. 2019;243:614-620.

[80] GaoY, ChenZ, ZhaoY, et al. Facile synthesis of MoP-Ru₂P on porous N, P co-doped carbon for efficiently electrocatalytic hydrogen evolution reaction in full pH range. Appl Catal, B. 2022;303:120879.

[81] LiP, ZhaoG, CuiP, et al. Nickel single atom-decorated carbon nanosheets as multifunctional electrocatalyst supports toward efficient alkaline hydrogen evolution. Nano Energy. 2021;83:105850.

[82] LiuY-Y, YeZ, ZhuZ, NiZ, XuQ, YuanD. Co-WC heterojunction nanoparticle composites with graphene embedded in porous carbon nanospheres as an electrocatalyst for the hydrogen evolution reaction. ACS Appl Nano Mater. 2021;4(11):11870-11880.

[83] LiJ, LiuY, LiX, et al. Ammonium polyphosphate induced bimetallic phosphides nanoparticles coated with porous Ndoped carbon for efficiently electrochemical hydrogen evolution. Chem Eng J. 2022;431:133696.

[84] PengX, HuangC, ZhangB, Liu Y. Vanadium carbide nanodots anchored on N doped carbon nanosheets fabricated by spatially confined synthesis as a high-efficient electrocatalyst for hydrogen evolution reaction. J Power Sources. 2021;490:229551.

[85] RongJ, ZhuG, Ryan OsterlohW, et al. In situ construction MoS₂-Pt nanosheets on 3D MOF-derived S, N-doped carbon substrate for highly efficient alkaline hydrogen evolution reaction. Chem Eng J. 2021;412:127556.

[86] YuJ, LiW-J, ZhangH, et al. Metallic FePSe₃ nanoparticles anchored on N-doped carbon framework for All-pH hydrogen evolution reaction. Nano Energy. 2019;57:222-229.

[87] HeD, CaoL, HuangJ, et al. Synergistic coupling of heterogeneous VN/WN nanoparticles embedded in N-doped carbon matrix for efficient hydrogen evolution reaction. Chem Eng J. 2022;429:131945.

[88] YaoM, WangB, WangN, et al. Self-supported composite of (Ni,Co)₃C mesoporous nanosheets/N-doped carbon as a flexible electrocatalyst for pH-universal hydrogen evolution. ACS Sustain Chem Eng. 2020;8(13):5287-5295.

[89] FanY, SunY, ZhangX, Guo J. Synergistic effect between sulfur and CoFe alloys embedded in N-doped carbon nanosheets for efficient hydrogen evolution under neutral condition. Chem Eng J. 2021;426:131922.

[90] LiY, ZhangB, WangW, et al. Selective-etching of MOF toward hierarchical porous Mo-doped CoP/N-doped carbon nanosheet arrays for efficient hydrogen evolution at all pH values. Chem Eng J. 2021;405:126981.

[91] ZhangP, LiuY, LiangT, et al. Nitrogen-doped carbon wrapped Co-Mo₂C dual Mott–Schottky nanosheets with large porosity for efficient water electrolysis. Appl Catal, B. 2021;284:119738.

[92] VrubelH, HuX. Molybdenum boride and carbide catalyze hydrogen evolution in both acidic and basic solutions. Angew Chem Int Ed. 2012;51:12703-12706.

[93] JingS, ZhangL, LuoL, et al. N-doped porous molybdenum carbide nanobelts as efficient catalysts for hydrogen evolution reaction. Appl Catal, B. 2018;224:533-540.

[94] XiaoP, YanY, GeX, LiuZ, WangJ-Y, Wang X. Investigation of molybdenum carbide nano-rod as an efficient and durable electrocatalyst for hydrogen evolution in acidic and alkaline media. Appl Catal, B. 2014;154-155:232-237.

[95] ZhouG, YangQ, GuoX, et al. Coupling molybdenum carbide nanoparticles with N-doped carbon nanosheets as a high-efficiency electrocatalyst for hydrogen evolution reaction. Int J Hydrogen Energy. 2018;43(19):9326-9333.

[96] ChenW-F, Muckerman JT, FujitaE. Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts. Chem Commun. 2013;49(79):8896-8909.

[97] ZhaoY, KamiyaK, HashimotoK, Nakanishi S. In situ CO₂-emission assisted synthesis of molybdenum carbonitride nanomaterial as hydrogen evolution electrocatalyst. JAmChem Soc. 2015;137(1):110-113.

[98] ShiY, ZhangB. Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction. Chem Soc Rev. 2016;45(6):1529-1541.

[99] SheikholeslamMA, Enayati MH, RaeissiK. Characterization of nanocrystalline and amorphous cobalt–phosphorous electrodeposits. Mat. Lett. 2008;62(21-22):3629-3631.

[100] LiX, ZhangR, LuoY, et al. A cobalt–phosphorus nanoparticle decorated N-doped carbon nanosheet array for efficient and durable hydrogen evolution at alkaline pH. Sustain Energy Fuels. 2020;4(8):3884-3887.

[101] XuY, RenT, RenK, et al. Metal-organic frameworks-derived Ru-doped Co₂P/N-doped carbon composite nanosheet arrays as bifunctional electrocatalysts for hydrogen evolution and urea oxidation. Chem Eng J. 2021;408:127308.

[102] GuanC, XiaoW, WuH, et al. Hollow Mo-doped CoP nanoarrays for efficient overall water splitting. Nano Energy. 2018;48:73-80.

[103] HuangX, XuX, LiC, WuD, ChengD, Cao D. Vertical CoP nanoarray wrapped by N,P-doped carbon for hydrogen evolution reaction in both acidic and alkaline conditions. Adv Energy Mater. 2019;9(22):1803970.

[104] NaumisGG. 5 -electronic properties of two-dimensional materials. In: Yang E-H, Datta D, Ding J, Hader G, eds. Synthesis, Modeling, and Characterization of 2D Materials, and Their Heterostructures. Elsevier;2020:77-109.

[105] ChackoL, Rastogi PK, AneeshPM. Phase engineering from 2H to 1T-MoS₂ for efficient Ammonia PL sensor and electrocatalyst for hydrogen evolution reaction. J Electrochem Soc. 2019;166(8): H263-H271.

[106] GaurA, Hartmann Dabros TM, HøjM, et al. Probing the active sites of MoS₂ based hydrotreating catalysts using modulation excitation spectroscopy. ACS Catal. 2019;9(3):2568-2579.

[107] ChangK, PangH, HaiX, et al. Ultra-small freestanding amorphous molybdenum sulfide colloidal nanodots for highly efficient photocatalytic hydrogen evolution reaction. Appl Catal, B. 2018;232:446-453.

[108] GaoC, HuaH, DuM, et al. 1T/2H MoS₂ nanoflowers decorated amorphous Mo-CoS_x skeleton: a ZIF-based composite electrocatalyst for the hydrogen evolution reaction. Appl Surf Sci. 2020;515:145842.

[109] AttanayakeNH, Thenuwara AC, PatraA, et al. Effect of intercalated metals on the electrocatalytic activity of 1T-MoS₂ for the hydrogen evolution reaction. ACS Energy Lett. 2018;3(1):7-13.

[110] YuY, NamG-H, HeQ, et al. High phase-purity 1T′-MoS₂-and 1T′-MoSe₂-layered crystals. Nat Chem. 2018;10(6):638-643.

[111] WuZ, WangJ, XiaK, LeiW, LiuX, WangD. MoS₂–MoP heterostructured nanosheets on polymer-derived carbon as an electrocatalyst for hydrogen evolution reaction. J Mater Chem A. 2018;6(2):616-622.

[112] LiY, TanX, ChenS, et al. Processable surface modification of nickel-heteroatom (N, S) bridge sites for promoted alkaline hydrogen evolution. Angew Chem Int Ed. 2019;58(2):461-466.

[113] WangX, ZhangY, SiH, et al. Single-atom vacancy defect to trigger high-efficiency hydrogen evolution of MoS₂. J Am Chem Soc. 2020;142(9):4298-4308.

[114] WuX, WangZ, ChenK, et al. Unravelling the role of strong metal–support interactions in boosting the activity toward hydrogen evolution reaction on Ir nanoparticle/N-doped carbon nanosheet catalysts. ACS Appl Mater Interfaces. 2021;13(19):22448-22456.

[115] JiK, Matras-Postolek K, ShiR, et al. MoS₂/CoS₂ heterostructures embedded in N-doped carbon nanosheets towards enhanced hydrogen evolution reaction. J Alloys Compd. 2022;891:161962.

[116] XueY, BaiX, XuY, et al. Vertically oriented Ni-doped MoS₂ nanosheets supported on hollow carbon microtubes for enhanced hydrogen evolution reaction and water splitting. Compos Part B Eng. 2021;224:109229.

[117] WanL, ShiC-w, Yu Z-b, et al. Preparation of WS₂/C composite material and its electrocatalytic hydrogen evolution performance. J Fuel Chem Technol. 2021;49(9):1362-1370.

[118] ZhuY, ChenG, ZhongY, Zhou W, ShaoZ. Rationally designed hierarchically structured tungsten nitride and nitrogen-rich graphene-like carbon nanocomposite as efficient hydrogen evolution electrocatalyst. Adv Sci. 2018;5(2):1700603.

[119] WangQ, ZhangY, NiW, et al. Free-standing phosphorousdoped molybdenum nitride in 3D carbon nanosheet towards hydrogen evolution at all pH values. J Energy Chem. 2020;50:44-51.

[120] LiuY, HuX, HuangB, Xie Z. Surface engineering of Rh catalysts with N/S-codoped carbon nanosheets toward highperformance hydrogen evolution from seawater. ACS Sustain Chem Eng. 2019;7(23):18835-18843.

[121] LinH, ShiZ, HeS, et al. Heteronanowires of MoC–Mo₂C as efficient electrocatalysts for hydrogen evolution reaction. Chem Sci. 2016;7(5):3399-3405.

[122] WangH, CaoY, SunC, et al. Strongly coupled molybdenum carbide on carbon sheets as a bifunctional electrocatalyst for overall water splitting. ChemSusChem. 2017;10(18):3540-3546.

[123] SongD, ShinJ, LeeY, et al. Thin nickel layer with embedded WC nanoparticles for efficient oxygen evolution. ACS Appl Energy Mater. 2019;2(5):3452-3460.

[124] ChenJ, RenB, CuiH, WangC. Constructing pure phase tungsten-based bimetallic carbide nanosheet as an efficient bifunctional electrocatalyst for overall water splitting. Small. 2020;16(23):1907556.

[125] HouC-C, ZouL, WangY, Xu Q. MOF-Mediated fabrication of a porous 3D superstructure of carbon nanosheets decorated with ultrafine cobalt phosphide nanoparticles for efficient electrocatalysis and zinc–air batteries. Angew Chem Int Ed. 2020;59(48):21360-21366.

[126] RenJ-T, WangY-S, ChenL, Gao L-J, TianW-W, YuanZ-Y. Binary FeNi phosphides dispersed on N,P-doped carbon nanosheets for highly efficient overall water splitting and rechargeable Zn-air batteries. Chem Eng J. 2020;389:124408.

[127] BianJ, SongZ, LiX, ZhangY, ChengC. Nickel iron phosphide ultrathin nanosheets anchored on nitrogen-doped carbon nanoflake arrays as a bifunctional catalyst for efficient overall water splitting. Nanoscale. 2020;12(15):8443-8452.

[128] TranDT, LeHT, HoaVH, Kim NH, LeeJH. Dual-coupling ultrasmall iron-Ni₂P into P-doped porous carbon sheets assembled Cu_xS nanobrush arrays for overall water splitting. Nano Energy. 2021;84:105861.

[129] ZhangG, WangG, LiuY, LiuH, QuJ, LiJ. Highly activeand stable catalysts of phytic acid-derivative transition metal phosphides for full water splitting. J Am Chem Soc. 2016;138(44):14686--14693.

[130] BurkeMS, KastMG, TrotochaudL, Smith AM, BoettcherSW. Cobalt–iron (Oxy)hydroxide oxygen evolution electrocatalysts: the role of structure and composition on activity, stability, and mechanism. J Am Chem Soc. 2015;137(10):3638-3648.

[131] RyuJ, JungN, JangJH, Kim H-J, YooSJ. In situ transformation of hydrogen-evolving CoP nanoparticles: toward efficient oxygen evolution catalysts bearing dispersed morphologies with Co-oxo/hydroxo molecular units. ACS Catal. 2015;5(7):4066-4074.

[132] LingC, ShiL, OuyangY, Zeng XC, WangJ. Nanosheet supported single-metal atom bifunctional catalyst for overall water splitting. Nano Lett. 2017;17(8):5133-5139.

[133] XingJ, LiY, GuoS, et al. Molybdenum carbide in-situ embedded into carbon nanosheets as efficient bifunctional electrocatalysts for overall water splitting. Electrochim Acta. 2019;298:305-312.

[134] XingJ, LinF, HuangL, Si Y, WangY, JiaoL. Coupled cobaltdoped molybdenum carbide@N-doped carbon nanosheets/nanotubes supported on nickel foam as a binder-free electrode for overall water splitting. Chin J Catal. 2019;40(9):1352-1359.

[135] XiaL, ZhangX, SongH, et al. Structural engineering of hierarchically hetestructured Mo₂C/Co conformally embedded in carbon for efficient water splitting. Int J Hydrogen Energy. 2020;45(43):22629-22637.

[136] LiuG, WangK, WangL, et al. A Janus cobalt nanoparticles and molybdenum carbide decorated N-doped carbon for high-performance overall water splitting. J Colloid Interface Sci. 2021;583:614-625.

[137] MohiteS, XingR, LiB, et al. Spatial compartmentalization of cobalt phosphide in P-doped dual carbon shells for efficient alkaline overall water splitting. Inorg Chem. 2020;59(3):1996-2004.

[138] MaB, DuanX, HanW, et al. Decorated nickel phosphide nanoparticles with nitrogen and phosphorus co-doped porous carbon for enhanced electrochemical water splitting. J Colloid Interface Sci. 2020;567:393-401.

[139] YuJ, LiQ, ChenN, et al. Carbon-coated nickel phosphide nanosheets as efficient dual-electrocatalyst for overall water splitting. ACS Appl Mater Interfaces. 2016;8(41):27850-27858.

[140] JiaoC, HassanM, BoX, ZhouM. Co_0.5Ni_0.5P nanoparticles embedded in carbon layers for efficient electrochemical water splitting. J Alloys Compd. 2018;764:88-95.

[141] HoaVH, TranDT, LeHT, KimNH, LeeJH. Hierarchically porous nickel–cobalt phosphide nanoneedle arrays loaded micro-carbon spheres as an advanced electrocatalyst for overall water splitting application. Appl Catal, B. 2019;253:235-245.

[142] ZhuY-X, ZhangL, ZhuG-G, Zhang X, LuS-Y. N-doped carbon armored metal phosphides grown in-situ on nickel foam as chainmail catalysts toward high efficiency electrolytic water splitting. J Colloid Interface Sci. 2020;562:42-51.

[143] GaoH, WangY, ZhouS, et al. Nickel-cobalt phosphate nanoparticles wrapped in nitrogen-doped carbon loading on partially phosphatized foamed nickel as efficient electrocatalyst for water splitting. Chem Eng J. 2021;426:130854.

[144] LiB, LiZ, PangQ, Zhang JZ. Core/shell cable-like Ni₃S₂ nanowires/N-doped graphene-like carbon layers as composite electrocatalyst for overall electrocatalytic water splitting. Chem Eng J. 2020;401:126045.

[145] YanL, WangH, ShenJ, Ning J, ZhongY, HuY. Formation of mesoporous Co/CoS/Metal-N-C@S, N-codoped hairy carbon polyhedrons as an efficient trifunctional electrocatalyst for Zn-air batteries and water splitting. Chem Eng J. 2021;403:126385.

[146] LaiF, FengJ, YeX, et al. Energy level engineering in transition-metal doped spinel-structured nanosheets for efficient overall water splitting. J Mater Chem A. 2019;7(2):827-833.

[147] YangH, ChenZ, HaoW, XuH, GuoY, WuR. Catalyzing overall water splitting at an ultralow cell voltage of 1.42 V via coupled Co-doped NiO nanosheets with carbon. Appl Catal, B. 2019;252:214-221.

[148] RamakrishnanS, Velusamy DB, SengodanS, et al. Rational design of multifunctional electrocatalyst: an approach towards efficient overall water splitting and rechargeable flexible solid-state zinc–air battery. Appl Catal, B. 2022;300:120752.

[149] ZhangQ, LiXL, TaoBX, et al. CoNi based alloy/oxides@Ndoped carbon core-shell dendrites as complementary water splitting electrocatalysts with significantly enhanced catalytic efficiency. Appl Catal, B. 2019;254:634-646.

[150] DaiK, ZhangN, ZhangL, Yin L, ZhaoY, ZhangB. Self-supported Co/CoO anchored on N-doped carbon composite as bifunctional electrocatalyst for efficient overall water splitting. Chem Eng J. 2021;414:128804.

[151] YaseenW, UllahN, XieM, et al. Ni-Fe-Co based mixed metal/metal-oxides nanoparticles encapsulated in ultrathin carbon nanosheets: a bifunctional electrocatalyst for overall water splitting. Surf Interf. 2021;26:101361.

[152] XiW, RenZ, KongL, et al. Dual-valence nickel nanosheets covered with thin carbon as bifunctional electrocatalysts for full water splitting. J Mater Chem A. 2016;4(19):7297-7304.

[153] YaseenW, UllahN, XieM, et al. Cobalt–Iron nanoparticles encapsulated in mesoporous carbon nanosheets: a one-pot synthesis of highly stable electrocatalysts for overall water splitting. Int J Hydrogen Energy. 2021;46(7):5234-5249.

[154] LiuH-l, Nosheen F, WangX. Noble metal alloy complex nanostructures: controllable synthesis and their electrochemical property. Chem Soc Rev. 2015;44(10):3056-3078.

[155] NovoselovKS, GeimAK, MorozovSV, et al. Electric field effect in atomically thin carbon films. Science. 2004;306(5696):666-669.

[156] ChenY, RenR, WenZ, et al. Superior electrocatalysis for hydrogen evolution with crumpled graphene/tungsten disulfide/tungsten trioxide ternary nanohybrids. Nano Energy. 2018;47:66-73.

[157] HeC, BoT, WangB, Tao J. RGO induced one-dimensional bimetallic carbide nanorods: an efficient and pH-universal hydrogen evolution reaction electrocatalyst. Nano Energy. 2019;62:85-93.

[158] MarcanoDC, Kosynkin DV, BerlinJM, et al. Correction to improved synthesis of graphene oxide. ACS Nano. 2018;12(2):2078.

[159] WangH, ZhangW, ZhangX, et al. Multi-interface collaboration of graphene cross-linked NiS-NiS₂-Ni₃S₄ polymorph foam towards robust hydrogen evolution in alkaline electrolyte. Nano Res. 2021;14(12):4857-4864.

[160] YapFM, LohJY, OngW-J. Synergistic integration of self-supported 1T/2H–WS₂ and nitrogen-doped rGO on carbon cloth for pH-universal electrocatalytic hydrogen evolution. Nano Res.2023. https://doi.org/10.1007/s12274-023-6118-8

[161] SamalR, ManeP, BhatM, Chakraborty B, LateDJ, RoutCS. Stabilization of orthorhombic CoSe₂ by 2D-rGO/MWCNT heterostructures for efficient hydrogen evolution reaction and flexible energy storage device applications. ACS Appl Energy Mater. 2021;4(10):11386-11399.

[162] PengK, WangJ, WangH, et al. MoS₂ nanosheets supported on carbon hybridized montmorillonite as an efficient heterogeneous catalyst in aqueous phase. Appl Clay Sci. 2019;183:105346.

[163] WangF, LiY, ShifaTA, et al. Selenium-enriched nickel selenide nanosheets as a robust electrocatalyst for hydrogen generation. Angew Chem Int Ed. 2016;55(24):6919-6924.

[164] LiuY, HuaX, XiaoC, et al. Heterogeneous spin states in ultrathin nanosheets induce subtle lattice distortion to trigger efficient hydrogen evolution. J Am Chem Soc. 2016;138:5087-5092.

[165] ShwetharaniR, KapseS, ThapaR, Nagaraju DH, BalakrishnaRG. Dendritic Ferroselite (FeSe₂) with 2D carbon-based nanosheets of rGO and g-C₃N₄ as efficient catalysts for electrochemical hydrogen evolution. ACS Appl Energy Mater. 2020;3(12):12682-12691.

[166] WeiH, XiQ, ChenX, et al. Molybdenum carbide nanoparticles coated into the graphene wrapping N-doped porous carbon microspheres for highly efficient electrocatalytic hydrogen evolution both in acidic and alkaline media. Adv Sci. 2018;5(3):1700733.

[167] ReynardD, NagarB, GiraultH. Photonic flash synthesis of Mo₂C/graphene electrocatalyst for the hydrogen evolution reaction. ACS Catal. 2021;11(9):5865-5872.

[168] ShanJ, LingT, DaveyK, Zheng Y, QiaoS-Z. Transition-metaldoped RuIr bifunctional nanocrystals for overall water splitting in acidic environments. Adv Mater. 2019;31(17):1900510.

[169] PutriLK, NgB-J, YeoRYZ, Ong W-J, MohamedAR, ChaiS-P. Engineering nickel phosphides for electrocatalytic hydrogen evolution: a doping perspective. Chem Eng J. 2023;461:141845.

[170] ZhangY, YangJ, DongQ, et al. Highly dispersive MoP nanoparticles anchored on reduced graphene oxide nanosheets for an efficient hydrogen evolution reaction electrocatalyst. ACS Appl Mater Interfaces. 2018;10(31):26258-26263.

[171] HanA, JinS, ChenH, Ji H, SunZ, DuP. A robust hydrogen evolution catalyst based on crystalline nickel phosphide nanoflakes on three-dimensional graphene/nickel foam: high performance for electrocatalytic hydrogen production from pH 0–14. J Mater Chem A. 2015;3(5):1941-1946.

[172] LiG, YuJ, JiaJ, et al. Cobalt–cobalt phosphide nanoparticles@nitrogen-phosphorus doped carbon/graphene derived from cobalt ions adsorbed Saccharomycete yeasts as an efficient, stable, and large-current-density electrode for hydrogen evolution reactions. Adv Funct Mater. 2018;28(40):1801332.

[173] MaL, ShenX, ZhouH, Zhu G, JiZ, ChenK. CoP nanoparticles deposited on reduced graphene oxide sheets as an active electrocatalyst for the hydrogen evolution reaction. J Mater Chem A. 2015;3(10):5337-5343.

[174] LiD, LiaoQ, RenB, JinQ, CuiH, WangC. A 3D-composite structure of FeP nanorods supported by vertically aligned graphene for the high-performance hydrogen evolution reaction. J Mater Chem A. 2017;5(22):11301-11308.

[175] YangD, YangJ-H, YangY-P, Liu Z-Y. High-dispersed ruthenium sites on copper phosphide/graphene for electrocatalytic hydrogen evolution in acidic and alkaline conditions. Appl Catal, B. 2023;326:122402.

[176] HeH, ChenY, YangC, Yang L, JiangQ, HuangH. Constructing 3D interweaved MXene/graphitic carbon nitride nanosheets/graphene nanoarchitectures for promoted electrocatalytic hydrogen evolution. J Energy Chem. 2022;67:483-491.

[177] ThirumalV, Yuvakkumar R, KumarPS, et al. Heterostructured two dimensional materials of MXene and graphene by hydrothermal method for efficient hydrogen production and HER activities. Int J Hydrogen Energy. 2023;48(17):6478-6487.

[178] NguyenTH, TranPKL, DinhVA, Tran DT, KimNH, LeeJH. Metal single-site molecular complex–MXene heteroelectrocatalysts interspersed graphene nanonetwork for efficient dual-task of water splitting and metal–air batteries. Adv Funct Mater. 2023;33(7):2210101.

[179] HuangC, PiC, ZhangX, et al. Electrocatalysts: in situ synthesis of MoP nanoflakes intercalated N-doped graphene nanobelts from MoO₃–Amine hybrid for high-efficient hydrogen evolution reaction (Small 25/2018). Small. 2018;14(25):1800667.

[180] LiJ-S, WangY, LiuC-H, et al. Coupled molybdenum carbide and reduced graphene oxide electrocatalysts for efficient hydrogen evolution. Nat Commun. 2016;7(1):11204.

[181] XuY, WangR, WangJ, Li J, JiaoT, LiuZ. Facile fabrication of molybdenum compounds (Mo₂C, MoP and MoS₂) nanoclusters supported on N-doped reduced graphene oxide for highly efficient hydrogen evolution reaction over broad pH range. Chem Eng J. 2021;417:129233.

[182] ZhangL, YangH, WanigarathnaDKJA, LiuB. Ultrasmall transition metal carbide nanoparticles encapsulated in N, S-doped graphene for all-pH hydrogen evolution. Small Methods. 2018;2(3):1700353.

[183] HegazyMBZ, BerberMR, YamauchiY, Pakdel A, CaoR, Apfel U-P. Synergistic electrocatalytic hydrogen evolution in Ni/NiS nanoparticles wrapped in multi-heteroatom-doped reduced graphene oxide nanosheets. ACS Appl Mater Interfaces. 2021;13(29):34043-34052.

[184] YuC, ShiY, YanF, et al. Three-dimensional FeP nanotube arrays fabricated through electrostatic-repulsion-limited-nucleation strategy for high-efficiency hydrogen evolution. Chem Eng J. 2021;423:130240.

[185] SunY, XuK, ZhaoZ, Li X, ChenG, LiC. Strongly coupled dual zerovalent nonmetal doped nickel phosphide Nanoparticles/N, B-graphene hybrid for pH-Universal hydrogen evolution catalysis. Appl Catal, B. 2020;278:119284.

[186] ChenZ, WuH, LiJ, et al. Defect enhanced CoP/Reduced graphene oxide electrocatalytic hydrogen production with pt-like activity. Appl Catal, B. 2020;265:118576.

[187] SideriIK, Tagmatarchis N. Noble-metal-free doped carbon nanomaterial electrocatalysts. Chem Eur J. 2020;26(67):15397-15415.

[188] WeiD, LiuY, WangY, Zhang H, HuangL, YuG. Synthesis of N-doped graphene by chemical vapor deposition and its electrical properties. Nano Lett. 2009;9(5):1752-1758.

[189] LiDJ, MaitiUN, LimJ, et al. Molybdenum sulfide/N-doped CNT forest hybrid catalysts for high-performance hydrogen evolution reaction. Nano Lett. 2014;14(3):1228-1233.

[190] ChiK, WuZ, TianX, et al. Boosting hydrogen evolution via integrated construction and synergistic cooperation of confined graphene/CoSe2 active interfaces and 3D graphene nanomesh arrays. Appl Catal, B. 2023;324:122256.

[191] ChenX, ZhuH, ZhuJ, ZhangH. Indium-based bimetallic clusters anchored onto silicon-doped graphene as efficient multifunctional electrocatalysts for ORR, OER, and HER. Chem Eng J. 2023;451:138998.

[192] ZhuY-P, LiuY-P, RenT-Z, Yuan Z-Y. Self-supported cobalt phosphide mesoporous nanorod arrays: a flexible and bifunctional electrode for highly active electrocatalytic water reduction and oxidation. Adv Funct Mater. 2015;25(47):7337-7347.

[193] MaL, HuY, ZhuG, et al. In situ thermal synthesis of inlaid ultrathin MoS₂/graphene nanosheets as electrocatalysts for the hydrogen evolution reaction. Chem Mater. 2016;28(16):5733-5742.

[194] LiY, HeB, LiuX, et al. Graphene confined MoS₂ particles for accelerated electrocatalytic hydrogen evolution. Int J Hydrogen Energy. 2019;44(16):8070-8078.

[195] AdityaT, NayakAK, PradhanD, Pal A, PalT. Fabrication of MoS₂ decorated reduced graphene oxide sheets from solid Mo-precursor for electrocatalytic hydrogen evolution reaction. Electrochim Acta. 2019;313:341-351.

[196] ZhangF, WangL, ParkM, et al. Nickel sulfide nanorods decorated on graphene as advanced hydrogen evolution electrocatalysts in acidic and alkaline media. J Colloid Interface Sci. 2021;608:2633-2640.

[197] DoHH, HaTDC, JoH, et al. Low-temperature synthesis of molybdenum sulfides, tungsten sulfides, and composites thereof as efficient electrocatalysts for hydrogen evolution reaction. Appl Surf Sci. 2022;576:151828.

[198] WangL, GuoT, SunS, et al. Tree-like NiS2/MoS₂-RGO nanocomposites as pH universal electrocatalysts for hydrogen evolution reaction. Catal Lett. 2019;149(5):1197-1210.

[199] LiuG, Thummavichai K, LvX, et al. Nanomaterials. 2021:11. https://www.mdpi.com/search?authors=Thummavichai&jou rnal=nanomaterials&volume=11

[200] AdarakattiPS, Mahanthappa M, HughesJP, et al. MoS₂-graphene-CuNi₂S₄ nanocomposite an efficient electrocatalyst for the hydrogen evolution reaction. Int J Hydrogen Energy. 2019;44(31):16069-16078.

[201] GuoM, QiuF, YuanY, Yu T, YuanC, LuZH. Active site engineering in CoP@NC/graphene heterostructures enabling enhanced hydrogen evolution. Inorg Chem. 2021;60(21):16761-16768.

[202] YuP, WangL, XieY, et al. High-efficient, stable electrocatalytic hydrogen evolution in acid media by amorphous Fe_xP coating Fe₂N supported on reduced graphene oxide. Small. 2018;14(35):1801717.

[203] ZhaoL, HongC, LinL, et al. Controllable nanoscale engineering of vertically aligned MoS₂ ultrathin nanosheets by nitrogen doping of 3D graphene hydrogel for improved electrocatalytic hydrogen evolution. Carbon. 2017;116:223-231.

[204] ZhangD, WangF, FanX, et al. Fabrication of amorphous molybdenum sulfide/nitrogen-doped reduced graphene oxide nanocomposites with a tailored composition and hydrogen evolution activity via plasma treatment. Carbon. 2022;187:386-395.

[205] GuruprasadK, Maiyalagan T, ShanmugamS. Phosphorus doped MoS₂ nanosheet promoted with nitrogen, sulfur dual doped reduced graphene oxide as an effective electrocatalyst for hydrogen evolution reaction. ACS Appl Energy Mater. 2019;2(9):6184-6194.

[206] KumaranY, Maiyalagan T, YiSC. An efficient CoMoS₂ nanosheets on nitrogen, sulfur dual doped reduced graphene oxide as an electrocatalyst for the hydrogen evolution reaction. Int J Energy Res. 2021;45(12):17397-17407.

[207] LuC, TrancaD, ZhangJ, et al. Molybdenum carbide-embedded nitrogen-doped porous carbon nanosheets as electrocatalysts for water splitting in alkaline media. ACS Nano. 2017;11(4):3933-3942.

[208] HuoL, LiuB, GaoZ, ZhangJ. 0D/2D heterojunctions of molybdenum carbide-tungsten carbide quantum dots/Ndoped graphene nanosheets as superior and durable electrocatalysts for hydrogen evolution reaction. J Mater Chem A. 2017;5(35):18494-18501.

[209] DengX-C, ChangH-Q, ZhangG-H. N-doped graphene supported W₂C/WC as efficient electrocatalyst for hydrogen evolution reaction. Int J Hydrogen Energy. 2022;47(2):902-916.

[210] AnjumMAR, LeeJS. Sulfur and nitrogen dual-doped molybdenum phosphide nanocrystallites as an active and stable hydrogen evolution reaction electrocatalyst in acidic and alkaline media. ACS Catal. 2017;7(4):3030-3038.

[211] ZhuangM, OuX, DouY, et al. Polymer-embedded fabrication of Co₂P nanoparticles encapsulated in N,P-doped graphene for hydrogen generation. Nano Lett. 2016;16(7):4691-4698.

[212] LiJ, YanM, ZhouX, et al. Mechanistic insights on ternary Ni_2–xCo_xP for hydrogen evolution and their hybrids with graphene as highly efficient and robust catalysts for overall water splitting. Adv Funct Mater. 2016;26(37):6785-6796.

[213] YanL, JiangH, XingY, et al. Nickel metal–organic framework implanted on graphene and incubated to be ultrasmall nickel phosphide nanocrystals acts as a highly efficient water splitting electrocatalyst. J Mater Chem A. 2018;6(4):1682-1691.

[214] ZhaoX, FanY, WangH, et al. Cobalt phosphide-embedded reduced graphene oxide as a bifunctional catalyst for overall water splitting. ACS Omega. 2020;5(12):6516-6522.

[215] ShaoQ, LiY, CuiX, et al. Metallophthalocyanine-based polymer-derived Co₂P nanoparticles anchoring on doped graphene as high-efficient trifunctional electrocatalyst for Zn-air batteries and water splitting. ACS Sustain Chem Eng. 2020;8(16):6422-6432.

[216] XuX, LiangH, TangG, et al. Accelerating the water splitting kinetics of CoP microcubes anchored on a graphene electrocatalyst by Mn incorporation. Nanoscale Adv. 2019;1:177-183.

[217] ZaiSF, ZhouYT, YangCC, Jiang Q. Al, Fe-codoped CoP nanoparticles anchored on reduced graphene oxide as bifunctional catalysts to enhance overall water splitting. Chem Eng J. 2021;421:127856.

[218] RiyajuddinS, AzmiK, PahujaM, et al. Super-hydrophilic hierarchical Ni-foam-graphene-carbon nanotubes-Ni₂P–CuP₂ nano-architecture as efficient electrocatalyst for overall water splitting. ACS Nano. 2021;15(3):5586-5599.

[219] JiX, LinY, ZengJ, et al. Graphene/MoS₂/FeCoNi(OH)_x and Graphene/MoS₂/FeCoNiPx multilayer-stacked vertical nanosheets on carbon fibers for highly efficient overall water splitting. Nat Commun. 2021;12(1):1380.

[220] SongHJ, YoonH, JuB, LeeG-H, Kim D-W. Catalysts:3D architectures of quaternary Co-Ni-S-P/graphene hybrids as highly active and stable bifunctional electrocatalysts for overall water splitting (Adv. Energy Mater. 33/2018). Adv Energy Mater. 2018;8(33):1802319.

[221] QianY, YuJ, ZhangF, et al. Hierarchical binary metal sulfides nanoflakes decorated on graphene with preciousmetal-like activity for water electrolysis. Chem Eng J. 2023;470:144372.

[222] GuY, ChenS, RenJ, et al. Electronic structure tuning in Ni3FeN/r-GO aerogel toward bifunctional electrocatalyst for overall water splitting. ACS Nano. 2018;12(1):245-253.

[223] BuF, ChenW, Aly AboudMF, Shakir I, GuJ, XuY. Microwave-assisted ultrafast synthesis of adjustable bimetal phosphide/graphene heterostructures from MOFs for efficient electrochemical water splitting. J Mater Chem A. 2019;7(24):14526-14535.

[224] LiH, ChenL, JinP, et al. NiCo₂S₄ microspheres grown on N, S co-doped reduced graphene oxide as an efficient bifunctional electrocatalyst for overall water splitting in alkaline and neutral pH. Nano Res. 2022;15(2):950-958.

[225] RamakrishnanS, Balamurugan J, VinothkannanM, KimAR, Sengodan S, YooDJ. Nitrogen-doped graphene encapsulated FeCoMoS nanoparticles as advanced trifunctional catalyst for water splitting devices and zinc–air batteries. Appl Catal, B. 2020;279:119381.

[226] WangL, FanJ, LiuY, et al. Phase-modulation of iron/nickel phosphides nanocrystals “armored”with porous P-doped carbon and anchored on P-doped graphene nanohybrids for enhanced overall water splitting. Adv Funct Mater. 2021;31(30):2010912.

[227] YangD, HouW, LuY, ZhangW, ChenY. Scalable synthesis of self-assembled bimetallic phosphide/N-doped graphene nanoflakes as an efficient electrocatalyst for overall water splitting. Nanoscale. 2019;11(27):12837-12845.

[228] YangD, SuZ, ChenY, et al. Double-shelled hollow bimetallic phosphide nanospheres anchored on nitrogen-doped graphene for boosting water electrolysis. J Mater Chem A. 2020;8(42):22222-22229.

[229] KuangP, HeM, ZouH, YuJ, FanK. 0D/3D MoS₂-NiS₂/N-doped graphene foam composite for efficient overall water splitting. Appl Catal, B. 2019;254:15-25.

[230] NguyenDC, TranDT, DoanTLL, Kim DH, KimNH, LeeJH. Rational design of Core@shell structured CoS_x@Cu₂MoS₄ hybridized MoS₂/N,S-codoped graphene as advanced electrocatalyst for water splitting and Zn-air battery. Adv Energy Mater. 2020;10(8):1903289.

[231] HuangYQ, ZhouT, AliA, ShenPK. Ni activated Mo₂C nanoparticles supported on stereotaxically-constructed graphene for efficient overall water splitting. Int J Hydrogen Energy. 2022;47(2):761-771.

[232] LiX, WangX, ZhouJ, et al. Ternary hybrids as efficient bifunctional electrocatalysts derived from bimetallic metal–organic-frameworks for overall water splitting. J Mater Chem A. 2018;6(14):5789-5796.

[233] ChenL, JangH, KimMG, Qin Q, LiuX, ChoJ. Fe, Al-co-doped NiSe₂ nanoparticles on reduced graphene oxide as an efficient bifunctional electrocatalyst for overall water splitting. Nanoscale. 2020;12(25):13680-13687.

[234] ArifM, YasinG, ShakeelM, et al. Highly active sites of NiVB nanoparticles dispersed onto graphene nanosheets towards efficient and pH-universal overall water splitting. J Energy Chem. 2021;58:237-246.

[235] ChenZ, XuH, HaY, LiX, LiuM, WuR. Two-dimensional dual carbon-coupled defective nickel quantum dots towards highly efficient overall water splitting. Appl Catal, B. 2019;250:213-223.

[236] XuW, ChangJ, ChengY, et al. A multi-step induced strategy to fabricate core-shell Pt-Ni alloy as symmetric electrocatalysts for overall water splitting. Nano Res. 2022;15(2):965-971.

[237] JoW-K, MoruS, TondaS. Cobalt-coordinated sulfur-doped graphitic carbon nitride on reduced graphene oxide: an efficient metal–(N,S)–C-class bifunctional electrocatalyst for overall water splitting in alkaline media. ACS Sustain Chem Eng. 2019;7(18):15373-15384.

[238] YangJ, GuoD, ZhaoS, et al. Cobalt phosphides nanocrystals encapsulated by P-doped carbon and Married with P-doped graphene for overall water splitting. Small. 2019;15(10):1804546.

[239] XuH, JiaH, FeiB, et al. Charge transfer engineering via multiple heteroatom doping in dual carbon-coupled cobalt phosphides for highly efficient overall water splitting. Appl Catal, B. 2020;268:118404.

[240] LiW, YuB, HuY, et al. Encapsulating hollow (Co,Fe)P nanoframes into N,P-codoped graphene aerogel for highly efficient water splitting. J Power Sources. 2020;456:228015.

[241] WangH, WangX, ZhengB, Yang D, ZhangW, ChenY. Self-assembled Ni₂P/FeP heterostructural nanoparticles embedded in N-doped graphene nanosheets as highly efficient and stable multifunctional electrocatalyst for water splitting. Electrochim Acta. 2019;318:449-459.

[242] YangZ, RenX, GuoK, ShaikF, JiangB. Tuning the composition of tri-metal iron based phosphides integrated on phosphorus-doped vertically aligned graphene arrays for enhanced electrocatalytic activity towards overall water splitting. Int J Hydrogen Energy. 2021;46(72):35559-35570.

[243] ZhouJ, WangZ, YangD, et al. NiSe2-anchored N, S-doped graphene/Ni foam as a free-standing bifunctional electrocatalyst for efficient water splitting. Nanoscale. 2020;12(17):9866-9872.

[244] HuQ, LiuX, ZhuB, et al. Crafting MoC₂-doped bimetallic alloy nanoparticles encapsulated within N-doped graphene as roust bifunctional electrocatalysts for overall water splitting. Nano Energy. 2018;50:212-219.

[245] ZhangL, HuJ-S, HuangX-H, Song J, LuS-Y. Particle-in-box nanostructured materials created via spatially confined pyrolysis as high performance bifunctional catalysts for electrochemical overall water splitting. Nano Energy. 2018;48:489-499.

[246] HeT, PengY, LiQ, et al. Nanocomposites based on ruthenium nanoparticles supported on cobalt and nitrogen-codoped graphene nanosheets as bifunctional catalysts for electrochemical water splitting. ACS Appl Mater Interfaces. 2019;11(50):46912-46919.

[247] YiL, FengB, ChenN, et al. Electronic interaction boosted electrocatalysis of iridium nanoparticles on nitrogen-doped graphene for efficient overall water splitting in acidic and alkaline media. Chem Eng J. 2021;415:129034.

[248] QianG, ChenJ, YuT, LuoL, YinS. N-doped graphenedecorated NiCo alloy coupled with mesoporous NiCoMoO nano-sheet heterojunction for enhanced water electrolysis activity at high current density. Nanomicro Lett. 2021;13(1):77.

[249] IvanovskiiAL. Graphynes and graphdyines. Prog Solid State Chem. 2013;41(1-2):1-19.

[250] ZhaoY, ChaiL, YanX, et al. Characteristics, properties, synthesis and advanced applications of 2D graphdiyne versus graphene. Mat. Chem. Front. 2022;6(5):528-552.

[251] LiB, LaiC, ZhangM, et al. Graphdiyne: a rising star of electrocatalyst support for energy conversion. Adv Energy Mater. 2020;10(16):2000177.

[252] GaoX, LiuH, WangD, Zhang J. Graphdiyne: synthesis, properties, and applications. Chem Soc Rev. 2019;48(3):908-936.

[253] LongM, TangL, WangD, Li Y, ShuaiZ. Electronic structure and carrier mobility in graphdiyne sheet and nanoribbons: theoretical predictions. ACS Nano. 2011;5(4):2593-2600.

[254] ZuoZ, WangD, ZhangJ, Lu F, LiY. Synthesis and applications of graphdiyne-based metal-free catalysts. Adv Mater. 2019;31(13):1803762.

[255] FuX, ZhaoX, LuT-B, Yuan M, WangM. Graphdiyne-based single-atom catalysts with different coordination environments. Angew Chem Int Ed. 2023;62(16):e202219242.

[256] HeJ, MaSY, ZhouP, Zhang CX, HeC, SunLZ. Magnetic properties of single transition-metal atom absorbed graphdiyne and graphyne sheet from DFT+U calculations. J Phys Chem C. 2012;116(50):26313-26321.

[257] HuiL, XueY, YuH, et al. Highly efficient and selective generation of ammonia and hydrogen on a graphdiyne-based catalyst. J Am Chem Soc. 2019;141(27):10677-10683.

[258] HuC, LiuH, LiuY, ChenJ-F, LiY, DaiL. Graphdiyne with tunable activity towards hydrogen evolution reaction. Nano Energy. 2019;63:103874.

[259] YinXP, WangHJ, TangSF, et al. Engineering the coordination environment of single-atom platinum anchored on graphdiyne for optimizing electrocatalytic hydrogen evolution. Angew Chem Int Ed. 2018;57(30):9382-9386.

[260] ChengN, Stambula S, WangD, et al. Platinum single-atom and cluster catalysis of the hydrogen evolution reaction. Nat Commun. 2016;7(1):13638

[261] HeT, MattaSK, WillG, Du A. Transition-metal single atoms anchored on graphdiyne as high-efficiency electrocatalysts for water splitting and oxygen reduction. Small Methods. 2019;3(9):1800419.

[262] XieW, LiuK, ShiG, et al. CoS₂ nanowires supported graphdiyne for highly efficient hydrogen evolution reaction. J Energy Chem. 2021;60:272-278.

[263] ChenLX, JiangM, LuZ, GaoC, ChenZW, Singh CV. Two-dimensional graphdiyne-confined platinum catalyst for hydrogen evolution and oxygen rseduction reactions. ACS Appl Mater Interfaces. 2021;13(40):47541-47548.

[264] YaoY, JinZ, ChenY, et al. Graphdiyne-WS₂ 2D-Nanohybrid electrocatalysts for high-performance hydrogen evolution reaction. Carbon. 2018;129:228-235.

[265] HuiL, XueY, HeF, JiaD, LiY. Ultrathin graphdiyne-wrapped iron carbonate hydroxide nanosheets toward efficient water splitting. Nano Energy. 2019;55(3):135-142. https://doi.org/10.1021/acsami.8b01887

[266] ZhuoS, ShiY, LiuL, et al. Dual-template engineering of triple-layered nanoarray electrode of metal chalcogenides sandwiched with hydrogen-substituted graphdiyne. Nat Commun. 2018;9(1):3132.

[267] GaoY, XueY, LiuT, et al. Bimetallic mixed clusters highly loaded on porous 2D graphdiyne for hydrogen energy conversion. Adv Sci. 2021;8(21):2102777.

[268] YinX-P, LuoS-W, TangS-F, Lu X-L, LuT-B. In situ synthesis of a nickel boron oxide/graphdiyne hybrid for enhanced photo/electrocatalytic H₂ evolution. Chin J Catal. 2021;42(8):1379-1386.

[269] ChenX, ZhangD, ZhengX, et al. Overall water electrolysis on a graphdiyne-iron oxyhydroxide heterostructure. J Mater Chem A. 2023;11(18):9824-9828.

[270] LvY, WuX, LiH, et al. Ultrathin oxygen-containing graphdiyne wrapping CoP for enhanced electrocatalytic hydrogen generation. Nano Res. 2023;16(4):5073-5079.

[271] YuH, HuiL, XueY, et al. 2D graphdiyne loading ruthenium atoms for high efficiency water splitting. Nano Energy. 2020;72:104667.

[272] YuH, XueY, HuiL, et al. Graphdiyne-engineered heterostructures for efficient overall water-splitting. Nano Energy. 2019;64:103928.

[273] HuiL, JiaD, YuH, XueY, LiY. Ultrathin graphdiyne-wrapped iron carbonate hydroxide nanosheets toward efficient water splitting. ACS Appl Mater Interfaces. 2019;11(3):2618-2625.

[274] SiH-Y, DengQ-X, ChenL-C, et al. Hierarchical Graphdiyne@NiFe layered double hydroxide heterostructures as a bifunctional electrocatalyst for overall water splitting. J Alloys Compd. 2019;794:261-267.

[275] YinX-P, LuD, WangJ-W, Lu X-L. 2D/2D heterojunction of Ni–Co–P/graphdiyne for optimized electrocatalytic overall water splitting. ChemCatChem. 2019;11(22):5407-5411.

[276] ZhangC, XueY, HuiL, FangY, LiuY, LiY. Graphdiyne@NiO_x(OH)_y heterostructure for efficient overall water splitting. Mat Chem Front. 2021;5(14):5305-5311.

[277] WeiC, RaoRR, PengJ, et al. Recommended practices and benchmark activity for hydrogen and oxygen electrocatalysis in water splitting and fuel cells. Adv Mater. 2019;31:1806296.

[278] XingZ, GanL, WangJ, Yang X. Experimental and theoretical insights into sustained water splitting with an electrodeposited nanoporous nickel hydroxide@nickel film as an electrocatalyst. J Mater Chem A. 2017;5(17):7744-7748.

[279] WuD, KusadaK, YoshiokaS, et al. Efficient overall water splitting in acid with anisotropic metal nanosheets. Nat Commun. 2021;12(1):1145.

[280] JiaoS, FuX, WangS, Zhao Y. Perfecting electrocatalysts via imperfections: towards the large-scale deployment of water electrolysis technology. Energy Environ Sci. 2021;14(4):1722-1770.

[281] WangYZ, YangM, DingY-M, et al. Sustained release of nitric oxide and cascade generation of reactive nitrogen/oxygen species via an injectable hydrogel for tumor synergistic therapy (Adv. Funct. Mater. 36/2022). Adv Funct Mater. 2022;32(36):2108681.

[282] ZhangJ, YuL, ChenY, Lu XF, GaoS, LouXW. Designed Formation of double-shelled Ni–Fe layered-double-hydroxide nanocages for efficient oxygen evolution reaction. Adv Mater. 2020;32(16):1906432.

[283] TangC, ZhongL, ZhangB, Wang H-F, ZhangQ. 3D mesoporous van der Waals heterostructures for trifunctional energy electrocatalysis. Adv Mater. 2018;30(5):1705110.

[284] SunX, WangS, HouY, LuXF, ZhangJ, Wang X. Self-supporting metal–organic framework-based hydrogen and oxygen electrocatalysts. J Mater Chem A. 2023;11(25):13089-13106.

[285] LiuY, HuangB, HuX, XieZ. Surfactant-assisted hydrothermal synthesis of nitrogen doped Mo₂C@C composites as highly efficient electrocatalysts for hydrogen evolution reaction. Int J Hydrogen Energy. 2019;44(7):3702-3710.

[286] LohJY, YapFM, OngW-J. 2D/2D heterojunction interface: engineering of 1T/2H MoS₂ coupled with Ti₃C₂T_x heterostructured electrocatalysts for pH-universal hydrogen evolution. J Mater Sci Technol. 2023;179:86-97.

[287] YanZ, Mallouk TE. Bipolar membranes for ion management in (photo)electrochemical energy conversion. Acc Mater Res. 2021;2(12):1156-1166.

[288] GnanasekarP, Eswaran MK, PalanichamyG, et al. Sustained solar-powered electrocatalytic H₂ production by seawater splitting using two-dimensional vanadium disulfide. ACS Sustain Chem Eng. 2021;9(25):8572-8580.

[289] LinR, LeiH, RuanD, et al. Solar-powered overall water splitting system combing metal-organic frameworks derived bimetallic nanohybrids based electrocatalysts and one organic solar cell. Nano Energy. 2019;56:82-91.

[290] ThalluriSM, BaiL, LvC, HuangZ, HuX, LiuL. Strategies for semiconductor/electrocatalyst coupling toward solar-driven water splitting. Adv Sci. 2020;7(6):1902102.

[291] AhsanMA, HeT, NoveronJC, Reuter K, Puente-SantiagoAR, LuqueR. Low-dimensional heterostructures for advanced electrocatalysis: an experimental and computational perspective. Chem Soc Rev. 2022;51(3):812-828.

[292] LiuJ, LuoW, WangL, Zhang J, FuX-Z, LuoJ-L. Toward excellence of electrocatalyst design by emerging descriptororiented machine learning. Adv Funct Mater. 2022;32:2110748.

[293] MedfordAJ, KunzMR, EwingSM, Borders T, FushimiR. Extracting knowledge from data through catalysis informatics. ACS Catal. 2018;8:7403-7429.

[294] LeeC-Y, TaylorAC, NattestadA, Beirne S, WallaceGG. 3D printing for electrocatalytic applications. Joule. 2019;3(8):1835-1849.

[295] LingGZS, OhVB-Y, HawCY, Tan L-L, OngW-J. g-C₃ N₄ photocatalysts: utilizing electron–hole pairs for boosted redox capability in water splitting. Energy Mater Adv. 2023;4:0038.

[296] NgS-F, ChenX, FooJJ, Xiong M, OngW-J. 2D carbon nitrides: regulating non-metal boron-doped C₃N₅ for elucidating the mechanism of wide pH range photocatalytic hydrogen evolution reaction. Chin J Catal. 2023;47:150-160.

[297] MoW, TanX-Q, OngW-J. Prospective life cycle assessment bridging biochemical, thermochemical, and electrochemical CO₂ reduction toward sustainable ethanol synthesis. ACS Sustain Chem Eng. 2023;11(14):5782-5799.

[298] WongKJ, FooJJ, SiangTJ, Ong W-J. Transition metal carbidebased photocatalysts for artificial photosynthesis. SmartMat. 2023:e1238.

[299] WongKJ, FooJJ, SiangTJ, Ong W-J. Shining light on carbon aerogel photocatalysts: unlocking the potentials in the quest for revolutionizing solar-to-chemical conversion and environmental remediation. Adv Funct Mater. 2023;33:2306014.

[300] TanX-Q, MoW, LinX, LohJY, MohamedAR, Ong W-J. Retrospective insights into recent MXene-based catalysts for CO₂ electro/photoreduction: how far have we gone? Nanoscale. 2023;15(14):6536-6562.

[301] AiL, NgS-F, OngW-J. Carbon dioxide electroreduction into formic acid and ethylene: a review. Environ Chem Lett. 2022;20(6):3555-3612.

[302] LinX, NgS-F, OngW-J. Coordinating single-atom catalysts on two-dimensional nanomaterials: a paradigm towards bolstered photocatalytic energy conversion. Coord Chem Rev. 2022;471:214743.

[303] TanX-Q, NgS-F, MohamedAR, Ong W-J. Point-to-face contact heterojunctions: interfacial design of 0D nanomaterials on 2D g-C₃N₄ towards photocatalytic energy applications. Carbon Energy. 2022;4(5):665-730.

[304] AiL, NgS-F, OngW-J. Front cover: a prospective life cycle assessment of electrochemical CO₂ reduction to selective formic acid and ethylene (ChemSusChem 19/2022). Chem-SusChem. 2022;15(19):e202200857.

[305] NgS-F, FooJJ, OngW-J. Back cover image. InfoMat. 2022;4(1):e12279.

[306] LinX, FooJJ, OngW-J. Unveiling environmental impacts of methanol production via electrocatalysis against conventional and thermochemical routes by life cycle assessment. Sustain Mater Technol. 2023;37:e00663.

[307] FooJJ, NgS-F, OngW-J. Dimensional heterojunction design: the rising star of 2D bismuth-based nanostructured photocatalysts for solar-to-chemical conversion. Nano Res. 2023;16(4):4310-4364.

[308] SunY-L, HuangJ-H. Improvement of the selectivity for hydrogen peroxide production via the synergy of TiO₂ and graphene. Chin J Struct Chem. 2022;41:2203085-2203091. https://doi.org/10.14102/j.cnki.0254-5861.2011-3299

[309] HouX, JiangT, XuX, et al. Coupling of NiFe-based metalorganic framework nanosheet arrays with embedded Fe-Ni₃S₂ clusters as efficient bifunctional electrocatalysts for overall water splitting. Chin J Struct Chem. 2022;41(7):2207074-2207080. https://doi.org/10.14102/j.cnki.0254-5861.2022-0145

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