Progress in MXene-based catalysts for oxygen evolution reaction

Abstract

Electrochemical water splitting for hydrogen generation is considered one of the most promising strategies for reducing the use of fossil fuels and storing renewable electricity in hydrogen fuel. However, the anodic oxygen evolution process remains a bottleneck due to the remarkably high overpotential of about 300 mV to achieve a current density of 10 mA cm^-2. The key to solving this dilemma is the development of highly efficient catalysts with minimized overpotential, long-term stability, and low cost. As a new 2D material, MXene has emerged as an intriguing material for future energy conversion technology due to its benefits, including superior conductivity, excellent hydrophilic properties, high surface area, versatile chemical composition, and ease of processing, which make it a potential constituent of the oxygen evolution catalyst layer. This review aims to summarize and discuss the recent development of oxygen evolution catalysts using MXene as a component, emphasizing the synthesis and synergistic effect of MXene-based composite catalysts. Based on the discussions summarized in this review, we also provide future research directions regarding electronic interaction, stability, and structural evolution of MXene-based oxygen evolution catalysts. We believe that a broader and deeper research in this area could accelerate the discovery of efficient catalysts for electrochemical oxygen evolution.

Keywords

MXene-based catalysts / oxygen evolution reaction / water splitting

References

[1] LiuM, ZhangR, ChenW. Graphene-supported nanoelectrocatalysts for fuel cells: synthesis, properties, and applications. Chem Rev. 2014;114(10):5117-5160.

[2] ChenC, KangY, HuoZ, et al. Highly crystalline multimetallic nanoframes with three-dimensional electrocatalytic surfaces. Science. 2014;343(6177):1339-1343.

[3] BenderMT, YuanX, ChoiKS. Alcohol oxidation as alternative anode reactions paired with (photo)electrochemical fuel production reactions. Nat Commun. 2020;11(1):4594.

[4] KumarA, DawP, MilsteinD. Homogeneous catalysis for sustainable energy: hydrogen and methanol economies, fuels from biomass, and related topics. Chem Rev. 2022;122(1):385-441.

[5] AntoliniE. Direct propane fuel cells. Fuel. 2022;315:123152.

[6] JiangD, Khivantsev K, WangY. Low-temperature methane oxidation for efficient emission control in natural gas vehicles: Pd and beyond. ACS Catal. 2020;10(23):14304-14314.

[7] ChuehWC, HaoY, JungW, Haile SM. High electrochemical activity of the oxide phase in model ceria-Pt and ceria-Ni composite anodes. Nat Mater. 2011;11(2):155-161.

[8] ZhangJ, YuJ, ZhangY, Li Q, GongJR. Visible light photocatalytic H₂-production activity of CuS/ZnS porous nanosheets based on photoinduced interfacial charge transfer. Nano Lett. 2011;11:4774-4779.

[9] ShiY, ZhangB. Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction. Chem Soc Rev. 2016;45(6):1529-1541.

[10] YangMQ, WangJ, WuH, HoGW. Noble metal-free nanocatalysts with vacancies for electrochemical water splitting. Small. 2018;14(15):e1703323.

[11] YanY, DuJS, GilroyKD, Yang D, XiaY, ZhangH. Intermetallic nanocrystals: syntheses and catalytic applications. Adv Mater. 2017;29(14):1605997.

[12] ChungDY, YooJM, SungYE. Highly durable and active Pt-based nanoscale design for fuel-cell oxygen-reduction electrocatalysts. Adv Mater. 2018;30(42):e1704123.

[13] PengY, LuB, ChenS. Carbon-supported single atom catalysts for electrochemical energy conversion and storage. Adv Mater. 2018;30(48):e1801995.

[14] DincerI, AydinMI. New paradigms in sustainable energy systems with hydrogen. Energy Convers Manag. 2023;283:116950.

[15] WangY, HuangX, WeiZ. Recent developments in the use of single-atom catalysts for water splitting. Chin J Catal. 2021;42(8):1269-1286.

[16] XuW, WangH. Earth-abundant amorphous catalysts for electrolysis of water. Chin J Catal. 2017;38(6):991-1005.

[17] LiQ, Molina Villarino A, PeltierCR, et al. Anion exchange membrane water electrolysis: the future of green hydrogen. J Phys Chem C. 2023;127(17):7901-7912.

[18] WangZ, YaoX, KangY, Miao L, XiaD, GanL. Structurally ordered low-Pt intermetallic electrocatalysts toward durably high oxygen reduction reaction activity. Adv Funct Mater. 2019;29(35):1902987.

[19] WenY, YangT, ChengC, Zhao X, LiuE, YangJ. Engineering Ru (IV) charge density in Ru@RuO₂ core-shell electrocatalyst via tensile strain for efficient oxygen evolution in acidic media. Chin J Catal. 2020;41(8):1161-1167.

[20] HuL, XiaoR, WangX, et al. MXene-induced electronic optimization of metal-organic framework-derived CoFe LDH nanosheet arrays for efficient oxygen evolution. Appl Catal B Environ. 2021;298:120599.

[21] LiuJ, WangJ, ZhangB, et al. Hierarchical NiCo₂S₄@NiFe LDH heterostructures supported on nickel foam for enhanced overall-water-splitting activity. ACS Appl Mater Interfaces. 2017;9(18):15364-15372.

[22] ShindePV, ManeP, ChakrabortyB, RoutCS. Spinel NiFe₂O₄ nanoparticles decorated 2D Ti₃C₂ MXene sheets for efficient water splitting: experiments and theories. J Colloid Interface Sci. 2021;602:232-241.

[23] HuC, ZhangL, ZhaoZJ, Li A, ChangX, GongJ. Synergism of geometric construction and electronic regulation:3D Se-(NiCo)S_x/(OH)_x nanosheets for highly efficient overall water splitting. Adv Mater. 2018;30(12):e1705538.

[24] AiZ, ShaoY, ChangB, et al. Rational modulation of p-n homojunction in P-doped g-C₃N₄ decorated with Ti₃C₂ for photocatalytic overall water splitting. Appl Catal B Environ. 2019;259:118077.

[25] ShangX, QinJF, LinJH, et al. Tuning the morphology and Fe/Ni ratio of a bimetallic Fe-Ni-S film supported on nickel foam for optimized electrolytic water splitting. J Colloid Interface Sci. 2018;523:121-132.

[26] LiB, LaiC, ZhangM, et al. A rising star of electrocatalyst support for energy conversion. Adv Energy Mater. 2020;10(16):2000177.

[27] TanC, CaoX, WuXJ, et al. Recent advances in ultrathin twodimensional nanomaterials. Chem Rev. 2017;117(9):6225-6331.

[28] QiaoJ, KongL, XuS, et al. Research progress of MXene-based catalysts for electrochemical water-splitting and metal-air batteries. Energy Storage Mater. 2021;43:509-530.

[29] KongW, DengJ, LiL. Recent advances in noble metal MXenebased catalysts for electrocatalysis. J Mater Chem A. 2022;10(28):14674-14691.

[30] GrimaudA, HongWT, Shao-HornY, Tarascon JM. Anionic redox processes for electrochemical devices. Nat Mater. 2016;15(2):121-126.

[31] GrimaudA, Diaz-Morales O, HanB, et al. Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution. Nat Chem. 2017;9(5):457-465.

[32] LinC, LiJ-L, LiX, et al. In-situ reconstructed Ru atom array on α-MnO₂ with enhanced performance for acidic water oxidation. Nat Catal. 2021;4(12):1012-1023.

[33] CraigMJ, Coulter G, DolanE, et al. Universal scaling relations for the rational design of molecular water oxidation catalysts with near-zero overpotential. Nat Commun. 2019;10(1):4993.

[34] WangX, ZhongH, XiS, LeeWSV, XueJ. Understanding of oxygen redox in the oxygen evolution reaction. Adv Mater. 2022;34(50):2107956.

[35] WangN, OuP, MiaoRK, et al. Doping shortens the metal/metal distance and promotes OH coverage in nonnoble acidic oxygen evolution reaction catalysts. J Am Chem Soc. 2023;145(14):7829-7836.

[36] Wohlfahrt-MehrensM, Heitbaum J. Oxygen evolution on Ru andRuO₂ electrodes studied using isotope labelling and on-line mass spectrometry. J ElectroanalChem Interfacial Electrochem. 1987;237(2):251-260.

[37] HuangZ-F, SongJ, DuY, et al. Chemical and structural origin of lattice oxygen oxidation in Co-Zn oxyhydroxide oxygen evolution electrocatalysts. Nat Energy. 2019;4:329-338.

[38] NiJ, ShiZ, WangY, et al. Suppressing the lattice oxygen diffusion via high-entropy oxide construction towards stabilized acidic water oxidation. Nano Res. 2023:1-17. https://doi.org/10.1007/s12274-023-5913-6

[39] SurendranathY, KananMW, NoceraDG. Mechanistic studies of the oxygen evolution reaction by a cobalt-phosphate catalyst at neutral pH. J Am Chem Soc. 2010;132(46):16501-16509.

[40] ZhuW, YaoF, ChengK, et al. Direct dioxygen radical coupling driven by octahedral ruthenium–oxygen–cobalt collaborative coordination for acidic oxygen evolution reaction. J Am Chem Soc. 2023;145(32):17995-18006.

[41] NaguibM, Kurtoglu M, PresserV, et al. Two-dimensional nanocrystals produced by exfoliation of Ti₃AlC₂. Adv Mater. 2011;23(37):4248-4253.

[42] LiuA, LiangX, RenX, et al. Recent progress in MXene-based materials: potential high-performance electrocatalysts. Adv Funct Mater. 2020;30(38):2003437.

[43] AkuzumB, Maleski K, AnasoriB, et al. Rheological characteristics of 2D titanium carbide (MXene) dispersions: a guide for processing MXenes. ACS Nano. 2018;12(3):2685-2694.

[44] AlhabebM, Maleski K, AnasoriB, et al. Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti₃C₂T_x MXene). Chem Mater. 2017;29(18):7633-7644.

[45] VahidMohammadiA, RosenJ, GogotsiY. The world of two-dimensional carbides and nitrides (MXenes). Science. 2021;372(6547):372.

[46] MathisTS, Maleski K, GoadA, et al. Modified MAX phase synthesis for environmentally stable and highly conductive Ti₃C₂ MXene. ACS Nano. 2021;15(4):6420-6429.

[47] LiY, ShaoH, LinZ, et al. A general Lewis acidic etching route for preparing MXenes with enhanced electrochemical performance in non-aqueous electrolyte. Nat Mater. 2020;19(8):894-899.

[48] ShuckCE, Sarycheva A, AnayeeM, et al. Scalable synthesis of Ti₃C₂T_x MXene. Adv Eng Mater. 2020;22(3):1901241.

[49] ZhangS, YingH, YuanB, Hu R, HanWQ. Partial atomic tin nanocomplex pillared few-layered Ti₃C₂T_x MXenes for superior lithium-ion storage. Nanomicro Lett. 2020;12(1):78.

[50] LiT, YaoL, LiuQ, et al. Fluorine-free synthesis of high-purity Ti₃C₂T_x (T=OH, O) via alkali treatment. Angew Chem Int Ed. 2018;57(21):6115-6119.

[51] YangS, ZhangP, WangF, et al. Fluoride-free synthesis of twodimensional titanium carbide (MXene) using a binary aqueous system. Angew Chem Int Ed. 2018;57(47):15491-15495.

[52] PangSY, WongYT, YuanS, et al. Universal strategy for HF-free facile and rapid synthesis of two-dimensional MXenes as multifunctional energy materials. JAmChem Soc. 2019;141(24):9610-9616.

[53] YangX, ZhangX, LuZ, YangZ, WuR. Design of highly stable and efficient bifunctional MXene-based electrocatalysts for oxygen reduction and evolution reactions. Phys Rev Appl. 2021;15(4):044053.

[54] LiuW, JiJ, YanX, et al. A cascade surface immobilization strategy to access high-density and closely distanced atomic Pt sites for enhancing alkaline hydrogen evolution reaction. J Mater Chem A. 2020;8(10):5255-5262.

[55] ZhouKL, WangC, WangZ, et al. Seamlessly conductive Co (OH)₂ tailored atomically dispersed Pt electrocatalyst with a hierarchical nanostructure for an efficient hydrogen evolution reaction. Energy Environ Sci. 2020;13(9):3082-3092.

[56] WuH, FengC, ZhangL, Zhang J, WilkinsonDP. Non-noble metal electrocatalysts for the hydrogen evolution reaction in water electrolysis. Electrochem Energy Rev. 2021;4(3):473-507.

[57] GuoF, ZouZ, ZhangZ, et al. Confined sub-nanometer PtCo clusters as a highly efficient and robust electrocatalyst for the hydrogen evolution reaction. J Mater Chem A. 2021;9:5468-5474.

[58] LeTA, TranNQ, HongY, Kim M, LeeH. Porosity-engineering of MXene as a support material for a highly efficient electrocatalyst toward overall water splitting. ChemSusChem. 2020;13(5):945-955.

[59] KanD, WangD, ZhangX, et al. Rational design of bifunctional ORR/OER catalysts based on Pt/Pd-doped Nb₂CT₂ MXene by first-principles calculations. J Mater Chem A. 2020;8(6):3097-3108.

[60] LiJ, HouC, ChenC, et al. Collaborative interface optimization strategy guided ultrafine RuCo and MXene heterostructure electrocatalysts for efficient overall water splitting. ACS Nano. 2023;17(11):10947-10957.

[61] LuY, FanD, ChenZ, Xiao W, CaoC, YangX. Anchoring Co₃O₄ nanoparticles on MXene for efficient electrocatalytic oxygen evolution. Sci Bull. 2020;65(6):460-466.

[62] TyndallD, GannonL, HughesL, et al. Understanding the effect of MXene in a TMO/MXene hybrid catalyst for the oxygen evolution reaction. npj 2D Mater Appl. 2023;7(1):15.

[63] ParkCE, Senthil RA, JeongGH, ChoiMY. Architecting the high-entropy oxides on 2D MXene nanosheets by rapid microwave-heating strategy with robust photoelectrochemical oxygen evolution performance. Small. 2023;19(27):2207820.

[64] GanC, ZhangY, LiuZ, et al. Integrated Co₄MnFe₃/Ti₃C₂: componential and structural engineering toward boosting electrocatalytic oxygen evolution. J Phys Chem C. 2021;125(29):15872-15881.

[65] TianM, JiangY, TongH, Xu Y, XiaL. Mxene-supported FeCo-LDHs as highly efficient catalysts for enhanced electrocatalytic oxygen evolution reaction. ChemNanoMat. 2019;6(1):154-159.

[66] YuM, WangZ, LiuJ, SunF, YangP, Qiu J. A hierarchically porous and hydrophilic 3D nickel–iron/MXene electrode for accelerating oxygen and hydrogen evolution at high current densities. Nano Energy. 2019;63:103880.

[67] ChenY, YaoH, KongF, et al. V₂C MXene synergistically coupling FeNi LDH nanosheets for boosting oxygen evolution reaction. Appl Catal B Environ. 2021;297:120474.

[68] YanL, ZhangB, WuS, YuJ. A general approach to the synthesis of transition metal phosphide nanoarrays on MXene nanosheets for pH-universal hydrogen evolution and alkaline overall water splitting. J Mater Chem A. 2020;8(28):14234-14242.

[69] LiN, HanJ, YaoK, et al. Synergistic phosphorized NiFeCo and MXene interaction inspired the formation of high-valence metal sites for efficient oxygen evolution. J Mater Sci Technol. 2022;106:90-97.

[70] XieY, YuH, DengL, et al. Anchoring stable FeS₂ nanoparticles on MXene nanosheets via interface engineering for efficient water splitting. Inorg Chem Front. 2022;9(4):662-669.

[71] HanS, ChenY, HaoY, et al. Multi-dimensional hierarchical CoS₂@MXene as trifunctional electrocatalysts for zinc-air batteries and overall water splitting. Sci China Mater. 2020;64(5):1127-1138.

[72] LiY, DuQ-X, CuiJ, ChenX, YangH-W, Qian H. Identifying the intrinsic active site in bimetallic Co₃S₄/Ni₃S₂ feathers on MXene nanosheets as a heterostructure for efficient oxygen evolution reaction. Inorg Chem Front. 2023;10(10):184-191.

[73] ZouH, HeB, KuangP, Yu J, FanK. Metal–organic framework-derived nickel–cobalt sulfide on ultrathin MXene nanosheets for electrocatalytic oxygen evolution. ACS Appl Mater Interfaces. 2018;10(26):22311-22319.

[74] YanL, LiangJ, LiH. In situ construction of heterostructure NiSe-NiO nanoarrays with rich oxygen vacancy on MXene for efficient oxygen evolution. Int J Hydrogen Energy. 2023;48(35):13159-13169.

[75] PangX, WuT, GuY, et al. Nb₂Se₂C: a new compound as a combination of transition metal dichalcogenide and MXene for oxygen evolution reaction. Chem Commun. 2020;56(63):9036-9039.

[76] ZhangJ, ZhaoY, GuoX, et al. Single platinum atoms immobilized on an MXene as an efficient catalyst for the hydrogen evolution reaction. Nat Catal. 2018;1(12):985-992.

[77] ZhaoQ, ZhangC, HuR, et al. Selective etching quaternary MAX phase toward single atom copper immobilized MXene (Ti₃C₂Cl_x) for efficient CO₂ electroreduction to methanol. ACS Nano. 2021;15(3):4927-4936.

[78] TalibSH, LuZ, BashirB, et al. COoxidation on MXene (Mo₂CS₂) supported single-atom catalyst: a termolecular Eley-Rideal mechanism. Chin Chem Lett. 2023;34(2):107412.

[79] ZhaiX, DongH, LiY, et al. Termination effects of single-atom decorated V-Mo₂CT_x MXene for the electrochemical nitrogen reduction reaction. J Colloid Interface Sci. 2022;605:897-905.

[80] ZhaoX, ZhengX, LuQ, et al. Electrocatalytic enhancement mechanism of cobalt single atoms anchored on different MXene substrates in oxygen and hydrogen evolution reactions. EcoMat. 2022;5(2):e12293.

[81] WangE, GuoM, ZhouJ, Sun Z. Reasonable design of MXene-supported dual-atom catalysts with high catalytic activity for hydrogen evolution and oxygen evolution reaction: a first-principles investigation. Materials. 2023;16(4):1457.

[82] ChenY, CuiH, JiangQ, et al. M-N₄-Gr/MXene heterojunction nanosheets as oxygen reduction and evolution reaction catalysts: machine learning and density functional theory insights. ACS Appl Nano Mater. 2023;6(9):7694-7703.

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